Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “F”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Conceptual Design for a Dual-Bell Rocket Nozzle System Using a NASA F-15 Airplane as the Flight Testbed

The dual-bell rocket nozzle was first proposed in 1949, offering a potential improvement in rocket nozzle performance over the conventional-bell nozzle. Despite the performance advantages that have been predicted, both analytically and through static test data, the dual-bell nozzle has still not been adequately tested in a relevant flight environment. In 2013 a proposal was constructed that offered a NASA F-15 airplane as the flight testbed, with the plan to operate a dual-bell rocket nozzle during captive-carried flight. If implemented, this capability will permit nozzle operation into an external flow field similar to that of a launch vehicle, and facilitate an improved understanding of dual-bell nozzle plume sensitivity to external flow-field effects. More importantly, this flight testbed can be utilized to help quantify the performance benefit with the dual-bell nozzle, as well as to advance its technology readiness level. Toward this ultimate goal, this paper provides plans for future flights to quantify the external flow field of the airplane near the nozzle experiment, as well as details on the conceptual design for the dual-bell nozzle cold-flow propellant feed system integration within the NASA F-15 Propulsion Flight Test Fixture. The current study shows that this concept of flight research is feasible, and could result in valuable flight data for the dual-bell nozzle.

nozzle↗
NASA NTRS2014

Conceptual Design for a Dual-Bell Rocket Nozzle System Using a NASA F-15 Airplane as the Flight Testbed

The dual-bell rocket nozzle was first proposed in 1949, offering a potential improvement in rocket nozzle performance over the conventional-bell nozzle. Despite the performance advantages that have been predicted, both analytically and through static test data, the dual-bell nozzle has still not been adequately tested in a relevant flight environment. In 2013 a proposal was constructed that offered a NASA F-15 airplane as the flight testbed, with the plan to operate a dual-bell rocket nozzle during captive-carried flight. If implemented, this capability will permit nozzle operation into an external flow field similar to that of a launch vehicle, and facilitate an improved understanding of dual-bell nozzle plume sensitivity to external flow-field effects. More importantly, this flight testbed can be utilized to help quantify the performance benefit with the dual-bell nozzle, as well as to advance its technology readiness level. This presentation provides highlights of a technical paper that outlines this ultimate goal, including plans for future flights to quantify the external flow field of the airplane near the nozzle experiment, as well as details on the conceptual design for the dual-bell nozzle cold-flow propellant feed system integration within the NASA F-15 Propulsion Flight Test Fixture. The current study shows that this concept of flight research is feasible, and could result in valuable flight data for the dual-bell nozzle.

flight-research↗
NASA NTRS2014

Conceptual Design for a Dual-Bell Rocket Nozzle System Using a NASA F-15 Airplane as the Flight Testbed

The dual-bell rocket nozzle was first proposed in 1949, offering a potential improvement in rocket nozzle performance over the conventional-bell nozzle. Despite the performance advantages that have been predicted, both analytically and through static test data, the dual-bell nozzle has still not been adequately tested in a relevant flight environment. In 2013 a proposal was constructed that offered a National Aeronautics and Space Administration (NASA) F-15 airplane as the flight testbed, with the plan to operate a dual-bell rocket nozzle during captive-carried flight. If implemented, this capability will permit nozzle operation into an external flow field similar to that of a launch vehicle, and facilitate an improved understanding of dual-bell nozzle plume sensitivity to external flow-field effects. More importantly, this flight testbed can be utilized to help quantify the performance benefit with the dual-bell nozzle, as well as to advance its technology readiness level. Toward this ultimate goal, this report provides plans for future flights to quantify the external flow field of the airplane near the nozzle experiment, as well as details on the conceptual design for the dual-bell nozzle cold-flow propellant feed system integration within the NASA F-15 Propulsion Flight Test Fixture. The current study shows that this concept of flight research is feasible, and could result in valuable flight data for the dual-bell nozzle.

nozzle↗
NASA NTRS2019

Near-Sun Observations of an F-Corona Decrease and K-Corona Fine Structures

Remote observations of the solar photospheric light scattered by electrons (K-corona) and dust (F-corona/Zodiacal light) have been made from the ground during eclipses and from space at 1 AU and as close as 0.3 AU. Previous observations of dust scattering have not confirmed the existence of a theoretically-predicted dust free zone near the Sun. The transient nature of the corona has been well characterized for large events, but questions still remain (e.g. initiation, production of solar energetic particles) and for small events even the structure is uncertain. Here we report on imaging the solar corona, from the Parker Solar Probe spacecraft, during the first two perihelion passes (0.16-0.25 AU), each of ten days duration. The view from these distances is qualitatively similar to the historical view, but there are some significant differences in the details. We have uncovered at short elongations a decrease in the intensity of the F-coronal intensity, which is suggestive of the long-sought dust free zone. Also we have resolved the plasma structure of very small eruptions, which are being frequently ejected from the Sun. They take two forms - the commonly observed magnetic flux ropes or the predicted, but not yet observed, magnetic islands arising from the tearing mode instability in the current sheet. Our observations of the coronal streamer evolution confirm the large-scale topology of the solar corona, but they also reveal that, as recently predicted, streamers are composed of yet smaller sub-streamers channeling continual density fluctuations at all visible scales.

Astronomy and astrophysics↗
NASA NTRS2024

The Plasma Proton Environment within Saturn’s F-G Ring Gap as Observed by the Cassini Plasma Spectrometer Ion Mass Spectrometer during Saturn Orbit Insertion

We report on the detection of protons and the potential detection of H 2 + between Saturn's F and G rings based on Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) time-of-flight (TOF) composition measurements acquired during Saturn Orbit Insertion (SOI) outbound pass. The range in dipole L shell is 2.3 < L < 2.8. Initial results based on TOF data were presented in E. C. Sittler et al., 2017. Here we present the latest results of our analysis. During the SOI outbound pass between the F and G rings the CAPS IMS was in a mode of reduced post-acceleration voltage at -6 kV instead of the usual -14.6 kV. This reduced voltage still allows the analysis of protons since 6 keV protons are minimally scattered by the instrument’s ultrathin carbon foils when compared to heavier ions O + and O 2 + , scattering. Background noise from penetrating radiation and ghost peaks produced by foil-scattered O + ions within the instrument were considered in our analysis. The analysis allowed determination of the proton density, temperature and flow velocity, accounting for spacecraft potential by assuming a convected Maxwellian for the proton velocity distribution function. We find average proton density n P = 3.2 ± 1.1 #/cm 3 , proton temperature T P = 1.74 ± 0.12 eV, proton rotational flow speed V P = 24 ± 1.5 km/s and spacecraft potential  SC = -0.8 ±1.5 V. These results are compared with previous theoretical estimates of H + and H 2 + ions within Saturn’s inner magnetosphere.

E C Sittler↗
DOE OSTI2022

Impact of f-element complexation on the radiolytic robustness of separations ligands

Impact of f-element complexation on the radiolytic robustness of separations ligands Gregory P. Horne, Makayla R. Baxter, Corey D. Pilgrim, Travis S. Grimes, Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID, 83415, USA Cristian Celis Barros, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA. E-mail: ccelisbarros@fsu.edu Andrew R. Cook, Department of Chemistry, Brookhaven National Laboratory, Upton, New York, 11973, USA Stephen P. Mezyk, Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Boulevard, Long Beach, California, 90840-9507, USA The effects of ionizing radiation are ubiquitous throughout all aspects of a nuclear fuel cycle. However, the complexity and intensity of these effects are greatest during the management of used nuclear fuel, owing to the presence of a wide spectrum of radionuclides from neutron capture and fission processes. With regards to used nuclear fuel (UNF) reprocessing, radiation-induced processes typically promote the destruction of active compounds (e.g., complexants and additives) with the concomitant formation of potentially detrimental degradation products and corresponding changes in physical and chemical properties, which ultimately impact the effectiveness and longevity of a given reprocessing system. Concerning UNF complexants, radiation chemistry studies have historically focused on their radiation robustness in the absence of the metal ions they were designed to selectively complex. This knowledge gap is worrisome as previous studies on aqueous phase complexants have demonstrated significant changes in radiolytic behavior upon metal ion complexation.1-4 More recently, the rate of reaction of the n-dodecane radical cation—believed to be the major organic phase radiation-induced transient species responsible for complexant radiolysis in n-dodecane based solvent systems—with hexa-n-octylnitrilo-triacetamide (HONTA) was shown to increase by an order-of-magnitude upon complexation of europium or americium.5 These findings have significant implications on the projected longevity of complexants in UNF reprocessing solvent systems. Consequently, a thorough understanding of metal ion complexation effects on the radiolytic integrity of UNF complexants is essential to evaluate their potential for process application. Presented here are two recent studies from the Idaho National Laboratory Center for Radiation Chemistry Research group that demonstrate the various impacts of f-element complexation (uranium, americium, and lanthanides) on the radiolytic integrity (gamma and electron pulse) of tributyl phosphate (TBP), N,N-di-(2-ethylhexyl)butyramide (DEHBA), N,N-di-2-ethylhexylisobutryamide (DEHiBA), and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) under UNF reprocessing conditions. References 1) Bhattacharyya and Kundu, Int. J. Radiat. Phys. Chem., 1971, 3, 1. 2) Kundu and Matuura, Int. J. Radiat. Phys. Chem., 1975, 7, 565. 3) Ilan and Czapski, Biochimica et Biophysica Acta, 1977, 498, 386. 4) Buettner, Doherty, and Patterson, Fed. Euro. Biochem. Soc., 1983, 158 (1), 143. 5) Toigawa, Peterman, Meeker, Grimes, Zalupski, Mezyk, Cook, Yamashita, Kumagai, Matsumura, Horne, PCCP, 2021, 23, 1343.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2025

Study of D s + → f 0 ( 980 ) ρ + and ϕ π + Decays through D s + → π + π + π − π 0

We perform the first amplitude analysis of D s + → π + π + π − π 0 decays based on data samples of electron-positron collisions recorded with the BESIII detector at center-of-mass energies between 4.128 and 4.226 GeV, corresponding to an integrated luminosity of 7.33 fb − 1 . We report the observation of D s + → f 0 ( 980 ) ρ ( 770 ) + with a statistical significance greater than 10 σ and determine the branching fractions B ( D s + → π + π + π − π 0 | non − η ) = ( 2.04 ± 0.0 8 stat ± 0.0 5 syst ) % and B ( D s + → η π + ) = ( 1.56 ± 0.0 9 stat ± 0.0 4 syst ) % . Moreover, we measure the relative branching fraction between ϕ → π + π − π 0 and ϕ → K + K − to be [ B ( ϕ ( 1020 ) → π + π − π 0 ) / B ( ϕ ( 1020 ) → K + K − ) ] = 0.230 ± 0.01 4 stat ± 0.01 0 syst ., which deviates from the world average value by more than 4 σ . Published by the American Physical Society 2025

Ablikim, M.↗
DOE OSTI2020

Synthesis, Electronic Properties and Reactivity of [B 12 X 11 (NO 2 )] 2– (X=F–I) Dianions

Nitro-functionalized undecahalogenated closo-dodecaborates [B 12 X 11 (NO 2 )] 2– were synthesized in high purities and characterized by NMR, IR, and Raman spectroscopy, single crystal X-diffraction, mass spectrometry, and gas-phase ion vibrational spectroscopy. The NO 2 substituent leads to an enhanced electronic and electrochemical stability compared to the parent perhalogenated [B 12 X 12 ] 2– (X=F–I) dianions evidenced by photoelectron spectroscopy, cyclic voltammetry, and quantum-chemical calculations. The stabilizing effect decreases from X=F to X=I. Thermogravimetric measurements of the salts indicate the loss of the nitric oxide radical (NO . ). The homolytic NO . elimination from the dianion under very soft collisional excitation in gas-phase ion experiments results in the formation of the radical [B 12 X 11 O] 2–. . Theoretical investigations suggest that the loss of NO . proceeds via the rearrangement product [B 12 X 11 (ONO)] 2– . The O-bonded nitrosooxy structure is thermodynamically more stable than the N-bonded nitro structure and its formation by radical recombination of [B 12 X 11 O] 2–. and NO . is demonstrated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Pressure-induced cation and vacancy disorder-order transition and near-zero τ f in deficient hexagonal perovskite Ba 8 ZnTa 6 O 24 dielectrics

Pressure applications can enable the tuning of atomic/defect ordering and provide access to new functional materials. Here, in this study, we report that pressure-induced structural transformation featuring disorder-order transition of both cations and vacancies in the 8-layer deficient hexagonal perovskite tantalate dielectrics Ba 8 ZnTa 6 O 24 , which transformed the structure from twin to shift and remarkably lowered the temperature coefficient of resonant frequency τ f down to near zero (∼0.56 ppm/°C) from 38 ppm/°C for the twinned precursor. The atomic scale STEM-HAADF and EDS results confirm the ordering of Zn in the Ta host at the nanometer scale in the shifted material featuring well-ordered Ba 8 ZnTa 6 O 24 slabs intergrown with Ba 3 ZnTa 2 O 9 and Ba 5 Ta 4 O 15 monolayers and anti-phase grain boundaries as planar defects. The pressure-induced twin-shift structural transformation of Ba 8 ZnTa 6 O 24 features the rare constant concentration of the hexagonal stacked layers, which is allowed by the vacancy ordering at the central layers of face-shared octahedral (FSO) trimers avoiding the FSO B-B repulsion, and remarkably the faster cationic ordering kinetics compared with the 2:1 ordered complex perovskites. Although the inclusion of numerous planar defects and the oxidizable atomic defects led to significant p-type conduction and inhomogeneous electrical microstructures, resulting in an extraordinarily high extrinsic dielectric loss for the high-pressure shifted Ba 8 ZnTa 6 O 24 pellet, the intrinsically near-zero τ f could make the shifted Ba 8 ZnTa 6 O 24 perovskite an ideal microwave dielectric resonator candidate if the defects could be eliminated.

high pressure↗
DOE OSTI2022

Synthesis of Eu(HCOO) 3 and $\mathrm{Eu(HCOO)_3}$ • $\mathrm{(HCONH_2)_2}$ crystals and observation of their 5 D 0 → 7 F 0 transition for quantum information systems

Two stoichiometric metal-organic frameworks containing Eu 3+ cations are probed as candidates for photon-based quantum information storage. Synthesis procedures for growing 0.2 mm, rod-shaped Eu(HCOO) 3 and 1–3 mm, rhombohedral $\mathrm{Eu(HCOO)_3}$ • $\mathrm{(HCONH_2)_2}$ single crystals are presented with visible precipitation as soon as 1 h into heating for Eu(HCOO) 3 and 24 h for $\mathrm{Eu(HCOO)_3}$ • $\mathrm{(HCONH_2)_2}$. Room temperature and 1.4 K photoluminescence measurements of the 5 D 0 → 7 F J transitions of Eu 3+ are analyzed for both compounds. Comparisons of peak width and intensity are discussed along with the notable first report for both of the 5 D 0 → 7 F 0 transition, the hyperfine structure of which has potential use in quantum memory applications. Furthermore, the air instability of $\mathrm{Eu(HCOO)_3}$ • $\mathrm{(HCONH_2)_2}$ and the transformation of its photoluminescence properties are discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Influence of weave architecture on mechanical response of SiC f -SiC m tubular composites

Due to their high resistance to radiation damage and elevated temperature, silicon carbide fiber-reinforced, silicon carbide matrix composites (SiC f -SiC m ) are identified as potential cladding structures for use in nuclear reactors. In this study, four composite architectures with varying ply numbers along the thickness direction and different biaxial or triaxial plain weave orientations at either 45° or 60°, were systematically evaluated under various stress states to assess the influence of weave architecture on mechanical performance. Experiments were conducted on SiC f -SiC m composite tubes under tensile hoop, axial compression, and rotating flexural loading to evaluate the mechanical response and investigate the failure modes using high-speed imaging and digital image correlation (DIC) techniques. It was found that for tensile hoop burst and flexural loading, the braiding angle had the most significant influence on the strength of the composite, whereas the effect of fiber angle was more limited for compression testing. Under axial compression a unique failure mode where a microcrack nucleates and grows only to a length equal to the thickness of a single yarn was identified. This crack growth behavior is reflected as periodic oscillations in the load-displacement response. For both axial and hoop loading, regardless of weave angle and number of plies, failure always initiated parallel to the tube axis in a single yarn and the cumulative interaction of these microcracks lead to either axial burst or fracture at an angle to the tube axis along a yarn. Furthermore, these results point to the importance of customizing the design of tube architecture for enhanced performance in specified nuclear applications.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Enhancing f -Element Separations with ADAAM-EH: The Impact of Phase Modifiers and a DGA Aqueous Complexant

Recent investigations have used a 2-ethylhexyl diamide amine (ADAAM-EH) for Am/Cm separations in combination with N,N,N ',N '-tetraethyldiglycolamide as an aqueous complexant to achieve an unprecedented separation factor of 41. The aim of this research effort is to understand the speciation of trivalent lanthanide (Ln) and actinide (An) ions in the organic phase of an ADAAM-EH extraction system, both with and without phase modifiers (PM) (1-octanol and tri-n-butyl phosphate (TBP)). Leveraging spectroscopic techniques in combination with distribution ratio measurements provides an understanding of organic phase f-element ligand complexation. In the absence of PM, Ln is extracted in a stoichiometric 1:1 [M(ADAAM-EH) 1 (NO 3 ) x (H 2 O) 1 ](NO 3 ) 3-x complex. The addition of 1-octanol at 20 vol % results in multiple species present. One of the species is the same as the no PM case, and the other species results in an increased -OH coordination to the inner sphere, potentially displacing some NO 3 . In the case of TBP, increasing concentration results in additional red-shifted bands in the UV-visible spectra, suggesting the complexation of additional ligands of either ADAAM-EH or TBP. Finally, the new system knowledge obtained by and spectroscopic experiments will provide benchmarking information for computational studies of the inner- and outer-sphere coordination environments of f-element cations and insights into ADAAM-EH adduct formation with PM, like 1-octanol and TBP.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Hydrolysis of Metal Dioxides Differentiates d-block from f-block Elements: Pa(V) as a 6d Transition Metal; Pr(V) as a 4f “Lanthanyl”

Gas-phase reactions of pentavalent metal dioxide cations M V O 2 + with water were studied experimentally for M = V, Nb, Ta, Pr, Pa, U, Pu, and Am. Addition of two H 2 O can occur by adsorption to yield hydrate (H 2 O) 2 M V O 2 + or by hydrolysis to yield hydroxide M V (OH) 4 + . Displacement of H 2 O by acetone indicates hydrates for Pr V , U V , Pu V , and Am V , whereas nondisplacement indicates hydroxides for Nb V , Ta V , and Pa V . Computed potential energy profiles agree with the experimental results and furthermore indicate that acetone unexpectedly induces dehydrolysis and displaces two H 2 O from (H 2 O)VO(OH) 2 + to yield (acetone) 2 VO 2 + . Structures and energies for several M V , as well as for Th IV and U VI , indicate that hydrolysis is governed by the involvement of valence f versus d orbitals in bonding: linear f-element dioxides are more resistant to hydrolysis than bent d-element dioxides. Accordingly, for early actinides, hydrolysis of Th IV is characteristic of a 6d-block transition metal; hydration of U V and U VI is characteristic of 5f actinyls; and Pa V is intermediate between 6d and 5f. The praseodymium oxide cation Pr V O 2 + is assigned as an actinyl-like lanthanyl with properties governed by 4f bonding.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Synthesis and Properties of the Helium Clathrate and Defect Perovskite [He 2– x $^\square$ x ][CaNb]F 6

The defect double perovskite [He 2– x $^\square$ x ][CaNb]F 6 , with helium on its A-site, can be prepared by the insertion of helium into ReO 3 -type CaNbF 6 at high pressure. Upon cooling from 300 to 100 K under 0.4 GPa helium, ~60% of the A-sites become occupied. Helium uptake was quantified by both neutron powder diffraction and gas insertion and release measurements. After the conversion of gauge pressure to fugacity, the uptake of helium by CaNbF 6 can be described by a Langmuir isotherm. The enthalpy of absorption for helium in [He 2– x $^\square$ x ][CaNb]F 6 is estimated to be ~+3(1) kJ mol –1 , implying that its formation is entropically favored. Helium is able to diffuse through the material on a time scale of minutes at temperatures down to ~150 K but is trapped at 100 K and below. The insertion of helium into CaNbF 6 reduces the magnitude of its negative thermal expansion, increases the bulk modulus, and modifies its phase behavior. On compressing pristine CaNbF 6 , at 50 and 100 K, a cubic (Fm$\overline{3}$m) to rhombohedral (R$\overline{3}$) phase transition was observed at <0.20 GPa. However, a helium-containing sample remained cubic at 0.4 GPa and 50 K. CaNbF 6 , compressed in helium at room temperature, remained cubic to >3.7 GPa, the limit of our X-ray diffraction measurements, in contrast to prior reports that upon compression in a nonpenetrating medium, a phase transition is detected at ~0.4 GPa.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

P-Type Doping of Mixed Tin–Lead Halide Perovskites Using Electron Transfer to Mo(tfd-COCF3) 3 and F 4 TCNQ

Mixed tin-lead halide perovskites are emerging as promising candidates to address the toxicity issues of lead-based perovskites and to provide additional bandgap tunability for optoelectronic applications. Electron-transfer doping offers a prospective pathway to modulate electronic properties of metal-halide perovskites, while not disturbing the underlying crystal structure. However, limited research exists comparing molecular dopants for these systems. Here, our study investigates the p-type electron-transfer doping of the mixed tin-lead halide perovskite MAPb 0.5 Sn 0.5 I 3 (MA = methylammonium) using a sequential deposition approach (perovskite film followed by dopant incorporation) and the molecular dopants F 4 TCNQ and Mo(tfd-COCF 3 ) 3 . Up to 3 orders of magnitude higher carrier density and up to 2 orders of magnitude greater conductivity are achieved relative to the undoped samples, with F 4 TCNQ and Mo(tfd-COCF 3 ) 3 demonstrating similar doping efficiencies (associated with the ratio of mobile charges added to the number of dopant molecules incorporated) of 0.031(3) % and 0.024(3) %, respectively. Differences in the doping effectiveness for a given molarity doping solution likely follow from variations in dopant incorporation within the film during the spin coating deposition step.

14 SOLAR ENERGY↗
DOE OSTI2022

An Energetic Diagnostic of Tropical Cyclone Size in f –Plane Simulations

As a major feature of tropical cyclones (TCs), controlling factors of TC outer size or size scaling remains a fundamental scientific question. The Rossby deformation radius and a natural extent associated with potential intensity have been proposed as two scalings of TC size. But neither of them satisfactorily captures the sensitivity of TC size to sea surface temperature (SST) in idealized f-plane simulations. Inspired by the studies of the Hadley circulation, here we proposed a new TC scaling based on an energetic diagnostic scaling. TC size is primarily a ratio of the secondary circulation strength to subsidence velocity, further determined by the total atmospheric heating in the ascending area, the gross moist stability, the diabatic cooling, and the dry static stability. The former two is based on the moist energetic budget applied to the whole storm structure, while the latter two is based on the dry thermodynamic budget applied to the subsidence areas. The new scaling well captured the sensitivity of TC size to SST in idealized f-plane simulations, partly resulted from expanded ascending area, increased surface moisture deficit, and weakened subsidence with increased SST.

58 GEOSCIENCES↗
DOE OSTI2026

Optimizing HAARP Beam Pattern for Generation of Strong F‐Region Field‐Aligned Irregularities

Field-aligned irregularities (FAIs) are the signatures of plasma turbulence and convection in the mid- and high-latitude F-region ionosphere, and also provide coherent backscatter targets for HF radars. To serve irregularity generation and characterization studies, we conducted experiments at the High-frequency Active Auroral Research Program (HAARP) in August 2023 with the goal of identifying the optimal HAARP beam pattern for reliable generation of intense FAIs over a large geographic region. The HAARP beam patterns we tested were the commonly-used narrow beam, also known as L0, as well as the wider L1 and L2 “twisted” beam patterns. The size and intensity of the FAI region generated by each HAARP beam pattern was quantified using the Kodiak Island Super Dual Auroral Radar Network (SuperDARN) radar. Stimulated electromagnetic emissions (SEE) from heater wave-FAI scattering were also recorded using a receiver located near HAARP. The L1 beam pattern was found to produce the strongest SuperDARN backscatter over the largest region. Although the heater frequency was intended to be tuned a few hundred kHz below the F-region critical frequency (foF2) during each experiment, difficulty in estimating foF2 during the campaign likely resulted in HAARP heating at significantly different frequency ranges around foF2 during each experiment. Although this additional free parameter complicated data analysis for this study, the SuperDARN and SEE measurements have led to further inquiry into the role heater frequency plays in the artificial generation of FAIs.

58 GEOSCIENCES↗
DOE OSTI2025

Resonant inelastic X-ray scattering tools to count 5 $f$ electrons of actinides and probe bond covalency

The actinides possess a complex electronic structure, making their chemical and physical properties among the least understood in the periodic table. Advanced spectroscopic tools, able to obtain deep insights into the electronic structure and binding properties of the actinides, are highly desirable. Here, we introduce two sensitive spectroscopic tools: one determines the number of localized 5f electrons on an actinide atom, and another assesses the covalent character of actinide-ligand bonding. Both tools are based on the multiplet structure present in actinide M 4 edge core-to-core resonant inelastic X-ray scattering (CC-RIXS) maps. The spectral intensity of different many-body final-state multiplets directly depends on the local many-electron ground-state symmetry including the local 5 f spin configuration. By comparing U M 4 edge CC-RIXS data for 21 U, Np, Pu and Am compounds, we demonstrate the ability to compare the number of localized 5 f electrons and bond covalency across the actinide series.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗