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At least 487 records · Page 27

Experimental Insights into the Coupling of Methane Combustion and Steam Reforming in a Catalytic Plate Reactor in Transient Mode

The microstructured reactor concept is very promising technology to develop a compact reformer for distributed hydrogen generation. In this work, a catalytic plate reactor (CPR) is developed and investigated for the coupling of methane combustion (MC) and methane steam reforming (MSR) over Pt/Al 2 O 3 -coated microchannels in cocurrent and counter-current modes in transient experiments during start-up. A three-dimensional (3D) computational fluid dynamics (CFD) simulation shows uniform velocity and pressure distribution profiles in microchannels. For a channel velocity from 5.1 to 57.3 m/s in the combustor, the oxidation of methane is complete and self-sustainable without explosion, blow-off, or extinction; nevertheless, flashbacks are observed in counter-current mode. In the reformer, the maximum methane conversion is 84.9% in cocurrent mode, slightly higher than that of 80.2% in counter-current mode at a residence time of 33 ms, but at the cost of three times higher energy input in the combustor operating at ~1000 °C. Nitric oxide (NO) is not identified in combustion products, but nitrous oxide (N 2 O) is a function of coupling mode and forms significantly in cocurrent mode. Furthermore, this research would be helpful to establish the start-up strategy and environmental impact of compact reformers on a small scale.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Iron - Whence it came, where it went

Determinations of the abundances of iron and related elements in the photosphere, chromosphere, and corona of the sun as well as in solar and galactic cosmic rays are reviewed and compared with abundances derived from meteoritic data. Observed solar system abundances are found to be in accord with predictions of nucleosynthesis under either hydrostatic or explosive conditions but cannot yet be used to define these processes uniquely. The distribution of iron among planets and meteorites can probably be adequately modelled by condensation and fragmentation under equilibrium conditions above about 700 K, but below that temperature it is likely that inhibited solid-state diffusion perturbed attainment of equilibrium. Pertinent factors which are presently unknown include the mechanism responsible for metal-silicate fractionation, the grain size achieved by metallic iron in the nebula, and whether iron-bearing silicate formed prior to accretion.

Kerridge, J. F.↗

The primitive solar accretion disk and the formation of the planets

The author develops the idea that the formation of the solar system was triggered by the explosion of a supernova near a compressed interstellar cloud, which was further compressed by the supernova ejecta until it went over the threshold for gravitational collapse. During the collapse it is expected that the cloud would fragment into much smaller pieces. The principle source of friction in the collapsing nebula is taken to be turbulent viscosity, the required stirring having been supplied possibly by meridional circulation currents. The theory can be shown to account for how a great deal of condensed matter in the form of cometary bodies could be put into elliptical orbits extending toward 100,000 AU, the region of the Oort reservoir.

Cameron, A. G. W.↗

How Massive Single Stars End Their Life

How massive stars die-what sort of explosion and remnant each produces-depends chiefly on the masses of their helium cores and hydrogen envelopes at death. For single stars, stellar winds are the only means of mass loss, and these are a function of the metallicity of the star. We discuss how metallicity, and a simplified prescription for its effect on mass loss, affects the evolution and final fate of massive stars. We map, as a function of mass and metallicity, where black holes and neutron stars are likely to form and where different types of supernovae are produced. Integrating over an initial mass function, we derive the relative populations as a function of metallicity. Provided that single stars rotate rapidly enough at death, we speculate on stellar populations that might produce gamma-ray bursts and jet-driven supernovae.

Heger, A.↗

Hydrodynamical instabilities and mixing in SN 1987A - Two-dimensional simulations of the first 3 months

Results are presented from numerical simulations of the early stages of the explosion of SN 1987A. Using a two-dimensional cylindrical geometry version of a smooth particle hydrodynamics code, the explosion is followed for three months to investigate both the early hydrodynamical instabilities and the effect of the subsequent radioactive decay of Ni-56 and Co-56 with half-lives of 6.1 and 77.8 days, respectively. It is shown that the mixing induced by hydrodynamical instabilities occurring during the first few hours is substantially modified at later time by the radioactive decay of Ni-56 and Co-56. The inner cavity of the expanding supernova remnant fills up with nickel, its decay products thus forming a giant 'nickel bubble'. The peak velocity of the nickel increases by approximately 30 percent after the decays. While these results adequately model the core of the observed Fe line profiles, they fail to reproduce the high velocity wings of the spectra.

Herant, Marc↗

A Scaling Analysis of Post-Detonation Mixing With Detailed Chemical Kinetics

This report documents a scaling study of hemispherical pentaerythritol tetranitrate explosives detonated in ambient air. The focus is on the mixing layer and evolution of the chemical species. The HyBurn code developed at the University of Florida is used to simulate center initiated 12, 38, 120, and 1200 mm diameter charges. The results show blast structures commonly found in the literature. Azimuthal averaging is used to radially average the flow variables to get mean values. The charges exhibit self-similar behavior at early times in a primarily gas dynamic regime, but discrepancies between the scales form at later times due to the finite rate chemistry. The turbulent mixing layer is calculated and used to define a region to conditionally average by mixture fraction. The results of the conditional averages imply a transition from a kinetic-limited regime to a mixing-limited regime with increasing scale. The scaling of the total heat release rate confirms an early time gas dynamic regime, and a later time regime where mixing and chemistry becomes impactful.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cosmic Background Explorer (COBE): Emergency support

The Cosmic Background Explorer (COBE) Mission will measure the diffuse radiation from the universe in the wavelength band 1 micron to 9.6 mm. The band includes the 3 K cosmic background radiation, the known relic of the primeval cosmic explosion. The COBE satellite will be launched from the Western Space and Missile Center (EWSMC) via a Delta launch vehicle into a circular parking orbit of about 300 km. COBE will be placed into a 900-km altitude circular orbit. Coverage will be provided by the Deep Space Network (DSN) for COBE emergencies that would prevent communications via the normal channels of the Tracking and Data Relay Satellite System (TDRSS). Emergency support will be provided by the DSN 26-m subnetwork. Information is given in tabular form for DSN network support, frequency assignments, telemetry, and command.

Stanford, R.↗

How Did the Universe Make People? A Brief History of the Universe from the Beginning to the End

Astronomers are beginning to know the easy part: How did the Big Bang make stars and galaxies and the chemical elements? How did solar systems form and evolve? How did the Earth and the Moon form, and how did water and carbon come to the Earth? Geologists are piecing together the history of the Earth, and biologists are coming to know the history and process of life from the earliest times. But is our planet the only life-supporting place in the universe, or are there many? Astronomers are working on that too. I will tell the story of the discovery of the Big Bang by Edwin Hubble, and how the primordial heat radiation tells the details of that universal explosion. I will tell how the James Webb Space Telescope will extend the discoveries of the Hubble Space Telescope to ever greater distances, will look inside dust clouds to see stars being born today, will measure planets around other stars, and examine the dwarf planets in the outer Solar System. I will show concepts for great new space telescopes to follow the JWST and how they could use future moon rockets to hunt for signs of life on planets around other stars.

Mather, John C.↗

Volcanism in Elysium Planitia, Mars

Geomorphic mapping revealed that the three volcanic constructs within Elysium Planitia (Hecates Tholus, elysium Mons and Albor Tholus) are very different in their overall morphology and represent three distinct types of martian volcano. Hecates Tholus was found to possess the most likely possible example of a young, explosively generated, air fall deposit, while the volume of magma erupted from Elysium Mons appears to have been orders of magnitude larger than that erupted from Albor Tholus. A primary aim of the regional geological analysis of Elysium Planitia is to further understand the volcanic and tectonic evolution of the area by the identification and interpretation of individual lava flows and their source vents. Lava flow size, spatial distribution, flow direction and the stratigraphic relationships of these lava flows to adjacent structural features were all measured. The topographic form of Elysium Mons has totally controlled the flow direction of lava flows within Elysium Planitia. Lava flows from Elysium Mons can be traced for distances of 150 to 250 km in a radial direction from the volcano. Parasitic vents located beyond the recognizable volcanic construct also conform to this radial pattern. A second unusual characteristic of the Elysium Planitia region is the high frequency of occurrence of sinuous channels that are morphologically similar to lunar sinuous rilles.

Mouginis-Mark, P. J.↗

Far-infrared spectrophotometry of SN 1987A - Days 265 and 267

The paper presents 16-66-micron spectra of SN 1987A taken on days 266 and 268 after core collapse. The spectrum consists of a nearly flat continuum, strong emission lines of hydrogen, and fine-structure lines of Fe II, Fe III, Co II, S I, and possibly Fe I, Ni II, and S III. From the relative strength of three lines which arise from transitions within the ground and excited states of Fe II, the temperature and a lower limit on the density of the line-emitting region are derived. From the line strengths, the abundances of Fe and S I, the end products of explosive nucleosynthesis in the supernova are estimated. An upper limit is also set to the amount of Co II remaining in the mantle. The low measured mass of Fe suggests that the ejecta are clumpy. The flat continuum is most likely free-free emission from the expanding supernova ejecta. About 35 percent of this emission arises from the ionized metals in the mantle; the rest arises from ionized hydrogen. At the time of these observations, there is no evidence for any emission from dust that may have formed in the supernova ejecta or from preexisting dust in the surrounding medium.

Moseley, S. H.↗

Current sheet formation in a sheared force-free-magnetic field

This paper presents the results of a study showing how continuous shearing motion of magnetic footpoints in a tenuous, infinitely conducting plasma can lead to the development of current sheets, despite the absence of such sheets or even of neutral points in the initial state. The calculations discussed here verify the earlier suggestion by Low and Wolfson (1988) that extended current sheets should form due to the shearing of a force-free quadrupolar magnetic field. More generally, this work augments earlier studies suggesting that the appearance of discontinuities - current sheets - may be a necessary consequence of the topological invariance imposed on the magnetic field geometry of an ideal MHD system by virtue of its infinite conductivity. In the context of solar physics, the work shows how the gradual and continuous motion of magnetic footpoints at the solar photosphere may lead to the buildup of magnetic energy that can then be released explosively when finite conductivity effects become important and lead to the rapid dissipation of current sheets. Such energy release may be important in solar flares, coronal mass ejections, and other eruptive events.

Wolfson, Richard↗

On Iron Enrichment, Star Formation, and Type Ia Supernovae in Galaxy Clusters

The nature of star formation and Type Ia supernovae (SNIa) in galaxies in the field and in rich galaxy clusters are contrasted by juxtaposing the buildup of heavy metals in the universe inferred from observed star formation and supernovae rate histories with data on the evolution of Fe abundances in the intracluster medium (ICM). Models for the chemical evolution of Fe in these environments are constructed, subject to observational constraints, for this purpose. While models with a mean delay for SNIa of 3 Gyr and standard initial mass function (IMF) are fully consistent with observations in the field, cluster Fe enrichment immediately tracked a rapid, top-heavy phase of star formation - although transport of Fe into the ICM may have been more prolonged and star formation likely continued beyond redshift 1. The means of this prompt enrichment consisted of SNII yielding greater than or equal to 0.1 solar mass per explosion (if the SNIa rate normalization is scaled down from its value in the field according to the relative number of candidate progenitor stars in the 3 - 8 solar mass range) and/or SNIa with short delay times originating during the rapid star formation epoch. Star formation is greater than 3 times more efficient in rich clusters than in the field, mitigating the overcooling problem in numerical cluster simulations. Both the fraction of baryons cycled through stars, and the fraction of the total present-day stellar mass in the form of stellar remnants, are substantially greater in clusters than in the field.

Loewenstein, Michael↗

A diagnosis of the explosive development of two extratropical cyclones

This paper examines the 24-h explosive development periods of two extratropical cyclones, the first occurring over the Gulf Stream off the coast of New England from 18 to 19 January 1979 and the second occurring over the southeastern United States from 20 to 21 January 1979. The data used in this study are the First GARP (Global Atmospheric Research Program) Global Experiment (FGGE) level IIIb (SOP I) global analyses on a 4 deg latitude x 5 deg longitude grid. The parameter used to diagnose development is the geostrophic relative vorticity tendency calculated using an extended form of the Zwack-Okossi development equation. This development equation is similar to the Petterssen-Sutcliffe development equation, but is shown to be more complete by explicitly coupling surface development with forcing at all levels above the surface. Cyclonic-vorticity advection, warm-air advection, and latent heat release act to develop the two cyclones, while adiabatic cooling in the ascending air opposes development. Further, vertical profiles of the development quantities for these two cases reveal that vorticity and temperature advection maximize in the 200-300-mb layer, while the latent heat release maximum is typically below 500 mb.

Lupo, Anthony R.↗

Learning Physically Interpretable Atmospheric Models From Data With WSINDy

The multiscale and turbulent nature of Earth's atmosphere has historically rendered accurate weather modeling a hard problem. Recently, there has been an explosion of interest surrounding data-driven approaches to weather modeling, which in many cases show improved forecasting accuracy and computational efficiency when compared to traditional methods. However, many of the current data-driven approaches employ highly parameterized neural networks, often resulting in uninterpretable models and limited gains in scientific understanding. In this work, we address the interpretability problem by explicitly discovering partial differential equations governing atmospheric phenomena, identifying symbolic mathematical models with direct physical interpretations. The purpose of this paper is to demonstrate that, in particular, the weak-form sparse identification of nonlinear dynamics (WSINDy) algorithm can learn effective atmospheric models from both simulated and assimilated data. Our approach adapts the standard WSINDy algorithm to work with high-dimensional fluid data of arbitrary spatial dimension.

58 GEOSCIENCES↗

High pressure suppression of plasticity due to an overabundance of shear embryo formation

Abstract High pressure shear band formation is a critical phenomenon in energetic materials due to its influence on both mechanical strength and mechanochemical activation. While shear banding is known to occur in a variety of these materials, the governing dynamics of the mechanisms are not well defined for molecular crystals. We conduct molecular dynamics simulations of shock wave induced shear band formation in the energetic material 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) to assess shear band nucleation processes. We find, that at high pressures, the initial formation sites for shear bands, “embryos”, form in excess and rapidly lower deviatoric stresses prior to shear band formation and growth. This results in the suppression of plastic deformation. A local cluster analysis is used to quantify and contrast this mechanism with a more typical shear banding seen at lower pressures. These results demonstrate a mechanism that is reversible in nature and that supersedes shear band formation at increased pressures. We anticipate that these results will have a broad impact on the modeling and development of high-strain rate application materials such as those for high explosives and hypersonic systems.

36 MATERIALS SCIENCE↗

A JWST Survey of the Supernova Remnant Cassiopeia A

We present initial results from a James Webb Space Telescope (JWST) survey of the youngest Galactic core-collapse supernova remnant, Cassiopeia A (Cas A), made up of NIRCam and MIRI imaging mosaics that map emission from the main shell, interior, and surrounding circumstellar/interstellar material (CSM/ISM). We also present four exploratory positions of MIRI Medium Resolution Spectrograph integral field unit spectroscopy that sample ejecta, CSM, and associated dust from representative shocked and unshocked regions. Surprising discoveries include (1) a weblike network of unshocked ejecta filaments resolved to ~0.01 pc scales exhibiting an overall morphology consistent with turbulent mixing of cool, low-entropy matter from the progenitor's oxygen layer with hot, high-entropy matter heated by neutrino interactions and radioactivity; (2) a thick sheet of dust-dominated emission from shocked CSM seen in projection toward the remnant's interior pockmarked with small (~1'') round holes formed by ≲0$^"_•$1 knots of high-velocity ejecta that have pierced through the CSM and driven expanding tangential shocks; and (3) dozens of light echoes with angular sizes between ~0$^"_•$1 and 1' reflecting previously unseen fine-scale structure in the ISM. NIRCam observations place new upper limits on infrared emission (≲20 nJy at 3 μm) from the neutron star in Cas A's center and tightly constrain scenarios involving a possible fallback disk. These JWST survey data and initial findings help address unresolved questions about massive star explosions that have broad implications for the formation and evolution of stellar populations, the metal and dust enrichment of galaxies, and the origin of compact remnant objects.

79 ASTRONOMY AND ASTROPHYSICS↗

The Radiative Magneto-Hydrodynamics of Colliding Flow: Instabilities, Reconnection and Exoplanet Atmosphere Connections

Hypersonic flows of magnetized plasmas naturally produce strong shocks when obstructions or self‐interactions (flow collisions) occur. Such complex flows occur in a wide variety of HEDP settings such as Z‐pinches and laser driven implosion experiments that include magnetic fields via explosive Helmholtz coils (MIFEDS) When thermal energy behind the shocks can be lost to optically thin radiation, the flow dynamics becomes even more complex, admitting a range of new instabilities such as the Nonlinear Thin Shell Instability (NTSI). Because of their inherent non‐ linearity, multi‐dimensionality and time‐dependence (i.e. turbulence), the ability to articulate the underlying physics of colliding hypersonic magnetized flows represents a significant frontier in HEDP studies. The addition of radiative cooling to these flows propels the study even further into the domain of extreme plasma physics. Exploration of these forms of HED plasmas is of interest to basic plasma physics as well as of interest for their application to Inertial Confinement Fusion.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Supervolcanoes Within an Ancient Volcanic Province in Arabia Terra, Mars

Several irregularly shaped craters located within Arabia Terra, Mars represent a new type of highland volcanic construct and together constitute a previously unrecognized martian igneous province. Similar to terrestrial supervolcanoes, these low-relief paterae display a range of geomorphic features related to structural collapse, effusive volcanism, and explosive eruptions. Extruded lavas contributed to the formation of enigmatic highland ridged plains in Arabia Terra. Outgassed sulfur and erupted fine-grained pyroclastics from these calderas likely fed the formation of altered, layered sedimentary rocks and fretted terrain found throughout the equatorial region. Discovery of a new type of volcanic construct in the Arabia volcanic province fundamentally changes the picture of ancient volcanism and climate evolution on Mars. Other eroded topographic basins in the ancient Martian highlands that have been dismissed as degraded impact craters should be reconsidered as possible volcanic constructs formed in an early phase of widespread, disseminated magmatism on Mars.

Mars↗