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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

High-Precision Measurement of Eu/Eu* in Geological Glasses via LA-ICP-MS Analysis

Elemental fractionation during laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis has been historically documented between refractory and volatile elements. In this work, however, we observed fractionation between light rare earth elements (LREEs) and heavy rare earth elements (HREEs) when using ablation strategies involving large spot sizes (greater than 100 millimeters) and line scanning mode. In addition: (1) ion yields decrease when using spot sizes above 100 millimeters; (2) (Eu/Eu*)(sub raw) (i.e. Europium anomaly) positively correlates with carrier gas (He) flow rate, which provides control over the particle size distribution of the aerosol reaching the ICP; (3) (Eu/Eu*)(sub raw) shows a positive correlation with spot size, and (4) the changes in REE signal intensity, induced by the He flow rate change, roughly correlate with REE condensation temperatures. The REE fractionation is likely driven by the slight but significant difference in their condensation temperatures. Large particles may not be completely dissociated in the ICP and result in preferential evaporation of the less refractory LREEs and thus non-stoichiometric particle-ion conversion. This mechanism may also be responsible for Sm-Eu-Gd fractionation as Eu is less refractory than Sm and Gd. The extent of fractionation depends upon the particle size distribution of the aerosol, which in turn is influenced by the laser parameters and matrix. Ablation pits and lines defined by low aspect ratios produce a higher proportion of large particles than high aspect ratio ablation, as confirmed by measurements of particle size distribution in the laser induced aerosol. Therefore, low aspect ratio ablation introduces particles that cannot be decomposed and/or atomized by the ICP and thus results in exacerbated elemental fractionation. Accurate quantification of REE concentrations and Eu/Eu* requires reduction of large particle production during laser ablation. For the reference materials analyzed in this work, the 100 millimeters spot measurements of Eu/Eu* agreed with GeoRem preferred values within 3 percent. Our long-term analyses of Eu/Eu* in MPI-DING glass KL-2G and USGS glass BIR-1G were reproducible at 3 percent (2 RSD).

geological glasses↗
NASA NTRS2004

History of Thermally Processed Solids in the Protoplanetary Disk: Reconciling Theoretical Models and Meteoritical Evidence

In this talk we assess theoretical models of the radial, temporal, and thermal evolution of nebula solids, and their ultimate accretion into planetesimals such as we see today, using meteorite evidence as a guide. Each class of chondrites contains a characteristic suite of chondrules and CAIs that may have formed over a period of several Myr during which planetesimals were accreting in the disk. Details of the various models for transient melting of chondrules and igneous CAIs will be left to others. However, high-temperature processes of different kinds evaporation, alteration, etc did affect these constituents and their environment over this time span. Here we describe evolutionary scenarios consistent with a large time gap between CAI and chondrule formation and the presence of distinctive suites of chondrules and CAIs in each chondrite class. Particle-gas dynamical processes transport particles of all relevant sizes (microns to many meters) within the nebula and affect their evolution in a variety of important ways. Turbulent radial diffusion spreads particles radially down their concentration gradients - as one example, it can prevent CAIs from being lost into the sun on several Myr timescales [1]. Vertical diffusion spreads the dense midplane particle layer, determining its volume density, which in turn affects the particle growth rate and even the dominant growth process [2-4]. Turbulent concentration selects aerodynamically sorted particles for orders-of-magnitude density enhancement, and is applicable to porous, fluffy particles of appropriate size as well as to solid chondrules [5]. Inward radial drift under gas drag brings a surprisingly large amount of material to regions where it evaporates; these evaporation fronts cause significant chemical modification of the nebula gas over a wide range of radii [6]. Radial transport by stellar winds can be important for small particles [7].

Cuzzi, J. N.↗
NASA NTRS2000

The Northeast Monsoon's Impact on Mixing, Phytoplankton Biomass and Nutrient Cycling in the Arabian Sea

In the northern Arabian Sea, atmospheric conditions during the Northeast (winter) Monsoon lead to deep convective mixing. Due to the proximity of the permanent pyncnocline to the sea surface, this mixing does not penetrate below 125 m. However, a strong nitracline is also present and the deep convection results in significant nitrate flux into the surface waters. This leads to nitrate concentrations over the upper 100 m that exceed 4 micrometers toward the end of the Monsoon. During the 1994/1995 US JGOFS/Arabian Sea expedition, the mean areal gross primary production over two successive Northeast Monsoons was determined to be 1.35gC/sq m/d. Thus, despite the deep penetrative convection, high rates of primary productivity were maintained. An interdisciplinary model was developed to elucidate the biogeochemical processes involved in supporting the elevated productivity. This model consists of a 1-D mixed-layer model coupled to a set of equations that tracked phytoplankton growth and the concentration of the two major nutrients (nitrate and ammonium). Zooplankton grazing was parameterized by rate constant determined by shipboard experiments. Model boundary conditions consist of meteorological time-series measured from the surface buoy that was part of the ONR Arabian Sea Experiment's central mooring. Our numerical experiments show that elevated surface evaporation, and the associated salinization of the mixed layer, strongly contributes to the frequency and penetration depth of the observed convective mixing. Cooler surface temperatures, increased nitrate entrainment, reduced water column stratification, and lower near-surface chlorophyll a concentrations all result from this enhanced mixing. The model also captured a dependence on regenerated nitrogen observed in nutrient uptake experiments performed during the Northeast Monsoon. Our numerical experiments also indicate that variability in mean pycnocline depth causes up to a 25% reduction in areal chlorophyll a concentration. We hypothesize that such shifts in pycnocline depth may contribute to the interannual variations in primary production and surface chlorophyll a concentration that have been previously observed in this region.

Wiggert, J. D.↗
NASA NTRS2013

Effect of Residual Noncondensables on Pressurization and Pressure Control of a Zero-Boil-Off Tank in Microgravity

The Zero-Boil-Off Tank (ZBOT) Experiment is a small-scale experiment that uses a transparent ventless Dewar and a transparent simulant phase-change fluid to study sealed tank pressurization and pressure control with applications to on-surface and in-orbit storage of propellant cryogens. The experiment will be carried out under microgravity conditions aboard the International Space Station in the 2014 timeframe. This paper presents preliminary results from ZBOT's ground-based research that focuses on the effects of residual noncondensable gases in the ullage on both pressurization and pressure reduction trends in the sealed Dewar. Tank pressurization is accomplished through heating of the test cell wall in the wetted and un-wetted regions simultaneously or separately. Pressure control is established through mixing and destratification of the bulk liquid using a temperature controlled forced jet flow with different degrees of liquid jet subcooling. A Two-Dimensional axisymmetric two-phase CFD model for tank pressurization and pressure control is also presented. Numerical prediction of the model are compared to experimental 1g results to both validate the model and also indicate the effect of the noncondensable gas on evolution of pressure and temperature distributions in the ullage during pressurization and pressure control. Microgravity simulations case studies are also performed using the validated model to underscore and delineate the profound effect of the noncondensables on condensation rates and interfacial temperature distributions with serious implications for tank pressure control in reduced gravity.

Marangoni and Natural Convection↗
NASA NTRS1981

Ultraviolet emission of the Vela supernova remnant and the Cygnus Loop

Ultraviolet emission spectra of several filaments in the Vela supernova remnant and the Cygnus Loop are compared with theoretical models of radiative shocks. Shock velocities range from 85 to 130 km/s. Little or no grain depletion is apparent. Several of the observed filaments deviate from the steady-flow models in the sense that much of the photoionization-recombination zone is absent. It is shown that resonance line scattering within the emitting region can account for the weakness of the C II 1335 and C IV 1550 lines. Evaporation fronts, which are basic to the McKee and Ostriker picture of supernova remnant evolution, do not contribute significantly to the observed emission. Some discrepancies in UV emission predicted by different sets of shock models are traced to differing atomic rates used in the calculations. A fluorescent emission line of H2 may be observable in some supernova remnants.

Raymond, J. C.↗
NASA NTRS1997

Timescales of Land Surface Evapotranspiration Response

Soil and vegetation exert strong control over the evapotranspiration rate, which couples the land surface water and energy balances. A method is presented to quantify the timescale of this surface control using daily general circulation model (GCM) simulation values of evapotranspiration and precipitation. By equating the time history of evaporation efficiency (ratio of actual to potential evapotranspiration) to the convolution of precipitation and a unit kernel (temporal weighting function), response functions are generated that can be used to characterize the timescales of evapotranspiration response for the land surface model (LSM) component of GCMS. The technique is applied to the output of two multiyear simulations of a GCM, one using a Surface-Vegetation-Atmosphere-Transfer (SVAT) scheme and the other a Bucket LSM. The derived response functions show that the Bucket LSM's response is significantly slower than that of the SVAT across the globe. The analysis also shows how the timescales of interception reservoir evaporation, bare soil evaporation, and vegetation transpiration differ within the SVAT LSM.

Scott, Russell↗
NASA NTRSDate not supplied

Meteorite Ablation at the HYMETS ARC-JET Facility

One of the primary goals of the Asteroid Threat Assessment Program (ATAP) is to understand the ablation phenomena of meteors (e.g., spallation, evaporation, melt flow, etc.). Therefore, a test campaign was executed at the Hypersonic Material Test System (HYMETS) facility on samples of an ordinary chondrite (e.g., Tamdakht) and samples of basalt from the Columbia plateau. High melt viscosities and low ablation rates are predicted for basalt due to higher concentrations of silica and alumina in the matrix phase. However, high-speed video and post-test analysis reveal that basalt experiences greater rates of ablation than Tamdakht. Post-test analysis of emission spectra reveals the presence of volatile species that may explain the discrepancy between model predictions and observed phenomena.

Meteor↗
NASA NTRSDate not supplied

Progress in Simulated Water Well Performance on Mars

Recent studies of human Mars missions considered the impacts of an abundant supply of in-situ, accessible water on these mission scenarios. Discovery of exposed water ice scarps in Martian mid-latitudes has bolstered the evidence for massive amounts of almost pure water in buried deposits in regions considered candidates for these future human missions. This paper describes progress towards adapting a long-standing terrestrial technique for accessing and extracting water from these mid-latitude sources of ice. This approach relies on mechanical drills to access the ice through overlying debris. Once the ice layer has been reached, a technique known as a Rodriguez Well, or Rodwell, is used to melt the ice, store the resulting water in a subsurface cavity until needed, and then pump the water to the surface for use. Previous work by the authors utilized a computer simulation to predict the performance of a Martian Rodwell. This simulation was originally developed to predict performance in terrestrial Polar Regions. Whereas the basic approach is appropriate for a similar well on Mars, several parameters had been empirically derived and required experiments simulating the Martian environment to determine the values appropriate for a Martian Rodwell simulation. These experiments have now been completed and preliminary values have been determined for the empirical parameters. Test results are consistent with a dimensionless Sh(Ra) correlation developed by Bower and Saylor (2009) and based on lab tests of water evaporating from a pool into a large air chamber. They are also consistent with correlations derived by Ingersoll (1970) and by Hecht (2002), based on natural-convection heat transfer. Each of these earlier correlations found Sh~Ra1/3, with the 1/3rd power characteristic of large Ra where the boundary layer over the pool surface is turbulent. A somewhat surprising result was that this power-law was found to extend into a range of Ra where laminar flow would be expected. Another surprising result was found in that instead of following established correlations for natural-convection heat transfer over flat plates, the dimensionless heat-transfer rates (Nu) were much larger and approximately independent of Ra. This suggests that mass transfer from the pool enhances convective heat transfer, possibly by enhanced mixing in the boundary layer. Although this possibility has been suggested in the literature, if it is proven to be true under these conditions it could play an important role in the use of a Rodwell on Mars, where evaporative mass transfer is enhanced relative to terrestrial wells.

Human Mars Mission↗
NASA NTRS2001

Advanced Methods for Aircraft Engine Thrust and Noise Benefits: Nozzle-Inlet Flow Analysis

Three connected sub-projects were conducted under reported project. Partially, these sub-projects are directed to solving the problems conducted by the HU/FM&AL under two other NASA grants. The fundamental idea uniting these projects is to use untraditional 3D corrugated nozzle designs and additional methods for exhaust jet noise reduction without essential thrust lost and even with thrust augmentation. Such additional approaches are: (1) to add some solid, fluid, or gas mass at discrete locations to the main supersonic gas stream to minimize the negative influence of strong shock waves forming in propulsion systems; this mass addition may be accompanied by heat addition to the main stream as a result of the fuel combustion or by cooling of this stream as a result of the liquid mass evaporation and boiling; (2) to use porous or permeable nozzles and additional shells at the nozzle exit for preliminary cooling of exhaust hot jet and pressure compensation for non-design conditions (so-called continuous ejector with small mass flow rate; and (3) to propose and analyze new effective methods fuel injection into flow stream in air-breathing engines. Note that all these problems were formulated based on detailed descriptions of the main experimental facts observed at NASA Glenn Research Center. Basically, the HU/FM&AL Team has been involved in joint research with the purpose of finding theoretical explanations for experimental facts and the creation of the accurate numerical simulation technique and prediction theory for solutions for current problems in propulsion systems solved by NASA and Navy agencies. The research is focused on a wide regime of problems in the propulsion field as well as in experimental testing and theoretical and numerical simulation analysis for advanced aircraft and rocket engines. The F&AL Team uses analytical methods, numerical simulations, and possible experimental tests at the Hampton University campus. We will present some management activity and theoretical numerical simulation results obtained by the FM&AL Team in the reporting period in accordance with the schedule of the work.

Morgan, Morris H.↗
NASA NTRS1994

Vapor Phase Catalytic Ammonia Reduction

This paper discusses the development of a Vapor Phase Catalytic Ammonia Reduction (VPCAR) teststand and the results of an experimental program designed to evaluate the potential of the technology as a water purification process. In the experimental program the technology is evaluated based upon product water purity, water recovery rate, and power consumption. The experimental work demonstrates that the technology produces high purity product water and attains high water recovery rates at a relatively high specific power consumption. The experimental program was conducted in 3 phases. In phase I an Igepon(TM) soap and water mixture was used to evaluate the performance of an innovative Wiped-Film Rotating-Disk evaporator and associated demister. In phase II a phenol-water solution was used to evaluate the performance of the high temperature catalytic oxidation reactor. In phase III a urine analog was used to evaluate the performance of the combined distillation/oxidation functions of the processor.

Flynn, Michael T.↗
NASA NTRS2013

The MJO Transition from Shallow to Deep Convection in CloudSat/CALIPSO Data and GISS GCM Simulations

The relationship between convective penetration depth and tropospheric humidity is central to recent theories of the Madden-Julian oscillation (MJO). It has been suggested that general circulation models (GCMs) poorly simulate the MJO because they fail to gradually moisten the troposphere by shallow convection and simulate a slow transition to deep convection. CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) data are analyzed to document the variability of convection depth and its relation to water vapor during the MJO transition from shallow to deep convection and to constrain GCM cumulus parameterizations. Composites of cloud occurrence for 10MJO events show the following anticipatedMJO cloud structure: shallow and congestus clouds in advance of the peak, deep clouds near the peak, and upper-level anvils after the peak. Cirrus clouds are also frequent in advance of the peak. The Advanced Microwave Scanning Radiometer for EarthObserving System (EOS) (AMSR-E) columnwater vapor (CWV) increases by;5 mmduring the shallow- deep transition phase, consistent with the idea of moisture preconditioning. Echo-top height of clouds rooted in the boundary layer increases sharply with CWV, with large variability in depth when CWV is between;46 and 68 mm. International Satellite Cloud Climatology Project cloud classifications reproduce these climatological relationships but correctly identify congestus-dominated scenes only about half the time. A version of the Goddard Institute for Space Studies Model E2 (GISS-E2) GCM with strengthened entrainment and rain evaporation that produces MJO-like variability also reproduces the shallow-deep convection transition, including the large variability of cloud-top height at intermediate CWV values. The variability is due to small grid-scale relative humidity and lapse rate anomalies for similar values of CWV. 1.

DelGenio, Anthony G.↗
NASA NTRS1975

Chemisorption kinetics of hydrogen on evaporated iron films

Measurements were made of the isothermal adsorption-desorption kinetics for H2 chemisorbed onto Fe films. The chemisorption process is observed to proceed via a precursor state of adsorbed molecular hydrogen similar to the H2-Ni system. The first measurements of the activation energy for desorption, and estimates of the values of the fast kinetic rates between the precursor and chemisorbed states are reported. Adsorption into the precursor state does not appear to be activated, but the process connecting the precursor state with the chemisorbed state will, under certain circumstances, be a rate limiting step for adsorption. The effects of contamination of the surface are evidenced in the measurements.

Shanabarger, M. R.↗
NASA NTRS1991

Applications of diamond films and related materials; Proceedings of the 1st International Conference, Auburn, AL, Aug. 17-22, 1991

The present conference discusses the nucleation and growth of diamond from hydrocarbons, the cutting tool performance of CVD thick-film diamond, the characterization of CVD diamond grinding powder, industrial applications of crystalline diamond-coated tools, standardized SEM tribometry of diamond-coated substrates, residual stress in CVD diamond films, the optical properties of CVD diamond films, polycrystalline diamond films for optical applications, and diamond growth on ferrous metals. Also discussed are ion beam-irradiation smoothing of diamond films, electronic circuits on diamond substrates, diamond-laminated surfaces for evaporative spray cooling, electron devices based on the unique properties of diamond, diamond cold cathodes, thin-film diamond microstructure applications, Schottky diodes from flame-grown diamond, diamond films for thermionic applications, methods of diamond nucleation and selective deposition, high-rate/large-area diamond film production, halogen-assisted diamond growth, the economics of diamond technology, and the optical and mechanical properties of diamondlike films.

Tzeng, Yonhua↗
NASA NTRS2001

Numerical Simulation of One- and Two-Phase Flows in Propulsion Systems

In this report, we present some results of problems investigated during joint research between the Hampton University Fluid Mechanics and Acoustics Laboratory (HU/FM&AL), NASA GRC, and the LaRC Hyper-X Program. This work is supported by joint research between the NASA GRC and the Institute of Mechanics at Moscow State University (IM/MSU) in Russia under a CRDF grant. The main areas of current scientific interest of the HU/FM&AL include an investigation of the proposed and patented advanced methods for aircraft engine thrust and noise benefits. These methods are based on nontraditional 3D corrugated and composite nozzle, inlet, propeller and screw designs such as a Bluebell and Telescope nozzle, Mobius-shaped screw, etc. This is the main subject of our other projects, of which one is presented at the current conference. Here we analyze additional methods for exhaust jet noise reduction without essential thrust loss and even with thrust augmentation. Such additional approaches are: (1) to add some solid, fluid, or gas mass at discrete locations to the main supersonic gas stream to minimize the negative influence of strong shock waves formed in propulsion systems. This mass addition may be accompanied by heat addition to the main stream as a result of the fuel combustion or by cooling of this stream as a result of the liquid mass evaporation and boiling; (2) Use of porous or permeable nozzles and additional shells at the nozzle exit for preliminary cooling of the hot jet exhaust and pressure compensation for off-design conditions (so-called continuous ejector with small mass flow rate); and (3) to propose and analyze new effective methods of fuel injection into the flow stream in air-breathing engines. The research is focused on a wide regime of problems in the propulsion field as well as in experimental testing and theoretical and numerical simulation analyses for advanced aircraft and rocket engines. The FM&AL Team uses analytical methods, numerical simulations, and experimental tests at the Hampton University campus, NASA, and IM/MSU. The main outcomes during this reporting period are: (1) Publications: The AIAA Paper #01-1893 has been accepted for the AIAA/NAL-NASDA-ISAS 10th International Space Planes and Hypersonic Systems and Technologies Conference, 24-27 April 2001, Kyoto, Japan. The AIAA Paper #01-3204 has been accepted for presentation at the 37th AIAA/ASME/SAE/ASEE Joint Propulsion Conference being held on 08-11 July, in Salt Lake City, UT; (2) Grants and proposals: The HU/FM&AL was awarded the NASA grant NAG3-2495 in October 2000 and the CRDF award was granted to the NASA GRC-HU FM&AL and IM/MSU (Russia) in July 2000. A solicited proposal was submitted for the NASA NRA-01GRC-02 competition and two unsolicited proposals to NASA are in preparation; (3) Theory and numerical simulations: Analytical theory, numerical simulation, comparison of theoretical with experimental results, and modification of theoretical approaches, models, grids, etc. Such investigations have been conducted for three main problems: (a) Combustion efficiency optimization in the half-duct combustor system; (b) Drag reduction effects for blunt bodies with solid needles; and (c) Solid particle injection from the butt-end against a supersonic flow. The NASA CFL3D, HU/FM&AL, and IM/MSU GODUNOV codes were used and modified for solution of these problems. The codes are based on full Euler and Navier-Stokes solvers with and without nonequilibrium oxygen-nitrogen and air-hydrogen chemical reactions in laminar and turbulent gas flow regimes; (4) Experimental tests: In the IM/MSU supersonic wind tunnel, experimental tests were conducted with different number, location, and geometric parameters of solid needles mounted at the front of the butt-end in supersonic flow. Optimal parameters were determined that provide minimal butt-end drag in the stationary flow regime. Experimental and numerical simulation results are in good agreement; (5) Student Research Activity: Involvement of one graduate and two undergraduate students as research assistants in the current project.

Gilinsky, Mikhail↗
NASA NTRS1992

Lunar base activities and the lunar environment

The Moon is an attractive site for astronomical observatories and other facilities because of the absence of a substantial lunar atmosphere and the stability of the lunar surface. The present lunar atmosphere is sufficiently transparent that there is no significant image distortion due to absorption or refraction. This thin atmosphere results from a combination of small sources and prompt losses. The major source that has been identified is the solar wind, whose total mass input into the lunar atmosphere is approximately 50 gm/sec. The major components of the solar wind are light elements (H and He) that promptly escape from the lunar surface by exospheric evaporation (Jeans' escape). The principal atmospheric loss mechanism for heavier gases is photoionization within a period of weeks to months, followed by immediate loss to the solar wind. Lunar base activities will modify the lunar atmosphere if gas is released at a larger rate than that now occurring naturally. Possible gas sources are rocket exhaust, processing of lunar materials, venting of pressurized volumes, and astronaut life support systems. For even modest lunar base activity, such sources will substantially exceed natural sources, although effects are expected to be localized and transient. The Apollo database serves as a useful reference for both measurements of the natural lunar environment and its modification by lunar base activities.

Vondrak, Richard R.↗
NASA NTRS2003

Predictability of Malaria Transmission Intensity in the Mpumalanga Province, South Africa, Using Land Surface Climatology and Autoregressive Analysis

There has been increasing effort in recent years to employ satellite remotely sensed data to identify and map vector habitat and malaria transmission risk in data sparse environments. In the current investigation, available satellite and other land surface climatology data products are employed in short-term forecasting of infection rates in the Mpumalanga Province of South Africa, using a multivariate autoregressive approach. The climatology variables include precipitation, air temperature and other land surface states computed by the Off-line Land-Surface Global Assimilation System (OLGA) including soil moisture and surface evaporation. Satellite data products include the Normalized Difference Vegetation Index (NDVI) and other forcing data used in the Goddard Earth Observing System (GEOS-1) model. Predictions are compared to long- term monthly records of clinical and microscopic diagnoses. The approach addresses the high degree of short-term autocorrelation in the disease and weather time series. The resulting model is able to predict 11 of the 13 months that were classified as high risk during the validation period, indicating the utility of applying antecedent climatic variables to the prediction of malaria incidence for the Mpumalanga Province.

Grass, David↗
NASA NTRSDate not supplied

Validation of Cryogenic Propellant Tank Filling using Computational Fluid Dynamics Simulation

Validation of cryogenic propellant tank filling was performed using the Computational Fluid Dynamics (CFD) solver Loci/STREAM-VoF. The validation effort helped identify modeling methodologies that enable NASA to best support its partners in both launch pad and on-orbit filling operations. Data from liquid hydrogen ground tests filled via jet injection were used for the validation effort which include a sensitivity to initial tank wall temperature. Initially hot walls are expected to yield rapid evaporation and possibly boiling. A Volume of Fluid (VoF) methodology was used to capture the gas-liquid interface. Rapid breakup of the liquid jet was observed in simulation results as liquid evaporated and expanded. Inflowing liquid transitioned to a contiguous jet as tank temperatures decreased, gas pressure increased, and saturation conditions at the incoming liquid temperature were approached. The final phase of filling was distinguished by rapid gas pressure rise due to a higher rate of gas volume compression than condensation at the liquid surface. Key physics of propellant tank filling were captured in the computational predictions, and opportunities for added simulation robustness and efficiency in future modeling efforts were identified.

CFM↗
NASA NTRS1979

Diffusion and phase change characterization by mass spectrometry

The high temperature diffusion of trace elements in metals and alloys was investigated. Measurements were made by high sensitivity mass spectrometry in which individual atoms were detected, and quantitative data was obtained for zircaloy-2, 304 stainless steel, and tantalum. Additionally, a mass spectrometer was also an analytical tool for determining an allotropic phase change for stainless steel at 955 C, and a phase transition region between 772 C and 1072 C existing for zircaloy-2. Diffusion rates were measured in thin (0.001" (0.0025 cm) and 0.0005" (0.0013 cm)) ribbons which were designed as high temperature thermal ion sources, with the alkali metals as naturally occurring impurities. In the temperature and pressure regime where diffusion measurements were made, the solute atoms evaporated from the ribbon filaments when the impurities diffused to the surface, with a fraction of these impurity atoms ionized according to the Langmuir-Saha relation. The techniques developed can be applied to many other alloys important to space vehicles and supersonic transports; and, with appropriate modifications, to the diffusion of impurities in composites.

Koslin, M. E.↗