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At least 487 records · Page 27

Evaluation of Increased Peak Temperatures for Spent Fuel Cladding Performance during Dry Storage (Rev.1)

NUREG-2214, “Managing Aging Processes in Storage (MAPS) Report,” (2019) documents the technical basis for age-related degradation mechanisms on spent nuclear fuel assemblies during dry storage operations. The technical bases have been reviewed, and hoop cladding stress calculations were conducted using the Fuel Analysis under Steady-state and Transients (FAST) code at elevated normal condition temperatures of 425°C and 450°C, and at an off-normal and accident conditions temperature of 600°C. The NUREG-2214 conclusions are substantiated by the referenced literature. The calculations demonstrate that the aging mechanisms primarily driven by hoop stress such as hydride reorientation, delayed hydride cracking, thermal and athermal (low-temperature) creep, and localized mechanical overload are either not credible or do not compromise the fuel assembly’s performance for increased peak normal condition temperatures of 425°C or 450°C during the up to 60-year dry storage period. Other aging mechanisms considered are also not credible for compromising the fuel assembly’s performance during 60-year dry storage with a peak temperature of 400ºC as specified in ISG – 11 Rev. 3, and the same is indicated for the increased peak normal condition temperatures of 425°C or 450°C.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Thermal Modeling of Advanced Test Reactor Fuel in a Generalized Dry Storage System Under Hypothetical Accident Conditions

Work was performed to investigate the thermal behavior of a sealed aluminum-clad spent nuclear fuel (ASNF) dry storage configuration under hypothetical accident conditions during long-term storage. The considered system consists of a concrete dry storage overpack; a welded over canister, backfilled with argon; and nine Department of Energy (DOE) standardized canisters (DOESCs) loaded with ASNF, backfilled with helium gas. One technical concern associated with the long-term storage of ASNF includes radiolytic hydrogen generation. The yield of large quantities of hydrogen could lead to DOESC over pressurization or a flammable internal atmosphere. While flammability concerns can be resolved by preventing the ingress of oxygen, the canister pressure is partially controlled by the atmosphere temperature. This memorandum summarizes the results of modeling and simulation (M&S) work completed with Star CCM+ (a computational fluid dynamics [CFD] software) considering the thermal effects of a fully engulfing flame and another scenario with the vent ports of the concrete dry storage overpack completely blocked. The goal was to determine the bounding maximum temperature of the DOESC internal atmosphere to evaluate a worst-case pressure scenario, as well as the critical vent port blockage durations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Thermal Modeling Aluminum-Clad Spent Fuel Dry Storage Configurations [Slides]

A presentation covering the work done by the C430 Department at Idaho National Lab on thermal concerns for extended dry storage of aluminum clad spent nuclear fuel (ASNF). Computational fluid dynamics software Star CCM+ was used to model hypothetical accident conditions applied to a dry storage configuration containing ASNF. The hypothetical accident conditions being examined were a fire in which the dry storage configuration is fully engulfed in flames and a situation in which the vent ports of the overpack are completely blocked.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Vacuum Drying Study of Simulated Failed Nuclear Fuel (FY23)

This report documents work performed under the Office of Spent Fuel and Waste Disposition’s (SFWD’s) Spent Fuel and Waste Science and Technology program for the US Department of Energy (DOE) Office of Nuclear Energy (NE). This work was performed to fulfill Level 4 milestone M4SF-23OR010203013. Over the 70 years of light-water reactor (LWR) operation, fuel rod failures have occurred during reactor operation. Based on the Unified Database that SFWD maintains, there are ~5,400 LWR fuel rods that developed leaks during reactor operation of the >19 million rods operated. The Unified Database indicates that ~4,200 of these rods remain in the spent fuel pool, and ~1,200 are in dry storage canisters. It is expected that all failed rods are “waterlogged” in the spent fuel pool, meaning the inside of the rods contain some volume of water. There are two related objectives of this work. The first is to develop a simple and inexpensive experiment to better understand removal of water from inside failed spent nuclear fuel (SNF) rods, and the second is to develop a model to predict drying of simulated failed fuel in the simple experiment. Once a model captures the phenomenon in the simple experiment, it can be extended to predict drying under more prototypical conditions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

ASNF Dry Storage Pilot with HFIR Fuel: Concept Plan

The U.S. Department of Energy (DOE) currently manages a large inventory of aluminum-clad spent nuclear fuel (ASNF) from U.S. High Performance Research Reactors and also some fuel from foreign research reactors. A transition to new dry storage configurations is desired to facilitate decisions related to potential storage of future ASNF and transitioning current ASNF out of aging storage facilities. DOE has developed designs for a set of DOE Standard Canisters (DSCs) to provide sealed, road-ready dry storage suitable for interim storage, transportation, and potentially disposition in a future repository. Extensive experiments and modeling activities have been carried out to develop the technical basis for such storage, with results to date indicating this storage approach should be safe and viable following suitable drying processes.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Analysis of Dust and Corrosion Witness Samples Recovered from SNF Dry Storage Systems, Maine Yankee, 2023

This report documents the results of a long-term (5.79 year) exposure of 4-point bend corrosion test samples in the inlet and outlet vents of four spent nuclear fuel dry storage systems at the Maine Yankee Independent Spent Fuel Storage Installation. The goal of the test was to evaluate the corrosiveness of salt aerosols in a realistic near-marine environment, providing a data set for improved understanding of stress corrosion cracking of spent nuclear fuel dry storage canisters. Examination of the samples after extraction showed minor corrosion was present, mostly on rough-ground surfaces. However, dye penetrant testing showed that no SCC cracks were present. Dust collected on coupons co-located with the corrosion specimens was analyzed by scanning electron microscopy and leached to determine the soluble salts present. The dust was mostly organic material (pollen and stellate trichomes), with lesser detrital mineral grains. Salts present were a mix of sea-salts and continental salts, with chloride dominating the anions, but significant amounts of nitrate were also present. Both corrosion samples and dust samples showed evidence of wetting, indicating entry of water into the vents. The results of this field test suggest that the environment at Maine Yankee is not highly aggressive, although extrapolation from the periodically wetted vent samples to the hot, dry, canister surface may be difficult. No stress corrosion cracks were observed, but minor corrosion was present despite high nitrate concentrations in the salts. These observations may help address the ongoing question of the importance of nitrate in suppressing corrosion and SCC.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Field Test Report Neutron Scintillator Array Dry Storage Cask Scanner FY2024

During two weeks of Field Testing at the Idaho National Laboratory INTEC Cask Farm in July and August 2024, the LLNL Dry Storage Cask Scanner Array was lifted on top of an MC-10 dry storage fuel cask and operated to acquire neutron and gamma-ray data from the 24 fuel bundle positions. Neutron and gamma-ray data acquisition scans across the top of the cask of varying dwell times were performed July 15-18, 2024 and August 19-22, 2024 to evaluate the ability of the scanner data to reveal asymmetries in the fuel positions that reflect asymmetries in the MC-10 cask fuel bundle loading. The MC-10 cask 24 position fuel bundle loading at the INTEC Cask Farm is well documented, including the locations of six empty fuel bundle positions. This loading presents an opportunity to test the ability of the scanner system to detect diversion of spent fuel bundles as well as to validate the MC-10 cask MCNP modeling. The cask scanner array consists of six Stilbene crystal scintillator detectors and a linear actuator frame that moves the six detectors across the MC-10 dry storage cask to obtain data above each of the 24 fuel bundle positions. The detectors are connected to a pulse-shape discrimination data acquisition system capable of generating separate neutron and gamma-ray spectra for each detector and for each scan position. From the prior single detector Field Test in 2021 and iteration with MCNP modeling, the neutron and gamma-ray data were analyzed in multiple energy regions to identify an analysis method that would provide the strongest and most consistent signature of the asymmetric MC-10 cask fuel loading1 . From both the 2021 Field Test and the current Field Test results, the neutron capture gamma-ray count rate around 2.2 MeV provides the strongest signature of the asymmetric MC-10 cask fuel loading and has qualitative agreement with MCNP calculations. Counting all gamma-rays produces a similar signature. Neutrons emerging from the cask top are moderated and captured by the hydrogen in the polyethylene moderator and scintillator detector, producing a 2.2 MeV gamma ray which is seen in the scintillator gamma-ray spectrum. The count rate in the 2.2 MeV gamma-ray region is ~50 c/s, which is ~1000x higher than the ~0.05 n/s rate in the > 4MeV neutron region, and ~50x greater than the ~1 n/s rate in the neutrons > 500 keV region. Analysis of the 2.2 MeV neutron-capture Compton-scattered gamma-rays produces a statistically significant signature of the INTEC Cask Farm MC-10 asymmetric fuel loading. MCNP simulations indicate that the average neutron energy spectrum offers the potential to detect a large asymmetry from several missing bundles as well as individual missing fuel bundles. Testing this feature will require measurements on a cask with single missing elements.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Update: structural uncertainty of used nuclear fuel in dry storage canisters

The Structural Uncertainty research task uses numerical modeling to help close knowledge gaps associated with extended dry storage of used nuclear fuel. Modeling helps to predict the expected range of mechanical loading on used nuclear fuel and dry storage system components, which is needed to help guide materials research. Knowledge of expected loads helps the materials researchers prioritize their research and focus only on the relevant material degradation phenomena that can have an effect on the ability of dry storage systems to function. The loads considered in this task are DSC tip-over, handling drops of the multipurpose fuel canister, and seismic loading of DSC systems while situated on the concrete pad of a storage facility. This document is a progress report that describes the work that was performed in fiscal year 2015. The work is a broad task that considers a number of physical phenomena and uses sophisticated LS-DYNA finite element models to predict used fuel and DSC system response to dynamic loads. Due to the broad list of topics and limited budgets, the topics of this task are prioritized at the beginning of the year and the priorities are subject to revision throughout the year as the Pacific Northwest National Laboratory team collaborates with other members of the Used Fuel Disposition Campaign. This year, three topics were investigated: options for modeling cladding in LS-DYNA, the effect of cladding thinning in the tip-over load case, and stress corrosion cracking in multipurpose canister welds. In each of these cases, significant progress was made. This report details the work that was done and identifies areas where more work is needed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Temperature-Time Modeling of Spent Fuel Cladding in Dry Storage Casks

This report uses thermal and decay heat modeling to investigate spent fuel performance and the potential for cladding to anneal in dry storage conditions. Annealing is an important feature to investigate in SNF cladding because it has a direct relationship to cladding response in storage, transportation and disposal conditions. Annealed cladding may have lower strength than unannealed cladding, however its increased ductility would provide better protection against rupture in high strain rate situations such as severe accidents. These consequences are the driver for this work however are outside of the scope of this report. The modeling focused on three representative storage systems, the TN-32B, MAGNASTOR with TSC-37 canister, and NUHOMS AHSM with a 32PTH2 canister. This covers the vertical dual-purpose, vertical ventilated and horizontal ventilated casks respectively. Decay heat modeling using high and low enrichment assemblies was used to bound the decay heat curves that might be expected in dry storage. To bound the temperature relationship, the storage casks were modeled starting at the design basis heat loads with heat decaying through time. Although the results are bounding there is not an attempt to maximize conservatism, rather the intent to form a reasonable upper limit on temperature that will be broadly applicable to the U.S. cask fleet. This will allow materials testing to focus on relevant conditions for annealing that may affect the U.S. spent fuel inventory. The results show a clear dependence on heat load pattern in time in Figure S-1 and Figure S-2. This dependence is due to the different assembly decay heat curves for different assemblies in preferentially loaded casks. It shows the need for careful decay heat modeling when examining in service fuel temperatures that are less than the cask design basis heat load. The body of the report shows percent cladding cutoffs of 300°C and 350 °C as well. These results can be used to inform testing and conclusions about cladding performance through time and the potential for cladding annealing during dry storage.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Metagenomes from Eastern Brazilian Amazonian floodplains in the wet and dry seasons

Brief sample description Sediment samples from 0 to 10 cm depth were collected in triplicate from two floodplains of the Eastern Brazilian Amazon, one located on the Amazonas River (FP2, 2°28'11.2"S 54°38'49.9"W) and the other at the intersection between the Amazonas and the Tapajós rivers (FP3, 2°22'44.8"S 54°44'21.1"W), in the wet and dry seasons (May and October 2016, respectively). Total DNA was extracted in duplicate from 0.25 g of sediment using PowerLyzer PowerSoil DNA Isolation Kit. The metagenomic libraries were constructed using NEBNext Ultra II DNA Library Prep Kit for Illumina and paired-end sequenced (2 x 150 bp) on an Illumina HiSeq 2500 platform. Detailed information about the study sites, sampling, sediment physicochemical properties, DNA extraction and quantification have been previously described by Gontijo et al. (2021). Sample IDs: M1, M2 and M3: FP2, wet season M4, M5 and M6: FP3, wet season M7, M8 and M9: FP2, dry season M10, M11 and M12: FP3, dry season

59 BASIC BIOLOGICAL SCIENCES↗

Modeling Solution Drying by Moving a Liquid-Vapor Interface: Method and Applications

A method of simulating the drying process of a soft matter solution with an implicit solvent model by moving the liquid-vapor interface is applied to various solution films and droplets. For a solution of a polymer and nanoparticles, we observe “polymer-on-top” stratification, similar to that found previously with an explicit solvent model. Furthermore, “polymer-on-top” is found even when the nanoparticle size is smaller than the radius of gyration of the polymer chains. For a suspension droplet of a bidisperse mixture of nanoparticles, we show that core-shell clusters of nanoparticles can be obtained via the “small-on-outside” stratification mechanism at fast evaporation rates. “Large-on-outside” stratification and uniform particle distribution are also observed when the evaporation rate is reduced. Polymeric particles with various morphologies, including Janus spheres, core-shell particles, and patchy particles, are produced from drying droplets of polymer solutions by combining fast evaporation with a controlled interaction between the polymers and the liquid-vapor interface. Our results validate the applicability of the moving interface method to a wide range of drying systems. The limitations of the method are pointed out and cautions are provided to potential practitioners on cases where the method might fail.

36 MATERIALS SCIENCE↗

What drives daily precipitation over the central Amazon? Differences observed between wet and dry seasons

This study offers an alternative presentation regarding how diurnal precipitation is modulated by convective events that developed over the central Amazon during the preceding nighttime period. We use data collected during the Observations and Modelling of the Green Ocean Amazon (GoAmazon 2014/2015) field campaign that took place from 1 January 2014 to 30 November 2015 in the central Amazon. Local surface-based observations of cloud occurrence, soil temperature, surface fluxes, and planetary boundary layer characteristics are coupled with satellite data to identify the physical mechanisms that control the diurnal rainfall in central Amazon during the wet and dry seasons. This is accomplished through evaluation of the atmospheric properties during the nocturnal periods preceding raining and non-raining events. Comparisons between these non-raining and raining transitions are presented for the wet (January to April) and dry (June to September) seasons. The results suggest that wet-season diurnal precipitation is modulated by nighttime cloud coverage and local influences such as heating induced turbulence, whereas the dry-season rain events are controlled by large-scale circulations.

54 ENVIRONMENTAL SCIENCES↗

Dry particle generation with a 3-D printed fluidized bed generator

Here we describe the design and testing of PRIZE (PRinted fluidIZed bed gEnerator), a compact fluidized bed aerosol generator manufactured using stereolithography (SLA) printing. Dispersing small quantities of powdered materials – due to either rarity or expense – is challenging due to a lack of small, low-cost dry aerosol generators. With this as motivation, we designed and built a generator that uses a mineral dust or other dry powder sample mixed with bronze beads that sit atop a porous screen. A particle-free airflow is introduced, dispersing the sample as airborne particles. Total particle number concentrations and size distributions were measured during different stages of the assembling process to show that the SLA 3-D printed generator did not generate particles until the mineral dust sample was introduced. Time-series measurements with Arizona Test Dust (ATD) showed stable total particle number concentrations of 10–150 cm -3 , depending on the sample mass, from the sub- to super-micrometer size range. Additional tests with collected soil dust samples are also presented. PRIZE is simple to assemble, easy to clean, inexpensive and deployable for laboratory and field studies that require dry particle generation.

54 ENVIRONMENTAL SCIENCES↗

Dry heat effects on survival of indigenous soil particle microflora and particle viability studies of Kennedy Space Center soil

Research efforts were concentrated on attempts to obtain data concerning the dry heat resistance of particle microflora in Kennedy Space Center soil samples. The in situ dry heat resistance profiles at selected temperatures for the aggregate microflora on soil particles of certain size ranges were determined. Viability profiles of older soil samples were compared with more recently stored soil samples. The effect of increased particle numbers on viability profiles after dry heat treatment was investigated. These soil particle viability data for various temperatures and times provide information on the soil microflora response to heat treatment and are useful in making selections for spacecraft sterilization cycles.

Ruschmeyer, O. R.↗

Inertial attitude control of Voyager spacecraft using dry tuned rotor gyro

The inertial attitude control system designed for the Voyager spacecraft, which will carry out flybys of Jupiter and Saturn in 1979 and 1981, respectively, is described. The attitude of the spacecraft in three-dimensional space will be measured by a Dry Inertial Reference Unit (DIRU) based on three identical two-degree-of-freedom dry gyros. A software estimation process has been developed to use DIRU data and other information to obtain optimum estimates of spacecraft position, velocity, and acceleration. The attitude of the spacecraft is corrected using these estimates by activating hydrazine thrusters. The operation of dry gyros is discussed, together with the network compensation techniques used in their associated capture loop to obtain a capture capability of 8 deg/sec and a frequency response of 10 Hz (3-dB point). The control law and estimation process are examined. Results of computer simulation studies of the performance of the attitude control system are presented.

Bahrami, K.↗

A dry-surface coating method for visualization of separation

A relatively simple and reasonably accurate dry-surface coating method for visualization of the separation line on a bluff body was devised and successfully tested. This technique is based on the color reaction of a dry film containing a pH indicator with an appropriate gas released in the body wake. The dry-surface coating method is effective at any Reynolds number and for both incident laminar and turbulent flows. It further supplies a colorful permanent of consistently good photographic quality of the separation line. The effectiveness and accuracy of this technique were tested in visualizing the separation angle on a circular cylinder in both laminar and turbulent crossflows at subcritical Reynolds numbers. Separation angles revealed by the visualization were within + or - 4 percent of their counterparts deduced from the mean wall pressure distribution.

Sadeh, W. Z.↗

Behavior of aircraft antiskid braking systems on dry and wet runway surfaces: Hydromechanically controlled system

The investigation utilized one main gear wheel, brake, and tire assembly of a McDonnell Douglas DC-9 series 10 airplane. The landing-gear strut was replaced by a dynamometer. During maximum braking, average braking behavior indexes based upon brake pressure, brake torque, and drag-force friction coefficient developed by the antiskid system were generally higher on dry surfaces than on wet surfaces. The three braking behavior indexes gave similar results but should not be used interchangeably as a measure of the braking of this antiskid sytem. During the transition from a dry to a flooded surface under heavy braking, the wheel entered into a deep skid but the antiskid system reacted quickly by reducing brake pressure and performed normally during the remainder of the run on the flooded surface. The brake-pressure recovery following transition from a flooded to a dry surface was shown to be a function of the antiskid modulating orifice.

Tanner, J. A.↗

Remote sensing of total dry-matter accumulation in winter wheat

Red and photographic-infrared spectral data collected on 21 dates over the growing season with a hand-held radiometer were quantitatively correlated with total dry-matter accumulation in winter wheat. The spectral data were found to be highly related to vigor and condition of the plant canopy. Two periods of drought stress and subsequent recovery from it were readily apparent in the spectral data. Simple ratios of the spectral radiance data compensated for variations in solar intensities and, when integrated over the growing season, explained 79% of the variation in total above-ground accumulation of dry matter. A satellite system is proposed to provide large-area assessment of total dry accumulation or net primary production from terrestrial vegetation.

Tucker, C. J.↗