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At least 487 records · Page 27

Sequential Recovery of Critical Metals from Leached Liquor of Processed Spent Lithium-Ion Batteries

The processing and extraction of critical metals from black mass is important to battery recycling. Separation and recovery of critical metals (Co, Ni, Li, and Mn) from other metal impurities must yield purified metal salts, while avoiding substantial losses of critical metals. Solvent extraction in batch experiments were conducted using mixed metal sulphates obtained from the leach liquor obtained from spent and shredded lithium-ion batteries. Selective extraction of Mn 2+ , Fe 3+ , Al 3+ and Cu 2+ from simulated and real leached mixed metals solution was carried out using di-2-ethylhexylphophoric acid (D2EPHA) and Cyanex-272 at varying pH. Further experiments with the preferred extractant (D2EPHA) were performed under different conditions: changing the concentration of extractant, organic to aqueous ratio, and varying the diluents. At optimum conditions (40% v/v D2EPHA in kerosene, pH 2.5, O:A = 1:1, 25 °C, and 20 min), 85% Mn 2+ , 98% Al 3+ , 100% Fe 3+ , and 43% Cu 2+ were extracted with losses of only trace amounts (<5.0%) of Co 2+ , Ni 2+ , and Li + . The order of extraction efficiency for the diluents was found to be kerosene > Exxal-10 >>> dichloromethane (CH 2 Cl 2 ) > toluene. Four stages of stripping of metals loaded on D2EPHA were performed as co-extracted metal impurities were selectively stripped, and a purified MnSO 4 solution was produced. Spent extractant was regenerated after Fe 3+ and Al 3+ were completely stripped using 1.0 M oxalic acid (C 2 H 2 O 4 ).

25 ENERGY STORAGE↗

Planning for the storm: Considering renewable energy for critical infrastructure resilience

This study uses the renewable energy optimization model to assess three critical facilities in North Carolina. Techno-economic results were then compared to analyses completed for critical facilities in California and New York to assess energy system cost effectiveness. Though solar photovoltaic (PV) arrays are cost-effective across each of the three North Carolina facilities, adopting battery storage to enable PV to operate with existing diesel generators in a hybrid energy system reduces the economic value of the system. This is in contrast to more economically viable systems in California and New York. All of these systems also offer unquantified resilience benefits by extending operation from hours to weeks across the facilities. If decision makers were able to value the resilience benefits offered by each system or utility rate structures were changed to incentivize battery storage during normal operations, it would impact these assessments. Even so, this analysis provides decision makers a key set of cost benchmarks when considering how they might improve resilience at their critical operations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Initial Criticality Assessments to Guide FMEAs on Rocket Engine Hot Fire Testing

Presented is an explanation of the use of the Initial Criticality Assessment (ICA) technique, a triage process for prioritizing required Failure Modes and Effects Analysis (FMEAs), for the European Service Module's main propulsion system's hot-fire test bed at White Sands New Mexico. Rather than instinctively performing many FMEAs of subsystems, or one large system level FMEA where every subcomponent is analyzed, the ICA guided an informed analysis of only the hardware that had a large impact to hazards. The low criticality hardware was documented via the ICA and no FMEA was performed; the work could then focus on the high criticality hardware. Thus a savings of Program resources was achieved. The experiences gained in creating these ICAs for this international collaborative project confirmed that the need for continuous communication across the technical teams is one of the greatest areas of emphasis. The European Space Agency (ESA) is developing the European Service Module (ESM), with its primary contractor, Airbus Defence and Space in Germany, for delivery to the National Aeronautics and Space Administration (NASA). The module will be equipped with a total of 21 engines to support NASA’s Orion spacecraft: one U.S. Space Shuttle Orbital Maneuvering System-Engine (OMS-E), eight auxiliary thrusters and 12 smaller RCS (Reaction Control System) thrusters. The main ESM propulsion system, used for large translational maneuvers, consists of one OMS-E... To qualify the design of the ESM propulsion subsystem (PSS) an all-steel Propulsion Qualification Module (PQM) structure is used to test the propulsion systems on Orion, including “hot firing” of the OMS engine, thrusters, and RCS. The PQM has been developed as a hot-fire test bed to be tested at the NASA White Sands Test Facility (WSTF). One of the objectives of the testing is to assure that the OMS-E can be safely operated with the PQM. Testing will also demonstrate that the PQM can set the proper upstream pressures and temperatures for the OMS-E to operate nominally given the PQM has never been tested in hot-fire operation with OMS-E before. In order to safely conduct the test campaign, hardware such as the engine subassembly, fluid feed lines, valves, electrical power lines, instrumentation, stiff links, installation Ground Support Equipment (GSE), and diffuser [whose objectives are to collect the exhaust of the OMS-E to actively cool down the exhaust gases, reduce thermal exchanges, and create a vacuum at OMS-E level before igniting], had to be analyzed for any hazards and failure modes.

Fault Tolerance↗

Verification and Validation of Safety-Critical Aircraft Systems Operating under Off-Nominal, Contingency, and Emergency Conditions

Verification and validation (V&V) of safety-critical technologies developed for loss of control (LOC) prevention and recovery and other aviation safety concerns pose significant challenges. Aircraft LOC can result from a wide spectrum of hazards, often occurring in combination, which cannot be fully replicated during evaluation. Technologies developed for LOC prevention and recovery must therefore be effective under a wide variety of hazardous and uncertain conditions, and the verification and validation of these technologies must provide some measure of assurance that the new vehicle safety technologies do no harm (i.e., that they themselves do not introduce new safety risks). V&V technologies must also enable the identification of system limitations and constraints, as well as enable the identification of safe and unsafe operating conditions (and their boundaries). Additionally, the V&V of complex, increasingly autonomous systems is a fundamental concern. Scalable, reproducible and cost-effective techniques for the assurance of safety critical systems during their design and operation is a key barrier to fielding new systems or updating current systems. Moreover, these techniques need to provide artifacts that enable a comprehensive evidence-based approach to certification. This briefing summarizes research performed under NASA’s Aviation Safety Program and follow-on research for the V&V of safety-critical aircraft system technologies developed for LOC prevention and recovery and increasingly autonomous systems, and for a broad assurance capability in both current and emerging aviation applications. Note that, in this briefing, the term “validation” refers to a confirmation that the system implementation (e.g., algorithms etc.) is performing the intended function(s), as well as an affirmation of effectiveness in these functions. “Verification” refers to a confirmation that the system implementation in the software and hardware meets its (hopefully validated) specifications (e.g., correctly executes algorithms as designed).

Validation↗

Improved Verification and Validation Testing and Tools including Nuclear Criticality Safety Applications with the MCNP6.3® Code [Abstract]

A new Python-based framework has been developed to enable a more consistent layout with automatable setup, execution, and documentation of all verification and validation (V&V) test suites previously established for use with the MCNP code. In this paper, the new general framework for the V&V test suites is discussed, including information on all of the current capabilities and plans for future capabilities. For nuclear criticality safety applications, the existing V&V benchmark problems within the criticality, extended criticality, and analytic k-effective test suites have been ported into this new framework. In addition, the status and updates to the Rossi-alpha and subcritical multiplicationtest suites will be discussed. Some V&V results exercising new MCNP6.3 capabilities will be demonstrated.

97 MATHEMATICS AND COMPUTING↗

Domestic Extremism: How to Counter Threats Posed to Critical Assets

Although facilities with sensitive information, hazardous materials, critical infrastructure, or other sensitive items have security measures in place to protect those critical assets, the threat of domestic extremism (DE) has challenged those security measures in new ways. The project described in this brief report used focus groups to identify best practices, tools, or techniques relevant to preventing or countering DE and sought to identify gaps in security measures. Five focus groups with twenty-two subject matter experts from government, healthcare, and other stakeholder groups were conducted to understand how organizations protect critical assets against the DE threat. The results of the focus groups underscore the importance of organizational culture, codes of conduct, and behavior observation programs in prevention of DE events. In addition, results emphasized the value of multidisciplinary teams, employee assistance programs, and regular threat assessment as resources when responding to DE incidents. However, monitoring of social media and lack of adequate resources remain challenges when attempting to prevent or counter the DE threat.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Hybrid Particle Swarm-Interpolation Algorithm for Improved Critical Experiment Design

The typical goal of designing a critical experiment is twofold: a system that is both critical and optimized for some other value. This value could be an energy-integrated sensitivity, percent fissions in a certain energy range, or some other value that can be calculated by a transport code. By simulating different combinations of reflector, moderator, and fuel thicknesses a designer can identify such a desirable configuration. The domain of all possible combinations of these thicknesses is referred to as the experiment search space. As more dimensions are added, the search space increases in size exponentially. For a three-dimensional case, which includes three thickness values between zero and ten centimeters to the nearest tenth of a millimeter, a total of 1,000 3 , configurations exists. Rather than check each configuration individually, which would be extremely computationally expensive, it has been shown to be more efficient to use a conventional particle swarm optimization (PSO) algorithm to identify critical and optimal configurations. This work presents the theory and implementation of a novel hybrid PSO interpolation algorithm to perform these optimizations faster than a conventional PSO algorithm. To demonstrate this, an example optimization will be carried out by the conventional and hybrid PSO algorithms and their performances will be compared.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Progress Towards the Reality of Low-Temperature Critical Experiments with Low-Temperature TEX

Integral benchmarks for criticality safety do not exist below room temperature. Incredible support for below room temperature benchmarks is present across the international community. Validation of low-temperature neutron cross sections is necessary to verify any operation at temperatures below room temperature which is typically observed in environments far from the equator. For example, a fissile material transportation truck may routinely observe ambient temperatures down to -40°C, which is the lower temperature bound of the normal conditions of transportation defined in the United States Title 10 Code of Federal Regulations §71.71c2. Similarly, the IAEA, which contains 176 member states, has the same requirement for subcriticality for fissile material transportation. Additionally, sub-room temperature benchmarks can validate newly produced cross sections, that include novel thermal scattering laws, from North Carolina State University. A six-case experiment designed based off the TEX-HEU baseline experiments has been proposed utilizing a chilled vacuum chamber capable of cooling the HEU stack down to -50°C. The six proposed configurations span the entire neutron fission energy range and can be tested at intermediate temperatures between room temperature and -40°C. Of the six configurations, the fastest case utilizes nearly 135 kg of HEU. Understanding the system is required prior to critical experiment operations. In order to test the functionality of the system, testing with surrogate fuel materials has been conducted. The following discusses the design of the low temperature TEX (LT-TEX) experiment as well as the progress made via surrogate testing towards a reality in which low-temperature integral benchmarks exist in the International Criticality Safety Benchmark Evaluation Project (ICSBEP).

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Criticality Consideration for Geologic Disposal of DOE-Owned Spent Nuclear Fuels - 20255

Decisions must be made relative to packaging spent nuclear fuel (SNF) for storage, transportation, and eventual disposal. This paper evaluates potential criticality-related loading and packaging considerations for Department of Energy (DOE)-owned SNF that could be impacted favorably or unfavorably by disposal uncertainties and proposes approaches to minimize such impacts. Using Al-Based SNF as an example and drawing on analyses performed in support of the Yucca Mountain Repository License Application (LA), this paper explores the role of natural barriers, engineered barriers, and waste form characteristics relative to reducing the potential for postclosure criticality. Several parameters important to postclosure criticality are considered in order to determine which are useful discriminators to support packaging decisions. Using these parameters, a qualitative assessment is performed relative to three options for managing DOE-owned SNFs. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

ANS-8 Nuclear Criticality Safety Consensus Standards - Current Initiatives

The nuclear criticality safety (NCS) consensus standards are developed as using rigorous procedures of the Standards Board of the American Nuclear Society. These procedures have been accredited by the American National Standards Institute, Inc., as meeting the criteria for American National Standards. The Nuclear Criticality Safety Consensus Committee (NCSCC) that approved all 18 NCS consensus standards is balanced to ensure that competent, concerned, and varied interests have had an opportunity to participate. The ANS-8 subcommittee (ANS-8) consists of 17 NCS experts with many years of experience as end users of ANS standards who serve on standard working groups to develop and maintain standards. ANS-8 ensures that the technical content of the standards is adequate for NCS community use. Attempts are made to ensure that ANS-8 consists of NCS professionals with a diverse range of experience such that all standards are applicable to as many sites as possible. ANS-8 is a very active subcommittee, and some active projects in progress are discussed in this paper: basis statement development for all standards, development of a glossary for consistency of definitions across all ANS-8 standards, and Considering the Criticality Safety Support Group (CSSG) Recommendation 2016-04 to the ANS Standards Board for changes in several ANS-8 standards.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Structural, Criticality, and Radiation Dose Calculations to Support SNF Loading into a DOE Standard Canister

The DOE Standard Canister Demonstration Project includes the development of an internal support structure (ISS) for the 4.6-m-long and 45.7-cm-diameter canister. This study presents structural evaluations, criticality safety assessments, and dose rate calculations conducted within the scope of the ISS design process to support smooth canister loading operations and to ensure safe storage, transportation, and disposal of Peach Bottom 1 Core II (PB2) and Fort St. Vrain (FSV) SNF, currently stored at INL’s CPP-603 facility. The ISS includes a 316L stainless-steel basket that holds 12 PB2 SNF rods. The PB2 basket rests on top of six individual, 78.7-cm-long, 316L stainless-steel columns that are equally spaced and welded to the inner canister wall at the lower end of the shell. These columns represent the FSV basket and can hold one FSV SNF element. An A92014 T6 aluminum spacer disc is bolted to the bottom plate of the PB2 basket to vertically restrain the FSV SNF element after the PB2 basket is placed inside the canister above the FSV basket. The structural evaluations of the ISS followed applicable ASME BPVC.III.3 guidelines and included finite element (FE) analyses of the PB2 basket structure; analyses of welds and bolds; buckling analyses of selected components, and acceptability assessments of the expected basket deformations under loading operations. The criticality safety assessments used the Monte Carlo N-Particle (MCNP) software architecture Version 6.2, including ENDF/B-V continuous-energy cross-section libraries, considering intact SNF in a single storage overpack or two multistorage overpack configurations and intact or failed SNF configured for disposal. The dose rate computations are based on source terms taken from the DOE Spent Fuel Database. The isotopic composition was decay corrected for the year 2022 using the ORIGEN module in the SCALE suite. A 19-group photon spectrum and a 27-group neutron-source spectrum were generated and used in MCNP to calculate estimated dose-equivalent rates, both on DOE Standard Canister contact and at a radial distance of 1 m from the canister surface. The results of this study indicate a structurally sound system that can uphold its criticality safety functions throughout its intended operational phases. Furthermore, this study provides confidence that sufficient radiological protection is technically achievable.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Structural, Criticality, and Radiation Dose Calculations to support SNF Loading into a DOE Standard Canister

The DOE Standard Canister Demonstration Project includes the development of an internal support structure (ISS) for the 4.6-m long and 45.7-cm diameter canister. This study presents structural evaluations, criticality safety assessments, and dose rate calculations conducted within the scope of the ISS design process to support smooth canister loading operations and to ensure safe storage, transportation, and disposal of Peach Bottom 1 Core II (PB2) and Fort St. Vrain (FSV) SNF, currently stored at the CPP-603 facility of the INL. The ISS includes a 316L stainless steel basket that holds twelve PB2 SNF rods. Further, six individual, 78.7-cm long, 316L stainless steel columns are equally spaced and welded to the inner canister wall at the lower end of the shell. These columns represent the FSV basket and can hold one FSV SNF element. An A92014 T6 aluminum spacer disc is bolted to the bottom plate of the PB2 basket to vertically restrain the FSV SNF element after the PB2 basket is placed inside the canister on top of the FSV basket. The structural evaluations of the ISS followed applicable ASME BPVC.III.3 guidelines and included finite element (FE) analyses of the PB2 basket structure; analyses of welds and bolds; buckling analyses of selected components, and acceptability assessments of the expected basket deformations under loading operations. The criticality safety assessments used the Monte Carlo N-Particle (MCNP) software architecture version 6.2 including ENDF/B-V continuous energy cross-section libraries, considering intact SNF in a single storage overpack or two multi-storage overpack configurations, and intact or failed SNF configured for disposal. The dose rate computations are based on source terms taken from the DOE Spent Fuel Database. The isotopic composition was decay corrected for the year 2022 using the ORIGEN module in the SCALE suite. A 19-group photon spectrum and 27-group neutron-source spectra were generated and used in MCNP to calculate estimated dose-equivalent rates, both on DOE Standard Canister contact and at a radial distance of from the canister surface. The results of this study indicate a structurally sound system that can uphold its criticality safety functions throughout its intended operational phases. Further, they increase confidence that sufficient radiological protection is technically achievable.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Why the US Needs an Enduring Plutonium Critical Assembly

Jezebel (operated from 1954-1977) has been the primary experiment for fast 239 Pu nuclear data validation for the last 70 years. Validation has included not only k eff , but also spectral indicies, Rossi-α, reactivity coefficients, and neutron leakage spectra. While this has been incredibly valuable to the community, there are three major issues. The first issue is that documentation on many of these experiments were lacking, leading to large uncertainties or (even worse) incorrect assumptions. The second issue is that while there have been many advances in research, there is no way to test those new advances today. The last issue is that since the assembly only operated for 23 years (and at time when 30 other critical assemblies were operating at the same facility and nuclear weapons testing was occurring), there were limited opportunities to observe how any system parameters changed as a function of time. Note that this work is not suggesting that a "Jezebel re placement" used for a limited experiment campaign would have great value. A new enduring (100 year target) plutonium (Pu) assembly with simple geometry and low uncertainties, however, would be extremely valuable. Such a capability would have a transformative impact on many research areas including nuclear data validation, analytical methods validation, dosimetry, reactor kinetics, and materials. The need for a new plutonium assembly is not new: it has been in the DOE Nuclear Criticality Safety Program (NCSP) Mission and Vision for over 10 years and was also the top priority established at the 2022 National Criticality Experiments Research Center (NCERC) Futures meeting. This work will discuss how such a new capability would help ensure that the US retains international leadership in plutonium research. Last, a brief overview of Lilith, a project aimed to design a new enduring plutonium assembly for operation at the NCERC will be given.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Investigation of Correlation Methods for Use in Criticality Safety

Although their adoption by practitioners has been limited, the introduction of similarity indices in criticality safety was a major step forward in reducing the reliance on expert judgement in discerning applicable experiments for the validation of new appliations in criticality safety analyses. Similarity indices have been successfully employed in bias trending and data assimilation techniques, but it is often unclear which acceptance criteria should be used. In their 2004 paper, Broadhead et al. specify the most widely used similarity parameter, ck, as an acceptance cutoff at 0.9. (Broadhead et al., ”Sensitivity and Uncertainty-Based Criticality Safety Validation Techniques,” Nucl. Sci. Eng. 146, 340–366, 2004). Experiments with a ck < 0.9 are often not considered applicable for code validation. This heuristic is based on quantitative studies and engineering judgement, but in some cases, experiments with ck < 0.9 can be used to accurately estimate computational bias. This suggests that further analysis is needed to determine what components of ck are driving applicability and accuracy in bias estimation. For cases in which applicable experiments may not be available (as is the case with UF6 transport canisters), understanding what distinguishes experiments in providing adequate bias estimates aside from just the similarity index is particularly necessary. To further the goal to better interpret ck values, several visualization tools were developed to assist in the investigation of which components of ck are driving applicability.

ck↗

Development of a New Criticality Safety Training Program for College Students

Nuclear criticality safety (NCS) expertise remains a crucial workforce need within the US Department of Energy (DOE) laboratory complex. To address this challenge, a novel university/laboratory-based nuclear criticality training certificate program is being developed through a collaborative effort between the Georgia Institute of Technology, Texas A&M University, and Oak Ridge National Laboratory. This comprehensive program implements a two-tiered certification approach that combines online theoretical coursework with hands-on experimental training to create a sustainable pipeline of nuclear criticality specialists. The program specifically targets undergraduate and graduate students in engineering, physics, and mathematics disciplines across the United States. Through integration of fundamental nuclear physics principles, practical safety applications, and experiential learning opportunities, this initiative aims to establish a standardized pathway for developing the next generation of NCS professionals.

K-Effective↗

Adapting Grid Criticality for Data Centers

This presentation explores the evolving definition of “critical load” in the electric grid, emphasizing the growing importance of digital infrastructure—particularly data centers—in grid resilience, restoration, and modernization. As utilities increasingly rely on AI-driven analytics and software-defined control systems, data centers have shifted from passive electricity consumers to essential computational hubs that enable National Critical Functions (NCFs) and support real-time grid operations. The deck examines the scale and impact of digital loads, the need for grid modernization to manage rapid load growth, and the diverse computing paradigms required for AI deployment. It introduces a tiered taxonomy for classifying critical loads, highlights operational dependencies between the grid and digital infrastructure, and discusses policy implications for integrating data centers into emergency planning and restoration protocols. Through case studies and practical frameworks, the presentation provides actionable insights for utilities, regulators, and planners navigating the digital transformation of the power sector.

29 - ENERGY PLANNING, POLICY AND ECONOMY↗

Pilot-Scale Modular Research Facility for Acidic Water Pollution Cleanup and Domestic Production of Critical Minerals for National Security

A recent study by Penn State researchers revealed that Pennsylvania AMD streams originate from abandoned mines, with coal refuse piles of the lower Kittanning coal seam containing the most valuable heavy rare earth elements. Penn State has developed a three-stage process to recover these critical minerals, tested it for proof of concept, and secured a patent. Funded by the US DOE, a modular pilot-scale research and development unit has been designed and built to process 1,000 gallons per day of AMD from a site managed by the Pennsylvania Department of Environmental Protection (PA DEP). The system will selectively recover iron, aluminum, rare earth elements, and cobalt-nickel-manganese concentrates from AMD, followed by a proprietary downstream purification process. These operations aim to produce concentrates of critical minerals while treating acid mine drainage to meet environmental standards and evaluate different feedstocks. This presentation will describe the design, operation, and innovations of the proposed process and pilot facility, emphasizing its role in promoting sustainable recovery of critical minerals from legacy waste streams.

Pisupati, Sarma V [Center for Critical Minerals, T↗

Adapting CLUTCH methodology to multigroup TSUNAMI-3D for eigenvalue sensitivity calculations

The sensitivity of the eigenvalue to uncertainties in nuclear data and its evaluation are important for nuclear criticality safety. TSUNAMI-3D sequences within the SCALE code system offer several options to the user community for calculating eigenvalue sensitivity coefficients with multigroup (MG) and continuous energy (CE) 3D transport capabilities. TSUNAMI-3D sequences implement the adjoint-based perturbation theory with MG KENO code, the Contributon Linked eigenvalue sensitivity/Uncertainty estimation via Track length importance CHaracterization (CLUTCH) method with CE KENO code, and the Iterated Fission Probability (IFP) method with CE KENO and Shift codes. Each method has benefits and limitations depending on the problem that is run. The work presented here aims to adapt the CLUTCH method, which enables the Contributon method's mesh-free, memory-efficient approach for calculating adjoint-weighted tallies for sensitivity calculations, to the MG TSUNAMI-3D sequence. This application would eliminate the explicit adjoint KENO calculation, as well as the memory-consuming mesh flux moment tallies required by the conventional MG TSUNAMI-3D. Smaller memory footprints in the CLUTCH methodology and relatively shorter runtimes in MG KENO transport can make MG TSUNAMI-3D a viable method for some complex problems. Moreover, this adaptation allows MG sensitivity calculations with Shift, ORNL's next-generation high-performance Monte Carlo transport code, which currently does not offer any sensitivity capabilities with MG particle transport simulations. Initial implementation of the new MG TSUNAMI-3D sequence and its preliminary results with a selected critical benchmark experiment in the Verified, Archived Library of Inputs and Data (VALID) are presented in this study.

KENO↗