Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Contamination Control Process”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
DOE OSTI2012

RAPID RADIOCHEMICAL ANALYSES IN SUPPORT OF FUKUSHIMA NUCLEAR ACCIDENT

There is an increasing need to develop faster analytical methods for emergency response, including emergency soil and air filter samples. The Savannah River National Laboratory (SRNL) performed analyses on samples received from Japan in April, 2011 as part of a U.S. Department of Energy effort to provide assistance to the government of Japan, following the nuclear event at Fukushima Daiichi, resulting from the earthquake and tsunami on March 11, 2011. Of particular concern was whether it was safe to plant rice in certain areas (prefectures) near Fukushima. The primary objectives of the sample collection, sample analysis, and data assessment teams were to evaluate personnel exposure hazards, identify the nuclear power plant radiological source term and plume deposition, and assist the government of Japan in assessing any environmental and agricultural impacts associated with the nuclear event. SRNL analyzed approximately 250 samples and reported approximately 500 analytical method determinations. Samples included soil from farmland surrounding the Fukushima reactors and air monitoring samples of national interest, including those collected at the U.S. Embassy and American military bases. Samples were analyzed for a wide range of radionuclides, including strontium-89, strontium-90, gamma-emitting radionuclides, and plutonium, uranium, americium and curium isotopes. Technical aspects of the rapid soil and air filter analyses will be described. The extent of radiostrontium contamination was a significant concern. For {sup 89,90}Sr analyses on soil samples, a rapid fusion technique using 1.5 gram soil aliquots to enable a Minimum Detectable Activity (MDA) of <1 pCi {sup 89,90} Sr /g of soil was employed. This sequential technique has been published recently by this laboratory for actinides and radiostrontium in soil and vegetation. It consists of a rapid sodium hydroxide fusion, pre-concentration steps using iron hydroxide and calcium fluoride precipitations, followed by Sr-Resin separation and gas flow proportional counting. To achieve a lower detection limit for analysis of some of the Japanese soil samples, a 10 gram aliquot of soil was taken, acid-leached and processed with similar preconcentration chemistry. The MDA using this approach was ~0.03 pCi/g (1.1 mBq/g)/, which is less than the 0.05-0.10 pCi/g {sup 90}Sr levels found in soil as a result of global fallout. The chemical yields observed for the Japanese soil samples was typically 75-80% and the laboratory control sample (LCS) and matrix spike (MS) results looked very good for this work Individual QC results were well within the ± 25% acceptable range and the average of these results does not show significant bias. Additional data for a radiostrontium in soil method for 50 gram samples will also be presented, which appears to be a significant step forward based on looking at the current literature, with higher chemical yields for even larger sample aliquots and lower MDA. Hou et al surveyed a wide range of separation methods for Pu in waters and environmental solid samples. While there are many actinide methods in the scientific literature, few would be considered rapid due to the tedious and time-consuming steps involved. For actinide analyses in soil, a new rapid method for the determination of actinide isotopes in soil samples using both alpha spectrometry and inductively-coupled plasma mass spectrometry was employed. The new rapid soil method utilizes an acid leaching method, iron/titanium hydroxide precipitation, a lanthanum fluoride soil matrix removal step, and a rapid column separation process with TEVA Resin. The large soil matrix is removed easily and rapidly using these two simple precipitations with high chemical recoveries and effective removal of interferences. Vacuum box technology and rapid flow rates were used to reduce analytical time. Challenges associated with the mineral content in the volcanic soil will be discussed. Air filter samples were reported within twenty-four (24) hours of receipt using rapid techniques published previously. The rapid reporting of high quality analytical data arranged through the U.S. Department of Energy Consequence Management Home Team was critical to allow the government of Japan to readily evaluate radiological impacts from the nuclear reactor incident to both personnel and the environment. SRNL employed unique rapid methods capability for radionuclides to support Japan that can also be applied to environmental, bioassay and waste management samples. New rapid radiochemical techniques for radionuclides in soil and other environmental matrices as well as some of the unique challenges associated with this work will be presented that can be used for application to environmental monitoring, environmental remediation, decommissioning and decontamination activities.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2018

Factorization and resummation for groomed multi-prong jet shapes

Observables which distinguish boosted topologies from QCD jets are playing an increasingly important role at the Large Hadron Collider (LHC). These observables are often used in conjunction with jet grooming algorithms, which reduce contamination from both theoretical and experimental sources. In this paper we derive factorization formulae for groomed multi-prong substructure observables, focusing in particular on the groomed D 2 observable, which is used to identify boosted hadronic decays of electroweak bosons at the LHC. Our factorization formulae allow systematically improvable calculations of the perturbative D 2 distribution and the resummation of logarithmically enhanced terms in all regions of phase space using renormalization group evolution. They include a novel factorization for the production of a soft subjet in the presence of a grooming algorithm, in which clustering effects enter directly into the hard matching. We use these factorization formulae to draw robust conclusions of experimental relevance regarding the universality of the D 2 distribution in both e+e- and pp collisions. In particular, we show that the only process dependence is carried by the relative quark vs. gluon jet fraction in the sample, no non-global logarithms from event-wide correlations are present in the distribution, hadronization corrections are controlled by the perturbative mass of the jet, and all global color correlations are completely removed by grooming, making groomed D 2 a theoretically clean QCD observable even in the LHC environment. Lastly, we compute all ingredients to one-loop accuracy, and present numerical results at next-to-leading logarithmic accuracy for e + e - collisions, comparing with parton shower Monte Carlo simulations. Results for pp collisions, as relevant for phenomenology at the LHC, are presented in a companion paper.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2014

Developmental exposure to 2,3,7,8 tetrachlorodibenzo-p-dioxin attenuates capacity of hematopoietic stem cells to undergo lymphocyte differentiation

The process of hematopoiesis, characterized by long-term self-renewal and multi-potent lineage differentiation, has been shown to be regulated in part by the ligand-activated transcription factor known as the aryl hydrocarbon receptor (AHR). 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD), a ubiquitous contaminant and the most potent AHR agonist, also modulates regulation of adult hematopoietic stem and progenitor cell (HSC/HPC) homeostasis. However, the effect of developmental TCDD exposure on early life hematopoiesis has not been fully explored. Given the inhibitory effects of TCDD on hematopoiesis and lymphocyte development, we hypothesized that in utero exposure to TCDD would alter the functional capacity of fetal HSC/HPCs to complete lymphocyte differentiation. To test this hypothesis, we employed a co-culture system designed to facilitate the maturation of progenitor cells to either B or T lymphocytes. Furthermore, we utilized an innovative limiting dilution assay to precisely quantify differences in lymphocyte differentiation between HSC/HPCs obtained from fetuses of dams exposed to 3 μg/kg TCDD or control. We found that the AHR is transcribed in yolk sac hematopoietic cells and is transcriptionally active as early as gestational day (GD) 7.5. Furthermore, the number of HSC/HPCs present in the fetal liver on GD 14.5 was significantly increased in fetuses whose mothers were exposed to TCDD throughout pregnancy. Despite this increase in HSC/HPC cell number, B and T lymphocyte differentiation is decreased by approximately 2.5 fold. These findings demonstrate that inappropriate developmental AHR activation in HSC/HPCs adversely impacts lymphocyte differentiation and may have consequences for lymphocyte development in the bone marrow and thymus later in life.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

Precipitation in pores: A geochemical frontier

This article's purpose is to review some of the recent research in which geochemists have examined precipitation of solid phases in porous media, particularly in pores a few nanometers in diameter (nanopores). While this is a “review,” it is actually more forward-looking in that the list of things about this phenomenon that we do not know or cannot control at this time is likely longer than what we do know and can control. For example, there are three directly contradictory theories on how to predict how precipitation proceeds in a medium of varying pore size, as will be discussed below. The confusion on this subject likely stems from the complexity of the phenomenon itself: One can easily clog a porous medium by inducing a rapid, homogeneous precipitation directly from solution, or have limited precipitation occur that does not affect permeability or even porosity substantially. It is more difficult to engineer mineral precipitation in order to obtain a specific outcome, such as filling all available pore space over a targeted area for the purposes of contaminant sequestration. However, breakthrough discoveries could occur in the next five to ten years that enhance our ability to predict robustly and finely control precipitation in porous media by understanding how porosity and permeability evolve in response to system perturbations. These discoveries will likely stem (at least in part) from advances in our ability to 1) perform and interpret X-ray/neutron scattering experiments that reveal the extent of precipitation and its locales within porous media (Anovitz and Cole 2015, this volume), and 2) utilize increasingly powerful simulations to test concepts and models about the evolution of porosity and permeability as precipitation occurs (Steefel et al. 2015, this volume). A further important technique to isolate specific phenomena and understand reactivity is also microfluidics cell experiments that allow specific control of flow paths and fluid velocities (Yoon et al. 2012). An improved ability to synthesize idealized porous media will allow for tailored control of pore distributions, mineralogy and will allow more reproducible results. This in turn may allow us to isolate specific processes without the competing and obfuscatory effects that hinder generalization of observations when working with solely natural samples. It is likely that no one single experiment, or simulation technique will provide the key discoveries: to make substantive progress will require a collaborative effort to understand the interplay between fluid transport and geochemistry. Finally, where rock fracturing and elevated pressures are of concern, an understanding and capability to model geomechanical properties are necessary (Scherer 1999).

58 GEOSCIENCES↗
DOE OSTI2013

Rapid Radiochemical Analyses in Support of Fukushima Nuclear Accident - 13196

There is an increasing need to develop faster analytical methods for emergency response, including emergency soil and air filter samples [1, 2]. The Savannah River National Laboratory (SRNL) performed analyses on samples received from Japan in April, 2011 as part of a U.S. Department of Energy effort to provide assistance to the government of Japan, following the nuclear event at Fukushima Daiichi, resulting from the earthquake and tsunami on March 11, 2011. Of particular concern was whether it was safe to plant rice in certain areas (prefectures) near Fukushima. The primary objectives of the sample collection, sample analysis, and data assessment teams were to evaluate personnel exposure hazards, identify the nuclear power plant radiological source term and plume deposition, and assist the government of Japan in assessing any environmental and agricultural impacts associated with the nuclear event. SRNL analyzed approximately 250 samples and reported approximately 500 analytical method determinations. Samples included soil from farmland surrounding the Fukushima reactors and air monitoring samples of national interest, including those collected at the U.S. Embassy and American military bases. Samples were analyzed for a wide range of radionuclides, including strontium-89, strontium-90, gamma-emitting radionuclides, and plutonium, uranium, americium and curium isotopes. Technical aspects of the rapid soil and air filter analyses will be described. The extent of radiostrontium contamination was a significant concern. For {sup 89,90}Sr analyses on soil samples, a rapid fusion technique using 1.5 gram soil aliquots to enable a Minimum Detectable Activity (MDA) of <1 pCi {sup 89,90}Sr /g of soil was employed. This sequential technique has been published recently by this laboratory for actinides and radiostrontium in soil and vegetation [3, 4]. It consists of a rapid sodium hydroxide fusion, pre-concentration steps using iron hydroxide and calcium fluoride precipitations, followed by Sr-Resin separation and gas flow proportional counting. To achieve a lower detection limit for analysis of some of the Japanese soil samples, a 10 gram aliquot of soil was taken, acid-leached and processed with similar preconcentration chemistry. The MDA using this approach was ∼0.03 pCi/g (1.1 mBq/g)/, which is less than the 0.05-0.10 pCi/g {sup 90}Sr levels found in soil as a result of global fallout. The chemical yields observed for the Japanese soil samples was typically 75-80% and the laboratory control sample (LCS) and matrix spike (MS) results looked very good for this work Individual QC results were well within the ± 25% acceptable range and the average of these results does not show significant bias. Additional data for a radiostrontium in soil method for 50 gram samples will also be presented, which appears to be a significant step forward based on looking at the current literature, with higher chemical yields for even larger sample aliquots and lower MDA [5, 6, 7] Hou et al surveyed a wide range of separation methods for Pu in waters and environmental solid samples [8]. While there are many actinide methods in the scientific literature, few would be considered rapid due to the tedious and time-consuming steps involved. For actinide analyses in soil, a new rapid method for the determination of actinide isotopes in soil samples using both alpha spectrometry and inductively-coupled plasma mass spectrometry was employed. The new rapid soil method utilizes an acid leaching method, iron/titanium hydroxide precipitation, a lanthanum fluoride soil matrix removal step, and a rapid column separation process with TEVA Resin. The large soil matrix is removed easily and rapidly using these two simple precipitations with high chemical recoveries and effective removal of interferences. [9, 10] Vacuum box technology and rapid flow rates were used to reduce analytical time. Challenges associated with the mineral content in the volcanic soil will be discussed. Air filter samples were reported within twenty-four (24) hours of receipt using rapid techniques published previously. [11] The rapid reporting of high quality analytical data arranged through the U.S. Department of Energy Consequence Management Home Team was critical to allow the government of Japan to readily evaluate radiological impacts from the nuclear reactor incident to both personnel and the environment. SRNL employed unique rapid methods capability for radionuclides to support Japan that can also be applied to environmental, bioassay and waste management samples. New rapid radiochemical techniques for radionuclides in soil and other environmental matrices as well as some of the unique challenges associated with this work will be presented that can be used for application to environmental monitoring, environmental remediation, decommissioning and decontamination activities. (authors)

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Use of Multiple Remote Systems for Calcine Retrieval Operations at Idaho - 16592

There are approximately 5000 m{sup 3} of radioactive calcine material stored in six Calcine Solids Storage Facilities (CSSFs) at the DOE Idaho site. Each CSSF contains from three to twelve stainless steel tanks surrounded by a concrete vault. In accordance with the Idaho Settlement Agreement (ISA), this waste has to be retrieved and immobilized by December 31 2035 although no final decision has yet been made on how the calcine wastes are going to be retrieved from the CSSF's. One of the primary issues with the retrieval is that, in accordance with the ISA, any existing risers into the tanks have to be used 'to the maximum extent possible' in the retrieval process. Since these risers are only 6-8'' in diameter, this limits the types of systems that can be used for the retrieval. In addition, each bin containing the calcine has a series of obstructions which need to be navigated around and so inflexible systems such as conventional hose-based vacuum type systems are not feasible. In addition, the retrieval system selected has to be able to manage multiple forms of calcine (powder, granular, agglomerated, chunks etc) and operate in a very highly radioactive environment. This paper describes the progress made to date in developing an approach based on the use of multiple remote system platforms to gain entry into the bin-sets and to safely and cost-effectively retrieve the calcine wastes. Much of the work has focused on the application of the OC Robotic snake-arm robot system although significant effort has also been allocated to understanding the deployment mechanism of the snake-arm and to the ancillary supporting systems such as those for contamination control, cutting and welding new risers into the bin-sets and vacuum hose management within the bin-set. Future work will include the construction of a scaled mock up to demonstrate the field implementation of the system. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Colonie, New York, FUSRAP Site: Pathway from Remediation to Redevelopment - 19465

The Colonie, New York, Formerly Utilized Sites Remedial Action Program (FUSRAP) Site consists of a 4.5-hectare (11.2-acre) US Department of Energy (DOE)-owned vacant property (Main Site) and 56 commercial and residential vicinity properties (VPs). The site was owned and operated by National Lead Industries (NL) from 1937 to 1984. The Main Site was used for manufacturing fuel and weapons components using uranium and thorium. Depleted uranium dust was emitted from exhaust stacks that contaminated the site and the VPs. NL also filled in portions of the site with industrial waste and released contaminants to groundwater. The state court shut the plant down in 1984. The site was acquired by DOE in 1985, which remediated the VPs and began to remediate the Main Site up to 1997. The US Army Corps of Engineers (USACE) undertook remedial actions beginning in 1997. The site has three Operable Units (Main Site, Groundwater, and VPs). The Main Site soil was remediated to residential standards except for three small easement areas. The soils in the easement areas are safe for exposure to workers. There is a groundwater plume beneath the site that will require the use of monitoring and temporary land use controls until cleanup standards are met. The VPs require no further action. A 2-year transition period from USACE to the DOE Office of Legacy Management (LM) began on June 18, 2018, with the receipt of the Site Closeout Report from USACE. LM has determined that the 4.5-hectare site is excess to its mission needs and intends to pursue sale of the property for redevelopment. There are several processes required before the disposal can occur. Organizations with similar sites that are federally owned and ready for private redevelopment may benefit from reviewing the Colonie site disposition processes. This paper will discuss (1) Determining disposal alternatives for the Colonie, New York, site. (2) Describing the federal requirements for the disposal of excess real property. (3) Communicating to stakeholders that the site is ready for disposal. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Effect of electrode manufacturing defects on electrochemical performance of lithium-ion batteries: Cognizance of the battery failure sources

During LIB electrode manufacturing, it is difficult to avoid the certain defects that diminish LIB performance and shorten the life span of the batteries. This study provides a systematic investigation correlating the different plausible defects (agglomeration/blisters, pinholes/divots, metal particle contamination, and non-uniform coating) in a LiNi 0.5 Mn 0.3 Co 0.2 O 2 positive electrode with its electrochemical performance. Additionally, an infrared thermography technique was demonstrated as a nondestructive tool to detect these defects. The findings show that cathode agglomerates aggravated cycle efficiency, and resulted in faster capacity fading at high current density. Electrode pinholes showed substantially lower discharge capacities at higher current densities than baseline NMC 532 electrodes. Metal particle contaminants have an extremely negative effect on performance, at higher C-rates. The electrodes with more coated and uncoated interfaces (non-uniform coatings) showed poor cycle life compared with electrodes with fewer coated and uncoated interfaces. Further, microstructural investigation provided evidence of presence of carbon-rich region in the agglomerated region and uneven electrode coating thickness in the coated and uncoated interfacial regions that may lead to the inferior electrochemical performance. In conclusion, this study provides the importance of monitoring and early detection of the electrode defects during LIB manufacturing processes to minimize the cell rejection rate after fabrication and testing.

25 ENERGY STORAGE↗
DOE OSTI2023

Total metals, carbon, nitrogen & anion concentration data; Slate River & East River floodplains, Crested Butte, CO; May 2022-October 2022

This data package includes processed and undiluted measurements for metal, total carbon, total nitrogen, and anion concentrations from pore water (groundwater) and surface water samples from the Slate River and East River floodplains of Crested Butte, CO, focus field sites for the SLAC Floodplain Hydro-Biogeochemistry SFA. The data was generated as part of the work targeting the overarching research question for the SLAC SFA: How do ubiquitous subsurface interfaces mediate molecular-scale biogeochemical processes and groundwater quality in floodplains and watersheds? Samples were collected between May and October of 2022. These measurements were all recorded at the Arizona Laboratory for Emerging Contaminants (ALEC) at the University of Arizona located in Tucson, AZ. Groundwater samples were extracted from a network of installed rhizon (Rhizosphere Research Products, part no. 19.60.21F, 0.6 micrometer mesh size) and piezometer wells within the river floodplain. All water samples were shaded from sun exposure during extraction from the subsurface and preserved at 4C until measured at ALEC.Analysis by ICP-MS (metals):Measurements for total metals were made on the Agilent 7700x ICP-MS (for total metals) – Agilent Technologies, Santa Clara, CA. The analytical QA/QC protocol was adapted from US EPA Method 200.8 for analysis by ICP-MS. Calibration standards were prepared from multi-element stock solutions (SPEX Certiprep, Metuchen, NJ). Calibration curves include at least 7 points with correlation coefficients > 0.995. The QC protocol includes a continuing calibration blank (CCB), a continuing calibration verification (CCV) solution and at least one quality control sample (QCS) to be analyzed just after calibration and again after every 12 samples and at the completion of the run. The QCS solutions are from an independent source, such as NIST SRM 1643e - Trace elements in water, or QCS solutions from High Purity Standards (Charleston, SC). Acceptable QC responses must be between 90 and 110% of the certified value. Lastly, a suitable internal standard (usually Rh, In, Ga or Ge) is added using on-line addition into the sample line and mixing tee.Analysis by Shimadzu TOC-L (TOC/TN):The TOC-L system is a combustion technique where liquid samples are injected and combusted into CO2 for carbon detection by non-dispersive infrared (NDIR) and NO for detection by chemiluminescence. A calibration curve using five standard solutions between 0.1 and 7 ppm for carbon and 0.05 and 3.5 ppm for nitrogen is made for each type of measurement with a linearity >0.99. All samples, standards, and QC’s are prepared in 24mL scintillation vials that have been baked for 4hrs at 475 Cº and made using RO water (18.2mΩ). QC’s include a calibration blank check (CCB), continuing calibration check (CCC), and a certified reference material check (CRM). All QC’s are within ±10% error and are run before and after each batch of samples. Samples are diluted and rerun if any measurement concentrations are above the highest standard.Analysis by Ion Chromatography (Anions):The instrument used is the Thermo Scientific Dionex ICS-6000 using AS+AG22 column set for anion analysis with sodium carbonate eluent. A calibration curve using five standard solutions between 5 and 250 umol/L is made with a linearity >0.99. Standards and QC’s are prepared in 15mL polypropylene conical tubes, pipetted along with the samples into 1.5mL polypropylene vials. Dilutions are made using RO water (18.2mΩ). QC’s include a calibration blank check (CCB), continuing calibration check (CCC), and a certified reference material check (CRM). All QC’s are within ±10% error and are run before and after each batch of samples. Samples are diluted and rerun if any measurement concentrations are above the highest standard.All files are in csv format.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Ambient vapor sampling and selective cluster formation for the trace detection of tributyl phosphate via atmospheric flow tube mass spectrometry

In addition to serving as an f-element ligand and rare-earth method complexing agent, tributyl phosphate (TBP) is a compound containing core functional groups that mimic those routinely found in degradation products from industrial processes. Because detection of trace quantities of TBP can provide insight into the routes of contamination and degradation in the environment, there is a need to develop methods capable of detecting trace quantities of TBP. Vapor detection at atmospheric pressure is one approach that is both sensitive and rapid. We present here the use of atmospheric flow tube mass spectrometry (AFT-MS) for the ambient vapor sampling of TBP from headspace of ppb-level solutions in methanol. Gas phase clustering reactions were to enhance detection levels via the addition of small quantities of the dopants diethylamine (DEA), triethylamine (TEA), and pinacolyl methylphosphonate (PMP) in the vapor stream. Detection of the TBP vapor emanating from these solutions demonstrated a linear range for the protonated TBP species of 1-1000 ppb from solution. The clusters of TBP with DEA, TEA, and PMP each yielded linear ranges of 1-250 ppb for TBP in solution. Despite smaller linear ranges, the addition of these dopant species added a layer of analytical selectivity and reduced variability in signals from quality control samples. These data were obtained using an AFT source coupled to a linear ion trap mass spectrometer, which demonstrates the applicability of trapping systems to the AFT ionization technique while monitoring positive ions.

Ambient vapor sampling, Dielectric barrier dischar↗
DOE OSTI2019

Evolution of Stakeholder Relations at the Mound Laboratory-End of DoE's Mission to the Present - 19551

In November 1989, the same month the Berlin Wall fell, the US Environmental Protection Agency (EPA) placed the Mound Laboratory (Mound Plant or Mound site) in Ohio on the National Priorities List (NPL) due to volatile organic compound contamination in the groundwater. As a result of the Cold War ending, the United States sought to greatly reduce the nation's nuclear weapons arsenal, consolidate the US Department of Energy's (DOE) mission, and close many DOE facilities. In 1991, the City of Miamisburg learned that DOE was planning to close the Mound Laboratory. The city spent two years lobbying in Washington, DC, to keep the facility open; however, that effort was not successful. By 1993, DOE, EPA, and Ohio EPA had signed a Federal Facility Agreement that formalized EPA and Ohio EPA oversight of the DOE environmental cleanup of the Mound NPL site under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). The decontamination and cleanup of the Mound site fell under two federal laws, CERCLA and the Resource Conservation and Recovery Act. DOE, EPA, Ohio EPA, the City of Miamisburg, and other local stakeholders all agreed that the Mound site should be cleaned up to an industrial/commercial land use standard. This would allow the site to transition into a privately owned business park. In 1994, the City of Miamisburg created the nonprofit Miamisburg Mound Community Improvement Corporation (MMCIC) that would own, market, and redevelop the site. The City also chartered the Mound Reuse Committee to act as an independent advisory organization, composed of representatives from the local community and business, government, education, and special interest groups. In 1994, DOE and the MMCIC entered into a lease agreement that facilitated immediate reuse of site buildings that were no longer required by DOE and did not require remediation. In 1995, DOE, EPA, and Ohio EPA developed the Mound 2000 Process to more effectively use CERCLA Removal Action authority to evaluate and remediate, as necessary, disparate areas of the Mound site. The Mound 2000 process divided the site into smaller, more manageable areas that accelerated cleanup and allowed areas to be reused more quickly. All areas of the Mound site were cleaned up to meet the EPA standard for industrial/commercial land use. The CERCLA process included opportunities for the public to review proposed cleanup strategies. Public input on cleanup and reuse included that from local citizens, businesses, Miamisburg City Council, local schools and financial institutions, Ohio EPA, Montgomery County, and the State of Ohio. In 1998, while site cleanup was still in process, DOE agreed to sell the entire Mound property to the MMCIC for $10.00. The site sales agreement accelerated reuse by allowing DOE to offer ownership of discrete land parcels to MMCIC as soon as EPA confirmed those areas met CERCLA standards for property transfer. This allowed the Mound site to become one of the first former DOE weapons sites to transition to reuse as a privately owned and operated community asset. Many other former DOE production facilities require continued federal ownership to protect the integrity of the environmental cleanup. In 2011, the MMCIC changed its name to the Mound Development Corporation (MDC) and continued to transition the site for reuse as part of the Mound Business Park. The MMCIC/MDC is a nonprofit economic development arm of the City of Miamisburg. DOE supported the economic development efforts with grants and matching funds. Individual land parcels were transferred from DOE to the MDC according to the DOE Mound Land Transfer Process. Ownership of parcels was transferred to the MDC via quitclaim deeds with no repair, replacements, or rebuild of areas. Each parcel's quitclaim deed contains the CERCLA institutional controls. To reduce the property tax burden, the Miamisburg City Council passed an ordinance that allowed the City to accept temporary ownership of specific parcels and hold ownership until the MDC could either lease or sell them. With the exception of one 23-acre parcel that includes the Operable Unit 1 area (site of former sanitary landfill), the entire site has been transferred to the MDC. Today, the former Mound Laboratory site is home to the vibrant Mound Business Park operated by the MDC. The site contains numerous buildings with active businesses and multiple areas suitable for new construction. Private companies continue cutting-edge work that carries forward the legacy of more than 50 years of DOE research, development, production, and inspiration from the former Mound Laboratory scientists, engineers, technicians, and support personnel. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Rapid denitrification of nitrate-contaminated groundwater in a low-gradient blackwater stream valley

Leaching of excess nitrogen (N) to groundwater in fertilized landscapes can overwhelm natural biogeochemical processes and cause long-term eutrophication of aquatic systems. We investigated N fate and transport from an intensively managed short-rotation woody crop (Pinus taeda) plantation through the riparian zone of an intermittent, low-gradient blackwater stream. Fertilization of the P. taeda plantation on the uplands resulted in contamination of groundwater with nitrate concentrations between 0.9 and 1.9 mg N L -1 . No corresponding increase in nitrate was observed in stream water or shallow groundwater in the riparian zone. Groundwater travel-time modeling predicted that N from near-stream, upland plantation areas should have reached streams during the monitoring period. Two years of measuring N species in well water in contrasting landscape positions (within the plantation, swale, riparian edge, forested hillslope, and valley), indicated rapid nitrate transformation and denitrification within the forested wetland valleys. Denitrification in the shallow groundwater system within the toeslopes and the riparian zone was estimated to have removed > 90% of nitrate. Finally, these results highlight the importance of riparian zones as pathways for the removal of N and for controlling downstream N loads.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Predicting the effectiveness of different mulching techniques in reducing post-fire runoff and erosion at plot scale with the RUSLE, MMF and PESERA models

Highlights: • RUSLE, MMF and PESERA, were able to predict the erosive response in burned areas and their mitigation. • These models can be calibrated at a small spatial scale and provide accurate results at greater spatial scales. • RUSLE model ideal for fast and simple risk assessment. • MMF or PESERA models could be the base of a post-fire management decision tool. Wildfires have become a recurrent threat for many Mediterranean forest ecosystems. The characteristics of the Mediterranean climate, with its warm and dry summers and mild and wet winters, make this a region prone to wildfire occurrence as well as to post-fire soil erosion. This threat is expected to be aggravated in the future due to climate change and land management practices and planning. The wide recognition of wildfires as a driver for runoff and erosion in burnt forest areas has created a strong demand for model-based tools for predicting the post-fire hydrological and erosion response and, in particular, for predicting the effectiveness of post-fire management operations to mitigate these responses. In this study, the effectiveness of two post-fire treatments (hydromulch and natural pine needle mulch) in reducing post-fire runoff and soil erosion was evaluated against control conditions (i.e. untreated conditions), at different spatial scales. The main objective of this study was to use field data to evaluate the ability of different erosion models: (i) empirical (RUSLE), (ii) semi-empirical (MMF), and (iii) physically-based (PESERA), to predict the hydrological and erosive response as well as the effectiveness of different mulching techniques in fire-affected areas. The results of this study showed that all three models were reasonably able to reproduce the hydrological and erosive processes occurring in burned forest areas. In addition, it was demonstrated that the models can be calibrated at a small spatial scale (0.5 m{sup 2}) but provide accurate results at greater spatial scales (10 m{sup 2}). From this work, the RUSLE model seems to be ideal for fast and simple applications (i.e. prioritization of areas-at-risk) mainly due to its simplicity and reduced data requirements. On the other hand, the more complex MMF and PESERA models would be valuable as a base of a possible tool for assessing the risk of water contamination in fire-affected water bodies and for testing different land management scenarios.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Tin Oxynitride Anodes by Atomic Layer Deposition for Solid-State Batteries

Major advances in thin-film solid-state batteries (TFSSBs) may capitalize on 3D structuring using high-aspect-ratio substrates such as nanoscale pits, pores, trenches, flexible polymers, and textiles. This will require conformal processes such as atomic layer deposition (ALD) for every active functional component of the battery. In this paper, we explore the deposition and electrochemical properties of SnO 2 , SnN y , and SnO x N y thin films as TFSSB anode materials, grown by ALD using tetrakisdimethylamido(tin), H 2 O, and N 2 plasma as precursors. By controlling the dose ratio between H 2 O and N 2 , the N–O fraction can be tuned between 0% N and 95% N. The electrochemical properties of these materials were tested across a composition range varying from pure SnO 2 , to SnON intermediates, and pure SnNy. In TFSSBs, the SnNy anodes are found to be more stable during cycling than the SnO 2 or SnO x N y films, with an initial reversible capacity beyond that of Li–Sn alloying, retaining 75% of their capacity over 200 cycles compared to only 50% for SnO 2 . Lastly, the performance of the SnO x N y anodes indicates that SnN y anodes should not be negatively impacted by small levels of O contamination.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Iodine-129 and Iodine-127 speciation in groundwater at the Hanford Site, U.S.: iodate incorporation into calcite

The Hanford Site, the most contaminated nuclear site in the United States, has large radioactive waste plumes containing high 129I levels. The geochemical transport and fate of radioiodine depends largely on its chemical speciation that is greatly affected by environmental factors. This study reports, for the first time, the speciation of stable and radioactive iodine in the groundwater from the Hanford Site. Iodate was the dominant species and accounts for up to 84%, followed by organo-iodine and minimal levels of iodide. The relatively high pH and oxidizing environment may have prevented iodate reduction. Our results identified that calcite precipitation caused by degassing of CO2 during deep groundwater sampling incorporated between 7 to 40% of dissolved iodine (including 127I and 129I) that was originally in the groundwater, transforming dissolved to particulate iodate during sampling. In order to understand the mechanisms underlying iodine incorporation by calcite, laboratory experiments were carried out to replicate this iodine sequestering processes. Two methods were utilized in this study, 1) addition of sodium carbonate; 2) addition of calcium chloride followed by sodium carbonate where the pH was well controlled at ~8.2, which is close to the average pH of Hanford Site groundwater. It was demonstrated that iodate was the main species incorporated into calcite and this incorporation process could be impeded by elevated pH and decreasing ionic strength in groundwater. This study provides critical information for predicting the long-term fate and transport of 129I at the Hanford Site and reveals a potential means for improved remediation strategies of 129I.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Deposition of novel nanocomposite films by a newly developed differential pumping co-sputtering system

A differential pumping co-sputtering system was developed to facilitate a controlled, but flexible fabrication of multifunctional nanocomposite films with compositions not limited by thermodynamic restrictions. This system features a multichamber design with a differential pumping system. Dividing atmospheres with this set up greatly reduced the cross-contamination between chambers, and each material could be co-deposited by rapid rotation of the substrate. The clearance between the substrate holder and the chamber was set at 1-2 mm, and the conductance of the clearance was examined roughly using conductance equations for typical types of orifices. It was found that the potential difference (PD) value of the clearance between the two chambers was less than 0.01; the gas flow between the two chambers through the clearance thus appears to be a practical molecular flow. The PD value, where P is a pressure (Pa) and D is a diameter of an orifice or a pipe (m), is a gas flow indicator or parameter obtained from an equation of Knudsen number. The changes in the oxygen partial pressure and glow discharge plasma in the left chamber were investigated using a process gas monitor (PGM) and optical emission spectroscope (OES) by introducing different gases to each chamber. The PGM results revealed that the cross-contamination of oxygen from the other chamber was suppressed to 10 {+-} 3% of the original. In addition, the OES measurement for glow discharge plasma did not detect substantial oxygen contamination from the other chamber. Using the newly developed system, an AlN/SiO{sub x} nanocomposite film consisting of B4-type AlN and amorphous SiO{sub x} was obtained successfully.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Development of In-Situation Radioactivity Inspection System for Food Materials

The impacts on the ocean of releases of radionuclides from the Fukushima nuclear power plants remain unclear. Korean people worry about radioactive contamination of Japanese and Korean sea products. Radioactive contamination of processed foodstuffs, livestock, sea products, farm products imported from Japan and fishes caught in coastal oceans of Korea has become an important social issue. Recently, there are also needs of inspection system for monitoring of public meals such like school feedings of kindergarten, elementary/middle/high school and university. Radioactivity inspections of food materials have been executed manually with portable measuring instruments or at labs using their samples. But, it's very important the radioactivity inspection should be performed at the field of feeding facilities. To protect the health of people from radioactivity contained in Japanese marine products imported to Korea, a system to inspect radioactivity in real time has been developed. The system is to measure the radioactivity level of farm and marine products and public meals continuously and automatically at inspection sites of an agency checking radiation of imported foodstuffs or school. The performance test of NaI(Tl) detector was examined using the quantified Cs-137 source 10 Bq/kg, 30 Bq/kg, 50 Bq/kg, 300 Bq/kg and 900 Bq/kg at Korea Research Institute of Standards and Science(KRISS). Source was put in a box and radioactivity was measured in the middle of the box. First of all, Background was measured and calibration was performed using the Cs-137 300 Bq and Ba-133 3700 Bq for 60 minutes. After setting the background and calibration data, tests of the Cs-137 10, 30, 50, 300, 900 Bq/kg were executed for 10 minutes. A peak-shaped graph is shown at the location of 662 KeV (80∼100 channel). This is due to the gamma radiation energy with 662 KeV emitted by the Cs-137. Because through KRISS examination, the MDA (minimum detectable activity) is about 23 Bq/kg, it is reasonable Cs-137 10 Bq/kg cannot be measured. And in cases of Cs-137 300 Bq/kg and 900 Bq/kg, there are some peak movement on the graph. It can be adjusted by controlling gain or high voltage. The examination was identified through the performance test (Cs-137 10, 30, 50, 300, 900 Bq/kg) at KRISS. In order to increase the measurement efficiency of Cs-137 and the system performance, database will be built up based on radioactivity measurement results from 10 to 300 Bq/kg with the unit 10. Thus, Cs-137 concentration of food materials can be identified below the maximum permissible concentration of 100 Bq/kg on a basis of the spectrum characteristic of Cs-137. Also, anxiety about radioactive contamination of foods after the Fukushima nuclear accident will be eased and trust of the radioactive inspection is expected definitely. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2025

Montane Conifer, Aspen, Meadow, and Sagebrush Metagenome Resolved Genomes and Traits in East River Watershed, Colorado, USA

Climate change is driving vegetation shifts in mountain watersheds, with unknown impacts on biogeochemical cycles. We hypothesize that these shifts will reshape soil microbiomes and associated biogeochemical processes. As a part of Lawrence Berkeley National Laboratory (LBNL) Watershed Science Focus Area (SFA), we assessed microbiome and microbial functional trait differences between soils under conifer, aspen, forby meadows, and sagebrush across the East River Watershed, CO, controlling for elevation and aspect.Here we present metagenome assembled genomes (MAGs) for the bacterial and archaeal communities from soils 0-20cm in depth across three locations in the watershed—Headwaters, Upper Reaches, and Lower Reaches from August 3-11th 2016. Each location was further subdivided into two blocks, with one block on a west facing aspect, and two on the east aspect of the valley. Within blocks, two samples per vegetation type were taken (one at each depth). This resulted in 66 samples, which were sequenced at JGI and can be found under the Joint Genome Institute (JGI) Genomes Online Database (GOLD) sequencing project Gs0118068. Metagenomes were assembled through an inhouse pipeline (see methods), binned using four autobinners (concoct, maxbin2, metabat2, and vamb) and consolidated using dastool. The consolidated bins from all metagenomes were pooled, filtered by completeness (>75%) and contamination (<25%), and dereplicated at 95% ANI using drep. The dataset includes a zip file of 687 genomes (Vegtype_MAGS.zip), the accession numbers for the underlying metagenomes, a csv file with MAG quality metrics and taxonomy from Genome Taxonomy Database (GTDB) and National Center for Biotechnology Information (NCBI) taxonomic representative genome proteins (EastRiver_Vegtype_drep_genome_info.csv), and a file containing MAG quality metrics and taxonomy (gtdb_drep_bin_taxonomy.csv). The dataset additionally includes a sample metadata file (EastRiver_Vegtype_sample_metadata.csv), a metadata file used to register associated samples with IGSNs (International Generic Sample Numbers) (samples.csv), a Google KML file for the sampled locations (sample_collection_sites.kml), a location metadata file (locations.csv), a file-level metadata file (flmd.csv), and a data dictionary (dd.csv) file.This work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231.

54 ENVIRONMENTAL SCIENCES↗