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At least 487 records · Page 27

Low-light video observations of frequent luminous structures in the stratosphere above thunderstorms

A new series of video measurements were made of the phenomenon provisionally termed the cloud-to-stratosphere (CS) event, an electrical discharge extending to great heights above thunderstorm tops. This new series of measurements were accomplished by properly positioning a sensor, the Xybion model ISS 225 low-light monochrome imaging system with a C-mount fl.8 manual zoom lens, and training it on the appropriate portion of the sky above a distant thunderstorm complex mean Fort Collins, Colorado. The resulting images are currently undergoing intensive analysis. Some tentative conclusions are given. Cloud-to-stratosphere events occur far more frequently than previously suspected and are perhaps a ubiquitous aspect of many larger convective systems. Cloud-to-stratosphere events are also of substantial horizontal extent, on the order of tens of kilometers in some cases.

Lyons, Walter A.↗

SiS2 in circumstellar shells

Solid state SiS2 is proposed as the material responsible for the recently discovered 21 micrometer emission feature that is observed in the carbon-rich circumstellar shells of certain protoplanetary nebulae. Sulfurized SiC, or SiS2 mantles on grains of either SiC or a:C-H are discussed as possible forms for which no spectroscopic laboratory observations yet exist. The identification with a relatively minor species and required special abundance ratios are consistent with the low incidence rate that the 21 micrometer feature presents in the population of carbon rich objects. It is also consistent with the lack of a good correlation between the 21 micrometer feature and the other solid-state spectroscopic features that have been observed in protoplanetaries that would be expected if the feature arose from molecules composed of H, C, N, and O. SiS2 condensate is consistent with the circumstellar shell temperature range, T(sub CS) approximately equal to or less than 150 K, at which the feature appears, and the available mass of SiS2, M(sub SiS2) approx. = 5 x 10(exp -6) solar mass, that is possible in the circumstellar shell.

Goebel, J. H.↗

Alkali elements in the Earth's core: Evidence from enstatite meteorites

The abundances of alkali elements in the Earth's core are predicted by assuming that accretion of the Earth started from material similar in composition to enstatite chondrites and that enstatite achondrites (aubrites) provide a natural laboratory to study core-mantle differentiation under extremely reducing conditions. If core formation on the aubrite parent body is comparable with core formation on the early Earth, it is found that 2600 (+/- 1000) ppm Na, 550 (+/- 260) ppm K, 3.4 (+/- 2.1) ppm Rb, and 0.31 (+/- 0.24) ppm Cs can reside in the Earth's core. The alkali-element abundances are consistent with those predicted by independent estimates based on nebula condensation calculations and heat flow data.

Lodders, K.↗

Line formation in collapsing cloud cores with rotation and applications to B335 and IRAS 16293-2422

We present radiative transfer models of collapsing clouds with rotation and apply them to B335 and IRAS 16293-2422, the two best candidates of protostellar collapse known to date. By including rotation in the manner of Tereby, Shu, & Cassen (1984), we can reproduce the profiles of several molecular lines not only toward the center position, but also toward a grid of positions near the center. We find that the model of B335 by Zhou et al. (1993) is not affected significantly by the presence of rotation. By including rotation, we can reproduce the observations of IRAS 16293-2422 by Menden et al. (1987); hence, we support the infall interpretations of spectral lines from IRAS 16293-2422 proposed by Walker et al. (1986). We also observed the large-scale rotation of IRAS 16293-2422 in the C(18)O J = 2 approaches 1 line. The observed rotation rate is a factor of 6 smaller than that required to explain the small-scale CS data of Menden et al. (1987). This probably means the precollapse cloud has differential rotation, possibly due to more efficient magnetic braking on large scales.

Zhou, Shudong↗

Multiple outflows in the bipolar planetary nebula M1-16: A molecular line study

Extensive observations of the molecular gas in the young, compact planetary nebula M1-16 have been made, using the Swedish-ESO-Submillimeter Telescope. A map of the CO J = 2-1 emission shows that the molecular envelope contains both a slow and a fast outflow with expansion velocities of 19 km/s and greater than 34 km/s, respectively. The slow outflow is mildly elliptical, while the fast molecular outflow is bipolar. This fast outflow is roughly aligned with the very fast outflows recently found in the optical, while the long axis of the slow elliptical outflow is roughly orthogonal to the optical outflow axis. The kinematic timescales for the CO fast outflow and the optical very fast outflow agree closely, supporting the view that the former represents material in the slow outflow accelerated by the very fast outflow. The kinematic signature of a disk expanding with about 15.5 km/s can also be seen in the CO J = 2-1 data. The mass-loss rate (a) for the slow outflow is greater than or equal to 2.8 x 10(exp -5) solar mass/yr and possibly as large as 9 x 10(exp -5) solar mass/yr, (b) for the fast outflow is greater than or equal to 5 x 10(exp -6) solar mass/yr, and (c) for the very fast optically visible outflow is approximately equal 5 x 10(exp -7) solar mass/yr. The disk mass is approximately equal 6 x 10(exp -3) solar mass. Grain photoelectric heating results in temperatures of 20-70 K in molecular gas of the slow outflow. The (13)C/(12)C abundance ratio in M1-16 is found to be 0.33, quite possibly the highest found for any evolved object. Upper limits for the (18)O/(16)O and (17)O/(16)O ratios were found to be consistent with the values found in AGB stars. A search for other molecular species in M1-16 resulted in the detection of the high-excitation species HCN, CN, (13)CN, HCO(+), and H(13)CO(+) and possibly N2H(+). Both the HCO(+)/HCN and CN/HCN line-intensity ratios are enhanced, the former by a very large factor, over the values found in the envelopes of AGB stars, probably as a result of enhancement of the CN and HCO(+) abundances due to photochemistry induced by the stellar UV. The CS J = 2-1, SiO J = 2-1 (v = 0), and SiS J = 6-5 lines were not detected to low levels. For the high-excitation molecules, adequate collisional excitation of rotational levels and survival against photodissociation by the UV radiation requires significant clumping of the molecular gas into clumps with H2 densities approximately 10(exp 5)/cu cm. The IRAS fluxes of M1-16, assuming negligible contribution from line emission, imply the presence of about (1.7-0.4) x 10(exp -3) solar mass of cool dust (temperature around 50 K) and a smaller quantity, (2.7-3.1) x 10(exp -6) solar mass, of warmer dust (temperature around 125 K) for a power-law emissivity index p = 1-2. The evolutionary nature of M1-16 cannot be explained by existing single-star models of post-AGB evolution. The very high (13)C/(12)C abundance ratio in M1-16 suggests a possible evolutionary connection between M1-16 and the rare class of J-type silicate-carbon stars which also have high (13)C/(12)C ratios and are thought to be binary systems with accretion disks.

Sahai, Raghvendra↗

A molecular line study of NGC 1333/IRAS 4

Molecular line surveys and fully sampled spectral line maps at 1.3 and 0.87 mm are used to examine the physical and chemical characteristics of the extreme Class I sources IRAS 4A and 4B in the L1450/NGC 1333 molecular cloud complex. A very well collimated, jetlike molecular flow emanates from IRAS 4A, with a dynamical age of a few thousand years. Symmetric, clumpy structure along the outflow lobes suggests that there is considerable variability in the mass-loss rate or wind velocity even at this young age. Molecular emission lines toward IRAS 4A and 4B are observed to be weak in the velocity range corresponding to quiescent material surrounding the young stellar objects (YSOs). Depletion factors of 10-20 are observed for all molecules, including CO, even for very conservative mass estimates from the measured millimeter and submillimeter dust continuum. However, abundance scaled with respect to CO are similar to other dark molecular cloud cores. Such depletions could be mimicked by high dust and optical depths or increased grain emissivities at the observing frequencies of 230 and 435 GHz, but the millimeter and submillimeter spectral energy distributions suggest that this is unlikely over the single-dish size scales of 5000-10,000 AU. Dense, outflowing gas is found to be kinematically, but not spatially, distinct from the quiescent material on these size scales. If CO is used as a chemical standard for the high-velocity gas, we find substantial enhancements in abundances of several molecules in outflowing material, most notably CS, SIO, and CH3OH. The SiO emission is kinematically well displaced from the bulk cloud velocity and likely arises from directly shocked material. As is the case for CO, however, the outflow features from more volatile species are centered near the cloud velocity and are often characterized by quite low rotational temperatures. We suggest that grain-grain collisions induced by velocity shear zones surrounding the outflow axes transiently desorb the grain mantles, resulting in large abundance enhancements of selected species. Similar results have recently been obtained in several other low-mass YSOs, where outflowing gas is often both kinematically and spatailly distinct, and are illustrative of the ability of accretion and outflow processes to simultaneously modify the composition of the gas and dust surrounding young stars.

Blake, Geoffrey A.↗

Operational overview of the NASA GTE/CITE 3 airborne instrument intercomparisons for sulfur dioxide, hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, and carbon disulfide

This paper reports the overall experimental design and gives a brief overview of results from the third airborne Chemical Instrumentation Test and Evaluation (CITE 3) mission conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment. The primary objective of CITE 3 was to evaluate the capability of instrumentation for airborne measurements of ambient concentrations of SO2, H2S, CS, dimethyl sulfide, and carbonyl sulfide. Ancillary measurements augmented the intercomparison data in order to address the secondary objective of CITE 3 which was to address specific issues related to the budget and photochemistry of tropospheric sulfur species. The CITE 3 mission was conducted on NASA's Wallops Flight Center Electra aircraft and included a ground-based intercomparison of sulfur standards and intercomparison/sulfur science flights conducted from the NASA Wallops Flight Facility, Wallops Island, Virginia, followed by flights from Natal, Brazil. Including the transit flights, CITE 3 included 16 flights encompassing approximately 96 flight hours.

Hoell, James M., Jr.↗

Chemical studies of H chondrites. 4: New data and comparison of Antarctic suites

We report data for the trace elements Au, Co, Sb, Ga, Rb, Ag, Se, Cs, Te, Zn, Cd, Bi, Ti, and In (ordered by putative volatility during nebular condensation and accretion) determined by neutron activation analysis in 13 H5 chondrites from Victoria Land and 20 H4-6 chondrites from Queen Maud Land, Antarctica. These and earlier results provide Antarctic sample suites of 34 chondrites from Victoria Land and 25 from Queen Maud Land. Treatment of data for the most volatile 10 elements (Rb to In) in these studies by multivariate statistical techniques more robust, as well as more conservative, than conventional linear discriminant analysis and logistic regression demonstrates that compositions differ at marginally significant levels. This difference cannot be explained by trivial (terrestrial) causes and becomes more significant, despite the smaller size of the database, when comparisons are limited to data from a single analyst and when all upper limits are eliminated from consideration. The Victoria Land and Queen Maud Land suites have different mean terrestrial ages (approximately 300 kyr and approximately 100 kyr, respectively) and age distributions, suggesting that a time-dependent variation of chondritic sources with different thermal histories is responsible. As a result, these two Antarctic suites are, on average, chemically distinguishable from each other. Since H chondrites serve as a paradigm for other meteorite classes, these results indicate that the near-Earth populations of planetary materials varied with time on the 10(exp 5)-year timescale.

Wolf, Stephen F.↗

Chemical studies of H chondrites. 6: Antarctic/non-Antarctic compositional differences revisited

We report data for the trace elements Au, Co, Sb, Ga, Rb, Ag, Se, Cs, Te, Zn, Cd, Bi, T1, and In (ordered by putative volatility during nebular condensation and accretion) determined by radiochemical neutron activation analysis of 14 additional H5 and H6 chondrite falls. Data for the 10 most volatile elements (Rb to In) treated by the multivariate techniques of linear discriminant analysis and logistic regression in these and 44 other falls are compared with those of 59 H4-6 chondrites from Antarctica. Various populations are tested by the multivariate techniques, using the previously developed method of randomization-simulation to assess significance levels. An earlier conclusion, based on fewer examples, that H4-6 chondrite falls are compositionally distinguishable from the Antarctic suite is verified by the additional data. This distinctiveness is highly significant because of the presence of samples from Victoria Land in the Antarctic population, which differ compositionally from falls beyond any reasonable doubt. However, it cannot be proven unequivocally that falls and Antarctic samples from Queen Maud Land are compositionally distinguishable. Trivial causes (e.g., analyst bias, weathering) cannot explain the Victoria Land (Antarctic)/non-Antarctic compositional difference for paradigmatic H4-6 chondrites. This seems to reflect a time-dependent variation of near-Earth meteoroid source regions differing in average thermal history.

Wolf, Stephen F.↗

Some velocity field results from the thermocapillary flow experiment aboard USML-1 spacelab

Results are reported of the Surface Tension Driven Convection Experiment (STDCE) aboard USML-1 Spacelab. Steady and transient thermocapillary flows were investigated in a 10 cm dia. circular container filled with 10 Cs silicone oil. The velocity and temperature fields were studied in detail under various conditions. It is shown in this paper how the Marangoni number affects the velocity field. A numerical analysis of the flows was also conducted and its results were compared to the experimental data. Good agreement is shown.

Kamotani, Y.↗

An experimental study of free surface deformation in oscillatory thermocapillary flow

Free surface deformation of a test fluid induced by steady and oscillatory thermocapillary flow in a small cylindrical container (diameter = 4.8 mm) is studied experimentally. The fluid (2 Cs oil) is heated by a cylindrical wire (diameter = 0.48 mm) placed along the centerline of the cylinder. The relative displacement and oscillation frequency of free surface are measured in a radial cross-section for various applied temperature differences. It is found that the amplitude of the free surface height oscillations is large near the heater and the cold wall and relatively small in the middle part. The frequency of the free surface oscillations is same as the frequency of the temperature oscillations. Based on these data, the free surface motion during oscillations is delineated.

Lin, Jianlian↗

Clinorotation affects soybean seedling morphology

Although spaceflight does not appear to significantly affect seed germination, it can influence subsequent plant growth. On STS-3 and SL-2, decreased growth (measured as plant length, fresh weight, and dry weight) was noted for pine, oat, and mung bean. In the CHROMEX-01 and 02 experiments with Haplopappus and in the CHROMEX-03 experiment with Arabidopsis, enhanced root growth was noted in the space-grown plants. In the CHROMEX-04 experiments with wheat, both leaf fresh weight and leaf area were diminished in the space-grown plants but there was no difference in total plant height (CS Brown, HG Levine, and AD Krikorian, unpublished data). These data suggest that microgravity impacts growth by whole plant partitioning of the assimilates. The objective of the present study was to determine the influence of clinorotation on the growth and the morphology of soybean seedlings grown in the Biological Research In Canister (BRIC) flight hardware. This experiment provided baseline data for a spaceflight experiment (BRIC-3) flown on STS-63 (February 3-11, 1995).

Hilaire, Emmanuel↗

Photodissociation Cross Sections for the Production of C2 from C2H Using Laser Induced Hg Photosensitization and Tunable Ultraviolet and Visible Lasers

The principle goal of our research was to understand the formation of free radicals in comets. To do this we compared laboratory results with cometary observations in attempt to make sure that the cometary observations agree with what is known about the photochemistry of the proposed parent molecule. Initially we concentrated on the CS emission in an effort to show the parent of this molecule was CS2, consistent with cometary observations of the photochemical lifetime. We then started to look into the problem of the C2 formation in comets. We set out to see if we could measure all of the nascent distributions of the C2 products in the hope that they would be a characteristic signature of the formation process.

Jackson, William M.↗

An MPA-IO interface to HPSS

This paper describes an implementation of the proposed MPI-IO (Message Passing Interface - Input/Output) standard for parallel I/O. Our system uses third-party transfer to move data over an external network between the processors where it is used and the I/O devices where it resides. Data travels directly from source to destination, without the need for shuffling it among processors or funneling it through a central node. Our distributed server model lets multiple compute nodes share the burden of coordinating data transfers. The system is built on the High Performance Storage System (HPSS), and a prototype version runs on a Meiko CS-2 parallel computer.

Jones, Terry↗

Post-SL9 Sulfur Photochemistry on Jupiter

We have modeled the photochemical evolution of the sulfur containing species that were observed in Jupiter's stratosphere after the Shoemaker Levy 9 (SL9) impacts. We find that most of the sulfur is converted to S8 in the first few days. Other important sulfur reservoirs are CS, whose abundance increases markedly with time, and possibly H2CS, HNCS, and NS, whose abundances depend on kinetic reaction rates that are unknown at the present. We discuss the temporal variation of the major sulfur compounds, make abundance and compositional predictions useful for comparison with observations, and discuss the possible condensation of sulfur containing species.

Moses, Julianne I.↗

Scanning Tunneling Microscopy Studies of Diamond Films and Optoelectronic Materials

We present a summary of the research, citations of publications resulting from the research and abstracts of such publications. We have made no inventions in the performance of the work in this project. The main goals of the project were to set up a Chemical Vapor Deposition (CVD) diamond growth system attached to an UltraHigh Vacuum (UHV) atomic resolution Scanning Tunneling Microscopy (STM) system and carry out experiments aimed at studying the properties and growth of diamond films using atomic resolution UHV STM. We successfully achieved these goals. We observed, for the first time, the atomic structure of the surface of CVD grown epitaxial diamond (100) films using UHV STM. We studied the effects of atomic hydrogen on the CVD diamond growth process. We studied the electronic properties of the diamond (100) (2x1) surface, and the effect of alkali metal adsorbates such as Cs on the work function of this surface using UHV STM spectroscopy techniques. We also studied, using STM, new electronic materials such as carbon nanotubes and gold nanostructures. This work resulted in four publications in refereed scientific journals and five publications in refereed conference proceedings.

Perez, Jose M.↗

An MPI-IO Interface to HPSS

This paper describes an implementation of the proposed MPI-IO standard for parallel I/O. Our system uses third-party transfer to move data over an external network between the processors where it is used and the I/O devices where it resides. Data travels directly from source to destination, without the need for shuffling it among processors or funneling it through a central node. Our distributed server model lets multiple compute nodes share the burden of coordinating data transfers. The system is built on the High Performance Storage System (HPSS), and a prototype version runs on a Meiko CS-2 parallel computer.

Parallel Processing↗

High-Pressure Equation of State for Partially Ionic Solids

Recently, we showed that the cohesive energy of partially ionic solids may be characterized by a two-term energy relationship consisting of a Coulomb term arising from the valence-charge transfer delta Z between the atoms, and a scaled universal energy function E(sup *)(a(sup *)), which accounts for the partially covalent character of the bond and for the repulsion between the atomic cores for small R; a(sup *) is a scaled length. Normalized cohesive-energy curves of alkali halide crystals and of Ti and Ag halide crystals were obtained, and the cohesive-energy-curve parameters were used to generate theoretical equation-of-state (EOS) curves for the Li, Na, K, Cs, and Ag halides. Good agreement was obtained with the experimental isothermal compression curves over a wide pressure range (0-90 kbar). In this paper we verify that the cohesive-energy relationship is valid for divalent partially ionic solids; physically reasonable charge-transfer values (1.80 less than delta Z less than 2.0) are obtained for MgO, CaO, and CaS. Next, EOS curves for LiF, NaF, Nal, CsCl, Csl, MgO, CaO, and CaS are generated in terms of the cohesive-energy parameters. These EOS's yield excellent fits to experimental isothermal-compression data and to shock-wave data to very high pressures (P(sub max)= 250-1350 kbar).

Schlosser, Herbert↗