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Structural and kinetic changes to small-pore Cu-zeolites after hydrothermal aging treatments and selective catalytic reduction of NO[subscript x] with ammonia
Abstract not provided
Nano-scale insights regarding coke formation in zeolite SSZ-13 subject to the methanol-to-hydrocarbons reaction
A correlation between the micro- and nano-scale coking behavior of SSZ-13 was discovered with in situ / operando spectroscopy and atom probe tomography (APT), which allows for spatial reconstruction and analysis of relations between framework elements and carbon atoms.
In situ flow pair distribution function analysis to probe the assembly–disassembly–organisation–reassembly (ADOR) mechanism of zeolite IPC-2 synthesis
A four step mechanism for the disassembly and organisation stages of the ADOR process was determined using in situ flow pair distribution function.
A multimodal analytical toolkit to resolve correlated reaction pathways: the case of nanoparticle formation in zeolites
Multimodal in situ experimental data probing a complex reaction have been integrated via a multi-level analysis involving non-negative matrix factorization and correlation analysis. This strategy can be applied generally to multimodal experiments.
Tunable hydrocarbon adsorption based on a zeolitic imidazolate framework in the sodalite topology
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Pre-zeolite framework super-MIEC anodes for high-rate lithium-ion batteries
New physical insights and a robust approach are provided to develop super-MIEC anodes for high-rate batteries, which would bridge two materials families—nanoporous framework materials and conductive oxides.
Engineering intraporous solvent environments: effects of aqueous-organic solvent mixtures on competition between zeolite-catalyzed epoxidation and H 2 O 2 decomposition pathways
A combination of kinetic, thermodynamic, and spectroscopic techniques demonstrates that increasing the water fraction within organic solvents accelerates alkene epoxidations while suppressing the undesired H 2 O 2 decomposition pathway.
Zeolite encapsulated organometallic complexes as model catalysts
Encapsulated complexes have potential as model heterogeneous catalysts for gap-phase reactions.
Zeolitic imidazolate frameworks as intrinsic light harvesting and charge separation materials for ph
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Dioxovanadium(V) complexes of Schiff and tetrahydro-Schiff bases encapsulated in zeolite-Y for the aerobic oxidation of styrene
Abstract not provided
IN-SITU PDF/DRIFTS STUDY OF THE ROLE OF WATER IN AG PARTICLE FORMATION IN ZEOLITES.
Abstract not provided.
Direct Electrical Detection of Target Environmental Gases by a Zeolite and MOF Based Sensors.
Abstract not provided.
Formation of Zeolites Responsible for Waste Glass Rate Acceleration: An Experimental and Computational Study for Understanding Thermodynamic and Kinetic Processes
Before nuclear waste glasses can be disposed at geological disposal facilities, a performance assessment (PA) must be conducted to provide confidence to the regulators and public that the release rates of radioisotopes and hazardous materials into the environment are below the regulatory limits. Because the release rate of radionuclides is directly related to the dissolution rate of the radionuclide-containing glass, the corrosion behavior of the glass must be well understood for the disposal site lifetime. For simplicity, glass dissolution in static conditions has been categorized into three different stages, referred to as initial rate (Stage I), residual rate (Stage II) and, depending upon the secondary phases formed, a possible delayed resumption in the alteration rate (Stage III). The last of these stages is the least understood and has the possibility to drive radionuclide release rates above regulatory thresholds.