Dynamic model investigation of the rough-water landing characteristics of a spacecraft
Dynamic model investigation of rough-water landing characteristics of Gemini-type spacecraft
DYNAMIC MODEL↗
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Results for “water model”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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General Kinetic Model for pH Dependence of Proton-Coupled Electron Transfer: Application to an Electrochemical Water Oxidation System
The pH dependence of proton-coupled electron transfer (PCET) reactions, which are critical to many chemical and biological processes, is a powerful probe for elucidating their fundamental mechanisms. Herein, a general, multichannel kinetic model is introduced to describe the pH dependence of both homogeneous and electrochemical PCET reactions. According to this model, a weak pH dependence can arise from the competition among multiple sequential and concerted PCET channels involving different forms of the redox species, such as protonated and deprotonated forms, as well as different proton donors and acceptors. The contribution of each channel is influenced by the relative populations of the reactant species, which often depend strongly on pH, leading to complex pH dependence of PCET apparent rate constants. This model is used to explain the origins of the experimentally observed weak pH dependence of the electrochemical PCET apparent rate constant for a ruthenium-based water oxidation catalyst attached to a tin-doped In2O3 (ITO) surface. The weak pH dependence is found to arise from the intrinsic differences in the rate constants of participating channels and the dependence of their relative contributions on pH. This model predicts that the apparent maximum rate constant will become pH-independent at higher pH, which is confirmed by experimental measurements. Our analysis also suggests that the dominant channels are electron transfer at lower pH and sequential PCET via electron transfer followed by fast proton transfer at higher pH. Furthermore, this work highlights the importance of considering multiple competing channels simultaneously for PCET processes.
Catalysts↗
Modeling of SAR signatures of shallow water ocean topography
A hydrodynamic/electromagnetic model was developed to explain and quantify the relationship between the SEASAT synthetic aperture radar (SAR) observed signatures and the bottom topography of the ocean in the English Channel region of the North Sea. The model uses environmental data and radar system parameters as inputs and predicts SAR-observed backscatter changes over topographic changes in the ocean floor. The model results compare favorably with the actual SEASAT SAR observed backscatter values. The developed model is valid for only relatively shallow water areas (i.e., less than 50 meters in depth) and suggests that for bottom features to be visible on SAR imagery, a moderate to high velocity current and a moderate wind must be present.
Shuchman, R. A.↗
Extended thermodynamic model for high salinity produced waters
To support the development of desalination processes for high salinity produced waters, we developed a comprehensive thermodynamic model that reliably predicts the thermodynamic properties and phase behavior of produced water. Here this study extends a previously developed thermodynamic model for the aqueous hexary oceanic salt system by incorporating the Sr 2+ and Ba 2+ ions. Based on the electrolyte nonrandom two-liquid theory, the model requires two adjustable binary interaction parameters for each water-electrolyte and electrolyte-electrolyte pair that has a common ion. The binary interaction parameters for the electrolyte-electrolyte pairs involving Sr 2+ and Ba 2+ ions were identified using thermodynamic and salt solubility data. The model was validated for temperatures from 273.15 K to 473.15 K and electrolyte concentrations from infinite dilution to salt saturation. Extension of the model to include HCO 3 − , CO 3 2− , and CO 2 is currently in progress.
42 ENGINEERING↗
Time-dependent water vapor desorption isotherm model of hardened cement paste
Highlights: • Short-term and long-term desorption isotherms of hardened cement paste are reviewed. • Water content at RH depends on both thermodynamic and microstructural equilibria. • An extended GAB equation is proposed to fit the cavitation drop during desorption. • A dynamic time-dependent sorption isotherm model is shown and used for simulations. • Numerical results capture anomalous drying in the same RH as seen experimentally. This study aims to enhance moisture transport modeling by elucidating the so-called anomalous water diffusion in cementitious materials. Water desorption isotherms are measured from samples at various drying stages using techniques with different durations to quantify the impact of the drying duration on the water sorption ability. A single water sorption isotherm does not solely give a relationship between the water content and relative humidity but also represents the state of microstructure. The continuous evolution of a desorption isotherm due to drying-induced microstructural rearrangement is demonstrated. For numerical modeling, the microstructural alteration can be explicitly considered through a dynamic desorption isotherm model, which governs the local thermodynamic equilibrium at the capillary meniscus. This approach is implemented into a multiphase transport code, whose ability to predict drying is validated using literature data. Finally, the effect of prolonged drying on the colloidal nature of the calcium-silicate-hydrate gel is discussed.
36 MATERIALS SCIENCE↗
Modeling the effect of water on mantle rheology
To study the thermal history of the Earth we use a parameterized model of mantle convection. This model includes a mathematical description of de- and regassing processes of water from the Earth's mantle. The rates of this processes are considered to be directly proportional to the seafloor spreading rate. The kinematic viscosity of the mantle depends on the temperature/pressure as well as on the volatile content. Dissolved volatiles such as water weaken the minerals by reducing their activation energy for solid state creep. Karato and Toriumi showed a power law dependence between creep rate and water fugacity derived from experimental results. Therefore, we use such flow parameters of diffusion creep in olivine under wet and dry conditions to calculate the mantle viscosity as a function of the water content. Because the creep rate is proportional to the concentration of water-related point deflects we assume that the water fugacity is proportional to the water weight fraction. An equation for the steady-state strain rate under wet conditions is established. To assess the unknown constant K in this equation, we use flow law parameters given by Karato and Wu as well as the results of McGovern and Schubert.
Bounama, CH.↗
Structural and dynamic properties of solvated hydroxide and hydronium ions in water from ab initio modeling
Predicting the asymmetric structure and dynamics of solvated hydroxide and hydronium in water from ab initio molecular dynamics (AIMD) has been a challenging task. The difficulty mainly comes from a lack of accurate and efficient exchange–correlation functional in elucidating the amphiphilic nature and the ubiquitous proton transfer behaviors of the two ions. By adopting the strongly constrained and appropriately normed (SCAN) meta-generalized gradient approximation functional in AIMD simulations, we systematically examine the amphiphilic properties, the solvation structures, the electronic structures, and the dynamic properties of the two water ions. In particular, we compare these results to those predicted by the PBE0-TS functional, which is an accurate yet computationally more expensive exchange–correlation functional. We demonstrate that the general-purpose SCAN functional provides a reliable choice for describing the two water ions. Specifically, in the SCAN picture of water ions, the appearance of the fourth and fifth hydrogen bonds near hydroxide stabilizes the pot-like shape solvation structure and suppresses the structural diffusion, while the hydronium stably donates three hydrogen bonds to its neighbors. We apply a detailed analysis of the proton transfer mechanism of the two ions and find the two ions exhibit substantially different proton transfer patterns. In conclusion, our AIMD simulations indicate that hydroxide diffuses more slowly than hydronium in water, which is consistent with the experimental results.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Interdependent Water And Power Infrastructure Model
The approach used is the Multi-Agent System (MAS) paradigms, where systems components are represented as agents, interacting both with each other, and with the environment in which they evolved. Agents behaviors correspond to components in the real Integrated Water-Power System. The model simulate actions and interactions of these (autonomous) agents to analyze their effects on the overall system. Agents in the water system capture components of water collection, treatment, transportation, distribution and use (e.g. pipe, canal, pump, water demands for agriculture, etc.). Agents in the power system capture components of power generation, transportation, distribution and use (electricity demands, sources, etc.).
Toba, Danho Ange Lionel [Idaho National Laboratory↗
Distillation Designs for the Lunar Surface
Gravity-based distillation methods may be applied to the purification of wastewater on the lunar base. These solutions to water processing are robust physical separation techniques, which may be more advantageous than many other techniques for their simplicity in design and operation. The two techniques can be used in conjunction with each other to obtain high purity water. The components and feed compositions for modeling waste water streams are presented in conjunction with the Aspen property system for traditional stage distillation. While the individual components for each of the waste streams will vary naturally within certain bounds, an analog model for waste water processing is suggested based on typical concentration ranges for these components. Target purity levels for recycled water are determined for each individual component based on NASA s required maximum contaminant levels for potable water Optimum parameters such as reflux ratio, feed stage location, and processing rates are determined with respect to the power consumption of the process. Multistage distillation is evaluated for components in wastewater to determine the minimum number of stages necessary for each of 65 components in humidity condensate and urine wastewater mixed streams.
Boul, Peter J.↗
Acceleration Measurements During Landings of a 1/5.5-Size Dynamic Model of the Columbia XJL-1 Amphibian in Smooth Water and in Waves: Langley Tank Model 208M, TED No. NACA 2336
A 1/5.5-size powered dynamic model of the Columbia XJL-1 amphibian was landed in Langley tank no. 1 in smooth water and in oncoming waves of heights from 2.1 feet to 6.4 feet (full-size) and lengths from 50 feet to 264 feet (full-size). The motions and the vertical accelerations of the model were continuously recorded. The greatest vertical acceleration measured during the smooth-water landings was 3.1g. During landings in rough water the greatest vertical acceleration measured was 15.4g, for a landing in 6.4-foot by 165-foot waves. The impact accelerations increased with increase in wave height and, in general, decreased with increase in wave length. During the landings in waves the model bounced into the air at stalled attitudes at speeds below flying speed. The model trimmed up to the mechanical trim stop (20 deg) during landings in waves of heights greater than 2.0 feet. Solid water came over the bow and damaged the propeller during one landing in 6.4-foot waves. The vertical acceleration coefficients at first impact from the tank tests of a 1/5.5-size model were in fair agreement with data obtained at the Langley impact basin during tests of a 1/2-size model of the hull.
Clement, Eugene P.↗
CalWave - Open Water Demonstration - Field Testing Content Models (10/21 - 7/22)
Data for the CalWave - Open Water Demonstration, a submerged pressure differential Wave Energy Converter (WEC) Device. Device is moored to the seabed, and the motion of the waves causes the sea level to rise and fall above the device, inducing a pressure differential in the device. The alternating pressure pumps fluid through a system to generate electricity, which is transmitted to shore via bidirectional cables. Documentation and data here includes: Open Water Demonstration, including field testing content models for nearly 10 months of continuous ocean operation, from October 2021 through July 2022.
16 TIDAL AND WAVE POWER↗
Radiative transfer model for remote sensing of suspended sediments in water
A Monte Carlo simulation model of radiative transfer in turbid water is discussed. The model can be used to calculate characteristics of the backscattered signal from an illuminated body of water as a function of the turbidity level and spectral properties of the suspended particulates. The dependence of remote sensing applications on the concentration and spectral properties of sediments in the environmental waters is considered in terms of the model. Attention is directed to the effects of various inputs for the volume-scattering function on backscattered radiance from natural waters. The wavelength dependence of single scattering albedo is investigated.
Ghovanlou, A. H.↗
Predictability and feedbacks of the ocean-soil-plant-atmosphere water cycle: deep learning water conductance in Earth System Model
This white paper responds to Focal Area 2. We seek to build predictive models of leaf and surface conductance of water by implementing deep learning (DL) data assimilation techniques. These new models would then be implemented in existing Land Surface Models (LSMs) and Earth System models (ESMs), generating novel water cycle feedbacks. In doing so, we would improve predictability of expected changes in land precipitation, soil moisture, and vegetation dynamics in the long-term, and the role of land cover on the impacts and feedbacks of extreme weather events in the short-term
54 ENVIRONMENTAL SCIENCES↗
Modeling and Optimal Design of a Desalination System Integrated Between a Glass-Covered Solar Collection Water Chamber and a Heat Dissipating Chimney
Abstract Solar thermal energy is trapped in a glass-covered water chamber/basin to provide the heat for evaporation of brackish water in a novel desalination system. To harvest clean water, a chimney is integrated with the water basin, which draws air into the chamber to be humidified by the vapor and then being ventilated via buoyance force. Uniquely, thermal conductive metal sheet is recommended to make the chimney, which allows the vapor in the humid air condenses easily when flowing up. The condensate at the inner wall of the chimney flows down to be collected as clean water. Mathematical modeling and numerical computation have been carried out to delineate the coupling of the buoyance-force-driven flow with the heat and mass transfer of air and water in the solar collection chamber and the condensation of vapor in the heat-dissipating chimney. The objective of the simulation and optimization of the system is to find the best match of the dimensions of the water chamber with a chimney to maximize the production of clean water and energy efficiency. The model has been used to simulation several cases (of water from 40 °C to 50 °C) with available experimental data from the authors’ previous work, and the agreement was satisfactory. The optimization studies found that there is a maximum air flowrate corresponding to a critical chimney height due to the requirement that the chimney is designated to dissipate heat as much as possible to condense water vapor. With the chimney height greater than the critical height, the airflow rate will have a slight decrease. Nevertheless, higher than a critical height is still needed for a chimney to condense more moisture. Optimized chamber diameters at different chimney heights are provided for reference of optimal system designs.
Engineering↗
Salt and Water Transport in Reverse Osmosis Membranes: Beyond the Solution-Diffusion Model
Not Available
54 ENVIRONMENTAL SCIENCES↗
Diabatic forcing and initialization with assimilation of cloud and rain water in a forecast model: Methodology
The focus of this part of the investigation is to find one or more general modeling techniques that will help reduce the time taken by numerical forecast models to initiate or spin-up precipitation processes and enhance storm intensity. If the conventional data base could explain the atmospheric mesoscale flow in detail, then much of our problem would be eliminated. But the data base is primarily synoptic scale, requiring that a solution must be sought either in nonconventional data, in methods to initialize mesoscale circulations, or in ways of retaining between forecasts the model generated mesoscale dynamics and precipitation fields. All three methods are investigated. The initialization and assimilation of explicit cloud and rainwater quantities computed from conservation equations in a mesoscale regional model are examined. The physical processes include condensation, evaporation, autoconversion, accretion, and the removal of rainwater by fallout. The question of how to initialize the explicit liquid water calculations in numerical models and how to retain information about precipitation processes during the 4-D assimilation cycle are important issues that are addressed. The explicit cloud calculations were purposely kept simple so that different initialization techniques can be easily and economically tested. Precipitation spin-up processes associated with three different types of weather phenomena are examined. Our findings show that diabatic initialization, or diabatic initialization in combination with a new diabatic forcing procedure, work effectively to enhance the spin-up of precipitation in a mesoscale numerical weather prediction forecast. Also, the retention of cloud and rain water during the analysis phase of the 4-D data assimilation procedure is shown to be valuable. Without detailed observations, the vertical placement of the diabatic heating remains a critical problem.
Raymond, William H.↗
Progressive Aerodynamic Model Identification From Dynamic Water Tunnel Test of the F-16XL Aircraft
Development of a general aerodynamic model that is adequate for predicting the forces and moments in the nonlinear and unsteady portions of the flight envelope has not been accomplished to a satisfactory degree. Predicting aerodynamic response during arbitrary motion of an aircraft over the complete flight envelope requires further development of the mathematical model and the associated methods for ground-based testing in order to allow identification of the model. In this study, a general nonlinear unsteady aerodynamic model is presented, followed by a summary of a linear modeling methodology that includes test and identification methods, and then a progressive series of steps suggesting a roadmap to develop a general nonlinear methodology that defines modeling, testing, and identification methods. Initial steps of the general methodology were applied to static and oscillatory test data to identify rolling-moment coefficient. Static measurements uncovered complicated dependencies of the aerodynamic coefficient on angle of attack and sideslip in the stall region making it difficult to find a simple analytical expression for the measurement data. In order to assess the effect of sideslip on the damping and unsteady terms, oscillatory tests in roll were conducted at different values of an initial offset in sideslip. Candidate runs for analyses were selected where higher order harmonics were required for the model and where in-phase and out-of-phase components varied with frequency. From these results it was found that only data in the angle-of-attack range of 35 degrees to 37.5 degrees met these requirements. From the limited results it was observed that the identified models fit the data well and both the damping-in-roll and the unsteady term gain are decreasing with increasing sideslip and motion amplitude. Limited similarity between parameter values in the nonlinear model and the linear model suggest that identifiability of parameters in both terms may be a problem. However, the proposed methodology can still be used with careful experiment design and carefully selected values of angle of attack, sideslip, amplitude, and frequency of the oscillatory data.
Murphy, Patrick C.↗
Effects of three transmission models in the rotational water-vapor band on radiance calculations and constituent inferences
Transmission model effects on water vapor mixing ratios and radiance calculations for infrared horizon scanners
Whitman, R. I.↗