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At least 469 records · Page 26

Spectroscopy of Moses Rock Kimberlite Diatreme

Three types of remote sensing data (Airborne Imaging Spectroscopy (AIS), NS001, Zeiss IR-photographs) were obtained for the Moses Rock kimberlite dike in southern Utah. The goal is to identify and characterize the mantle derived mafic component in such volcanic features. The Zeiss and NS001 images provide information on the regional setting and allow units of the dike to be distinguished from surrounding material. A potential unmapped satellite dike was identified. The AIS data provide characterizing information of the surface composition of the dike. Serpentized olivine-bearing soils are (tentatively) identified from the AIS spectra for a few areas within the dike.

Pieters, C. M.↗

Use of Landsat Thematic Mapper images in regional correlation of syntectonic strata, Colorado river extensional corridor, California and Arizona

Enhanced Landsat TM images were used in conjunction with field work to investigate the regional correlation of Miocene rocks in the Colorado River extensional corridor of California and Arizona. Based on field investigations, four sequences of sedimentary and volcanic strata could be recognized in the Mohave Mountains (Arizona) and the eastern Whipple Mountains (California), which display significantly different relative volumes and organization of lithologies. The four sequences were also found to have distinctive appearances on the TM image. The recognition criteria derived from field mapping and image interpretation in the Mohave Mountains and Whipple Mountains were applied to an adjacent area in which stratigraphic affinities were less well known. The results of subsequent field work confirmed the stratigraphic and structural relations suggested by the Tm image analysis.

Beratan, K. K.↗

Tartarus Colles: A sampling of the Martian highlands

Several of the most fundamental issues about the geology of Mars can be addressed using information on composition and structure of the plateau plains ('highlands') that cover approximately half the planet. The units that compose the highlands are interpreted as a mixture of volcanic, fluvial, lacustrine, and impact ejecta deposits. A more precise inventory of differing of igneous and sedimentary lithologies in highland rock units would not only lead to a better understanding of how the plateau plains formed, but would also clarify the nature of the surface environment during the first 800 m.y. of martian history. Structural features including bedforms, joints, and small faults that are unresolved from orbit record a history of the emplacement and deformation of the highlands. In addition, weathering products present in this very ancient terrain represent a mineralogic record of past climate and of the pathways by which bedrock is altered chemically. Their similarity or dissimilarity to bright soils observed spectroscopically and in situ at the Viking Lander sites will be evidence for the relative roles of regional sources and global eolian transport in producing the widespread cover of 'dust.' Unfortunately, these issues are difficult to address in the plateau plains proper, because bedrock is covered by mobile sand and weathering products, which dominate both surface composition and remotely measurable spectral properties. However, the 'Tartarus Colles' site, located at 11.41 deg N, 197.69 deg W at an elevation of -1 km, provides an excellent opportunity to address the highland geology within the mission constraints of Mars Pathfinder. The site is mapped as unit HNu, and consists of knobby remnants of deeply eroded highlands. It contains rolling hills, but lacks steep escarpments and massifs common in most highland remnants, and is free of large channels that would have removed colluvium from eroded upper portions of the stratigraphic column. These characteristics indicate that variety of bedrock types from throughout the Noachian-Hesperian stratigraphic column may remain at the site.

Murchie, Scott↗

Recrystallized Impact Glasses of the Onaping Formation and the Sudbury Igneous Complex, Sudbury Structure, Ontario, Canada

The origin of the Sudbury Structure and of the associated heterolithic breccias of the Onaping Formation and the Sudbury Igneous Complex have been controversial. While an impact origin of the structure has gained wide acceptance over the last 15 years, the origin of the recrystallized Onaping Formation glasses and of the igneous complex is still being debated. Recently the interpretation of the breccias of the Onaping Formation as suevitic fall-back impact breccias has been challenged. The igneous complex is interpreted either as a differentiated impact melt sheet or as a combination of an upper impact melt represented by the granophyre, and a lower, impact-triggered magmatic body consisting of the norite-sublayer formations. The Onaping Formation contains glasses as fluidal and nonfluidal fragments of various shapes and sizes. They are recrystallized, and our research indicates that they are petrographically heterogeneous and span a wide range of chemical compositions. These characteristics are not known from glasses of volcanic deposits. This suggests an origin by shock vitrification, an interpretation consistent with their association with numerous and varied country rock clasts that exhibit microscopic shock metamorphic features. The recrystallized glass fragments represent individual solid-state and liquid-state vitrified rocks or relatively small melt pods. The basal member lies beneath the Gray and Black members of the Onaping Formation and, where not metamorphic, has an igneous matrix. Igneous-textured melt bodies occur in the upper two members and above the Basal Member. A comparison of the chemical compositions of recrystallized glasses and of the matrices of the Basal Member and the melt bodies with the components and the bulk composition of the igneous complex is inconclusive as to the origin of the igneous complex. Basal Member matrix and Melt Bodies, on average, are chemically similar to the granophyre of the Sudbury Igneous Complex, suggesting that they are genetically related. Our chemical results allow interpretation of the entire igneous complex as a differentiated impact melt. However, they are also consistent with the granophyre alone being the impact melt and the nofite and quartz gabbro beneath it representing an impact-triggered magmatic body. This interpretation is preferred, as it is consistent with a number of field observations. A re-evaluation and extension of structural field studies and of geochemical data, as well as a systematic study of the contact relationships of the various igneous phases of the igneous complex, are needed to establish a Sudbury impact model consistent with all data and observations

Dressler, B. O.↗

Iron-tolerant Cyanobacteria as a Tool to Study Terrestrial and Extraterrestrial Iron Deposition

We are investigating biological mechanisms of terrestrial iron deposition as analogs for Martian hematite recently confirmed by. Possible terrestrial analogs include iron oxide hydrothermal deposits, rock varnish, iron-rich laterites, ferricrete soils, moki balls, and banded iron formations (BIFs). With the discovery of recent volcanic activity in the summit craters of five Martian volcanoes, renewed interest in the iron dynamics of terrestrial hydrothermal environments and associated microorganisms is warranted. In this study we describe a new genus and species of CB exhibiting elevated dissolved iron tolerance and the ability to precipitate hematite on the surface of their exopolymeric sheathes.

Brown, I. I.↗

NASA Tech Briefs, September 2013

Topics include: ISS Ammonia Leak Detection Through X-Ray Fluorescence; A System for Measuring the Sway of the Vehicle Assembly Building; Fast, High-Precision Readout Circuit for Detector Arrays; Victim Simulator for Victim Detection Radar; Hydrometeor Size Distribution Measurements by Imaging the Attenuation of a Laser Spot; Quasi-Linear Circuit; High-Speed, High-Resolution Time-to-Digital Conversion; Li-Ion Battery and Supercapacitor Hybrid Design for Long Extravehicular Activities; Ultrasonic Low-Friction Containment Plate for Thermal and Ultrasonic Stir Weld Processes; High-Powered, Ultrasonically Assisted Thermal Stir Welding; Next-Generation MKIII Lightweight HUT/Hatch Assembly; Centrifugal Sieve for Gravity-Level-Independent Size; Segregation of Granular Materials; Ion Exchange Technology Development in Support of the Urine Processor Assembly; Nickel-Graphite Composite Compliant Interface and/or Hot Shoe Material; UltraSail CubeSat Solar Sail Flight Experiment; Mechanism for Deploying a Long, Thin-Film Antenna From a Rover; Counterflow Regolith Heat Exchanger; Acquisition and Retaining Granular Samples via a Rotating Coring Bit; Very-Low-Cost, Rugged Vacuum System; Medicine Delivery Device With Integrated Sterilization and Detection; FRET-Aptamer Assays for Bone Marker Assessment, C-Telopeptide, Creatinine, and Vitamin D; Multimode Directional Coupler for Utilization of Harmonic Frequencies from TWTAs; Dual-Polarization, Multi-Frequency Antenna Array for use with Hurricane Imaging Radiometer; Complementary Barrier Infrared Detector (CBIRD) Contact Methods; Autonomous Control of Space Nuclear Reactors; High-Power, High-Speed Electro-Optic Pockels Cell Modulator; Covariance Analysis Tool (G-CAT) for Computing Ascent, Descent, and Landing Errors; Enigma Version 12; Micrometeoroid and Orbital Debris (MMOD) Shield Ballistic Limit Analysis Program; Spitzer Telemetry Processing System; Planetary Protection Bioburden Analysis Program; Wing Leading Edge RCC Rapid Response Damage Prediction Tool (IMPACT2); ISSM: Ice Sheet System Model; Automated Loads Analysis System (ATLAS); Integrated Main Propulsion System Performance Reconstruction Process/Models. Phoenix Telemetry Processor; Contact Graph Routing Enhancements Developed in ION for DTN; GFEChutes Lo-Fi; Advanced Strategic and Tactical Relay Request Management for the Mars Relay Operations Service; Software for Generating Troposphere Corrections for InSAR Using GPS and Weather Model Data; Ionospheric Specifications for SAR Interferometry (ISSI); Implementation of a Wavefront-Sensing Algorithm; Sally Ride EarthKAM - Automated Image Geo-Referencing Using Google Earth Web Plug-In; Trade Space Specification Tool (TSST) for Rapid Mission Architecture (Version 1.2); Acoustic Emission Analysis Applet (AEAA) Software; Memory-Efficient Onboard Rock Segmentation; Advanced Multimission Operations System (ATMO); Robot Sequencing and Visualization Program (RSVP); Automating Hyperspectral Data for Rapid Response in Volcanic Emergencies; Raster-Based Approach to Solar Pressure Modeling; Space Images for NASA JPL Android Version; Kinect Engineering with Learning (KEWL); Spacecraft 3D Augmented Reality Mobile App; MPST Software: grl_pef_check; Real-Time Multimission Event Notification System for Mars Relay; SIM_EXPLORE: Software for Directed Exploration of Complex Systems; Mobile Timekeeping Application Built on Reverse-Engineered JPL Infrastructure; Advanced Query and Data Mining Capabilities for MaROS; Jettison Engineering Trajectory Tool; MPST Software: grl_suppdoc; PredGuid+A: Orion Entry Guidance Modified for Aerocapture; Planning Coverage Campaigns for Mission Design and Analysis: CLASP for DESDynl; and Space Place Prime.

Source record↗

Permeability scaling relationships of volcanic tuff from core to field scale measurements

A recent chemical explosive test in P-Tunnel at the Nevada National Security Site, Nevada, USA, was conducted to better understand how signals propagate from explosions in the subsurface. A primary signal of interest is the migration of gases that can be used to differentiate chemical from nuclear explosions. Gas migration is highly dependent on the rock permeability which is notoriously difficult to determine experimentally in the field due to a potentially large dependence on the scale over which measurements are made. Here, we present pre-explosion permeability estimates to characterize the geologic units surrounding the recent test. Permeability measurements were made at three scales of increasing size: core samples (≈2 cm), borehole packer system tests (≈1 m), and a pre-shot cavity pressurization test (> 10 m) across ten tuff units. Permeability estimates based on core measurements showed little difference from borehole packer tests. However, permeability in most rock units calibrated from cavity pressurization tests resulted in higher permeability estimates by up to two orders of magnitude. Here, we demonstrate that the scale of the measurement significantly impacts the characterization efforts of hydraulic properties in volcanic tuff, and that local-scale measurements (< 10 m scale) do not incorporate enough heterogeneity to accurately predict field-scale flow and mass transport.

Environmental sciences↗

Is Tridymite at Gale Crater Evidence for Silicic Volcanism on Mars?

The X-ray diffraction (XRD) instrument (CheMin) onboard the MSL rover Curiosity detected 17 wt% of the SiO2 polymorph tridymite (relative to bulk sample) for the Buckskin drill sample (73 wt% SiO2) obtained from sedimentary rock in the Murray formation at Gale Crater, Mars. Other detected crystalline materials are plagioclase, sanidine, cristobalite, cation-deficient magnetite, and anhydrite. XRD amorphous material constitutes approx. 60 wt% of bulk sample, and the position of its broad diffraction peak near approx. 26 deg. 2-theta is consistent with opal-A. Tridymite is a lowpressure, high-temperature mineral (approx. 870 to 1670 deg. C) whose XRD-identified occurrence on the Earth is usually associated with silicic (e.g., rhyolitic) volcanism. High SiO2 deposits have been detected at Gale crater by remote sensing from martian orbit and interpreted as opal-A on the basis H2O and Si-OH spectral features. Proposed opal-A formation pathways include precipitation of silica from lake waters and high-SiO2 residues of acid-sulfate leaching. Tridymite is nominally anhydrous and would not exhibit these spectral features. We have chemically and spectrally analyzed rhyolitic samples from New Mexico and Iwodake volcano (Japan). The glassy (by XRD) NM samples have H2O spectral features similar to opal-A. The Iwodake sample, which has been subjected to high-temperature acid sulfate leaching, also has H2O spectral features similar to opal-A. The Iwodake sample has approx. 98 wt% SiO2 and 1% wt% TiO2 (by XRF), tridymite (>80 wt.% of crystalline material without detectable quartz by XRD), and H2O and Si-OH spectral features. These results open the working hypothesis that the opal-A-like high-SiO2 deposits at Gale crater detected from martian orbit are products of alteration associated with silicic volcanism. The presence or absence of tridymite will depend on lava crystallization temperatures (NM) and post crystallization alteration temperatures (Iwodake).

Morris, Richard V.↗

Lunar ash flows - Isothermal approximation.

Suggestion of the ash flow mechanism as one of the major processes required to account for some features of lunar soil. First the observational background and the gardening hypothesis are reviewed, and the shortcomings of the gardening hypothesis are shown. Then a general description of the lunar ash flow is given, and a simple mathematical model of the isothermal lunar ash flow is worked out with numerical examples to show the differences between the lunar and the terrestrial ash flow. The important parameters of the ash flow process are isolated and analyzed. It appears that the lunar surface layer in the maria is not a residual mantle rock (regolith) but a series of ash flows due, at least in part, to great meteorite impacts. The possibility of a volcanic contribution is not excluded. Some further analytic research on lunar ash flows is recommended.

Pai, S. I.↗

Growth of the lower continental crust

One of the largest uncertainties in crustal composition and growth models is the nature of the lower continental crust. Specifically, by what processes is it formed and modified, and when is it formed, particularly in reference to the upper crust? The main reason for this lack of information is the scarcity of lower crustal rock samples. These are restricted to two types: rocks which outcrop in granulite facies terrains and granulite facies xenoliths which are transported to the earth's surface by young volcanics. The important conclusions arising from the xenolith studies are: the majority of mafic lower crustal xenoliths formed through cumulate process, resitic xenoliths are rare; and formation and metamorphism of the deep crust is intimately linked to igneous activity and/or orogeny which are manifest in one form or another at the earth's surface. Therefore, estimates of crustal growth based on surface exposures is representative, although the proportion of remobilized pre-existing crust may be significantly greater at the surface than in the deep crust.

Rudnick, Roberta L.↗

A Model for Formation of Dust, Soil and Rock Coatings on Mars: Physical and Chemical Processes on the Martian Surface

This model is one of many possible scenarios to explain the generation of the current surface material on Mars using chemical, magnetic and spectroscopic data From Mars and geologic analogs from terrestrial sites. One basic premise of this model is that the dust/soil units are not derived exclusively from local rocks, but are rather a product of global, and possibly remote, weathering processes. Another assumption in this model is that there are physical and chemical interactions of the atmospheric dust particles and that these two processes create distinctly different results on the surface. Physical processes distribute dust particles on rocks and drift units, forming physically-aggregated layers; these are reversible processes. Chemical reactions of the dust/soil particles create alteration rinds on rock surfaces and cohesive, crusted surface units between rocks, both of which are relatively permanent materials. According to this model the dominant components of the dust/soil particles are derived from alteration of volcanic ash and tephra, and contain primarily nanophase and poorly crystalline ferric oxides/oxyhydroxide phases as well as silicates. These phases are the alteration products that formed in a low moisture environment. These dust/soil particles also contain a smaller amount of material that was exposed to more water and contains crystalline ferric oxides/oxyhydroxides, sulfates and clay silicates. These components could have formed through hydrothermal alteration at steam vents or fumeroles, thermal fluids, or through evaporite deposits. Wet/dry cycling experiments are presented here on mixtures containing poorly crystalline and crystalline ferric oxides/oxyhydroxides, sulfates and silicates that range in size from nanophase to 1-2 pm diameter particles. Cemented products of these soil mixtures are formed in these experiments and variation in the surface texture was observed for samples containing smectites, non-hydrated silicates or sulfates. Reflectance spectra were measured of the initial particulate mixtures, the cemented products and ground versions of the cemented material. The spectral contrast in the visible/near-infrared and mid-infrared regions is significantly reduced for the cemented material compared to the initial soil, and somewhat reduced for the ground, cemented soil compared to the initial soil. The results of this study suggest that diurnal and seasonal cycling on Mars will have a profound effect on the texture and spectral properties of the dust/soil particles on the surface. The model developed in this study provides an explanation for the generation of cemented or crusted soil units and rock coatings on Mars and may explain albedo variations on the surface observed near large rocks or crater rims.

Bishop, Janice↗

HCMM: Soil moisture in relation to geologic structure and lithology, northern California

Heat capacity mapping mission images of about 80,000 sq km in northern California were qualitatively evaluated for usefulness in regional geologic investigations of structure and lithology. The thermal characteristics recorded vary among the several geomorphic provinces and depend chiefly on the topographic expression and vegetation cover. Identification of rock types, or groups of rock types, was most successfully carried out within the semiarid parts of the region; however, extensive features, such as faults, folds and volcanic fields could be delineated. Comparisons of seasonally obtained HCMM images are of limited value except in semiarid regions.

Rich, E. I.↗

40 Years of Collecting Martian Meteorites

This year marks the 40th anniversary of the first Martian meteorite found in Antarctica by ANSMET, ALH 77005. Since then, an additional 14 Martian meteorites have been found by the ANSMET team making for a total of 15 Martian meteorites in the Antarctic collection at Johnson Space Center. Of the 15 meteorites, some have been paired so the 15 meteorites actually represent a total of approximately 9 separate meteorites. The first Martian meteorite found by ANSMET was ALH 77005 (482.500 g), a lherzolitic shergottite. When collected, this meteorite was split as a part of the joint expedition with the National Institute of Polar Research (NIPR) Japan. Originally classified as an "achondrite-unique", it was re-classified as a Martian lherzolitic shergottites in 1982 [1]. This meteorite has been allocated to ~125 scientists for research and there are 181.964 g remaining at Johnson Space Center (JSC). Two years later, one of the most significant Martian meteorites of the collection at JSC was found at Elephant Moraine, EET 79001 (7942.000 g), a shergottite. This meteorite is the largest in the Martian collection at JSC and was the largest stony meteorite sample collected during the 1979 season. In addition to its size, this meteorite is of particular interest because it contains a linear contact separating two different igneous lithologies, basaltic and olivine-phyric. EET 79001 has glass inclusions that contain chemical compositions that are proportionally identical to the Martian atmosphere, as measured by the Viking spacecraft [2]. This discovery helped scientists to identify where the "SNC" meteorite suite had originated, and that we actually possessed Martian samples. This meteorite has been allocated to ~195 scientists for research and there are 5304.770 g of sample is available. Five years later, ANSMET found ALH 84001 (1930.900 g), the only Martian orthopyroxenite. This meteorite was initially classified as a diogenite but was reclassified as being a Martian meteorite in 1993 [3,4]. ALH 84001 is known as the "Life on Mars" meteorite, sparked debate about whether it contained evidence of Martian life [5] and significantly influenced the field of astrobiol-ogy. This sample has been allocated to 173 scientists for research and has 1426.694 g remaining at JSC. In 1988, another lherzolitic shergottite was found, LEW 88516, (13.203 g). This meteorite wasn't recognized in the field as an achondrite until it was broken during processing 2 years later. LEW 88516 has been allocated to 43 scientists for research and 5.351 g of this meteorite remains at JSC. Six years later a basaltic shergottite was found in the Queen Alexandra Range, QUE 94201 (12.020 g). This meteorite was believed to be of terrestrial origin until maskelynite was seen in a thin section. QUE 94201 has been allocated to 57 scientists for research and there are 3.629 g of this meteorite left at JSC. In 2003, the NASA Mars Exploration Program joined the ANSMET team with the hopes of finding another Martian mete-orite. During this expedition, MIL 03346 (715.200 g) was found. This meteorite is a nakhlite. MIL 03346 has been allocated to 98 scientists for research and there are 579.046 g of this sample remaining at JSC. Six years later, 3 more meteorites that have been paired with MIL 03346 were found, MIL 090030 (452.630 g), 090032 (532.190 g ) and 090136 (170.980 g). MIL 090030 has been allocated to 21 scientists for research and has 434.420 g remaining at JSC, MIL 090032 has been allocated to 21 scientists for re-search and has 508.710 g remaining at JSC and MIL 090136 has been allocated to 14 scientists for research and has 156.790 g remaining at JSC. During the 2004 expedition, 2 identical meteorites where found together on the ice, RBT 04261 (78.763 g) and RBT 04262 (204.600 g). These paired meteorites are olivine-phyric shergottites. RBT 04261 has been allocated to 33 scientists for research and has 32.335 g remaining at JSC. RBT 04262 has been allocated to 46 scientists for research and has 171.886 g remaining. In 2006, another olivine-phyric shergottite was found, LAR 06319 (78.572 g). This meteorite has 61.414 g remaining at JSC and has been allocated to 39 scientists for research. During the 2012 season, 3 more olivine-phyric shergottites were found at Larkman Nunatak, LAR 12011 (701.170 g), LAR 12095 (133.132 g) and LAR 12240 (57.596 g). LAR 12011 is paired with LAR 06319 and LAR 12095 and LAR 12240 are paired with each other. LAR 12011 has been allocated to 43 scientists for research and there are 685.778 g of LAR 12011 remaining at JSC. LAR 12095 has been allocated to 18 scientists for research and has 119.744 g remaining at JSC. LAR 12240 has been allocated to 10 scientists for research and has 52.231 g remaining at JSC. Martian meteorites are the only samples available from Mars because no mission has returned samples from there to date. All Martian meteorites are crustal rocks with most of them being crystallized magmas, so they are an important source for under-standing Martian geological history and volcanism. The ANSMET program has greatly contributed to the scientific community by collecting these meteorites

Funk, R. C.↗

Spectral Interpretation of Magmatic Evolution, Oxidation, and Crystallinity in a Volcanic Planetary Analog System

Volcanic surfaces are common and varied throughout the terrestrial planets. Remote spectroscopy is often the only method for determining surface chemistry and mineralogy of such provinces, and is thus critical for understanding petrologic processes and constraining planetary interior evolution and chemistry. Natural volcanic systems exhibit variability in magmatic chemical evolution, crystallinity, oxidation, and eruption-related alteration (e.g. hydrothermal). The extent to which spectroscopy can identify these characteristics alongside each other is thus a key question for interpreting volcanic processes from orbit. While the effects of each of these on visible/near infrared (VNIR) and thermal infrared (TIR) spectra of igneous rocks has been studied separately to varying degrees, their combined spectral effects (and interpretability of such spectra) are understudied.

Scudder, N. A.↗

Preliminary Results of the Magnetic Properties Experiments on the Mars Exploration Rovers, Spirit and Opportunity

The Mars Exploration Rovers each carry a set of Magnetic Properties Experiments designed to investigate the properties of the air-borne dust in the Martian atmosphere. It is a preferred interpretation of previous experiments (Viking 1 & 2, 1976 and Mars Pathfinder, 1997) that the airborne dust in the Martian atmosphere is primarily composed by composite silicate particles containing one or more highly magnetic minerals as a minor constituent, this minor constituent probably being dominated by the mineral maghemite (gamma-Fe2O3). The ultimate goal of the magnetic properties experiments on the Mars Exploration Rover mission is to provide some information/constraints on whether the dust is formed by volcanic, meteoritic, aqueous, or other processes. In detail, the objectives are: a) To identify the magnetic mineral(s) in the dust, soil and rocks on Mars. b) To establish if the magnetic material is present in the form of nanosized (d < 10 nm) superparamagnetic crystallites embedded in the micrometer sized airborne dust part icles. c) To establish if the magnets are culling a subset of strongly magnetic particles or if essentially all particles of the airborne dust are sufficiently magnetic to be attracted by the magnets. d) Detect compositional differences between the airborne dust and the soil and rock sites which are investigated at two landing sites. To accomplish these goals the Mars Exploration Rovers each carry a set of permanent magnets of several different strengths and sizes. Each magnet has its own specific objective.

Hviid, S. F.↗

An East to West Mineralogical Trend in Mars Exploration Rover Spirit Moessbauer Spectra of Home Plate

Home Plate is a light-toned plateau approx.90 m in diameter within the Inner Basin of the Columbia Hills in Gusev crater on Mars. It is the most extensive exposure of layered bedrock encountered by Spirit to date, and it is composed of clastic rocks of moderately altered alkali basalt composition, enriched in some highly volatile elements. Textural observations suggest an explosive origin and geochemical observations favor volcanism, probably a hydrovolcanic explosion [1]. Since it first arrived at Home Plate on sol 744, Spirit has circumnavigated the plateau (Fig. 1) and is now, since sol 1410, resting at its Winter Haven 3 location at the north end of Home Plate. Results: The MER Moessbauer spectrometers determine Fe oxidation states, identify Fe-bearing mineral phases and quantify the distribution of Fe among oxidation states and mineral phases [2]. Moessbauer spectra of Home Plate bedrock were obtained in five different locations from nine different targets (Fig. 1): Barnhill Ace, Posey Manager, and James Cool Papa Bell Stars at the northwest side of Home Plate; Pesapallo, June Emerson, and Elizabeth Emery on the east side; Texas Chili on the south side; Pecan Pie on the west side; and Chanute on the north side.

Schroder, C.↗

Mars Exploration Rover APXS Results from Matijevic Hill

Correlation analysis of APXS results on the eastern slope rocks indicate that the Matijevic Hill rocks are overall compositionally distinct from the Shoemaker Formation rocks [6]. Compared to the Shoemaker impactites, Matijevic Hill rocks are higher in Al, Si, and Ni, and lower in Ti, Fe, and Zn. No significant variation is evident in the APXS analyses that indicate the presence of a smectite or other phyllosilicate, as opposed to basaltic rocks. However, APXS data cannot in themselves rule out phyllosilicates. If indeed this material contains smectite, as seen from orbit, it implies that the rock has been isochemically altered to create the phyllosilicate content. The Cl content of the Cape York rocks is relatively high, and whereas the S/Cl ratio in the Burns Formation is 4x higher than in soil, in the Cape York rocks it is lower than in soil. These trends indicate that the alteration processes and types of aqueous salt loads were different between Cape York and Meridiani. In addition, significant deviations from the Martian Mn/Fe ratio are observed in Whitewater Lake coatings and the altered Grasford/Deadwood rocks (Fig. 3). These variations indicate that the redox/pH conditions during alteration of the Shoemaker Formation rocks and the Matijevic Hill rocks were similar, but that the Deadwood/Grasberg unit may have undergone alteration under different conditions, possibly at a later time. The Matijevic Hill outcrops appear to share a common genetic origin. It is not yet clear whether both the Shoemaker impactites and Matijevic Hill rocks are related to the formation of Endeavour Crater, or whether the Matijevic Hill suite represents a prior episode of Martian impact or volcanism. Opportunity continues to investigate both hypotheses.

Cohen, B. A.↗

Chlorine Isotopic Compositions of Apatite in Apollo 14 Rocks: Evidence for Widespread Vapor-Phase Metasomatism on the Lunar Nearside ~4 Billion Years Ago

Compared to most other planetary materials in the Solar System, some lunar rocks display high delta (sup 37) Cl signatures. Loss of Cl in a H<<Cl environment has been invoked to explain the heavy signatures observed in lunar samples, either during volcanic eruptions onto the lunar surface or during large scale degassing of the lunar magma ocean. To explore the conditions under which Cl isotope fractionation occurred in lunar basaltic melts, five Apollo 14 crystalline samples were selected (14053,19, 14072,13, 14073,9, 14310,171 along with basaltic clast 14321,1482) for in situ analysis of Cl isotopes using secondary ion mass spectrometry. Cl isotopes were measured within the mineral apatite, with delta (sup 37) Cl values ranging from +14.6 ± 1.6 per mille to +40.0 ± 2.9 per mille. These values expand the range previously reported for apatite in lunar rocks, and include some of the heaviest Cl isotope compositions measured in lunar samples to date. The data here do not display a trend between increasing rare earth elements contents and delta (sup 37) Cl values, reported in previous studies. Other processes that can explain the wide inter- and intra-sample variability of delta (sup 37) Cl values are explored. Magmatic degassing is suggested to have potentially played a role in fractionating Cl isotope in these samples. Degassing alone, however, could not create the wide variability in isotopic signatures. Our favored hypothesis, to explain small scale heterogeneity, is late-stage interaction with a volatile-rich gas phase, originating from devolatilization of lunar surface regolith rocks ~4 billion years ago. This period coincides with vapor-induced metasomastism recorded in other lunar samples collected at the Apollo 16 and 17 landing sites, pointing to the possibility of widespread volatile-induced metasomatism on the lunar nearside at that time, potentially attributed to the Imbrium formation event.

apatit↗