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At least 469 records · Page 26

The optical spectrum of R136a - The central object of the 30 Doradus nebula

R136 (HD 38268) is the brightest member of the compact cluster of stars at the center of the 30 Doradus Nebula, a massive H II region in the Large Magellanic Cloud (LMC). The far-ultraviolet luminosity is equivalent to at least 1000 ordinary O type stars. Optically, R136 is an unresolved patch corresponding to a linear extent of about 0.7 pc. Several components are known to be present, of which R136a is the brightest. A quantitative description of the optical spectrum of R136a has not been available in the literature. The present investigation is concerned with the analysis of spectrograms in the visible region. It is found that the optical spectrum of R136a shows broad but rather weak emission lines of ions which are frequently seen in early WN-type stars. The centroid of H-alpha is displaced by approximately 100 km/s redward of the nebular H-alpha emission. The Balmer series is visible, in absorption, up to H11.

Ebbets, D. C.↗

On-Orbit Radiometric Characterization of OLI (Landsat 8) for Applications in Aquatic Remote Sensing

Landsat-8 carries two separate sensors, namely the Operational Land Imager (OLI) and the Thermal Infrared Radiometer Suite (TIRS), that image the earth surface throughout the visible and thermal portions of the spectrum. Compared to Landsat heritage sensors, the OLI has enhanced features, which include its 12-bit radiometric resolution and the addition of a band centered at 443 nm. The dramatically improved data quality/quantity expands existing applications of Landsat imagery in aquatic sciences from the retrieval of bio-geochemical properties, such as near-surface concentrations of chlorophyll-a (CHL) and total suspended solids (TSS), to benthic mapping. This study offers analysis of OLI's absolute radiometric performance over bodies ofwater using benchmark observations, namely the top-of-atmosphere (TOA) ocean color observations and marine in situ radiometric measurements. Sensor-to-sensor comparisons are performed to derive gain factors (g1) from near-concurrent observations in TOA radiance and reflectance domains. The gains in the radiance domain were further validated/adjusted by determining a second set of gains (g2) via analysis of OLI-derived water-leaving radiance, i.e., L(sub w) (gamma), against in situ measurements made either at the Ocean Color AErosol RObotic NETwork (AERONETOC) sites or during field campaigns. The analyses yield the OLI calibration uncertainties that need to be accounted forwhen studying aquatic environments. Itwas found that, for the visible and near-infrared channels, the OLI radiometric responses, on average, are well in agreement (b 2 % discrepancies) with the TOA radiances estimated by ocean color satellites or those predicted by models based onmeasurements of aquatic and atmospheric properties. However, the TOA radiance at the new 443-nm band is found to be, on average, 3.4 % larger than the reference observations. The inter-sensor comparisons in the reflectance domain, however, indicated slightly different results with the OLI responses being low in the blue bands. To enhance the retrieval accuracy of aquatic-science products from OLI datasets, sets of temporally averaged gains (radiance and reflectance) are derived and recommended for use prior to the retrieval of in-water products.

Remote Sensing↗

Triel-Defined Helicity in One-Dimensional III–VI–VII van der Waals Crystals

Inorganic extended lattice solids that bear complex helical motifs manifest unusual physical and quantum states that arise due to their noncentrosymmetric or chiral nature. However, the systematic understanding of how elemental composition influences the structure and physical properties in helical inorganic crystals has been precluded by the rarity of these materials and the lack of modular phases that display such motifs. Here, we report the synthesis of AlSeI single crystals, the first aluminum-containing helical crystal in the III-VI-VII 1D van der Waals class. AlSeI completes the experimentally accessible triel series in the helical selene iodides alongside InSeI and GaSeI. Using the Al, Ga, and In triel series in this selene iodide class, we experimentally demonstrate the evolution of the local quasi-tetrahedral building unit geometry, chain packing, helical parameters, and band gaps based primarily on the identity of the triel atom. Our results underscore the chemical modularity of these phases, the broad range of helical parameters, and the spectrum of electronic states from the visible to the ultraviolet range in this emergent class of 1D, exfoliable, and helical extended lattice solids.

Chemical structure↗

Photoluminescence of a Uranium(IV) Alkoxide Complex

In this report, we describe the photoluminescence of a homoleptic uranium(IV) alkoxide complex. Excitation of [Li(THF)] 2 [U IV (O t Bu) 6 ] leads to the first example of photoluminescence from a well-defined actinide complex originating from an f–f excitation, supported by second order multiconfigurational electronic structure calculations including spin–orbit coupling. These calculations show strong spin–orbit coupling between the excited triplet and singlet states for the 5f-orbital manifold, which leads to a long-lived excited state lifetime of 0.85 s at low temperature. The photophysical properties of homoleptic uranium(V) and uranium(VI) tertbutoxide complexes are also presented; we find that oxidation of the uranium(IV) alkoxide results in quenching of luminescence in [Li(THF)][U V (O t Bu) 6 ] and [U VI (O t Bu) 6 ]. This is attributed to competing ligand to metal charge transfer absorption processes shifted to lower energy upon oxidation of the actinide center, which mask the relevant f–f transitions in the visible region of the electronic absorption spectrum.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Extreme-ultraviolet spatiotemporal vortices via high harmonic generation

Spatiotemporal optical vortices (STOVs) are space–time structured light pulses with a unique topology that couples spatial and temporal domains and carry transverse orbital angular momentum (OAM). Up to now, their generation has been limited to the visible and infrared regions of the spectrum. During the last decade, it was shown that through the process of high-order harmonic generation, it is possible to upconvert spatial optical vortices that carry longitudinal OAM from the near-infrared into the extreme-ultraviolet (EUV), thereby producing vortices with distinct femtosecond and attosecond structure. In this work, we demonstrate theoretically and experimentally the generation of EUV spatiotemporal and spatiospectral vortices using near-infrared STOV driving laser pulses. Here, we use analytical expressions for focused STOVs to perform macroscopic calculations of high-order harmonic generation that are directly compared to the experimental results. As STOV beams are not eigenmodes of propagation, we characterize the highly charged EUV STOVs in both the near and far fields to show that they represent conjugated spatiotemporal and spatiospectral vortex pairs. Our work provides high-frequency light beams topologically coupled at the nanometre/attosecond scales domains with transverse OAM that could be suitable to explore electronic dynamics in magnetic materials, chiral media and nanostructures.

High-harmonic generation↗

Model of photoemission and framework for relating quantum efficiency to stoichiometry

Simulating the quantum efficiency (QE) from photocathodes used in accelerators and photoinjectors requires accounting for the properties of the photoemissive material, the optical properties, scattering coefficients, and doping concentrations of which are dependent upon the stoichiometry. We present a rapid and flexible optical model that can be used to investigate the consequences of changes in the dielectric properties and their impact on the QE through such factors as reflectivity and laser penetration depth. Differences in materials can then be characterized by changes to parameters used to evaluate the dielectric function in a Lorentz–Drude–Resonant model. A method to characterize data is motivated by the example of copper and vetted by application to an exact analytical model. The effects of changes in parameters describing the resonant terms, which aggregate in the visible and UV regions of the spectrum, are shown.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Red clouds in reducing atmospheres

A dark reddish-brown high-molecular weight polymer is produced by long wavelength ultraviolet irradiation of abundant gases in reducing planetary atmospheres. The polymer is examined by paper chromatography, mass spectrometry, and infrared, visible, and ultraviolet spectroscopy. High carbon-number straight-chain alkanes with NH2 and, probably, OH and C = O groups are identified, along with amino acids. There are chemical similarities between this polymer and organic compounds recovered from carbonaceous chondrites and precambrian sediments. The visible and near-ultraviolet transmission spectrum of the polymer shows its absorption optical depth to be redder than lambda(-2) and perhaps similar in coloration to the clouds of Jupiter, Saturn, and Titan. The nitrile content is small, and the polymer should be semitransparent in the 5 micrometer atmospheric window. Such polymers may be a common constituent of clouds in the outer solar system and on the early earth.

Khare, B. N.↗

Infrared tunable laser: A concept

Apparatus in which laser wavelengths of two dyes are mixed in intracavity, nonlinear crystal provides intense source of coherent laser radiation which is tunable from visible through infrared wavelengths of electromagnetic spectrum.

Billman, K. W.↗

Identification of HgO/x/ species by matrix isolation spectroscopy

The condensation of Hg atoms in an ozone-doped argon matrix gas with irradiation from a medium-pressure mercury arc lamp at 10 K resulted in the formation of several trapped HgO(x) species. Tentative identification of HgO has been made from absorption bands appearing in the visible and IR regions of the spectrum based on (O-16)2 and (O-18)2 isotope studies. The following spectroscopic constants were obtained: nu(00) = 14634 cm, nu(1) = 548 cm, and nu(11) = 676 cm. Some qualitative evidence was obtained for the existence of HgO2.

Butler, R.↗

Titan aerosols - Optical properties and vertical distribution

An analysis of Titan's solar phase variation as a function of wavelength together with the continuum geometric albedo makes it possible to set limits on the real part of the refractive index and on the average particle size of the aerosol component of Titan's atmosphere of between about 1.5 and 2.0 and between 0.20 microns and about 0.35 microns, respectively. If the real part of the refractive index is known the average particle size can be determined to within a few percent, and varies inversely with the real part of the refractive index. Using this information in a two-layer model of a methane-aerosol atmosphere and comparing the result with Titan's visible and near-infrared methane spectrum leads to the conclusion that the top layer of Titan's atmosphere contains 0.01 km atm of methane and 2.5 extinction optical depths of aerosol, while the data are consistent with a bottom layer containing 2.2 km atm of methane and about 7.5 aerosol optical depths for a real part of the refractive index equal to 1.7 and an average particle size of 0.25 microns.

Rages, K.↗

Ultraviolet spectroscopic observations of VV Cephei

Observations with the International Ultraviolet Explorer satellite (IUE) of the recent egress of the eclipsing binary VV Cep(M2Iabep + B) are presented. Egress in the ultraviolet lagged behind the visible egress by 2 to 3 months, as a result of higher opacity of the M star atmosphere in the ultraviolet. Shortly after visible egress, the low-dispersion spectrum from 1200-1900 wavelengths was dominated by fluorescent emission lines arising in the atmosphere of the M star and excited by the ultraviolet continuum of the hot companion. High-dispersion spectra show a hot continuum blanketed by absorption lines, some of which weaken or disappear as the egress continues. A year after eclipse, the absorption spectrum is still too complex to permit determination of a spectral type for the hot companion. The Mg II h and k lines both exhibit asymmetric double-peaked emission features indicative of an expanding chromosphere in the M supergiant.

Hagan, W.↗

Portable Radiometer Monitors Plant Growth

Three-band hand-held spectral radiometer measures electromagnetic energy reflected from plant canopies in the visible and infrared portions of the spectrum. It is mobile and easy to use for rapid, repeated measurements. Radiometer probe is held level over plant canopy, readout range switches are set and measurements are recorded. Chlorophyll content, leaf area index and leaf water content can be quickly and easily measured.

Tucker, C. J., III↗

Ultraviolet albedo of Comet West /1976 VI/

The nature of the dust scattered radiation shown in the ultraviolet spectrum of Comet West is analyzed. The continuum of solar radiation scattered by cometary dust is detected to wavelengths as short as 2100 A and is found to follow closely the solar spectrum. The flux from the entire visible coma is included in the spectrometer slit. A comparison of the ultraviolet with the visible solar flux gives the ratio of the albedo at 2700 A to that of 5500 A as about 0.3. Even with all the uncertainties included (the absolute calibration uncertainty is plus or minus 15%), the evidence for strong reddening between the visible and the ultraviolet is clear. A further decrease in albedo is found near 2200 A. The value of the visible albedo of 0.2 is used to derive a value of 0.6 for the cometary albedo at 2700 A. This value is similar to that found for the moon and lunar dust in this spectral region.

Feldman, P. D.↗

A stochastic atmospheric model for remote sensing applications

There are many factors which reduce the accuracy of classification of objects in the satellite remote sensing of Earth's surface. One important factor is the variability in the scattering and absorptive properties of the atmospheric components such as particulates and the variable gases. For multispectral remote sensing of the Earth's surface in the visible and infrared parts of the spectrum the atmospheric particulates are a major source of variability in the received signal. It is difficult to design a sensor which will determine the unknown atmospheric components by remote sensing methods, at least to the accuracy needed for multispectral classification. The problem of spatial and temporal variations in the atmospheric quantities which can affect the measured radiances are examined. A method based upon the stochastic nature of the atmospheric components was developed, and, using actual data the statistical parameters needed for inclusion into a radiometric model was generated. Methods are then described for an improved correction of radiances. These algorithms will then result in a more accurate and consistent classification procedure.

Turner, R. E.↗

Shuttle glow emissions due to radiative relaxation of highly vibrationally excited NO molecules produced by surface reflection

A new mechanism is proposed for the Space Shuttle glow, which is due to the radiative relaxation of ambient nitric-oxide molecules that are excited to very high vibrational levels by collisions with the Shuttle surface. Many of the particles colliding with the Shuttle surface at a very high speed (about 8 km/sec) would bounce off, exciting vibrational and rotational motions of molecules up to the level of vibrational quantum number v not greater than 35. Radiative transfer from these high levels should cause emissions in the spectrum range from infrared (IR) to visible red depending upon the transition paths. A perturbation method is used to calculate the transition probability and the emission intensity for the transitions of Delta-v not greater than 4. The result indicates that the Delta-v not greater than 4 transitions from high vibrational levels dominates the other transitions; the Delta-v = 4 transitions generally occur at the IR range.

Shimazaki, T.↗

Remote sensing of atmosphere-surface interaction parameters

Examples are given of the accuracy of the results obtained from the HIRS 2/MSU (High Resolution Infrared Sounder and Microwave Sounding Unit) analysis of ocean, atmosphere, and land parameters. Sea surface temperatures are compared with available ship and buoy radiosonde data, and land surface temperatures are compared with shelter temperatures. The seasonal change in land and ocean skin surface temperature is reviewed. The distribution of clouds is examined and their opacities in the visible and infrared parts of the spectrum are compared.

Chahine, M. T.↗

Detection of a 'rotating' gas cloud 100 kiloparsecs in diameter surrounding 3C 275.1, a quasar at the center of a rich cluster of galaxies

The distorted radio quasar 3C 275.1 (z = 0.55) is the first QSO found to lie at the center of a rich cluster of galaxies. The quasar is surrounded by an extremely large elliptical nebulosity whose major axis exceeds 100 kpc. Spectroscopic observations of this nebulosity were obtained, with the spectrograph slit aligned along the nebulosity's major axis. The spectrum of the nebulosity in the visible is dominated by O II and O III forbidden emission lines, which yield a well-defined 'solid-body rotation curve' extending 40 kpc from the quasar nucleus, a rotation curve very different from those of normal spiral galaxies. The 3C 275.1 nebulosity is both the largest yet discovered around a quasar and the first in which organized large-scale motions (rotation?) have been identified. The nebulosity may be residue from multiple tidal interactions with cluster members, or it may be accumulated material from a 'cooling flow' of the type seen in low-redshift clusters which are X-ray sources.

Hintzen, P.↗

Measuring and modeling spectral characteristics of a tallgrass prairie

This study was conducted to evaluate the diurnal and seasonal, spectral reflectance characteristics of burned and unburned areas of a tallgrass prairie, based on field measurements and models of radiation transport in plant canopies. Burning of the senescent vegetation, resulting from the previous years' growth, is a common management practice, which results in improved productivity and affects the succession of grass species. The burned and unburned grass canopies showed distinctly different, diurnal and seasonal, spectral reflectance characteristics in the visible and infrared regions of the spectrum. These were attributed to the differences in development of the two plant canopies and the azimuthal differences in sensor-sun-canopy positions during field measurements of spectral reflectance. The radiation transfer model properly simulated the diurnal spectral behavior of the two canopies. The simulated, seasonal, spectral reflectance values for the unburned grass canopy were greater than the measured ones, because of limitations in proper representation of the layer of senescent vegetation in the model.

Asrar, G.↗