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At least 469 records · Page 26

Advanced Systems Map, Monitor, and Manage Earth's Resources

SpecTIR LLC, headquartered in Reno, Nevada, is recognized for innovative sensor design, on-demand hyperspectral data collection, and image-generating products for business, academia, and national and international governments. SpecTIR's current vice president of business development has brought a wealth of NASA-related research experience to the company, as the former principal investigator on a NASA-sponsored hyperspectral crop-imaging project. This project, made possible through a Small Business Technology Transfer (STTR) contract with Goddard Space Flight Center, aimed to enhance airborne hyperspectral sensing and ground-truthing means for crop inspection in the Mid-Atlantic region of the United States. Areas of application for such technology include precision farming and irrigation; oil, gas, and mineral exploration; pollution and contamination monitoring; wetland and forestry characterization; water quality assessment; and submerged aquatic vegetation mapping. Today, SpecTIR maintains its relationship with Goddard through programs at the University of Maryland in College Park, Maryland, and at the U.S. Department of Agriculture campus in Beltsville, Maryland. Additionally, work continues on the integration of hyperspectral data with LIDAR systems and other commercial-off-the-shelf technologies.

Source record↗

Autonomous Radiation Mapping and Quantification using an Unmanned Ground Vehicle. Part I - Environment Mapping

When characterizing facilities, advanced autonomous systems are safe, efficient, and cost-effective tools, which can safely deploy state-of-the-art instrumentation without exposing workers to radiation risks. One main focus of the research is the visual mapping of the environment.This paper presents a framework for the mapping aspect that utilizes lidar and SLAM technologies coupled with a monocular camera to create a point cloud of the environment. Upon completion, the present research work aims to provide an autonomous mobile robot the capability to localize itself and aid the user with visualizing the radiation data. Challenges: C++ node needs to properly synchronize image and point cloud data. 3D lidar has resolution of ± 3 cm. Proper camera calibration needed. Transforms need to be precise for proper alignment of image and point-cloud. Results: Voxelated point clouds. Accurate colors from calibrated cameras including details smaller than lidar resolution. Developed Robotics Operating System (ROS) package for ease of transfer to other robot platforms.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Mineralogic variations in fluvial sediments contaminated by mine tailings as determined from AVIRIS data, Coeur D'Alene River Valley, Idaho

The success of imaging spectrometry in mineralogic mapping of natural terrains indicates that the technology can also be used to assess the environmental impact of human activities in certain instances. Specifically, this paper describes an investigation into the use of data from the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) for mapping the spread of, and assessing changes in, the mineralogic character of tailings from a major silver and base metal mining district. The area under investigation is the Coeur d'Alene River Valley in northern Idaho. Mining has been going on in and around the towns of Kellogg and Wallace, Idaho since the 1880's. In the Kellogg-Smelterville Flats area, west of Kellogg, mine tailings were piled alongside the South Fork of the Coeur d'Alene River. Until the construction of tailings ponds in 1968 much of these waste materials were washed directly into the South Fork. The Kellogg-Smelterville area was declared an Environmental Protection Agency (EPA) Superfund site in 1983 and remediation efforts are currently underway. Recent studies have demonstrated that sediments in the Coeur d'Alene River and in the northern part of Lake Coeur d'Alene, into which the river flows, are highly enriched in Ag, Cu, Pb, Zn, Cd, Hg, As, and Sb. These trace metals have become aggregated in iron oxide and oxyhydroxide minerals and/or mineraloids. Reflectance spectra of iron-rich tailing materials are shown. Also shown are spectra of hematite and goethite. The broad bandwidth and long band center (near 1 micron) of the Fe(3+) crystal-field band of the iron-rich sediment samples combined with the lack of features on the Fe(3+) -O(2-) charge transfer absorption edge indicates that the ferric oxide and/or oxyhydroxide in these sediments is poorly crystalline to amorphous in character. Similar features are seen in poorly crystalline basaltic weathering products (e.g., palagonites). The problem of mapping and analyzing the downriver occurrences of iron rich tailings in the Coeur d'Alene (CDA) River Valley using remotely sensed data is complicated by the full vegetation cover present in the area. Because exposures of rock and soil were sparse, the data processing techniques used in this study were sensitive to detecting materials at subpixel scales. The methods used included spectral mixture analysis and a constrained energy minimization technique.

Farrand, W. H.↗

Retrieval of Vertical LAI Profiles Over Tropical Rain Forests using Waveform Lidar at La Selva, Costa Rica

This study explores the potential of waveform lidar in mapping the vertical and spatial distributions of leaf area index (LAI) over the tropical rain forest of La Selva Biological Station in Costa Rica. Vertical profiles of LAI were derived at 0.3 m height intervals from the Laser Vegetation Imaging Sensor (LVIS) data using the Geometric Optical and Radiative Transfer (GORT) model. Cumulative LAI profiles obtained from LVIS were validated with data from 55 ground to canopy vertical transects using a modular field tower to destructively sample all vegetation. Our results showed moderate agreement between lidar and field derived LAI (r2=0.42, RMSE=1.91, bias=−0.32), which further improved when differences between lidar and tower footprint scales (r2=0.50, RMSE=1.79, bias=0.27) and distance of field tower from lidar footprint center (r2=0.63, RMSE=1.36, bias=0.0) were accounted for. Next, we mapped the spatial distribution of total LAI across the landscape and analyzed LAI variations over different land cover types. Mean values of total LAI were 1.74, 5.20, 5.41 and 5.62 over open pasture, secondary forests, regeneration forests after selective-logging and old-growth forests respectively. Lastly, we evaluated the sensitivities of our LAI retrieval model to variations in canopy/ground reflectance ratio and to waveform noise such as induced by topographic slopes. We found for both, that the effects were not significant for moderate LAI values (about 4). However model derivations of LAI might be inaccurate in areas of high-slope and high LAI (about 8) if ground return energies are low. This research suggests that large footprint waveform lidar can provide accurate vertical LAI profile estimates that do not saturate even at the high LAI levels in tropical rain forests and may be a useful tool for understanding the light transmittance within these canopies.

Tang, Hao↗

Saturns Thermal Emission at 2.2-cm Wavelength as Imaged by the Cassini RADAR Radiometer

We present well-calibrated, high-resolution maps of Saturn's thermal emission at 2.2-cm wavelength obtained by the Cassini RADAR radiometer through the Prime and Equinox Cassini missions, a period covering approximately 6 years. The absolute brightness temperature calibration of 2% achieved is more than twice better than for all previous microwave observations reported for Saturn, and the spatial resolution and sensitivity achieved each represent nearly an order of magnitude improvement. The brightness temperature of Saturn in the microwave region depends on the distribution of ammonia, which our radiative transfer modeling shows is the only significant source of absorption in Saturn's atmosphere at 2.2-cm wavelength. At this wavelength the thermal emission comes from just below and within the ammonia cloud-forming region, and yields information about atmospheric circulations and ammonia cloud-forming processes. The maps are presented as residuals compared to a fully saturated model atmosphere in hydrostatic equilibrium. Bright regions in these maps are readily interpreted as due to depletion of ammonia vapor in, and, for very bright regions, below the ammonia saturation region. Features seen include the following: a narrow equatorial band near full saturation surrounded by bands out to about 10deg planetographic latitude that demonstrate highly variable ammonia depletion in longitude; narrow bands of depletion at -35deg latitude; occasional large oval features with depleted ammonia around -45deg latitude; and the 2010-2011 storm, with extensive saturated and depleted areas as it stretched halfway around the planet in the northern hemisphere. Comparison of the maps over time indicates a high degree of stability outside a few latitudes that contain active regions.

composition↗

Kelvin probe force microscopy under ambient conditions

Kelvin probe force microscopy (KPFM) is a technique derived from atomic force microscopy that provides maps of surface potential or work function differences across material systems, with nanometre-scale resolution. KPFM is a useful tool for investigating electrical phenomena such as dipole orientation, interfacial charge transfer, charge accumulation, band bending and doping levels. This Primer aims to provide an overview of typical ambient-condition KPFM measurements, covering their underlying principles, experimental implementations and wide-ranging applications. Key KPFM variants, including amplitude and frequency modulation, heterodyne detection schemes and innovative open loop and pulsed force techniques, are discussed, with practical guidance on optimizing signal acquisition and reducing errors. Specialized approaches, such as time-resolved KPFM and multimodal KPFM, are discussed for their ability to capture dynamic charge processes and chemical information, respectively. Here, we highlight recent advances in KPFM applications, spanning metal alloys, soft matter, ferroelectrics, photovoltaics and 2D materials, showcasing its versatility across research domains. By addressing current limitations and identifying future opportunities, this Primer underscores the transformative potential of KPFM in advancing the understanding of nanoscale electrical phenomena.

Zahmatkeshsaredorahi, Amirhossein [Lehigh Univ., B↗

Dominant effect of anharmonicity on the equation of state and thermal conductivity of MgO under extreme conditions

Understanding heat transfer in the earth mantle region is of great scientific interest but highly challenging due to dissimilar conditions from our daily lives. Thermal conductivity of highly pressured and thermally activated materials can be completely different from that at ambient condition. In this study we calculate the equation of state and thermal conductivity of cubic crystalline MgO, a major component of the mantle, in such an environment. It is shown that the material properties are not accurately captured unless rigorous treatment of anharmonicity of phonon vibrational motion is explicitly applied. To predict renormalized phonon dispersion relations, interatomic force constants of high-order expansion are required, especially at elevated temperature. The anharmonicity plays an increasingly substantial role for regulating volume expansion as temperature rises, because the Gibbs free energy of MgO considerably deviates from what was predicted by the quasiharmonic approximation. We find that the lattice thermal conductivity of MgO and the heat transfer of the earth's mantle are reliably estimated only when both the temperature-dependent renormalization of phonon frequencies and four-phonon scattering effects are taken into consideration. We map the characteristics at Geotherm into contour diagrams in which equilibrium volumes and the thermal conductivities are described as functions of temperature and pressure. Furthermore, the thermal conductivity values of MgO in this study are smaller than those in previous theoretical studies due to the additional incorporation of four-phonon scatterings in the calculations. Specifically, deviation between the values in previous studies and in this study becomes larger as thermodynamic variables reach those near the core-mantle boundary. For instance, thermal conductivities of 52.15 and 23.67 Wm -1 K -1 are estimated at ambient and extreme conditions (T = 4000K and P = 135 GPa), respectively.

36 MATERIALS SCIENCE↗

Introductory aerothermodynamics of advanced space transportation systems

An assessment is made of the severity of the physical phenomena affecting the aerothermodynamics of advanced space transportation system hypervelocity flights at low ambient density, and flight domains corresponding to these phenomena are mapped. The development of advanced computational codes that will be needed when approximate conceptual studies have defined advantageous configurations is discussed. The advanced space transportation systems considered are an aeroassisted orbital transfer vehicle and a small, rapid response maneuverable craft which is launched either from earth or a conventional aircraft, assumes near-earth orbit, and finally reenters with lift and cross range capability to land on an airstrip.

Howe, J. T.↗

Mapping transformations for broadband atmospheric radiation calculations

Two methods of mapping the line-by-line absorption coefficient (k) spectrum onto a new variable to produce a set of k coefficients which can be used for accurate and efficient broadband radiative transfer calculations in vertically inhomogeneous, nongray scattering atmospheres are described. These methods are intended for applications for which the less accurate correlated-k method is inadequate. These methods are tested for model atmospheres containing CO2 and H2O, with pressure in the range 0.05-0.9 bar. The results obtained differed by no more than 1 or 2 percent from the line-by-line results if the number of k coefficients was about 100 times less than the number required for the line-by-line calculation. These algorithms can be used for gas mixtures and for a variety of pressure-temperature profiles.

West, Robert↗

Multiple GISS AGCM Hindcasts and MSU Versions of 1979-1998

Multiple realizations of the 1979-1998 time period have been simulated by the Goddard Institute for Space Studies Atmospheric General Circulation Model (GISS AGCM) to explore its responsiveness to accumulated forcings, particularly over sensitive agricultural regions. A microwave radiative transfer postprocessor has produced the AGCM's lower tropospheric, tropospheric and lower stratospheric brightness temperature (Tb) time series for correlations with the various Microwave Sounding Unit (MSU) time series available. MSU maps of monthly means and anomalies were also used to assess the AGCM's mean annual cycle and regional variability. Seven realizations by the AGCM were forced by observed sea surface temperatures (sst) through 1992 to gather rough standard deviations associated with internal model variability. Subsequent runs hindcast January 1979 through April 1998 with an accumulation of forcings: observed ssts, greenhouse gases, stratospheric volcanic aerosols. stratospheric and tropospheric ozone and tropospheric sulfate and black carbon aerosols. The goal of narrowing gaps between AGCM and MSU time series was complicated by MSU time series, by Tb simulation concerns and by unforced climatic variability in the AGCM and in the real world. Lower stratospheric Tb correlations between the AGCM and MSU for 1979-1998 reached as high as 0.91 +/-0.16 globally with sst, greenhouse gases, volcanic aerosol, stratospheric ozone forcings and tropospheric aerosols. Mid-tropospheric Tb correlations reached as high as 0.66 +/-.04 globally and 0.84 +/-.02 in the tropics. Oceanic lower tropospheric Tb correlations similarly reached 0.61 +/-.06 globally and 0.79 +/-.02 in the tropics. Of the sensitive agricultural areas considered, Nordeste in northeastern Brazil was simulated best with mid-tropospheric Tb correlations up to 0.75 +/- .03. The two other agricultural regions, in Africa and in the northern mid-latitudes, suffered from higher levels of non-sst variability. Zimbabwe had a maximum mid-tropospheric correlation of 0.54 +/- 0.11 while the U.S. Cornbelt had only 0.25 +/- .10. Precipitation and surface temperature performance are also examined over these regions. Correlations of MSU and AGCM time series mostly improved with addition of explicit atmospheric forcings in zonal bands but not in agricultural regional bins each encompassing only six AGCM gridcells.

Shah, Kathryn Pierce↗

Aerobraking at Mars: The MGS Mission

The Mars Global Surveyor (MGS) mission, scheduled for launch in November 1996, will employ aerobraking as a means of reaching a low altitude, sun-synchronous mapping orbit. This technique is necessary to minimize the cost of the mission. The dry mass of the spacecraft and the launch vehicle capability do not permit an all-propulsive transfer to the desired orbit. Aerobraking concepts are discussed.

Mars↗

Accelerated thermal property mapping of TRISO advanced nuclear fuel

TRistructural ISOtropic (TRISO) fuel is a leading-edge nuclear fuel form representing a departure from the more traditional nuclear fuel forms utilized in the reactor fleet of today. Rather than a monolithic fuel pellet of uranium dioxide, integral fuel forms containing TRISO fuel are composed of thousands of microencapsulated uranium-bearing fuel kernels and individually coated with multiple layers of pyrolytic carbon and silicon carbide. These multilayered ceramic coatings serve as an environmental barrier to ensure radioactive and chemically reactive fission products are contained within the reactor fuel elements, but also participate in the transfer of heat generated in the nuclear fuel to the coolant – the primary purpose of a nuclear reactor. Since traditional thermal property measurement techniques, such as laser flash analysis, would be unable to resolve the thermal properties of the individual TRISO coating layers, a simplified frequency-domain thermoreflectance technique has been developed to rapidly map the thermal properties of TRISO particles. Using this technique, the thermal properties of TRISO particles have been mapped from room temperature up to 1000 °C to examine the spatial variation and temperature-dependency of the thermal properties within each layer. Additionally, spatial-domain thermoreflectance was used to examine the anisotropy of the thermal properties for each layer at different locations within a single TRISO particle, and across multiple TRISO particles to assess the intra- and inter-particle uniformity of thermal properties, respectively. To elucidate the underlying causes for the measured variations in thermal properties, scanning electron microscopy and Raman spectroscopy were used to examine variations in microstructure and chemical bonding within the different coating layers. Results from this work are then compared with previous examinations of TRISO fuel particles and microstructurally driven mechanisms for the variations in the measured thermal properties of the different carbonaceous layers are discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Trust-Enhancing Probabilistic Transfer Learning for Sparse and Noisy Data Environments

There is an increasing aspiration to utilize machine learning (ML) for various tasks of relevance to national security. ML models have thus far been mostly applied to tasks and domains that, while impactful, have sufficient volume of data. For predictive tasks of national security relevance, ML models of great capacity (ability to approximate nonlinear trends in input-output maps) are often needed to capture the complex underlying physics. However, scientific problems of relevance to national security are often accompanied by various sources of sparse and/or incomplete data, including experiments and simulations, across different regimes of operation, of varying degrees of fidelity, and include noise with different characteristics and/or intensity. State-of-the-art ML models, despite exhibiting superior performance on the task and domain they were trained on, may suffer detrimental loss in performance in such sparse data environments. This report summarizes the results of the Laboratory Directed Research and Development project entitled Trust-Enhancing Probabilistic Transfer Learning for Sparse and Noisy Data Environments. The objective of the project was to develop a new transfer learning (TL) framework that aims to adaptively blend the data across different sources in tackling one task of interest, resulting in enhanced trustworthiness of ML models for mission- and safety-critical systems. The proposed framework determines when it is worth applying TL and how much knowledge is to be transferred, despite uncontrollable uncertainties. The framework accomplishes this by leveraging concepts and techniques from the fields of Bayesian inverse modeling and uncertainty quantification, relying on strong mathematical foundations of probability and measure theories to devise new uncertainty-aware TL workflows.

97 MATHEMATICS AND COMPUTING↗

Orbital Engineering Mediated by Cation Conjugation in Luminescent Uranyl–Organic Hybrid Materials

A series of compounds of the form [HAr]2[UO2X4] is reported here, wherein Ar is systematically varied between pyridine (1-X), quinoline (2-X), acridine (3-X), 2,5-dimethylpyrazine (4-X), quinoxaline (5-X), and phenazine (6-X), and X = Cl or Br. With greater conjugation in the organic cation, a larger quenching in uranyl luminescence is observed in the solid state. Supporting our luminescence experiments with computation, we map out the potential energy diagrams for the singlet and triplet states of both the [HAr]+ cations and [UO2Cl4]2– anion in the crystalline state, and of the assembly. The distinct energy transfer pathways in each compound are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dissolution of periodic arrays of grains: Upscaling of pore-scale simulations with fast reactions

Upscaling methods are frequently used to derive transport equations at the macroscopic scale from more fundamental equations formulated at the pore scale. These methods typically give a suitable structure for the macroscopic equations and can also provide explicit expressions for the constitutive parameters, such as permeability and dispersion coefficients. Introducing chemical reactions complicates upscaling in at least two important ways. First, the interplay between chemical reactions and transport processes introduces a new length scale, which can be much smaller than the convective or dispersive length scales. A small reactive length scale breaks one of the key assumptions in upscaling; that there is a significant separation in length between the pore-scale and macro-scale processes. The second complication is that if reactions take place at mineral surfaces (dissolution or precipitation) then the pore space itself is evolving in time. In this paper we suggest ways in which these difficulties can be approached, based on analysis of pore-scale simulation data. First, we noticed that the concentration field in successive unit cells has an almost identical spatial variation, with a single scaling factor for each unit cell that is proportional to the incoming reactant flux. Using pore-scale simulations to determine the mass transfer coefficient in a few unit cells, we can calculate the concentration field in the whole domain, even when dissolution is entirely transport limited. Second, we have noticed a time-dependent mapping of the grain shapes from different unit cells. From these observations, we can deduce constitutive relations where the only time-varying parameter is the porosity. Here, we show that a model based on these ideas can quantitatively account for the pore-scale simulation data.

58 GEOSCIENCES↗

Radio and optical observations of the R Aquarii jet

VLA observations at 6 cm and Lick Observatory optical plates of R Aquarii indicate the existence of a jetlike feature extending 7 to 10 arcsec from the central star. A wide field map at 6 cm shows an unresolved compact radio source which lies close to the axis defined by the jet at a distance of about three arcmin from R Aqr. Episodic mass transfer in this symbiotic variable could explain the erratic outbursts that R Aqr is known to undergo. Formation of an accretion disk and the accompanying radio-optical jet may characterize the observed outbursts in this system.

Sopka, R. J.↗

Asymptotic unbounded root loci - Formulas and computation

A new geometric way of computing the asymptotic behavior of unbounded root loci of a strictly proper linear time-invariant control system as loop gain goes to infinity is presented. Properties of certain restricted linear maps and nested restrictions of linear maps are developed, and formulas are obtained for the leading coefficient of the asymptotic values of the unbounded multivariable root loci are obtained in terms of eigenvalues of those maps. Published results and a certain simple null structure assumption are used to relate these asymptotic values to the structure at infinity of the Smith-McMillan form of the open loop transfer function. Explicit matrix formulas for the more abstract derived formulas are given and additional geometric insights are developed with orthogonal projections and singular value decomposition. Formulas for the pivots of the unbounded root loci are calculated and shown to have the same form as the coefficients of the unbounded asymptotic root loci.

Sastry, S. S.↗

System Modeling of Metabolic Heat Regenerated Temperature Swing Adsorption (MTSA) Subassembly for Prototype Design

This paper describes modeling methods for the three core components of a Metabolic heat regenerated Temperature Swing Adsorption (MTSA) subassembly: the sorbent bed, a sublimation (cooling) heat exchanger (SHX), and a condensing icing (warming) heat exchanger (CIHX). The primary function of the MTSA, removing carbon dioxide from a ventilation loop, is performed via the sorbent bed. The CIHX is used to heat the sorbent bed for desorption and to remove moisture from the ventilation loop while the SHX is alternately employed to cool the sorbent bed via sublimation of a spray of water at low pressure to prepare the reconditioned bed for the next cycle. This paper describes a system level model of the MTSA as developed in Thermal Desktop and SINDA/FLUINT including assumptions on geometry and physical phenomena, modeling methodology and relevant pa ra mete rizatio ns. Several areas of particular modeling interest are discussed. In the sorbent bed, capture of the translating CO2 saturation front and associated local energy and mass balance in both adsorbing and desorbing modes is covered. The CIHX poses particular challenges for modeling in SINDA/FLUINT as accounting for solids states in fluid submodels are not a native capability. Methods for capturing phase change and latent heat of ice as well as the transport properties across a layer of low density accreted frost are developed. This extended modeling capacity is applicable to temperatures greater than 258 K. To extend applicability to the minimum device temperature of 235 K, a method for a mapped transformation of temperatures from below the limit temperatures to some value above is given along with descriptions for associated material property transformations and the resulting impacts to total heat and mass transfer. Similar considerations are shown for the SHX along with assumptions for flow mechanics and resulting model methods for sublimation in a flow.

Bower, Chad↗