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At least 469 records · Page 26

Flow tracing fidelity of scattering aerosol in laser Doppler velocimetry

An experimental method for the determination of the flow-tracing fidelity of a scattering aerosol used in laser Doppler velocimeters was developed with particular reference to the subsonic turbulence measurements. The method employs the measurement of the dynamic response of a flow-seeding aerosol excited by acoustic waves. The amplitude and frequency of excitation were controlled in order to simulate the corresponding values of fluid turbulence components. Experimental results are presented on the dynamic response of aerosols over the size range from 0.1 to 2.0 microns in diam and over the frequency range 100 Hz to 100 kHz. It was observed that unit-density spherical scatterers with diameters of 0.2 micron followed subsonic air turbulence frequency components up to 100 kHz with 98% fidelity.

Mazumder, M. K.↗

Cosmic ray particle dosimetry and trajectory tracing

Five pocket mice (Perognathus longimembris) were flown on Apollo XVII, each with a solid-state (plastic) nuclear track detector implanted beneath its scalp. The subscalp detectors were sensitive to HZE cosmic ray particles with a LET greater than or approximately equal to 0.15 million electron volts per micrometer (MeV/micron). A critical aspect of the dosimetry of the experiment involved tracing individual particle trajectories through each mouse head from particle tracks registered in the individual subscalp detectors, thereby establishing a one-to-one correspondence between a trajectory location in the tissue and the presence or absence of a lesion. The other major aspect was the identification of each registered particle. An average of 16 particles with Z greater than or equal to 6 and 2.2 particles with Z greater than or equal to 20 were found per detector. The track density, 29 tracks/sq cm, when adjusted for detection volume, was in agreement with the photographic emulsion data from an area dosimeter located next to the flight package.

Cruty, M. R.↗

Trace elements by instrumental neutron activation analysis for pollution monitoring

Methods and technology were developed to analyze 1000 samples/yr of coal and other pollution-related samples. The complete trace element analysis of 20-24 samples/wk averaged 3-3.5 man-hours/sample. The computerized data reduction scheme could identify and report data on as many as 56 elements. In addition to coal, samples of fly ash, bottom ash, crude oil, fuel oil, residual oil, gasoline, jet fuel, kerosene, filtered air particulates, ore, stack scrubber water, clam tissue, crab shells, river sediment and water, and corn were analyzed. Precision of the method was plus or minus 25% based on all elements reported in coal and other sample matrices. Overall accuracy was estimated at 50%.

Sheibley, D. W.↗

Estimate of contribution of jet aircraft operations to trace element concentration at or near airports

Samples of ASTM type A jet fuel were analyzed for trace element content by instrumental neutron activation techniques. Forty-nine elements were sought. Only ten, aluminum, gold, indium, lanthanum, titanium, vanadium, barium, dysprosium, tellurium, and uranium, were observed at levels above the detection limits encountered; of these only aluminum, titanium, and barium were present at concentrations greater than 0.1 ppm. Estimates of exhaust gas concentrations are made, and the ambient contribution at or near airports is calculated by using the Los Angeles International Airport dispersion model. It is shown that the ambient contribution is about an order of magnitude below typical urban levels for virtually all elements sought.

Fordyce, J. S.↗

Extensive 1-year survey of trace elements and compounds in the airborne suspended particulate matter in Cleveland, Ohio

Concentrations of 75 chemical constituents in the airborne particulate matter were measured in Cleveland, Ohio, during 1971 and 1972. Values covering a 1-year period (45 to 50 sampling days) at each of 16 sites are presented for 60 elements. A lesser number of values is given for sulfate, nitrate, fluoride, acidity, 10 polynuclear aromatic hydrocarbon compounds, and the aliphatic hydrocarbon compounds as a group. Methods used included instrumental neutron activation, emission spectroscopy, gas chromatography, combustion techniques, and colorimetry. Uncertainties in the concentrations associated with the sampling procedures, the analysis methods, the use of several analytical facilities, and samples with concentrations below the detection limits are evaluated in detail. The data is discussed in relation to other studies and source origins. The trace constituent concentrations as a function of wind direction are used to suggest a practical method for air pollution source identification.

King, R. B.↗

Trajectory Traces of Charged Particles in the Magnetosphere

The characteristic enhancements of ring current particles with energies of about 1 to 100 keV, associated with magnetospheric substorms, were observed by Explorer 45 around the plasmapause in the afternoon to midnight region, and showed the characteristic structure called a 'nose' in the proton spectrograms. The motion of these particles in the equatorial magnetosphere, under a recently proposed convection electric field and a dipole magnetic field is described. Approximate equations of a bounce period, a second adiabatic invariant, and a bounce-average azimuthal velocity are given with inaccuracies less than about 0.001 for all pitch angles. The complete set of flow patterns of 90 deg pitch angle particles is also presented by means of stagnation lines through which radial drifts and/or azimuthal drifts change their directions. The particle tracings in the magnetosphere give a basic concept to explain the observed nose characteristics.

Ejiri, M.↗

Design, fabrication and test of a trace contaminant control system

A trace contaminant control system was designed, fabricated, and evaluated to determine suitability of the system concept to future manned spacecraft. Two different models were considered. The load model initially required by the contract was based on the Space Station Prototype (SSP) general specifications SVSK HS4655, reflecting a change from a 9 man crew to a 6 man crew of the model developed in previous phases of this effort. Trade studies and a system preliminary design were accomplished based on this contaminant load, including computer analyses to define the optimum system configuration in terms of component arrangements, flow rates and component sizing. At the completion of the preliminary design effort a revised contaminant load model was developed for the SSP. Additional analyses were then conducted to define the impact of this new contaminant load model on the system configuration. A full scale foam-core mock-up with the appropriate SSP system interfaces was also fabricated.

Source record↗

Space Shuttle Trace Gas Analyzer

A Trace Gas Analyzer (TGA) with the ability to detect the presence of toxic contaminants in the Space Shuttle atmosphere within the subparts-per-million range is under development. The design is a modification of the miniaturized Gas Chromatograph-Mass Spectrometer (GCMS) developed for the Viking Mars Lander. An ambient air sample is injected onto the GC column from a constant volume sample loop and separated into individual compounds for identification by the MS. The GC-MS interface consists of an effluent divider and a silver-paladium separator, an electrochemical cell which removes more than 99.99% of the hydrogen carrier gas. The hydrogen is reclaimed and repressurized without affecting the separator efficiency, a feature which enables a considerable weight reduction in the carrier gas supply system.

Dencker, W.↗

Rb, Sr and strontium isotopic composition, K/Ar age and large ion lithophile trace element abundances in rocks and glasses from the Wanapitei Lake impact structure

Shock metamorphosed rocks and shock-produced melt glasses from the Wanapitei Lake impact structure have been examined petrographically and by electron microprobe. Eleven clasts exhibiting varying degrees of shock metamorphism and eight impact-produced glasses have been analyzed for Rb, Sr and Sr isotopic composition. Five clasts and one glass have also been analyzed for large ion lithophile (LIL) trace element abundances including Li, Rb, Sr, and Ba and the REE's. The impact event forming the Wanapitei Lake structure occurred 37 m.y. ago based on K/Ar dating of glass and glassy whole-rock samples. Rb/Sr isotopic dating failed to provide a meaningful whole-rock or internal isochron. The isotopic composition of the glasses can be explained by impact-produced mixing and melting of metasediments.

Winzer, S. R.↗

Major and trace element chemistry of Boulder 1 at Station 2, Apollo 17

Twenty-seven samples from Boulder 1 at Station 2 are analyzed for major and trace elements by atomic absorption spectrophotometry and neutron activation analysis. Two types of matrix and several types of clast materials are characterized on the basis of their chemistry. It is shown that one matrix type is a common material at the Apollo 17 site, while the other is probably exotic to that site. The most unusual clast materials found are coarse norite (an old rock no longer found in millimeter fragments at the site) and pigeonite basalt (possibly a highland volcanic rock). It is concluded that the boulder-forming process combined materials from at least two different localities or vertical strata.

Blanchard, D. P.↗

History of Boulder 1 at Station 2, Apollo 17 based on trace element interrelationships

Correlations among the trace and minor element pairs Cl and Br, Cl and P2O5, and Ru and Os, present in parent igneous rocks, generally survived the processes of boulder breccia formation. Fractions of Cl, Br, and Hg that are mobilized by water leaching or volatilization at moderate temperatures place constraints on the thermal history of Boulder 1 and its component breccias. Since, and possibly during, consolidation, the boulder has probably not been subjected to temperatures in excess of 450 C. The parent rocks of the Apollo 17 boulder and breccia samples studied could have been derived from two initial magmas. Vapor clouds from apparently external sources permeated the source regions of the boulders.

Jovanovic, S.↗

Equivalence of equations describing trace element distribution during equilibrium partial melting

It is shown that four equations used for calculating the evolution of trace-element abundances during equilibrium partial melting are mathematically equivalent. The equations include those of Hertogen and Gijbels (1976), Shaw (1970), Schilling (1971), and O'Nions and Clarke (1972). The general form to which all these equations reduce is presented, and an analysis is performed to demonstrate their mathematical equivalence. It is noted that the utility of the general equation flows from the nature of equilibrium (i.e., the final state is independent of the path by which that state is attained).

Consolmagno, G. J.↗

Extraction of trace elements from ores

Trace elements, such as interstitial impurities, can be extracted by low-pressure, relatively low-temperature vaporization from compositions in which they occur.

Ikramuddin, M.↗

Trace Gas Analyzer (TGA) program

The design, fabrication, and test of a breadboard trace gas analyzer (TGA) is documented. The TGA is a gas chromatograph/mass spectrometer system. The gas chromatograph subsystem employs a recirculating hydrogen carrier gas. The recirculation feature minimizes the requirement for transport and storage of large volumes of carrier gas during a mission. The silver-palladium hydrogen separator which permits the removal of the carrier gas and its reuse also decreases vacuum requirements for the mass spectrometer since the mass spectrometer vacuum system need handle only the very low sample pressure, not sample plus carrier. System performance was evaluated with a representative group of compounds.

Source record↗

In situ measurements of Arctic atmospheric trace constituents from an aircraft

In situ measurements of the ambient concentrations of several atmospheric trace constituents were obtained using instruments installed on board the NASA Convair 990 aircraft at altitudes up to 12.5 kilometers over Alaska and the Arctic Ocean. Concentration data on ozone, carbon monoxide, water vapor, and particles larger than 0.5 micrometer in diameter were acquired.

Reck, G. M.↗

A measurement system for the atmospheric trace gases CH4 and CO

A system for measuring ambient clean air levels of the atmospheric trace gases methane and carbon monoxide is described. The analytical method consists of a gas chromatographic technique that incorporates sample preconcentration with catalytic conversion of CO to CH4 and subsequent flame ionization detection of these gases. The system has sufficient sensitivity and repeatability to make the precise measurements required to establish concentration profiles for CO and CH4 in the planetary boundary layer. A discussion of the bottle sampling program being conducted to obtain the samples for the concentration profiles is also presented.

Condon, E. P.↗

A dispersion model approach to the preliminary design of adsorber beds for trace contaminants

It is shown that a dispersion model for the transport of a gas through a porous medium can be useful in the preliminary design of adsorber beds for the control of trace contaminants. The transmission function is considered, taking into account the transmission of 102-ppm acetaldehyde in helium flowing at various flow rates through an absorber bed. The experiments were conducted at a temperature of 25.0 C. Attention is given to a representation of the experimental breakthrough curve, the volume adsorption capacity, temperature studies, and correlations.

Madey, R.↗