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At least 469 records · Page 26

Gaussian Process Optimization of Sensitivity-Based Similarity Metrics between New Nuclear Applications and New/Existing Benchmarks

Confidently designing safe, new nuclear criticality experiments requires expert judgement, which could take years of experience. Sensitivity/uncertainty (S/U) analysis can be utilized by less experienced individuals to conservatively estimate uncertainties in important parameters, such as k eff , in newly proposed nuclear applications. This type of analysis relies on matching new nuclear applications with existing benchmark experiments. The Whisper-1.1 software package included in MCNP6.2 ®1 contains more than 1,100 International Criticality Safety Benchmark Evaluation Project (ICSBEP) benchmarks. These benchmarks however rarely match new nuclear applications. The number of benchmarks available to match a given set of materials or geometric configurations varies significantly. Furthermore, recently performed benchmark experiments may not have had enough time to be properly documented and published. Benchmarks are vital for determining the accuracy of nuclear data and can assist nuclear physics and evaluators in improving nuclear data libraries. Exhaustively exploring the parameter space using simulations with software such as MCNP is too computationally expensive. In this work, Gaussian process optimization was implemented to reduce the number of simulations needed for optimization over multiple parameters. This optimization scheme was designed to selectively generate new benchmarks with high sensitivity-based similarity metrics to user-defined nuclear applications. Two benchmark models of spherically nested shells containing plutonium, uranium, tantalum, and water were used in the optimization to match an application containing plutonium plates, stacked in a tantalum reflector, surrounded by water.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Proton beam power limits for stationary water-cooled tungsten target with different cladding materials

The proton beam power limit for a solid-tungsten spallation target is largely determined by beam induced thermomechanical structural loads and decay heat power deposition, while its lifetime is limited by radiation damage and fatigue life of the target materials. In this paper, we studied the power limits of a stationary water-cooled solid tungsten target concept. Tantalum clad tungsten was considered as a reference case. Being a low activation material, zircaloy 2 cladding option was studied and its decay heat driven power limit was compared with the reference case. Zirconium alloys have proven operations records in spallation target and nuclear fission environments, supported by materials data obtained from post irradiation examinations. Recent study also demonstrated feasibility of diffusion bonding zirconium to tungsten using vanadium foil inter layer. Particle transport simulations code FLUKA was used to calculate energy deposition and decay heat power deposition in the target, based on the beam parameters technically feasible at the Second Target Station of the Spallation Neutron Source at Oak Ridge National Laboratory. The energy deposition data were used for flow, thermal, and structural analyses to determine the beam intensity limit on the target concept studied. The decay heat deposition data were used to calculate the transient temperature evolution in the tungsten volumes in a loss of coolant accident (LOCA) scenario to determine its beam power limit. For a 1.3 GeV proton beam, the power limit on a stationary target was 400 kW for a tantalum clad target model and 800 kW for a zircaloy 2 clad target model.

Lee, Yong Joong↗

Impact Response of Cold Spray Deposited Materials

Solid-state cold spraying (CS) of metals and respective blends is becoming increasingly attractive compared to conventional high temperature processes due to the unique properties such as increased yield strength, low ductility, and differences in tensile and compressive strengths that result from microstructural features due to the CS process. Here we report the results of plate impact experiments applied to CS deposits of tantalum (Ta), niobium (Nb), and a tantalum- niobium blend (TaNb). These methods allowed for definition of the Hugoniot for each material type and allowed for assessment of the Hugoniot Elastic Limit (HEL). Scanning electron microscopy was used on recovered samples to characterize the fracture mechanism during spallation.

36 MATERIALS SCIENCE↗

IHS-60 Stored Energy Analysis

The IHS-60 consists of a General Purpose Heat Source (GPHS) Fueled Clad (FC) that has been hot isostatically pressed to eliminate the gap between the iridium clad and the fuel pellet, thus preventing differential motion between the pellet and the clad in shock and vibration environments. The vented FC is enclosed within a Molybdenum barrier comprising the liner body and the lower support member. The slip- t Molybdenum liner members serve as a mechanical barrier to plutonia contact of the tantalum alloy (T-111) strength member in the event the iridium clad should fail. The slip- t liner is not a barrier to gaseous transport, so a tantalum getter is installed near the vent region of the FC to preclude potential oxygen transport to the T-111 interior surface. The T-111 strength member encloses the Molybdenum liner assembly and provides for both helium gas retention and isotope fuel containment under impact and external pressure environments. It is surrounded by an outer clad of Hastelloy-S which protects the strength member from external oxidation and corrosive sources during nominal operation and in the event of off-nominal operation or accidents. Both the strength member and outer clad parts are closed with seal welds. The strength member and outer clad are the primary containment members of the 60-Watt IHS. The iridium clad contains the fuel pellet during nominal operation and mild accident environments, but it is not considered to be a primary containment member.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Assembly Operations Welding Filter(s) in Drum Calculation

This calculation documents the estimation of temperature and pressure rise inside a 55-gal TRU waste drum with a HEPA filter containing Titanium and Tantalum fume dust based on operational history. Actual Titanium values are believed to be less than 10g on any given filter. Actual Tantalum values are believed to be less than 1g on any given filter

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Impact Response of Control Atmosphere Plasma Spray Deposited Materials

Thermal spray processing of metals and respective blends is becoming increasingly attractive due to the unique properties such as increased yield strength, low ductility, and differences in tensile and compressive strengths that result from microstructural features due to the spray process compared to other additive manufacturing methods. Here we report the results of plate impact experiments applied to Controlled Atmosphere Plasma Spray deposits of tantalum (Ta), niobium (Nb), and a tantalum-niobium blend (TaNb). These methods allowed for definition of the Hugoniot for each material type and the assessment of the Hugoniot Elastic Limit (HEL). Spallation experiments were conducted, and soft recovery of each material type allowed for scanning electron microscopy to characterize the fracture mechanism during tensile loading.

36 MATERIALS SCIENCE↗

Pinwheel Experiment Confirmatory Shot 1 Pre-Shot Report

The purpose of this experimental series is to validate the reactive burn model in the PAGOSA hydrodynamic code. It will also help validate the EOS and Strength models for the aluminum and tantalum cylinders. C4 high explosive (HE) is used to drive an aluminum cylinder into an aluminum sandwiched PBX-9501. The follow-on experiment will drive the aluminum cylinder into a tantalum sandwiched PBX-9501. The experiment will provide time of arrival (TOA) data for the burn front in the HE through the metal cylinders using Fiber Bragg Gratings (FBG). Photon Doppler Velocimetry (PDV) will provide shock wave TOA and the velocity of the inward moving cylinder. The PAGOSA code will be used to predict TOA and cylinder wall velocity using PDV and tracers.

42 ENGINEERING↗

Synthesis and Characterization of Superconductor Diodes

In the era of modern computing, quantum bits (or qubits) are extensively researched due to their ability to perform computations exponentially faster than classical computers. One promising method for synthesizing qubits on a macroscopic scale is through superconductor diodes (SDs). Unfortunately, SDs are currently limited by their dependence on extremely low temperatures (T ≈ 0K), which restricts their practical usability at larger scales. To address this limitation, researchers are exploring new materials and methods to identify superconductors with higher critical temperatures. My research at the Lawrence Livermore National Laboratory (LLNL) focuses on synthesizing and characterizing superconductor diodes to determine their efficiency for quantum computing applications. Bismuth thin films were synthesized with magnetron sputtering with separate thicknesses which provides information on methods to alter their resistivity. Bismuth was characterized as the topological insulator used in the diode, and its resistivity was measured using a standard four-point probe technique with 1 mA current. Bismuth (99.99% pure) was then purified in a tubular furnace at 400C to use within a Josephson junction as a topological insulator. Niobium and Tantalum Josephson junctions were then synthesized, and they were characterized using a lock-in amplifier four-point probe technique. Materials such as niobium and tantalum are used in high-entropy alloy research, which is a relatively new class of material that has little research within the superconductor diode community, yet the current research shows promise. We anticipate that testing high-entropy superconductors will reveal crucial factors, potentially leading to the development of high-temperature superconductors in the future.

36 MATERIALS SCIENCE↗

Machine-Guided Design of Oxidation-Resistant Superconductors for Quantum Information Applications

Decoherence in superconducting qubits has long been attributed to two-level systems arising from the surfaces and interfaces present in real devices. A recent significant step in reducing decoherence was the replacement of superconducting niobium by superconducting tantalum, resulting in a tripling of transmon qubit lifetimes (T1). The identity, thickness, and quality of the native surface oxide, is thought to play a major role, as tantalum only has one oxide whereas niobium has several. Here we report the development of a thermodynamic metric to rank materials based on their potential to form a well-defined, thin, surface oxide. We first computed this metric for known binary and ternary metal alloys using data available from the Materials Project and experimentally validated the strengths and limits of this metric through the preparation and controlled oxidation of eight known metal alloys. Then we trained a convolutional neural network to predict the value of this metric from atomic composition and atomic properties. This allowed us to compute the metric for materials that are not present in the Materials Project, including a large selection of known superconductors, and, when combined with Tc, allowed us to identify new candidate superconductors for quantum information science and engineering (QISE) applications. We tested the oxidation resistance of a pair of these predictions experimentally. Our results are expected to lay the foundation for the tailored and rapid selection of improved superconductors for QISE.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Metallic transfer between metals in sliding contact examined by auger emission spectroscopy

Metallic transfer between polycrystalline metals in sliding contact was examined. Hemispherical riders of iron, nickel, and cobalt were slid on tungsten, tantalum, niobium, and molybdenum disks in ultrahigh vacuum. Auger emission spectroscopy was used to monitor the elemental composition of the disk surfaces. Iron, nickel, and cobalt transferred to tungsten, whereas only cobalt transferred to tantalum, niobium, and molybdenum. The results of this investigation are discussed in terms of the cohesive energy and strain hardening characteristics of the specimen materials.

Pepper, S. V.↗

Generation of long time creep data on refractory alloys at elevated temperatures

Ultrahigh vacuum creep tests were conducted on tantalum, tungsten, and molybdenum alloys to develop creep data and to evaluate the influence of liquid lithium exposure on the creep behavior of the tantalum alloy T-111. Test conditions were generally selected to provide 1% creep in 1000 to 10,000 hours, with test temperatures ranging from 1600 to 2912 F (1144 to 1873 K). Tests on T-111 specimens exposed to vacuum and to liquid lithium for various times and temperatures showed large reductions in creep strength for exposures in the 1800 to 1900 F (1255 to 1310 K) range. Tests on the ASTAR 811c showed a significant influence of grain size on the creep strength of this material, with larger grain size specimens being significantly stronger above the equicohesive temperature of 2000 F (1366 K).

Sheffler, K. D.↗

Gettering capsule for removing oxygen from liquid lithium systems

Capsule consisting of tantalum shell lined with tantalum screen and partially filled with lithium and pieces of yttrium is immersed in hot lithium stream. Oxygen is removed from stream by being absorbed by gettering capsule. Oxygen passes through capsule wall and into lithium inside capsule where it reacts with yttrium to form Y2O3.

Tower, L. K.↗

Electrodes for the thermionic converters, phase 2 - 3

The characteristics of electrodes for thermionic converters are discussed. A metal/ceramic Marchuk tube was constructed and operated with a quiescent cesium vapor plasma corresponding to cesium liquid reservoir temperatures from 376 to 427 K. The work function characteristics of tantalum test emitters coated with anodic films were measured to evaluate the applicability of the materials as the collector surface in a plasma mode thermionic converter. Work function minimum values between 1.4 and 1.5 electron volts were observed. The effect of the electronegative surface layers was partially obscured by additive vapor impurities detected by the clean tantalum reference emitter.

Desteese, J. G.↗

Feasibility study of oxygen-dispensing emitters for thermionic converters, phase 1

A metal/ceramic Marchuk tube was used to measure work functions of oxygen-doped tantalum, to determine applicability of the material to plasma-mode thermionic converters. Oxygen-doped tantalum was shown to increase in work function monotonically with oxygen doping in the range 0.1 to 0.3 atomic percent. Oxygenated test emitters were run at an average temperature of 2165 K and a T/T sub Cs ratio -5.8 to observe the influence of oxygen depletion. Bare work function decreased with outgassing of oxygen. Projections were made based on outgassing kinetics and area/volume ratios to calculate the longevity of oxygen doping in a practical converter. Calculations indicated that the program goal of 10,000 hr could be achieved at 1800 K with an initial oxygen doping of 1 atomic percent and a practical emitter area/volume ratio.

Desteese, J. G.↗

Identification of a new lithium oxide, Li3O2

Lithium oxide (Li3O2) was prepared by decomposing anhydrous lithium hydroxide at 360 C in 48 hours and between 640 and 730 C in times up to 1.3 hours and pressures of about 0.00001 torr. Decompositions were done in nickel, molybdenum, niobium, tantalum, and the T-111 tantalum alloy (Ta - 8-wt.% W - 2 wt.% Hf) containers. This oxide probably belongs to the simple orthorhombic system with the following lattice parameters: a = 108.4 + or - 0.4 nm (10.84 + or - 0.04 A), b = 128.4 + or - 0.5 nm (12.84 + or - 0.05 A), and c = 103.6 + or - 0.4 nm (10.36 + or - 0.04 A).

Stecura, S.↗

Thin-film temperature sensor.

A new device has been developed for sensing small and rapid temperature changes accompanying biochemical reactions. The active element consists of an evaporated thin-film capacitor having a relatively strong temperature dependence. This dependence is derived from electron trapping effects in the thin amorphous dielectric film. A voltage output of at least 50 mV/deg can be obtained prior to amplification by using a resonant ac bridge circuit operating at 100 kHz. The corresponding noise output for a 10 kHz bandwidth can with an optimum circuit be as low as 4 microvolts. Therefore, the minimum detectable temperature change would be 80 microdegrees at 10 kHz. Rapid thermal response is assured by supporting the thin-film capacitor on a thin anodic tantalum oxide film suspended across an electrolytically etched window in a tantalum foil.

Maserjian, J.↗