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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Investigation of long-term light stability of negative charge injected into oxide-nitride-oxide passivation stack of crystalline silicon solar cells

A negatively charged oxide-nitride-oxide stack for field-effect passivation of crystalline silicon solar cells is discussed. The negative charge was injected into the stack by a plasma charge injection technology. Charge stability was studied by exposing samples to AM1.5 simulation visible light and full-spectrum light at temperatures ranging from 55 to 78 °C for up to 300 h. Charge injection and loss were quantified based on shifts in the flatband voltage of capacitance–voltage curves measured with a mercury probe. The most probable mechanism of charge loss was found to be diffusion of negative charged hydrogen atoms through nitride and bottom oxide. The optimum recipe for each layer of the stack was investigated to minimize the loss of injected charge. The flatband voltage decay of the optimized stack was found to fit a power-law trend, suggesting the dispersive transport of hydrogen atoms with a dispersion parameter of ~0.06–0.07. The optimized stack is projected to maintain a negative charge density of about 3.6 × 10 12 cm –2 or more after 25 years of field operation in an environment such as Arizona, which would be sufficient for field-effect passivation under one-sun illumination. Furthermore, the high stability of the negative injected charge makes the plasma charging technology a safer and lower cost alternative to Al 2 O 3 -passivation technology commonly used to passivate p-type surfaces.

14 SOLAR ENERGY↗
DOE OSTI2023

Laboratory study of the failed torus mechanism in arched, line-tied, magnetic flux ropes

Coronal mass ejections (CMEs) are some of the most energetic and violent events in our solar system. The prediction and understanding of CMEs are of particular importance due to the impact that they can have on Earth-based satellite systems and, in extreme cases, ground-based electronics. CMEs often occur when long-lived magnetic flux ropes (MFRs) anchored to the solar surface destabilize and erupt away from the Sun. One potential cause for these eruptions is an ideal magnetohydrodynamic (MHD) instability, such as the kink or torus instability. Previous experiments on the magnetic reconnection experiment revealed a class of MFRs that were torus-unstable but kink-stable, which failed to erupt. These “failed-tori” went through a process similar to Taylor relaxation, where the toroidal current was redistributed before the eruption ultimately failed. Herein we have investigated this behavior through additional diagnostics that measure the current distribution at the foot points and the energy distribution before and after an event. These measurements indicate that ideal MHD effects are sufficient to explain the energy distribution changes during failed torus events. This excludes Taylor relaxation as a possible mechanism of current redistribution during an event. A new model that only requires non-ideal effects in a thin layer above the electrodes is presented to explain the observed phenomena. This work broadens our understanding of the stability of MFRs and the mechanism behind the failed torus through the improved prediction of the torus instability and through new diagnostics to measure the energy inventory and current profile at the foot points.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Leaving in the lead: Priorities for perovskite photovoltaics

The need for moving electricity generation to a sustainable model requires the development of low cost ubiquitous photovoltaics (PVs) to harvest the planet’s primary energy source, the Sun. Building upon the successes of Si-based and CdTe-based PV technologies, PVs with lower-embodied energy and requiring lower carbon dioxide equivalent to produce will be required to meet long-term sustainability goals. In particular, thin-film technologies, such as high-efficiency metal halide perovskite (MHP) PV modules, provide avenues to reduced embodied energy, lower energy payback times, and enabling energy-dense tandems [H. M. Wikoff et al., Joule 6(7), 1710–1725 (2022) and V. Fthenakis, Renewable Sustainable Energy Rev. 13(9), 2746–2750 (2009)]. The ability to improve efficiency and lower energy payback time of next generation thin-film PV modules is a critical foundation for green H2 and electrification more broadly. In this regard, Pb-based MHP-PVs have separated themselves as a result of the high-efficiencies that can be realized across a range of electronic gaps. Questions regarding Pb-based MHP-PVs that are often asked, as the challenges of efficiency and reliability are met, revolve around the “problem” of the Pb content. Specifically, “does Pb toxicity preclude MHP-PV modules from being deployed at the TW scale?” To provide this sense of scale, in 2021, the United States burned 10.5 quads of coal, with 90% of that used for electricity generation. Given the energy content of coal of 29 MJ/kg and a residual lead content in that coal of 30 mg/kg, electricity generation from coal resulted in more lead emitted into the atmosphere than what would be required to produce over 2 TW of MHP-PV name plate capacity (assuming a 20% module efficiency and an ∼700 nm active layer). This amounts to more PV power than has been deployed across all PV technologies and geographies to date. This only includes US coal consumption; the rest of the world would be much larger. This example illustrates the scale of the material usage relative to the energy production. Imagine a power-generation technology that offsets these Pb emissions from coal and essentially sequesters this Pb content between two sheets of impermeable glass. Why should we let Pb’s history of misuse prevent it from being included in next generation PV modules that can enable a sustainable energy future?

14 SOLAR ENERGY↗
DOE OSTI2023

The Impact of Circumsolar Diffuse Radiation on the Numerical Computation and Forecasting of DNI

Weather Research and Forecasting model with solar extensions (WRF-Solar) uses the Fast All-sky Radiation Model for Solar applications (FARMS) to predict solar radiation from the forecasted atmospheric gases, aerosols, and clouds. The Beer-Bouguer-Lambert law utilized by FARMS as well as other radiative transfer models assumes Direct Normal Irradiance (DNI) is a narrow beam only covering the sun disk. This assumption is interpreted differently in solar observations by pyrheliometers where the circumsolar diffuse radiation is accounted. This study precisely computes circumsolar diffuse radiation in all-sky conditions using a radiative transfer model based on a parameterization of precomputed cloud transmittance and reflectance. The model is implemented in WRF-Solar to provide day-ahead DNI forecast in the north America. The computation and forecasting of DNI is compared with the Beer-Bouguer-Lambert law to understand the impact of circumsolar diffuse radiation.

aerosols↗
DOE OSTI2024

Creating and studying a scaled interplanetary coronal mass ejection

The Sun, being an active star, undergoes eruptions of magnetized plasma that reach the Earth and cause the aurorae near the poles. These eruptions, called coronal mass ejections (CMEs), send plasma and magnetic fields out into space. CMEs that reach planetary orbits are called interplanetary coronal mass ejections (ICMEs) and are a source of geomagnetic storms, which can cause major damage to our modern electrical systems with limited warning. To study ICME propagation, we devised a scaled experiment using the Big Red Ball (BRB) plasma containment device at the Wisconsin Plasma Physics Laboratory. These experiments inject a compact torus of plasma as an ICME through an ambient plasma inside the BRB, which acts as the interplanetary medium. Magnetic and temperature probes provide three-dimensional magnetic field information in time and space, as well as temperature and density as a function of time. Using this information, we can identify features in the compact torus that are consistent with those in real ICMEs. We also identify the shock, sheath, and ejecta similar to the structure of an ICME event. This experiment acts as a first step to providing information that can inform predictive models, which can give us time to shield our satellites and large electrical systems in the event that a powerful ICME were to strike.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Constraining the 3He + 3He Gamow energy probed in high energy density plasmas at the National Ignition Facility

Polar-direct-drive implosions at the National Ignition Facility generated large plasma volumes to study the 3He + 3He fusion reaction. The ion temperature, which determines the Gamow peak energy, was constrained by isolating the thermal contribution to the D3He-proton spectral width in a 3He plasma doped with deuterium. X-ray penumbral imaging was used to measure electron temperature, density, and hotspot volume, which was subsequently used to model the spectral broadening from plasma stopping power. Results showed 30% of the D3He-proton spectral width was due to stopping power, with residual flows contributing ≈10%. The 3He temperature was determined as T3He = 12.4 ± 3.2 keV, corresponding to a Gamow energy of 95 ± 14 keV. These experiments achieved the lowest Gamow energy to date for studying 3He + 3He fusion in high energy density plasma, approaching conditions in the Sun.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Charge carrier extraction and recombination effects in GaInAs/GaAsP multi-quantum well solar cells

The carrier extraction and transport mechanisms as well as the relative contributions of radiative and non-radiative recombination processes are investigated in high-quality strain-balanced GaInAs/GaAsP multi-quantum well solar cells recently implemented in record efficiency multijunction solar cells. A comprehensive suite of complementary characterization techniques including temperature- and suns-dependent photoluminescence and photovoltaic measurements are employed to analyze thermal escape and tunneling rates, which demonstrate the need to move beyond simple drift-diffusion models of p–n junctions. This study examines the processes that best characterize the operation of these devices across varying temperatures using a simple two-diode model, incorporating multiple transport protocols, and provides insights into the performance-limiting processes and pathways for their optimization.

14 SOLAR ENERGY↗
DOE OSTI2020

A molecular tandem cell for efficient solar water splitting

Artificial photosynthesis provides a way to store solar energy in chemical bonds. Achieving water splitting without an applied external potential bias provides the key to artificial photosynthetic devices. We describe here a tandem photoelectrochemical cell design that combines a dye-sensitized photoelectrosynthesis cell (DSPEC) and an organic solar cell (OSC) in a photoanode for water oxidation. When combined with a Pt electrode for H 2 evolution, the electrode becomes part of a combined electrochemical cell for water splitting, 2H 2 O → O 2 + 2H 2 , by increasing the voltage of the photoanode sufficiently to drive bias-free reduction of H + to H 2 . The combined electrode gave a 1.5% solar conversion efficiency for water splitting with no external applied bias, providing a mimic for the tandem cell configuration of PSII in natural photosynthesis. The electrode provided sustained water splitting in the molecular photoelectrode with sustained photocurrent densities of 1.24 mA/cm 2 for 1 h under 1-sun illumination with no applied bias.

14 SOLAR ENERGY↗
DOE OSTI2023

Interactions between nonfullerene acceptors lead to unstable ternary organic photovoltaic cells

For organic photovoltaic (OPV) devices to achieve consistent performance and long operational lifetimes, organic semiconductors must be processed with precise control over their purity, composition, and structure. This is particularly important for high volume solar cell manufacturing where control of materials quality has a direct impact on yield and cost. Ternary-blend OPVs containing two acceptor–donor–acceptor (A–D–A)-type nonfullerene acceptors (NFAs) and a donor have proven to be an effective strategy to improve solar spectral coverage and reduce energy losses beyond that of binary-blend OPVs. Here, we show that the purity of such a ternary is compromised during blending to form a homogeneously mixed bulk heterojunction thin film. We find that the impurities originate from end-capping C=C/C=C exchange reactions of A–D–A-type NFAs, and that their presence influences both device reproducibility and long-term reliability. The end-capping exchange results in generation of up to four impurity constituents with strong dipolar character that interfere with the photoinduced charge transfer process, leading to reduced charge generation efficiency, morphological instabilities, and an increased vulnerability to photodegradation. As a consequence, the OPV efficiency falls to less than 65% of its initial value within 265 h when exposed to up to 10 suns intensity illumination. We propose potential molecular design strategies critical to enhancing the reproducibility as well as reliability of ternary OPVs by avoiding end-capping reactions.

14 SOLAR ENERGY↗
DOE OSTI2021

Foreword: Selected papers from the 2020 Nuclear and Emerging Technologies for Space Topical Meeting (NETS 2020)

Humanity’s curiosity of and intrigue for exploring space has been with our species since we first looked up into the night sky. This age-old curiosity has driven humankind to innovate technologies for millennia, including efforts ranging from the construction of Stonehenge to track the annual movements of the sun to the investigation of advanced propulsion systems capable of transporting people to distant planets. Today’s technical communities dedicated to researching and developing innovative technologies for space exploration have seen a recent reinvigoration. Over the past few years, impressive progress made by industry, with exceptional support from government agencies, to reestablish and develop new capabilities has renewed confidence in humanity’s ability to reach the stars—a confidence that has not been present since the days of the Apollo program. Moreover, history shows that innovation and collaboration within the scientific and engineering communities reaches unparalleled pinnacles during periods of astrophilia. Finally, given the advancements in computational capacities for advanced modeling and simulation, unprecedented breakthroughs in commercializing advanced manufacturing techniques, and powerful collaborative relationships between industry and national scientific organizations, today we are limited only by our own imaginations.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2025

Efficient Decision Trees for Tensor Regressions

Here, we proposed the tensor-input tree (TT) method for scalar-on-tensor and tensor-on-tensor regression problems. We first address scalar-on-tensor problem by proposing scalar-output regression tree models whose input variables are tensors (i.e., multi-way arrays). We devised and implemented fast randomized and deterministic algorithms for efficient fitting of scalar-on-tensor trees, making TT competitive against tensor-input GP models (Yu, Li, and Liu; Sun et al.). Based on scalar-on-tensor tree models, we extend our method to tensor-on-tensor problems using additive tree ensemble approaches. Theoretical justification and extensive experiments, including testing robustness to entrywise input tensor noise, are provided on real and synthetic datasets to illustrate the performance of TT. Our implementation is provided at https://github.com/hrluo/TensorDecisionTreeRegressor. Supplementary materials for this article are available online.

Decision tree regressions↗
DOE OSTI2021

Optimizing Vehicle Fleet and Assignment for Concentrating Solar Power Plant Heliostat Washing

Concentrating solar power central-receiver plants use thousands of sun-tracking mirrors, i.e., heliostats, to reflect sunlight to a central receiver, which collects and uses the heat to generate electricity. Over time, soiling reduces the reflectivity of the heliostats and, therefore, the efficiency of the system. Current industry practice sends vehicles to wash heliostats in an ad hoc fashion. We present a mixed-integer nonlinear program that determines wash vehicle fleet size, mix, and assignment of wash crews to heliostats to minimize the sum of (i) the revenues lost due to heliostat soiling, (ii) the costs of hiring wash crews and operating the vehicles, and (iii) the costs of purchasing wash vehicles. We establish conditions for convexity of the objective function, and then propose a decomposition method that enables near-optimal solutions to the wash vehicle fleet sizing and assignment problem on the order of a couple of minutes. Furthermore, these solutions yield hundreds of thousands of dollars in savings per year over current industry practices.

14 SOLAR ENERGY↗
DOE OSTI2024

The Effect of Natural Disasters and Extreme Weather on Household Location Choice and Economic Welfare

Natural disasters have increased in the United States in recent decades. At the same time, there has been a shift in population away from the states in the Northeast and Midwest to areas in the Sun Belt, many of which face increased risks from natural disasters. Spatial equilibrium theory predicts that households trade off risk for income in making location decisions. This study estimates a spatial equilibrium model of household location choice to understand these trade-offs. The results show that households require as much as 0.40% of annual household income to endure an additional disaster over the course of a decade. They also show that these values differ substantially depending on household skill level with higher-skill, higher-income households willing to pay three times more in annual income to avoid an additional natural disaster. Furthermore, these results have important implications for policymakers thinking about climate change adaptation and environmental justice.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Spurious solar-wind effects on acceleration noise in LISA Pathfinder

Spurious solar-wind effects are a potential noise source in future Laser Interferometer Space Antenna (LISA) measurements. One noise coupling mechanism is constrained by estimating solar-wind effects on acceleration noise in LISA Pathfinder (LPF). While LISA is designed for drag-free differential measurement, predicting the realistic impact both bounds the operational environment and assesses whether LISA could provide serendipitous space-weather observations. Data from NASA's Advanced Composition Explorer (ACE), situated at the L1 Lagrange point, serves as a reliable source of solar-wind data. The data sets are compared over the 114 d time period from 1 March 2016 to 23 June 2016. This period gives the longest readily-available open data set, without interference from other commissioning activities. To evaluate space weather effects, the data from both satellites are formatted, gap-filled/interpolated, and fast-Fourier transformed for amplitude spectral density and coherence comparisons. Solar wind effects are not seen in a coherence plot between LPF and ACE; modest coherence in the planned LISA observational frequency band can be attributed to chance. This result indicates that measurable correlation due to solar-wind acceleration noise over 3 month timescales will be a negligible noise source. LISA is unlikely to inform solar wind measurements routinely. Another source of noise from the Sun, solar radiation pressure, is estimated to impart greater acceleration noise, but has yet to be analyzed.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Lamination of transparent conductive adhesives for tandem solar cell applications

A transparent conductive adhesive (TCA) interlayer for mechanically stacked multijunction solar cells provides adhesive strength and electrical connection between sub-cells when stacked. The fabrication of TCA sheets from an ethyl-vinyl acetate (EVA) matrix and silver coated compliant conductive microspheres, similar to industry-standard EVA encapsulant sheets, compatible with a standard lamination process was developed. Blade coating TCA sheets using 3D printed blades and testing of vertical conduction through the interlayer with a TCA conductivity jig allowed for reproducible measurements and low-cost fabrication. The supplemental information provides design files to enable other researchers to produce their own blades and testing jigs. We identified 0.5 mm as an optimal blade height for producing lab-scale TCA sheets and 120 °C at 3 psi for 10 min as the optimal vacuum lamination process to minimize resistance and possible damage to samples. For TCA sheets with coverages between 0.75% and 9%, the series resistance was approximately 0.2 O cm2 which should result in minimal losses for one-sun photovoltaic applications.

14 SOLAR ENERGY↗
DOE OSTI2020

Self-organization in 1 atm DC glows with liquid anodes: current understanding and potential applications

Self-organization refers to the spontaneous generation of spatially or temporally organized patterns in an otherwise disordered system. Self-organization is ubiquitous in plasma physics particularly in the low-pressure regime as observed in astrophysical jets or plasma loaded flux loops that form on the surface of the Sun. In recent times, self-organization in atmospheric pressure plasmas has captured the attention of researchers. Its occurrence has been observed in DBD discharges as well as DC 1 atm glows with liquid electrodes. The mechanism of pattern formation is still not well understood. In this work, we briefly review the current understanding of pattern formation in DC glows with liquid anode, surveying past work, application areas, theories on mechanisms of formation from the context of reaction diffusion systems, current experimental work and computational progress towards predicting pattern formation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Novel constraints on fifth forces and ultralight dark sector with asteroidal data

Here, we study for the first time the possibility of probing long-range fifth forces utilizing asteroid astrometric data, via the fifth force-induced orbital precession. We examine nine Near-Earth Object (NEO) asteroids whose orbital trajectories are accurately determined via optical and radar astrometry. Focusing on a Yukawa-type potential mediated by a new gauge field (dark photon) or a baryon-coupled scalar, we estimate the sensitivity reach for the fifth force coupling strength and mediator mass in the mass range m ≃ (10 -21 -10 -15 ) eV, near the "fuzzy" dark matter region. Our estimated sensitivity is comparable to leading limits from equivalence principle tests, potentially exceeding these in a specific mass range. The fifth force-induced precession increases with the orbital semi-major axis in the small m limit, motivating the study of objects further away from the Sun. We also demonstrate that precession tests are particularly strong in probing long-range forces which approximately conserve the equivalence principle. We discuss future prospects for extending our study to more than a million asteroids, including NEOs, main-belt asteroids, Hildas, and Jupiter Trojans, as well as trans-Neptunian objects and exoplanets.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Scalar dark matter vortex stabilization with black holes

Galaxies and their dark-matter halos are commonly presupposed to spin. But it is an open question how this spin manifests in halos and soliton cores made of scalar dark matter (SDM, including fuzzy/wave/ultralight-axion dark matter). One way spin could manifest in a necessarily irrotational SDM velocity field is with a vortex. But recent results have cast doubt on this scenario, finding that vortices are generally unstable except with substantial repulsive self-interaction. Here, in this paper, we introduce an alternative route to stability: in both (non-relativistic) analytic calculations and simulations, a black hole or other central mass at least as massive as a soliton can stabilize a vortex within it. This conclusion may also apply to AU-scale halos bound to the sun and stellar-mass-scale Bose stars.

79 ASTRONOMY AND ASTROPHYSICS↗