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At least 469 records · Page 26

Experimental evaluation of direct current magnetron sputtered and high-power impulse magnetron sputtered Cr coatings on SiC for light water reactor applications

Two types of physical vapor deposition Cr coatings were deposited on chemical vapor deposited SiC coupons using conventional direct current magnetron sputtering (DCMS) and high-power impulse magnetron sputtering (HiPIMS) to mitigate the corrosion of SiC, an advanced fuel and structural material in light water nuclear reactor cores. Coating microstructure was characterized using scanning electron microscopy and scanning transmission election microscopy. X-ray diffraction analysis was conducted for phase identification and qualitative analysis of residual stresses. The mechanical integrity of the coatings was evaluated using scratch testing, micro-indentation, and nano-indentation tests. Additionally, the microstructure of the DCMS coating consisted of fine columnar grains with nanoscale intercolumnar channels, while the HiPIMS microstructure was denser and free of any columnar defects. The DCMS coating showed a small tensile residual stress, while the HiPIMS coating was under compressive stress. Both types of coatings showed good mechanical integrity in terms of ductility and adhesion to the substrate. Corrosion performance of the coatings was assessed with a 30-day high temperature water autoclave test. Both types of coatings formed a protective Cr 2 O 3 surface layer 20-30 nm thick during the autoclave test. In the DCMS coating, the columnar defects provided permeation pathways for water penetration resulting in oxide formation in the intercolumnar regions in the interior of the coating. Overall, both types of Cr coatings offer promise for the mitigation of hydrothermal corrosion of SiC in light water reactor operating environments.

36 MATERIALS SCIENCE↗

Edgewise Compression Testing of STIPS-0 (Structurally Integrated Thermal Protection System)

The Structurally Integrated Thermal Protection System (SITPS) task was initiated by the NASA Hypersonics Project under the Fundamental Aeronautics Program to develop a structural load-carrying thermal protection system for use in aerospace applications. The initial NASA concept for SITPS consists of high-temperature composite facesheets (outer and inner mold lines) with a light-weight insulated structural core. An edgewise compression test was performed on the SITPS-0 test article at room temperature using conventional instrumentation and methods in order to obtain panel-level mechanical properties and behavior of the panel. Three compression loadings (10, 20 and 37 kips) were applied to the SITPS-0 panel. The panel behavior was monitored using standard techniques and non-destructive evaluation methods such as photogrammetry and acoustic emission. The elastic modulus of the SITPS-0 panel was determined to be 1.146x106 psi with a proportional limit at 1039 psi. Barrel-shaped bending of the panel and partial delamination of the IML occurred under the final loading.

Brewer, Amy R.↗

Elastic light-scattering modulator: A concept

Simple structure can be used as electrically-controlled light valve, to scatter both transmitted and reflected beams. Its operation is based on physical phenomenon called frosting. Device may be of interest to manufacturers of page composers, alphanumeric displays, flat-panel displays, large-screen televisions, and optical input terminals for computers.

Vilkomerson, D. H. R.↗

Comparing the influence of cation order and composition in simulated Zn(Sn, Ge)N 2 on structure, elastic moduli, and polarization for solid state lighting

Alloying and site ordering play complementary roles in dictating a material’s properties. However, deconvolving the impacts of these separate phenomena can be challenging. In this work, we simulate structures of Zn(Sn,Ge)N 2 with varied Sn content and site ordering to determine the impacts of order and composition on structural and electronic properties. We assess the formation enthalpy, lattice parameters, elastic constants, spontaneous polarization, and piezoelectric coefficients. In mostly disordered structures (order parameters ranging from 0.2 to 0.4), the formation enthalpy exhibits local extrema as a function of the order parameter, deviating from the more linear trends seen in both fully disordered and fully ordered systems. This anomalous deviation from the otherwise linear trend in formation enthalpy with order manifests in each of the other properties calculated. This range of order parameters of interest may be caused by a transition in the ordering of the quaternary material similar to phase changes seen in ternary compounds but stretched over a region inclduing 20% of the order parameter range. Most parameters calculated are more sensitive to order than to composition in the limited composition range tested; however, the lattice parameter c, piezoelectric coefficient e 33 , and elastic moduli C 12 , C 13 , and C 23 are more sensitive to composition. Of the properties compared, the piezoelectric coefficients are influenced most significantly by changes in both the composition and order parameter. Lattice parameters undergo the smallest changes with order and composition, but these small differences appear to impart large trends in the other properties. Better understanding the effects of disorder and group IV alloying in Zn(Sn,Ge)N 2 allows for more accurate modeling of characteristics of this material system for solid state lighting and other applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Cristispira from oyster styles: complex morphology of large symbiotic spirochetes

Crystalline styles (digestive organs) of bivalve mollusks provide the habitat for highly motile bacteria. Styles from freshly-collected oysters, Crassostrea virginica, were studied by electron microscopy; Cristispira spirochetes were abundant in these organs. Detailed study reveals these spirochetes to be among the most complex prokaryotic cells known. More than 600 periplasmic flagella and an adhering outer lipoprotein membrane (e.g., a 270 degrees sillon) form the ultrastructural basis for the "crista," first described by light microscopy. Unique rosette structures corresponding to the "chambers" or "ovoid inclusions" of light microscopy were detected at the periphery of all protoplasmic cylinders. Polar organelles and linearly aligned flagellar insertions are conspicuous. In size and complexity, Cristispira more resembles Pillotina, Diplocalyx, Clevelandina and Hollandina (large spirochetes symbiotic in termites) than it does Treponema. Cristispira pectinis (Gross, 1910), the type species; Spirillum ostrea (Noguchi, 1921); and another, less frequent bacterial symbiont are the predominant inhabitants of the dense style matrix. The ultrastructure of the spirillum and an electron micrograph of the third bacterium are shown.

NASA Program Exobiology↗

Light domain walls, massive neutrinos and the large scale structure of the Universe

Domain walls generated through a cosmological phase transition are considered, which interact nongravitationally with light neutrinos. At a redshift z greater than or equal to 10(exp 4), the network grows rapidly and is virtually decoupled from the matter. As the friction with the matter becomes dominant, a comoving network scale close to that of the comoving horizon scale at z of approximately 10(exp 4) gets frozen. During the later phases, the walls produce matter wakes of a thickness d of approximately 10h(exp -1)Mpc, that may become seeds for the formation of the large scale structure observed in the Universe.

Massarotti, Alessandro↗

Graphite-epoxy panel compression strength reduction due to local impact

A review of results from on-going research to investigate the effects of low-velocity impact on the compressive strength of graphite-epoxy structures is presented. Extensive tests have been conducted on sandwich beams, laminated plates and stiffened panels. Conditions for failures were investigated by impact tests on statically loaded test specimens. The effects of compression load intensity were such that lightly loaded graphite structures (such as aircraft secondary structure) were insensitive to impact damage. In more heavily loaded structures, (such as wing panels), however, appreciable reductions in compressive strength occurred. The implications of the tests for structural design are discussed by comparing panel masses for designs where ultimate strains have been reduced due to impact considerations with the masses of designs with higher ultimate strains. Finally, preliminary test data is presented to show the possibility of improvements in damage tolerance achievable by using an alternate matrix material.

Card, M. P.↗

Five X-ray observations of the intermediate polar FO Aqr spanning ten years

The comparison of five X-ray observations of FO Aqr reveals that the morphology of the X-ray light curve changes considerably with time. Power spectra from 1988 and 1993 reveal a sideband component, while power spectra from 1990 do not. This suggests that the amount of disk overflow accretion varies as a function of time. From structured spin folded light curves, the presence of complex, multicomponent emitting regions near the white dwarf's surface can be inferred.

Beardmore, A. P.↗

The Heating of the Solar Atmosphere: from the Bottom Up?

The heating of the solar atmosphere remains a mystery. Over the past several decades, scientists have examined the observational properties of structures in the solar atmosphere, notably their temperature, density, lifetime, and geometry, to determine the location, frequency, and duration of heating. In this talk, I will review these observational results, focusing on the wealth of information stored in the light curve of structures in different spectral lines or channels available in the Solar Dynamic Observatory's Atmospheric Imaging Assembly, Hinode's X-ray Telescope and Extreme-ultraviolet Imaging Spectrometer, and the Interface Region Imaging Spectrograph. I will discuss some recent results from combined data sets that support the heating of the solar atmosphere may be dominated by low, near-constant heating events.

Winebarger, Amy↗

"Sandwich" Stiffener for Composite Structural Panels

Concept uses commercial titanium honeycomb core brazed to cap material and panel skin. In fabrication of stringers, large sheets of cap material are brazed to pieces of honeycomb core of desired height. After brazing, individual stringers are cut by electrical-discharge machining, and stringers are subsequently brazed to skin. Sandwich beam stringer is light-weight, structurally-efficient, low-cost stiffener for metal-matrix composite structural panels.

Mcwithey, R. R.↗

Complementarity of neutron, XFEL and synchrotron crystallography for defining the structures of metalloenzymes at room temperature

Room-temperature macromolecular crystallography allows protein structures to be determined under close-to-physiological conditions, permits dynamic freedom in protein motions and enables time-resolved studies. In the case of metalloenzymes that are highly sensitive to radiation damage, such room-temperature experiments can present challenges, including increased rates of X-ray reduction of metal centres and site-specific radiation-damage artefacts, as well as in devising appropriate sample-delivery and data-collection methods. It can also be problematic to compare structures measured using different crystal sizes and light sources. In this study, structures of a multifunctional globin, dehaloperoxidase B (DHP-B), obtained using several methods of room-temperature crystallographic structure determination are described and compared. Here, data were measured from large single crystals and multiple microcrystals using neutrons, X-ray free-electron laser pulses, monochromatic synchrotron radiation and polychromatic (Laue) radiation light sources. These approaches span a range of 18 orders of magnitude in measurement time per diffraction pattern and four orders of magnitude in crystal volume. The first room-temperature neutron structures of DHP-B are also presented, allowing the explicit identification of the hydrogen positions. The neutron data proved to be complementary to the serial femtosecond crystallography data, with both methods providing structures free of the effects of X-ray radiation damage when compared with standard cryo-crystallography. Comparison of these room-temperature methods demonstrated the large differences in sample requirements, data-collection time and the potential for radiation damage between them. With regard to the structure and function of DHP-B, despite the results being partly limited by differences in the underlying structures, new information was gained on the protonation states of active-site residues which may guide future studies of DHP-B.

36 MATERIALS SCIENCE↗

Combined modeling and experiments to predict corrosion and embrittlement in dual-phase stainless steels within the MARMOT framework

Extending service of Light Water Reactors (LWRs) to beyond 60 years will demand high integrity of materials and components in the reactors. The accurate evaluation and prediction of materials performance under anticipated operating conditions are of particular importance for ensuring the safety of nuclear power plants over their extended lifetime. Stainless steels are extensively used as structural alloys in light water reactor (LWR) systems because of their excellent combination of mechanical properties and corrosion resistance. Austenitic stainless steel welds and cast austenitic stainless steels (CASS) contain significant amounts of ferrite ~5-30% and are ubiquitous in LWR piping (elbows, pump casings, valves) and internal structural components. During their lifetime, these components are subjected to thermal aging at the temperature range of 288-327°C for pressurized water reactors (PWR). A phase transformation within the ferrite phase of these materials leads to embrittlement and degradation in corrosion resistance, which undermines the materials selection criteria.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Light-induced electron pairing in a bilayer structure

We demonstrate the existence of doubly charged exciton states in strongly screened bilayers of transition metal dichalcogenide layers. These complexes are important because they are preformed electron pairs that can, in principle, undergo Bose–Einstein condensation, in which case they would also form a new type of superconductor, consisting of stable bosons with net charge. Our measurements include 1) continuous control of the doping density with both positive and negative carriers, showing the expected population dependencies on the free carrier density, and 2) measurement of the dependence on magnetic field, showing that this new bound state is a spin triplet. These results imply that it is promising to look for superconductivity in this system.

2D material↗

Impact of the MARATHON data on F 2⁢n⁡ /F 2⁢p and off-shell effects in light nuclei

The neutron structure function, F 2⁢n⁡ , has historically been extracted from measurements of the deuteron structure function, which is limited by our understanding of the nuclear effects on the bound proton and neutron. The MARATHON Collaboration recently extracted F 2⁢n⁡ from the comparison of 3 H and 3 He targets, where the nuclear effects are larger but nearly identical, yielding a precise extraction of F 2⁢n⁡ /F 2⁢p . Here, to ensure that this comparison is not biased by the specific model of nuclear effects used by MARATHON, we examine a range of models of the nuclear effects to obtain a more conservative, but more model-independent, extraction of F 2⁢n⁡ /F 2⁢p for comparison with deuteron extractions. Even with this approach, the results are precise enough to compare to deuteron extractions, providing new constraints on the nuclear effects in the deuteron and indicating the need for larger nuclear corrections than those included in most models.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Small scale structure in the brightness of the zodiacal light - Ground-based observations

Ground-based observations of the evening zodiacal light are used to derive a table of zodiacal light brightnesses at spatial resolutions as small as 0.5 deg in differential ecliptic longitude and 1.0 deg in ecliptic latitude. Significant differences are found in the brightness distribution above and below the ecliptic plane. Attention is given to a feature found in the brightness at all ecliptic latitudes, between differential ecliptic longitudes 39 deg and 42 deg.

Misconi, Nebil Y.↗