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At least 469 records · Page 26

Bioconversion of self-neutralized chemically depolymerized lignin streams into polyhydroxyalkanoates

Lignin is a chemically complex, diverse, and abundant plant polymer mainly composed of aromatic monomers. These aromatic monomers make lignin a potential source of aromatics and a viable substitute for petrochemically-derived aromatics. However, the structural recalcitrance of lignin requires harsh reagents from the chemical process and expensive catalysts for effective depolymerization. This chemical process often results in poor yields of chemical intermediate mixtures of varying bioavailability and/or toxicity. Furthermore, the cost of additional reagents required to separate or detoxify these intermediates makes processing lignin impractical. We report progress towards the use of such chemically depolymerized lignin streams by employing bacterial strains to produce polyhydroxyalkanoates (PHA). PHAs are a group of biodegradable microbial polyesters that have potential as a replacement for petroleum-based plastics. In this study we utilized two distinct lignin streams obtained after chemical depolymerization of lignin under alkaline and acidic pH in the presence of catalysts. We mixed the alkali-treated depolymerized stream with the acid-treated depolymerized stream to create a solution of neutral-pH chemically depolymerized lignin (CDL). We found moderate to substantial growth of both native and non-native PHA producers on the mixture of CDL as well as its aliphatic and aromatic components. PHA was detected by Sudan Black B staining in C. necator H16, P. putida KT2440, and E. coli LSBJ STQKAB grown on mixed CDL as the sole carbon source. For C. necator H16 and E. coli LSBJ STQKAB we found that PHA content was greater when grown on mixed CDL when compared to their preferred carbon source by GC-FID quantification. Our study provided progress towards a cost-competitive, sustainable, and industrially relevant use for lignin.

Winkler, Gordon L. W. [Univ. of Wisconsin, Madison↗

Simple and Scalable Streaming: The GRETA Data Pipeline

The Gamma Ray Energy Tracking Array (GRETA) is a state of the art gamma-ray spectrometer being built at Lawrence Berkeley National Laboratory to be first sited at the Facility for Rare Isotope Beams (FRIB) at Michigan State University. A key design requirement for the spectrometer is to perform gamma-ray tracking in near real time. To meet this requirement we have used an inline, streaming approach to signal processing in the GRETA data acquisition system, using a GPU-equipped computing cluster. The data stream will reach 480 thousand events per second at an aggregate data rate of 4 gigabytes per second at full design capacity. We have been able to simplify the architecture of the streaming system greatly by interfacing the FPGA-based detector electronics with the computing cluster using standard network technology. A set of highperformance software components to implement queuing, flow control, event processing and event building have been developed, all in a streaming environment which matches detector performance. Prototypes of all high-performance components have been completed and meet design specifications.

Cromaz, Mario↗

Photoelectron spectroscopy of aqueous solutions: Streaming potentials of NaX (X = Cl, Br, and I) solutions and electron binding energies of liquid water and X{sup −}

The streaming potentials of liquid beams of aqueous NaCl, NaBr, and NaI solutions are measured using soft X-ray, He(I), and laser multiphoton ionization photoelectron spectroscopy. Gaseous molecules are ionized in the vicinity of liquid beams and the photoelectron energy shifts are measured as a function of the distance between the ionization point and the liquid beam. The streaming potentials change their polarity with concentration of electrolytes, from which the singular points of concentration eliminating the streaming potentials are determined. The streaming currents measured in air also vanish at these concentrations. The electron binding energies of liquid water and I{sup −}, Br{sup −}, and Cl{sup −} anions are revisited and determined more accurately than in previous studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The upcycling of post-industrial PP/PET waste streams through in-situ microfibrillar preparation

Post-industrial plastic waste streams can be re-used as secondary material streams for polymer processing by extrusion or injection moulding. One of the major commercially available waste stream contains polypropylene (PP) contaminated with polyesters (mostly polyethylene tereftalate - PET). An important practical hurdle for the direct implementation of this waste stream is the immiscibility of PP and PET in the melt, which leads to segregation within the polymer structure and adversely affects the reproducibility and mechanical properties of the manufactured parts. It has been indicated in literature that the creation of PET microfibrils in the PP matrix could undo these drawbacks and upcycle the PP/PET combination. Within the current research, a commercially available virgin PP/PET was evaluated for the microfibrillar preparation. The mechanical (tensile and impact) properties, thermal properties and morphology of the composites were characterized at different stages of the microfibrillar preparation.

36 MATERIALS SCIENCE↗

The Physics Imposed on a Streaming Operator by Spherical Transport Problems

The streaming operator, which generates a displacement of a particle on a straight line at a constant speed in transport theory, is derived algebraically from a spherical coordinate formulation of Newton’s second law. This derivation leads to an operator that has more partial derivatives than a Cartesian coordinate formulation of the operator. The additional partial derivatives, which are with respect to the normalized velocity variables of a particle, take into account the intrinsic curvature of a ball. Moreover, these partial derivatives mitigate ray effects, which arise when a finite number of normalized velocities (also called directions or discrete ordinates) are used to simulate a continuous S 2 sphere of directions, by rotating the polar axis of the S 2 sphere into the radial direction of the coordinate system. As a consequence of this rotation, the number of actual discrete ordinates is greatly amplified to an enormous number of effective discrete ordinates by a multiplier that is equal to the number of patches that partitions a spherical surface. In addition to the derivation of the streaming operator, we provide in closed form a solution to the system of characteristic equations that is equivalent to the streaming operator. Furthermore, the solution to the system of characteristic equations enables the construction of an integral operator that is the inverse to the streaming operator. Examples in which ray effects are immensely mitigated by spherical coordinates are presented.

integral operator↗

Imaging and spectroscopic observations of a filament channel and the implications for the nature of counter-streamings

The dynamics of a filament channel are observed with imaging and spectroscopic telescopes before and during the filament eruption on 2011 January 29. The extreme ultraviolet (EUV) spectral observations reveal that there are no EUV counterparts of the Hα counter-streamings in the filament channel, implying that the ubiquitous Hα counter-streamings found by previous research are mainly due to longitudinal oscillations of filament threads, which are not in phase between each other. However, there exist larger-scale patchy counter-streamings in EUV along the filament channel from one polarity to the other, implying that there is another component of unidirectional flow (in the range of ±10 km s{sup –1}) inside each filament thread in addition to the implied longitudinal oscillation. Our results suggest that the flow direction of the larger-scale patchy counter-streaming plasma in the EUV is related to the intensity of the plage or active network, with the upflows being located at brighter areas of the plage and downflows at the weaker areas. We propose a new method to determine the chirality of an erupting filament on the basis of the skewness of the conjugate filament drainage sites. This method suggests that the right-skewed drainage corresponds to sinistral chirality, whereas the left-skewed drainage corresponds to dextral chirality.

79 ASTRONOMY AND ASTROPHYSICS↗

The PAndAS field of streams: Stellar structures in the milky way halo toward Andromeda and Triangulum

We reveal the highly structured nature of the Milky Way (MW) stellar halo within the footprint of the Pan-Andromeda Archaeological Survey (PAndAS) photometric survey from blue main sequence (MS) and MS turn-off stars. We map no fewer than five stellar structures within a heliocentric range of ∼5-30 kpc. Some of these are known (the Monoceros Ring, the Pisces/Triangulum globular cluster stream), but we also uncover three well-defined stellar structures that could be, at least partly, responsible for the so-called Triangulum/Andromeda and Triangulum/Andromeda 2 features. In particular, we trace a new faint stellar stream located at a heliocentric distance of ∼17 kpc. With a surface brightness of Σ {sub V} ∼ 32-32.5 mag arcsec{sup –2}, it follows an orbit that is almost parallel to the Galactic plane north of M31 and has so far eluded surveys of the MW halo as these tend to steer away from regions dominated by the Galactic disk. Investigating our follow-up spectroscopic observations of PAndAS, we serendipitously uncover a radial velocity signature from stars that have colors and magnitudes compatible with the stream. From the velocity of eight likely member stars, we show that this stellar structure is dynamically cold, with an unresolved velocity dispersion that is lower than 7.1 km s{sup –1} at the 90% confidence level. Along with the width of the stream (300-650 pc), its dynamics point to a dwarf-galaxy-accretion origin. The numerous stellar structures we can map in the MW stellar halo between 5 and 30 kpc and their varying morphology is a testament to the complex nature of the stellar halo at these intermediate distances.

79 ASTRONOMY AND ASTROPHYSICS↗

On the feeding zone of planetesimal formation by the streaming instability

The streaming instability is a promising mechanism to overcome the barriers in direct dust growth and lead to the formation of planetesimals. Most previous studies of the streaming instability, however, were focused on a local region of a protoplanetary disk with a limited simulation domain such that only one filamentary concentration of solids has been observed. The characteristic separation between filaments is therefore not known. To address this, we conduct the largest-scale simulations of the streaming instability to date, with computational domains up to 1.6 gas scale heights both horizontally and vertically. The large dynamical range allows the effect of vertical gas stratification to become prominent. We observe more frequent merging and splitting of filaments in simulation boxes of high vertical extent. We find multiple filamentary concentrations of solids with an average separation of about 0.2 local gas scale heights, much higher than the most unstable wavelength from linear stability analysis. This measures the characteristic separation of planetesimal forming events driven by the streaming instability and thus the initial feeding zone of planetesimals.

79 ASTRONOMY AND ASTROPHYSICS↗

A COMPACT HIGH VELOCITY CLOUD NEAR THE MAGELLANIC STREAM: METALLICITY AND SMALL-SCALE STRUCTURE

The Magellanic Stream (MS) is a well-resolved gaseous tail originating from the Magellanic Clouds. Studies of its physical properties and chemical composition are needed to understand its role in Galactic evolution. We investigate the properties of a compact HVC (CHVC 224.0-83.4-197) lying close on the sky to the MS to determine whether it is physically connected to the Stream and to examine its internal structure. Our study is based on analysis of HST/COS spectra of three QSOs (Ton S210, B0120-28, and B0117-2837) all of which pass through this single cloud at small angular separation (≲0.°72), allowing us to compare physical conditions on small spatial scales. No significant variation is detected in the ionization structure from one part of the cloud to the other. Using Cloudy photoionization models, toward Ton S210 we derive elemental abundances of [C/H] = –1.21 ± 0.11, [Si/H] = –1.16 ± 0.11, [Al/H] = –1.19 ± 0.17, and [O/H] = –1.12 ± 0.22, which agree within 0.09 dex. The CHVC abundances match the 0.1 solar abundances measured along the main body of the Stream. This suggests that the CHVC (and by extension the extended network of filaments to which it belongs) has an origin in the MS. It may represent a fragment that has been removed from the Stream as it interacts with the gaseous Galactic halo.

79 ASTRONOMY AND ASTROPHYSICS↗

100 Gb/s High Throughput Serial Protocol (HTSP) for data acquisition systems with interleaved streaming

Demands on Field-Programmable Gate Array (FPGA) data transport have been increasing over the years as frame sizes and refresh rates increase. As the bandwidths requirements increase the ability to implement data transport protocol layers using "soft" programmable logic becomes harder and start to require harden IP blocks implementation. To reduce the number of physical links and interconnects, it is common for data acquisition systems to require interleaving of streams on the same link (e.g. streaming data and streaming register access). Further, this paper presents a way to leverage existing FPGA harden IP blocks to achieve a robust, low latency 100 Gb/s point-to-point link with minimal programmable logic overhead geared towards the needs of data acquisition systems with interleaved streaming requirements.

47 OTHER INSTRUMENTATION↗

via machinae : Searching for stellar streams using unsupervised machine learning

ABSTRACT We develop a new machine learning algorithm, via machinae, to identify cold stellar streams in data from the Gaia telescope. via machinae is based on ANODE, a general method that uses conditional density estimation and sideband interpolation to detect local overdensities in the data in a model agnostic way. By applying ANODE to the positions, proper motions, and photometry of stars observed by Gaia, via machinae obtains a collection of those stars deemed most likely to belong to a stellar stream. We further apply an automated line-finding method based on the Hough transform to search for line-like features in patches of the sky. In this paper, we describe the via machinae algorithm in detail and demonstrate our approach on the prominent stream GD-1. Though some parts of the algorithm are tuned to increase sensitivity to cold streams, the via machinae technique itself does not rely on astrophysical assumptions, such as the potential of the Milky Way or stellar isochrones. This flexibility suggests that it may have further applications in identifying other anomalous structures within the Gaia data set, for example debris flow and globular clusters.

79 ASTRONOMY AND ASTROPHYSICS↗

Auriga Streams – I: disrupting satellites surrounding Milky Way-mass haloes at multiple resolutions

In a hierarchically formed Universe, galaxies accrete smaller systems that tidally disrupt as they evolve in the host’s potential. We present a complete catalogue of disrupting galaxies accreted onto Milky Way-mass haloes from the Auriga suite of cosmological magnetohydrodynamic zoom-in simulations. We classify accretion events as intact satellites, stellar streams, or phase-mixed systems based on automated criteria calibrated to a visually classified sample, and match accretions to their counterparts in haloes re-simulated at higher resolution. Most satellites at the present day have lost substantial amounts of stellar mass – 67 per cent have $f_\text{bound} < 0.97$ (our threshold of lost stellar mass to no longer be considered intact), while 53 per cent satisfy a more stringent $f_\text{bound} < 0.8$. Streams typically outnumber intact systems, contribute a smaller fraction of overall accreted stars, and are substantial contributors at intermediate distances from the host centre ($\sim$0.1 to $\sim 0.7R_\text{200m}$, or $\sim$35 to $\sim$250 kpc for the Milky Way). We also identify accretion events that disrupt to form streams around massive intact satellites instead of the main host. Streams are more likely than intact or phase-mixed systems to have experienced pre-processing, suggesting this mechanism is important for setting disruption rates around Milky Way-mass haloes. All of these results are preserved across different simulation resolutions, though we do find some hints that satellites disrupt more readily at lower resolution. The Auriga haloes suggest that disrupting satellites surrounding Milky Way-mass galaxies are the norm and that a wealth of tidal features waits to be uncovered in upcoming surveys.

galaxies: haloes↗

The Dark Energy Survey view of the Sagittarius stream: Discovery of two faint stellar system candidates

We report the discovery of two new candidate stellar systems in the constellation of Cetus using the data from the first two years of the Dark Energy Survey (DES). The objects, DES J0111–1341 and DES J0225+0304, are located at a heliocentric distance of ~25 kpc and appear to have old and metal-poor populations. Their distances to the Sagittarius orbital plane, ~1.73 kpc (DES J0111–1341) and ~0.50 kpc (DES J0225+0304), indicate that they are possibly associated with the Sagittarius dwarf stream. The half-light radius (rh ≃ 4.55 pc) and luminosity (MV ≃ +0.3) of DES J0111–1341 are consistent with it being an ultrafaint stellar cluster, while the half-light radius (rh ≃ 18.55 pc) and luminosity (MV ≃ –1.1) of DES J0225+0304 place it in an ambiguous region of size–luminosity space between stellar clusters and dwarf galaxies. Determinations of the characteristic parameters of the Sagittarius stream, metallicity spread (–2.18 ≲ [Fe/H] ≲ –0.95) and distance gradient (23 kpc ≲ D⊙ ≲ 29 kpc), within the DES footprint in the Southern hemisphere, using the same DES data, also indicate a possible association between these systems. If these objects are confirmed through spectroscopic follow-up to be gravitationally bound systems and to share a Galactic trajectory with the Sagittarius stream, DES J0111–1341 and DES J0225+0304 would be the first ultrafaint stellar systems associated with the Sagittarius stream. Moreover, DES J0225+0304 would also be the first confirmed case of an ultrafaint satellite of a satellite.

79 ASTRONOMY AND ASTROPHYSICS↗

Modelling the Tucana III stream - a close passage with the LMC

In this work, we present results of the first dynamical stream fits to the recently discovered Tucana III stream. These fits assume a fixed Milky Way potential and give proper motion predictions, which can be tested with the upcoming Gaia Data Release 2 (DR2). These fits reveal that Tucana III is on an eccentric orbit around the Milky Way and, more interestingly, that Tucana III passed within 15 kpc of the Large Magellanic Cloud (LMC) approximately 75 Myr ago. Given this close passage, we fit the Tucana III stream in the combined presence of the Milky Way and the LMC. We find that the predicted proper motions depend on the assumed mass of the LMC and that the LMC can induce a substantial proper motion perpendicular to the stream track. A detection of this misalignment will directly probe the extent of the LMC’s influence on our Galaxy, and has implications for nearly all methods which attempt to constraint the Milky Way potential. Lastly, such a measurement will be possible with the upcoming Gaia DR2, allowing for a measurement of the LMC’s mass.

79 ASTRONOMY AND ASTROPHYSICS↗

The total mass of the Large Magellanic Cloud from its perturbation on the Orphan stream

In a companion paper by Koposov et al., RR Lyrae from Gaia Data Release 2 are used to demonstrate that stars in the Orphan stream have velocity vectors significantly misaligned with the stream track, suggesting that it has received a large gravitational perturbation from a satellite of the Milky Way. We argue that such a mismatch cannot arise due to any realistic static Milky Way potential and then explore the perturbative effects of the Large Magellanic Cloud (LMC). We find that the LMC can produce precisely, the observed motion-track mismatch and we therefore use the Orphan stream to measure the mass of the Cloud. We simultaneously fit the Milky Way and LMC potentials and infer that a total LMC mass of |$1.38^{+0.27}_{-0.24} \times 10^{11}\, \rm {M_\odot}$| is required to bend the Orphan stream, showing for the first time that the LMC has a large and measurable effect on structures orbiting the Milky Way. This has far-reaching consequences for any technique which assumes that tracers are orbiting a static Milky Way. Furthermore, we measure the Milky Way mass within 50 kpc to be |$3.80^{+0.14}_{-0.11}\times 10^{11} \, \mathrm{M}_\odot$|. Finally, we use these results to predict that, due to the reflex motion of the Milky Way in response to the LMC, the outskirts of the Milky Way’s stellar halo should exhibit a bulk, upwards motion.

79 ASTRONOMY AND ASTROPHYSICS↗

Large-scale structure perturbation theory without losing stream crossing

Here, we suggest an approach to perturbative calculations of large-scale clustering in the Universe that includes from the start the stream crossing (multiple velocities for mass elements at a single position) that is lost in traditional calculations. Starting from a functional integral over displacement, the perturbative series expansion is in deviations from (truncated) Zel’dovich evolution, with terms that can be computed exactly even for stream-crossed displacements. We evaluate the one-loop formulas for displacement and density power spectra numerically in 1D, finding dramatic improvement in agreement with N-body simulations compared to the Zel’dovich power spectrum (which is exact in 1D up to stream crossing). Beyond 1D, our approach could represent an improvement over previous expansions even aside from the inclusion of stream crossing, but we have not investigated this numerically. In the process we show how to achieve effective-theory-like regulation of small-scale fluctuations without free parameters.

79 ASTRONOMY AND ASTROPHYSICS↗

Evaporation and propagation of liquid drop streams at vacuum pressures: Experiments and modeling

Evaporation of streams of liquid droplets in environments at vacuum pressures below the vapor pressure has not been widely studied. Here, experiments and simulations are reported that quantify the change in droplet diameter when a steady stream of ≈100 μm diameter drops is injected into a chamber initially evacuated to <10 –8 bar. In experiments, droplets fall through the center of a 0.8 m long liquid nitrogen cooled shroud, simulating infinity radiation and vapor mass flux boundary conditions. Furthermore, experimentally measured changes in drop diameters vary from ≈0 to 6 μm when the initial vapor pressure is increased from 10 –6 to 10 –3 bar by heating the liquid. Measured diameter changes are predicted by a model based on the Hertz-Knudsen equation. One uncertainty in the calculation is the “sticking coefficient” β. Assuming a constant β for all conditions studied here, predicted diameter changes best match measurements with β≈0.3. This value falls within the range of β reported in the literature for organic liquids. Finally, at the higher vapor pressure conditions considered here, the drop stream disperses transverse to the main flow direction. This spread is attributed to forces imparted by an absolute pressure gradient produced by the evaporating stream.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DRIPS: Dynamic Rebalancing of Pipelined Streaming Applications on CGRAs

Coarse-grained reconfigurable arrays (CGRAs) provide higher flexibility than application-specific integrated circuits (ASICs) and higher efficiency than fine-grained reconfigurable devices such as Field Programmable Gate Arrays (FPGAs). However, CGRAs are generally designed to support offloading of a single kernel. While their design, based on communicating functional units, appears to naturally suit data streaming applications composed of multiple cooperating kernels, current approaches only statically partition the resources across application kernels. However, emerging streaming applications at the edge (scientific instruments, sensor networks, network processing) perform much more than digital signal processing and often are data and input dependent. This leads to extremely variable kernel execution times, severely impacting the throughput of the entire pipeline if resources are only statically allocated. Therefore, in this paper, we propose DRIPS — a coarse-grained, dynamically, and partially reconfigurable array for data-dependent streaming applications. We present a unified compiler framework to facilitate the mapping of a given streaming application onto the DRIPS CGRA architecture. The experimental results show that DRIPS achieves an average throughput improvement of 1.46$\times$ across a set of representative applications over a statically partitioned solution. The additional area overhead to enable dynamic rebalancing consumes 16.34% of the entire area for a 5x5 CGRA prototype.

Tan, Cheng↗