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At least 469 records · Page 26

Hanford Site Composite Analysis: Dose Sensitivity Analyses

This environmental calculation file (ECF) documents the methodologies, assumptions, and results of five analyses that evaluate parameter changes to the revised Hanford Site Composite Analysis (CA) (DOE-RL-2019-52, Composite Analysis for Low-Level Waste Disposal in the Hanford Site Central Plateau). Specifically, this ECF describes the impact on total dose and analyte-specific doses for five sensitivity cases where changes to the following exposure-related parameters were implemented – (1) inventory, (2) recharge rate, (3) external dose conversion factors (DCFs) based on Federal Guidance Report (FGR) No. 15 in (EPA-402-R-19-002, Federal Guidance Report No. 15, External Exposure to Radionuclides in Air, Water, and Soil) instead of FGR No. 12 (EPA 402-R-93-081, Federal Guidance Report No. 12, External Exposure to Radionuclides in Air, Water, and Soil) for groundwater pathway scenario; (4) use of mean instead of 95th percentile intake assumptions for groundwater pathway scenario; and (5) consideration of limited sources based on U.S. Department of Energy (DOE) owned waste sites regulated under DOE O 435.1, Radioactive Waste Management. It should be noted that dose assessments for both base and sensitivity cases are based on the all-pathways representative person groundwater exposure scenario presented in DOE/RL-2022-52, Composite Analysis for Low-Level Waste Disposal in the Hanford Site Central Plateau.

54 ENVIRONMENTAL SCIENCES↗

Annual Status Report (FY 2020): Performance Assessment for the Disposal of Low Level Waste in the 200 East Area Burial Grounds

This annual review provides the projected dose estimates of radionuclide inventories disposed in the 200 East Area Low-Level Waste Burial Grounds (LLBGs) since September 26, 1988. These estimates are calculated using the original dose methodology developed in the performance assessment (PA) analysis (WHC-SD-WM-TI-730). The estimates are compared with requirements of DOE O 435.1 Chg 1 and performance objectives defined in companion documents DOE M 435.1-1 Chg 1and DOE-STD-5002-2017). All performance objectives are currently satisfied, and operational waste acceptance criteria (HNF-EP-0063) and waste acceptance practices continue to be sufficient to maintain compliance with performance objectives. Inventory estimates and associated dose estimates from future waste disposal actions are unchanged from previous years’ evaluations that indicate potential impacts well below performance objectives; therefore, future compliance with DOE O 435.1 Chg 1 is expected. A new PA study was initiated in fiscal year (FY) 2019 for evaluation of active disposal sites within the 200 East and 200 West Areas (Trench 94 in 200 East; Trenches 31 and 34 in 200 West) due to extended time elapsing between the current annual status report and the original PA for the active disposal sites. The new PA for the active disposal sites is expected to be completed in FY 2021. Within the active burial grounds in the 200 East Area, low-level waste and mixed low-level waste will continue to be disposed of in the dedicated U.S. Navy reactor compartment trench at the 218-E-12B Burial Ground (Trench 94). During this reporting period (FY 2020, from October 1, 2019, through September 30, 2020), two reactor compartments were disposed in Trench 94. Results from sorption experiments are summarized for this reporting period to quantify the efficacy of concrete waste forms in retaining key radionuclides (e.g., technetium-99 and iodine-129). The test durations ranged from 1 to 3 months. Continued groundwater monitoring of the 200 East Area LLBGs indicates no groundwater contamination due to LLBG waste. Current assumptions about future land use at the Hanford Site are consistent with PA analysis1 assumptions of a post-closure facility that will not be degraded by human activity. The LLBGs are located in an area identified for waste management and containment of residual contamination. This area will remain after final environmental remediation and the proposed shrinkage of Hanford Site boundaries to small sections within the 200 East and 200 West Areas in the Central Plateau (DOE/EIS-0391). The current closure plan for the LLBGs (DOE/RL-2000-707) estimates that the 200 East LLBGs will be closed in the 2050 timeframe. The Disposal Authorization Statement, other technical basis documents, and the radioactive waste management basis are of continued adequacy to meet the performance objectives of DOE O 435.1 Chg 1. Overall, there are no substantive changes to primary PA assumptions nor the PA analysis conclusion; therefore, compliance with DOE O 435.1 Chg 1 and the Disposal Authorization Statement is maintained.

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Machine learning surrogates for surface complexation model of uranium sorption to oxides

Abstract The safety assessments of the geological storage of spent nuclear fuel require understanding the underground radionuclide mobility in case of a leakage from multi-barrier canisters. Uranium, the most common radionuclide in non-reprocessed spent nuclear fuels, is immobile in reduced form (U(IV) and highly mobile in an oxidized state (U(VI)). The latter form is considered one of the most dangerous environmental threats in the safety assessments of spent nuclear fuel repositories. The sorption of uranium to mineral surfaces surrounding the repository limits their mobility. We quantify uranium sorption using surface complexation models (SCMs). Unfortunately, numerical SCM solvers often encounter convergence problems due to the complex nature of convoluted equations and correlations between model parameters. This study explored two machine learning surrogates for the 2-pK Triple Layer Model of uranium retention by oxide surfaces if released as U(IV) in the oxidizing conditions: random forest regressor and deep neural networks. Our surrogate models, particularly DNN, accurately reproduce SCM model predictions at a fraction of the computational cost without any convergence issues. The safety assessment of spent fuel repositories, specifically the migration of leaked radioactive waste, will benefit from having ultrafast AI/ML surrogates for the computationally expensive sorption models that can be easily incorporated into larger-scale contaminant migration models. One such model is presented here.

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Nuclear Power Plant Infrastructure Evaluations for Removal of Spent Nuclear Fuel

This report provides evaluations of the NPP site infrastructure and near-site transportation infrastructure for removing spent nuclear from 16 (NPP) sites. The material to be removed from the NPP sites includes both the spent nuclear fuel (SNF) and the greater-than-Class C low level radioactive waste (GTCC waste) that is stored, or will be stored, at the sites.

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Quantification of Raman-Interfering Polyoxoanions for Process Analysis: Comparison of Different Chemometric Models and a Demonstration on Real Hanford Waste

The Hanford site represents a complicated environmental remediation challenge, remaining from the production of nuclear weapons. Over 100 million gallons of liquid radioactive waste of unknown composition will be chemically processed and vitrified, but the varying chemical composition and highly radioactive nature of the waste preclude the implementation of more developed, offline technologies to determine the composition. The only practical approach to waste treatment will require the significant utilization of real-time, chemometric modeling approaches. Although chemometric approaches have been applied to the analysis of Hanford waste, the models developed were highly tank-specialized, and limited discussion was provided on how models fared with interfering signals. As the tank waste is largely composed of oxoanions, which tend to have interfering Raman spectra, the general question was posed as to what chemometric approach is best suited to accurately quantify analytes in the presence of interfering signals. This was carried out by examining the ability of classical least square (CLS), principal component regression (PCR), partial least square (PLS), and locally weighted regression (LWR) to quantify NO 3 – and CO 3 2– using their bands around 1050 cm –1 . Finally, for all samples, the PLS-based model was found to be the most efficient approach from a model building and application perspective.

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Contaminant Transport Simulation with the P2R Model for the Composite Analysis Base Case

In order to meet the requirements of U.S. Department of Energy (DOE) in DOE O 435.1, Radioactive Waste Management, a composite analysis (CA) must be completed for the Central Plateau at the Hanford Site. The updated Hanford CA requires estimates of fate and transport of radionuclides in the groundwater from multiple sources within and downgradient of the Central Plateau.

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High-Burnup Spent Fuel Data Project Sibling Pin Test Campaign Closeout Summary

The Used Fuel Disposition Campaign (UFDC) was established within the United States (U.S.) Department of Energy (DOE) Office of Nuclear Energy (NE) to conduct research and development (R&D) activities associated with storage, transportation, and disposal of used or spent nuclear fuel (UNF or SNF) and high-level radioactive waste.

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Long-length Scintillating Fibers for Nuclear Geological Repositories

This research focuses on the usage of plastic scintillating fibers as ruggedized detectors in long-length sections coupled to long-length standard optical fiber segments for the purpose of radiation detection and monitoring. This technology addresses a need for monitoring radiation in difficult-to-access or inaccessible areas, such as monitoring: radioactive waste within geological repositories, nuclear material storage facilities, spent fuel dry storage areas, inaccessible areas within nuclear facilities including reactors and reprocessing facilities, decommissioning of nuclear facilities, and other similar areas. The fiber can be placed along the tunnels of a geological repository to monitor the radiation field along its length. This can detect an increase of radiation due to movement, leakage, or unexpected opening of the containers, as well as decrease in the radiation due to removal of material. These capabilities have been demonstrated at INL’s Radioactive Scrap Waste Facility by successfully detecting the removal of an interim storage containers from the storage area. The poster focuses on explaining the technology and its capability in monitoring deep geological repositories (DGRs), especially in the domain of safety and international safeguards. As more countries consider the development of DGRs, technologies such as the one being presented can help establish continuity of knowledge of the material, maintain public confidence, and ensure safe operation of the facility. Furthermore, the poster looks at the future steps of the technology and its potential role in the international safeguards regime.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗

Nuclear Safety [Vol. 16, No. 2, March-April 1975]

Nuclear Safety covers significant developments in the field of nuclear safety. The scope is limited to topics relevant to the analysis and control of hazards associated with nuclear energy, operations involving fissionable materials, and the products of nuclear fission and their effects on the environment. Primary emphasis is on safety in reactor design, construction, and operation; however, safety considerations in regard to the entire fuel cycle, including fuel fabrication, spent-fuel processing, nuclear waste disposal, handling of radioisotopes, and environmental effects of these operations, are also treated. Table of Contents for this issue follows. Table of Contents for this issue follows. GENERAL SAFETY CONSIDERATIONS: 127 Quality Assurance in the Construction of Nuclear Power Plants by Sidney A. Bernsen, 141 1974 ANS Topical Meeting on Fast Reactor Safety by M. H. Fontana; CONTROL AND INSTRUMENTATION: 150 GBR-4 Protection Systems: Failures and Their Consequences by Peter Burgsmüller, J. J. Dekais, Albert Krähe, Raffaello Pignatelli, and Gottfried Vieider, 162 Standby Emergency Power Systems. Part 2—The Later Plants by E. W. Hagen; PLANT SAFETY FEATURES: 180 Radiotoxic Hazard Measure for Buried Solid Radioactive Waste by J. Hamstra, 190 The Thirteenth AEC Air-Cleaning Conference by D. W. Moeller, D. W. Underhill, and M. W. First, 203 Book Review: Nuclear Criticality Safety; CONSEQUENCES OF EFFLUENT RELEASE: 204 Environmental Radiation Effects of Nuclear Facilities in New York State by M. S. Terpilak and B. L. Jorgensen, 222 Book Review: Thermal Ecology; OPERATING EXPERIENCES: 223 Set-Point Drift in Nuclear Power-Plant Safety-Related Instrumentation Adapted by the Nuclear Safety Staff, 224 Diesel-Generator Operating Experience at Nuclear Power Plants, 227 Summary of Operating U. S. Power Reactors as of Jan. 1, 1975, 232 Selected Safety-Related Occurrences Reported in November and December 1974 Compiled by William R. Casto, 235 Recent Occurrences at Nuclear Reactors and Their Causes Compiled by William R. Casto; CURRENT EVENTS: 243 General Administrative Activities Compiled by Wm. B. Cottrell, 251 Action on Power-Reactor Projects Undergoing Regulatory Review or Consideration Compiled by Wm. B. Cottrell, 266 Action on Nonreactor Projects Undergoing Regulatory Review or Consideration Compiled by Wm. B Cottrell, 268 Proposed Rule Changes as of Jan. 1, 1975; MISCELLANY: 149 Course in Italy on High-Energy Radiation Dosimetry and Protection (Announcement), 250 Course at Northwestern on Safety of Light-Water-Cooled Nuclear Power Plants (Announcement), 266 Symposium of the Combined Effects on the Environment of Radioactive, Chemical, and Thermal Releases from the Nuclear Industry (Announcement), 271 Short Course on Engineering for Extreme Winds and Tornadoes (Announcement), 272 Three 1-Week Courses at MIT on Nuclear Power-Reactor Safety (Announcement), 272 Harvard University Short Courses (Announcement).

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Area V: Waste Management and Subsurface Science (FY21-23 Final Report)

The objective of the Waste Management and Subsurface Science Topic Area V project is to evaluate the feasibility and safety of an intermediate-depth borehole for disposal of Israel Atomic Energy Commission (IAEC) nuclear waste. The IAEC nuclear waste is currently stored in above ground and/or in near-surface facilities that provide short-term radiological worker safety but do not provide long-term, full security and safeguards protection for the nuclear material. Disposal of the IAEC nuclear waste several hundred meters below the surface in a sealed borehole would provide long-term security and safeguards due to its depth underground, as well as long-term radiological safety, due to its isolation in a stable geological formation. This project supports the nuclear security and safeguards initiatives of the Science and Technology Working Group of the NNSA/IAEC Memorandum of Understanding (MOU) and addresses the Topic Area V objective and associated goals. The goals for Topic Area V are: (1) Assess the suitability of the vadose zone in the Yamin Plain of the northern Negev Desert, Israel as a host location for intermediate-depth borehole disposal of radioactive waste, (2) Define and refine the necessary characterization needs to better understand the regional climate, structure, and stratigraphy, geomechanics, geochemistry, hydrogeology, and seismicity of the stratigraphic sequence from the surface to the water table in the vicinity of the proposed host location for the disposal borehole(s), and (3) Develop a preliminary plan and schedule, including necessary resources and costs, for a borehole disposal concept and robust and transparent pre-closure and post-closure safety assessments. The safety assessments will require iteration with process level models at both site and regional scales. Upon completion, the information collected by this effort will allow the IAEC to make decisions regarding the viability and applicability of an intermediate depth (<500m) borehole for disposal in the vadose zone of the Yamin Plain. This FY21-23 final report is provided in lieu of a workshop report that was originally planned for delivery in January, 2024. Due to the conflict in Israel and associated delays, the workshop has been delayed to April 2024. The workshop will be held at LLNL but offsite and will switch to hybrid if travel restrictions remain in place. The associated workshop report will be provided as part of a new FY24-26 LCP.

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Performance Assessment Closure Plan for the Active Low-Level Burial Ground Trenches 31, 34, and 94 at the Hanford Site

This report documents the closure plan for the active trenches within the Low-Level Burial Grounds of the Hanford Site, namely Trenches 31 and 34 in the 200 West Area and Trench 94 in 200 East Area. This closure plan is developed to meet the requirements of DOE O 435.1, Radioactive Waste Management. It is one of the several technical basis documents, along with the performance assessment (DOE/RL-2021-26, Performance Assessment of Active Trenches in 200 East and West Low-Level Burial Grounds at the Hanford Site), which is required for maintaining the Operating Disposal Authorization Statement as described in DOE-STD-5002-2017, Disposal Authorization Statement and Tank Closure Documentation.

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Cell G 7606A Mockup Measurement Analysis Methods and Results

The production of research isotopes at the Radiochemical Engineering Development Center (REDC) invariably leads to the accumulation of radioactive waste. Storage of this waste onsite at ORNL serves as an interim solution prior to shipment to long term storage facilities, however onsite capacity is limited. Proper characterization of the activity of waste products is essential for determining the appropriate waste stream and, ultimately, mitigating the cost of disposal. This is typically done via gamma spectrometry and use of the In-Situ Object Counting System (ISOCS), a software package from Mirion that serves as an accepted community standard. However, variability in the contents, density, and activity distribution in waste containers can introduce large errors in ISOCS quantification. A measurement campaign using a mockup of the proposed setup in Cell G seeks to quantify the magnitude and source of these systematic errors. Analysis of this data will guide the creation of ISOCS geometry templates and measurement methods designed to minimize overall uncertainty in reported activities.

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Equity Considerations in Siting Consolidated Interim Storage Facilities for Commercial Spent Nuclear Fuel

Questions of equity and fairness are often raised by representatives from State, Tribal and local governments and members of the public when resolving conflicts over siting of nuclear facilities. However, the two terms are not synonymous: equity can be quantified while fairness is much more subjective. The Department of Energy's (DOE) December 2021 Request for Information sought input on how to site federal facilities for the temporary, consolidated storage of spent nuclear fuel (SNF) using a consent-based approach. It is anticipated that just such questions about equity and fairness associated with the potential emergence of more than one host site may be raised by the twelve groups of university, nonprofit and private sector partners (Consortia) working to support community engagement, inclusively involve stakeholders, build relationships, and develop innovative forms of mutual learning and public capacity to participate in the consent-based siting process for a federal consolidated interim storage facility during the current Planning & Capacity Building stage of the consent-based siting process. In terms of DOE's Integrated Waste Management System (IWMS), sociopolitical equity concepts are a factor in all aspects of IWMS development and operations and will be particularly applicable should two or more host sites become a possibility, either by the emergence of multiple volunteer hosts or by pursuit as a IWMS program strategy. This paper summarizes recent analyses that explore how four equity metrics - number of states, division of the projected SNF total by the year 2083, current population and land area - might be perceived by host communities, states and regions if two, three or four sites for hosting federal consolidated interim storage facilities were to be contemporaneously realized. Existing institutional arrangements, including Nuclear Regulatory Commission regions, Federal Energy Regulatory Commission regions and Low-Level Radioactive Waste Disposal Compacts, were selected to create hypothetically merged two, three and four-region scenarios to calculate how the four metrics balance out. Projected SNF burden was prioritized with regional contiguity of the consolidated regions a requirement for a functional scenario. The intent was not to promote or suggest any construct as a program objective; the configurations are geopolitical abstractions only to explore potential perceptions of equity. Understanding the possible issues of equity that could arise may benefit program efforts toward achieving a cooperative federalism wherein both the federal and multiple State governments share the goal of manifesting more than one federal consolidated interim storage facility. The main finding is that it is not possible to optimize for all four metrics simultaneously. The analyses demonstrate that trying to create a sense of equity by backfitting a solution to a random population and land distribution will always contain a degree of artificiality.

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DECOVALEX-2023: Task F2-Salt Final Report

The subject of Task F of DECOVALEX-2023 concerns performance assessment modelling of radioactive waste disposal in deep mined repositories. The primary objectives of Task F are to build confidence in the models, methods, and software used for performance assessment (PA) of deep geologic nuclear waste repositories, and/or to bring to the fore additional research and development needed to improve PA methodologies. In Task F2-(salt), these objectives have been accomplished through staged development and comparison of the models and methods used by participating teams in their PA frameworks. Coupled-process submodels and deterministic simulations of the entire PA model for a reference scenario for waste disposal in domal salt have been conducted. The task specification has been updated continuously since the initiation of the project to reflect the staged development of the conceptual repository model and performance metrics.

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Early age hydration and application of blended magnesium potassium phosphate cements for reduced corrosion of reactive metals

Highlights: • Magnesium potassium phosphate cements were studied for nuclear waste encapsulation. • The optimised formulation in this study was determined to be 0.24 w/s ratio. • Different reaction kinetics were discovered for the FA/MKPC and BFS/MKPC binders. • Struvite-K was the only crystalline reaction product observed via in-situ SXPD. • Uranium trials revealed MKPC corrosion was reduced compared to a UK nuclear grout. Magnesium potassium phosphate cements (MKPC) were investigated to determine their efficacy towards retardation of reactive uranium metal corrosion. Optimised low-water content, fly ash (FA) and blast furnace slag (BFS) blended MKPC formulations were developed and their fluidity, hydration behaviour, strength and phase assemblage investigated. In-situ time resolved synchrotron powder X-ray diffraction was used to detail the early age (~60 h) phase assemblage development and hydration kinetics, where the inclusion of BFS was observed to delay the formation of struvite-K by ~14 h compared to FA addition (~2 h). All samples set within this period, suggesting the possible formation of a poorly crystalline binding phase prior to struvite-K crystallisation. Long-term corrosion trials using metallic uranium indicated that MKPC systems are capable of limiting uranium corrosion rates (reduced by half), when compared to a UK nuclear industry grout, which highlights their potential application radioactive waste immobilisation.

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Surveillance of Site A and Plot M Report (2019)

The environmental surveillance program discussed in this report is an ongoing activity that resulted from the 1976-1978 radiological characterization of the former site of Argonne National Laboratory and its predecessor, the University of Chicago's Metallurgical Laboratory. This site was part of the World War II Manhattan Engineer District Project and was located in a forested area southwest of Chicago, IL, owned by the Forest Preserve District of Cook County, now known as the Palos Area Preserves. Research was conducted at two locations in the Palos Area Preserves: Site A, a 19-acre area that contained experimental laboratories and nuclear reactor facilities; and Plot M, a 150 ft x 140 ft area used for the burial of radioactive waste. The location of the Palos Area Preserves is shown in Figure 2.1. The locations of Site A and Plot M are shown in Figure 2.2. Previous comprehensive reports on this subject provide additional detail and illustrations on sampling locations and provide descriptive material along with the results through 1981. Annual reports are available for 1982 through 2018. While earlier data will not be repeated in this report, reference is made to some of the results.

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Generic FEPs Catalogue and Salt Knowledge Archive

This report describes the development of a comprehensive catalogue of generic features, events, and processes (FEPs) that are potentially important for the post-closure performance of a repository for high-level radioactive waste (HLW) and spent nuclear fuel (SNF) in salt (halite) host rock. The FEPs and other supporting information have been entered into a “SaltFEP” Database. The generic salt repository FEPs include consideration of relevant FEPs from a number of U.S., Dutch, German, and international FEP lists and should be a suitable starting point for any repository program in salt host rock. The salt FEP catalogue and database employ a FEP classification matrix approach that is based on the concept that a FEP is typically a process or event acting upon or within a feature. The FEP matrix provides a two-dimensional structure consisting of a Features/Components axis that defines the “rows” and a Processes/Events axis that defines the “columns” of the matrix. The design of the FEP classification matrix is consistent with repository performance assessment – the Features/Components axis is organized vertically to generally correspond to the direction of potential radionuclide migration (from the waste to the biosphere) and the Processes/Events axis is designed to represent the common two-way couplings between thermal processes and other processes (such as thermal-mechanical or thermal-hydrologic processes). Related FEPs can be easily identified – related FEPs will typically be grouped in a single matrix cell or aligned along a common row (Feature/Component) or column (Process/Event). The online SaltFEP database can be downloaded from www.saltfep.org. It contains the FEP matrix, the FEPs, and the associated processes for each FEP. It provides a starting point to create and document site-specific individual FEPs. Furthermore, the FEP matrix is connected to the Salt Knowledge Archive (SKA), a database of about 20,000 references and documents representing the historical knowledge on radioactive disposal in salt. This work is the result of an ongoing collaboration between researchers in the U.S., the Netherlands, and Germany, and supports the NEA Salt Club Mandate. It builds upon prior work which is documented.

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FY25 Task 5: Small-Scale Mixing

The U.S. Department of Energy (DOE) Hanford Site has 177 underground storage tanks that contain a complex and diverse mix of chemical and radioactive wastes from past nuclear fuel reprocessing and waste management operations. The strategy of the DOE Hanford Field Office is to retrieve this waste, ~20 vol% of which is in the form of insoluble undissolved solids (UDS) or sludge, and treat it via immobilization at the Hanford Waste Treatment and Immobilization Plant (WTP). The diverse properties and characteristics of Hanford tank waste lead to major challenges related to its transport from the underground tanks to the WTP. These challenges, however, can be addressed by investigating the behavior of tank waste samples and simulant materials and evaluating their behavior against the capabilities of mixing and transport system designs that may be incorporated to retrieve and treat the waste.

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