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NASA NTRS1990

Actinide abundances in ordinary chondrites

Measurements of actinide and light REE (LREE) abundances and of phosphate abundances in equilibrated ordinary chondrites were obtained and were used to define the Pu abundance in the solar system and to determine the degree of variation of actinide and LREE abundances. The results were also used to compare directly the Pu/U ratio with the earlier obtained ratio determined indirectly, as (Pu/Nd)x(Nd/U), assuming that Pu behaves chemically as a LREE. The data, combined with high-accuracy isotope-dilution data from the literature, show that the degree of gram-scale variability of the Th, U, and LREE abundances for equilibrated ordinary chondrites is a factor of 2-3 for absolute abundances and up to 50 percent for relative abundances. The observed variations are interpreted as reflecting the differences in the compositions and/or proportions of solar nebula components accreted to ordinary chondrite parent bodies.

Hagee, B.↗

NASA NTRS1991

Generation of abnormal trace element abundances in Antarctic eucrites by weathering processes

Data were obtained on the trace- and major-element compositions of 16 Antarctic abnormal eucrites, many of which exhibiting positive (but sometimes negative) Ce anomalies, positive Eu anomalies, and low abundances of the remainder of the REEs. The results of data analysis suggest that the unusual REE patterns of abnormal Antarctic eucrites arise from weathering effects generated in or on the Antarctic ice. The suggested scenario involves the formation of melt water and its equilibration with the atmosphere, promoting the dissolution of REE-rich phosphates and the oxidation of Ce. As a result, tetravalent Ce is fractionated from the trivalent REE in solution.

Mittlefehldt, David W.↗

NASA NTRS1991

Compositional variations among whole-rock fragments of the L6 chondrite Bruderheim

Twenty about 100-mg random fragments of the Bruderheim chondrite were analyzed by INAA to determine extents of heterogeneity and to check earlier results that gave anomalous LREE concentrations. Considerable compositional heterogeneity was observed in both concentrations (maximum/minimum of 1.7 for Ir, 1.8 for Na, 6.8 for La, 7.4 for Co) and concentration ratios (greater than 3 x for Ni/Co and La/Eu). Compositions could be modeled quantitatively in terms of end-member components of constant composition representing the minerals olivine + orthopyroxene, clinopyroxene, plagioclase, kamacite, taenite, troilite, chromite, and phosphate. The model yields the proportions of minerals in each sample as well as the meteorite as a whole; accurate determination of the end members depends on high intrasample precision for many elements. No evidence of compositional heterogeneity of end members for trace elements was found. It is shown that these analyses, which used only about 2 grams of the meteorite, are equivalent in accuracy to a single sample of several tens of grams, and that knowledge of the extent of heterogeneity is essential to knowing the quality of sampling as well as for comparing results from one analysis with another and of one meteorite with another.

Haas, Johnson R.↗

NASA NTRS1991

Nonlinear optical properties of organic materials: A theoretical study

Replacement of electronic switching circuits in computing and telecommunication systems with purely optical devices offers the potential for extremely high throughput and compact information processing systems. The potential application of organic materials containing molecules with large nonresonant nonlinear effects in this area have triggered intensive research during the last decade. Interest on this area was due to two facts: (1) that many organic materials show nonlinearities that are orders of magnitude larger than those of conventional inorganic materials such as lithium niobate and potassium dihydrogen phosphate; and (2) that organic materials show much flexibility in terms of molecular designs. Some of the desirable characteristics that these materials should have are that they be transparent to the frequency of the incident laser and its second or third harmonic, that they have a high damage threshold, and, in the case of second-order effects, that their crystal structure or molecular orientation be accentric. Since polymeric assemblages can enhance the nonlinear response of organic molecules severalfold, efforts have been directed toward the synthesis of thin films with interpenetrating lattices of electroactive molecules. The goal of this theoretical investigation is to predict the magnitude of the molecular polarizabilities of organic molecules that could be incorporated into films. These calculations are intended to become a powerful tool to assist material scientists in screening for the best candidates for optical applications. The procedure that was developed for the present calculations is based on the static-field approach, and is a modification to the method developed by Dewar and Stewart, 1984 for calculating molecular linear polarizabilities.

Cardelino, Beatriz H.↗

NASA NTRS1992

Space sickness predictors suggest fluid shift involvement and possible countermeasures

Preflight data from 64 first time Shuttle crew members were examined retrospectively to predict space sickness severity (NONE, MILD, MODERATE, or SEVERE) by discriminant analysis. From 9 input variables relating to fluid, electrolyte, and cardiovascular status, 8 variables were chosen by discriminant analysis that correctly predicted space sickness severity with 59 pct. success by one method of cross validation on the original sample and 67 pct. by another method. The 8 variables in order of their importance for predicting space sickness severity are sitting systolic blood pressure, serum uric acid, calculated blood volume, serum phosphate, urine osmolality, environmental temperature at the launch site, red cell count, and serum chloride. These results suggest the presence of predisposing physiologic factors to space sickness that implicate a fluid shift etiology. Addition of a 10th input variable, hours spent in the Weightless Environment Training Facility (WETF), improved the prediction of space sickness severity to 66 pct. success by the first method of cross validation on the original sample and to 71 pct. by the second method. The data suggest that WETF training may reduce space sickness severity.

Simanonok, K. E.↗

NASA NTRS1992

Results of the TTF-TCNQ and the calcium carbonate crystallization on the Long Duration Exposure Facility

Experiment A0139A on the Long Duration Exposure Facility (LDEF) carried four large containers into orbit five years with crystal growth solutions for lead sulfide, calcium carbonate, and TTF-TCNQ. Although temperature data was lost, the experimental program had been working since the valves in all containers had been opened. All four experiments produced crystals of varying quality. The calcium carbonate crystals had the best appearance. The TTF-TCNQ crystals were packed together near the valve openings of the container. When taken apart, the single crystals showed some unusual morphological properties. X ray investigations as well as conductivity measurements on long duration space grown TTF-TCNQ crystals will be presented. Comparisons will be made with our previous space solution growth experiments. The TTF-TCNQ crystals are no longer of the highest interest, so this activity has been terminated in favor of calcium carbonate and calcium phosphate crystallizations.

Nielsen, Kjeld Flemming↗

NASA NTRS1992

Follow up on the crystal growth experiments of the LDEF

The 4 solution growth experiments on the LDEF were presented thoroughly elsewhere. The CaCO3-experiment, and to a certain extent also the TTF-TCNQ-experiments yielded useful results. In Jan. 1992, the next series of solution growth experiments were sent to ESA for shipment to KSC. As on the LDEF, the SGF (solution growth facility) of the EURECA-1 contains 4 large experiments. From the beginning, the planning and developments were introduced. Still, the basic concept was maintained, and the CaCO3-experiment, that showed the best results on the LDEF, will now be repeated with improved technology and in larger scale on the EURECA-1. The contents of the 4 SGF experiments are as follows: (1) growth of calcium-carbonate crystals; (2) formation and transformation of tri-calcium-phosphate; (3) growth of zeolite crystals; and (4) soret coefficient measurements (diffusion). The scientific background for the choice of experiments and the major improvements of the SGF are reviewed. Furthermore, some ideas on basic microgravity solution growth experimentation from ESA's newly established EWG (Expert Working Group) on solution growth are reported.

Nielsen, K. F.↗

NASA NTRS1991

The cyclization of arabinosyladenine-5-prime-phosphorimidazolide

When arabinosyladenine-5-prime-phosphorimidazolide is allowed to decompose in aqueous solution at room temperature and pH 7.2, depending on the buffer, 5-24 percent is converted to the 2-prime,5-prime-cyclic phosphate (V). Although the extent of cyclization is much greater than for adenosine-5-prime-phosphorimidazolide, cyclization is less efficient than hydrolysis and so would not substantially decrease the efficiency of condensation reactions in aqueous solution. The significance of this result for prebiotic chemistry is discussed.

Harada, Kazuo↗

NASA NTRS1992

Effect of surface condition on the formation of solid lubricating films at high temperatures

Solid films were produced on active metal or ceramic surfaces using lubricants (such as tricresyl phosphate) delivered as a vapor at high temperatures, and the lubricity of these deposits under different dynamic wear conditions was investigated. A method is described for chemically activating ceramic surfaces resulting in a surface that could promote the formation of lubricating polymeric derivative of TCP. Experiments were carried out to evaluate the wear characteristics of unlubricated cast iron and of Sialon ceramic at 25 and 280 C, and lubricated with a vapor of TCP at 280 C. It is shown that continuous vapor phase lubrication of chemically treated Sialon reduced its coefficient of friction from 0.7 to less than 0.1.

Hanyaloglu, Bengi↗

NASA NTRS1988

Hematology and biochemical findings of Spacelab 1 flight

The changes in erythropoiesis in astronauts caused by weightlessness was experimentally studied during the Spacelab 1 flight. Immediately after landing showed a mean decrease of 9,3 percent in the four astronauts. Neither hyperoxia nor an increase in blood phosphate caused the decrease. Red cell survival time and iron incorporation postflight were not significantly different from their preflight levels. Serum haptoglobin did not decrease, indicating that intravascular hemolysis was not a major cause of red cell mass change. An increase in serum ferritin after the second day of flight may have been caused by red cell breakdown early in flight. The space flight-induced decrease in red cell mass may result from a failure of erythropoesis to replace cells destroyed by the spleen soon after weightlessness is attained.

Leach, Carolyn S.↗

NASA NTRS1992

Analyses of plasma for metabolic and hormonal changes in rats flown aboard Cosmos 2044

Plasmas samples from rats flown aboard Cosmos 2044 were analyzed for the levels of key metabolites, electrolytes, enzymes, and hormones. The major differences between the flight group and the synchronous control were elevations in glucose, cholesterol, phosphate, creatinine, blood urea nitrogen, lactate dehydrogenase, and aspartate aminotransferase and decreased levels of thyroxine. Most of these differences were not mimicked by tail suspension of ground-based rats; however, both flight and suspended rats exhibited inhibited testosterone secretion. Corticosterone, immunoreactive growth hormone, and prolactin showed inconsistent differences from the various control groups, suggesting that the levels of these hormones were not due to actual or simulated microgravity.

Merrill, Alfred H., Jr.↗

NASA NTRS1993

Imide/Arylene Ether Copolymers Containing Phosphine Oxide

Phosphine oxide groups react with oxygen to form protective phosphate surface layers. Series of imide/arylene ether block copolymers containing phosphine oxide units in backbone synthesized and characterized. In comparison with commercial polyimide, these copolymers display better resistance to etching by oxygen plasma. Tensile strengths and tensile moduli greater than those of polyarylene ether homopolymer. Combination of properties makes copolymers attractive for films, coatings, adhesives, and composite matrices where resistance to atomic oxygen needed.

Jensen, Brian J.↗

NASA NTRS1992

Development of a stable electro-optical modulator

The activity of the sun can be studied through the measurement of its magnetic field. The measurement of the polarization state of the sunlight in a narrow spectral bandwidth can be related to the magnetic fields strengths and directions over the active sunspots. Measuring the polarization state can be done using the vector magnetograph. The essential component of the vector magnetograph is the polarization modulators. Electro-optical modulators are used as dynamic retarders. KDP (potassium dideuterium phosphate) crystals provide variable retardation which can be controlled by the applied voltage. KDP's have a high contrast ratio but suffer some problems; they require a high voltage and have a limited modulation lifetime. The KDP modulator forms the heart of the polarimeter assembly which is used for carrying out accurate measurements of linear polarization of the sun. It is therefore important to study the optical and electrical behavior of the KDP crystals so that the ultimate goal of making stable electro-optical modulators in the laboratory is achieved. A number of activities were performed in coating and testing the KDP crystals. A summary of these activities is given.

Abushagur, Mustafa A. G.↗

NASA NTRS1992

Slow-release fertilizer

A synthetic apatite containing agronutrients and a method for making the apatite are disclosed. The apatite comprises crystalline calcium phosphate having agronutrients dispersed in the crystalline structure. The agronutrients can comprise potassium, magnesium, sulfur, iron, manganese, molybdenum, chlorine, boron, copper and zinc in amounts suited for plant growth. The apatite can optionally comprise a carbonate and/or silicon solubility control agent. The agronutrients are released slowly as the apatite dissolves.

Ming, Douglas W.↗

NASA NTRS1992

Characterization of the Water Soluble Component of Inedible Residue from Candidate CELSS Crops

Recycling of inorganic nutrients required for plant growth will be a necessary component of a fully closed, bioregenerative life support system. This research characterized the recovery of plant nutrients from the inedible fraction of three crop types (wheat, potato, and soybean) by soaking, or leaching, in water. A considerable portion of the dry weight of the inedible biomass was readily soluble (29 percent for soybean, 43 percent for wheat, and 52 percent for potato). Greater weight loss from potato was a result of higher tissue concentrations of potassium, nitrate, and phosphate. Approximately 25 percent of the organic content of the biomass was water soluble, while the majority of most inorganic nutrients, except for calcium and iron, were recovered in the leachate. Direct use of the leachates in hydroponic media could provide between 40-90 percent of plant nutrient demands for wheat, and 20-50 percent of demand for soybean and potato. Further evaluation of leaching as a component of resource recovery scheme in a bioregenerative system requires study of (1) utilization of plant leachates in hydroponic plant culture; and (2) conversion of organic material (both soluble and insoluble) into edible, or other useful, products.

Garland, Jay↗

NASA NTRS1992

Geochemistry and petrology of primitive achondrite meteorites LEW 88280, MAC 88177, ALHA 81187, EET 84302, and LEW 88663

Primitive achondrites are meteorites that have mineral and bulk chemical compositions similar to the most primitive meteorites (chondrites) but have textures similar to more evolved meteorites (achondrites). The unique geochemistry and texture of the primitive achondrites suggest these meteorites may be genetic intermediates between chondrites and achondrites and may preserve evidence of processes occurring in the early solar system. Five primitive achondrites LEW 88280, MAC 88177, ALHA 81187, EET 84302, and LEW 88663 were examined in this study in order to classify the meteorites and to determine processes that have affected them. Bulk chemical analyses of Nap, K2O, CaO, FeO, Cr, Co, Ni, Sc, Ir, Au, As, Sb, Se, Br, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, and Lu were determined for each meteorite by Instrumental Neutron Activation Analysis (INAA). Concentrations of Hf, U, and Th were determined for some meteorites. Polished thin sections of the five meteorites were examined in transmitted and reflected light microscopy to identify minerals and examine petrographic relationships. Minerals found in the meteorites include olivine, orthopyroxene, clinopyroxene, plagioclase, Cr-spinel, phosphates, troilite, kamecite, and taenite along with other minor phases. Mineral compositions were determined with an electron microprobe. The initial study suggests that the meteorites have been altered by metamorphic processes although igneous processes may also have played a role in the evolution of these rocks. Further studies of isotope and bulk chemistry are planned for these meteorites.

Field, Stephen W.↗

NASA NTRS1992

The role of pyridoxine as a countermeasure for in-flight loss of lean body mass

Ground based and in flight research has shown that humans, under conditions of microgravity, sustain a loss of lean body tissue (protein) and changes in several biological processes including, reductions in red blood cell mass, and neurotransmitters. The maintenance of muscle mass, the major component of lean body mass, is required to meet the needs of space station EVAs. Central to the biosynthesis of amino acids, the building blocks of protein, is pyridoxine (vitamin B-6). Muscle mass integrity requires the availability of vitamin B-6 for protein metabolism and neurotransmitter synthesis. Furthermore, the formation of red blood cells require pyridoxine as a cofactor in the biosynthesis of hemoglobin, a protein that carries oxygen to tissues. In its active form, pyridoxal-5'-phosphate (PLP), vitamin B-6 serves as a link between amino acid and carbohydrate metabolism through intermediates of glycolysis and the tricarboxylic acid cycle. In addition to its role in energy metabolism, PLP is involved in the biosynthesis of hemoglobin and neurotransmitter which are necessary for neurological functions. Alterations in pyridoxine metabolism may affect countermeasures designed to overcome some of these biochemical changes. The focus of this research is to determine the effects of microgravity on the metabolic utilization of vitamin B-6, integrating nutrition as an integral component of the countermeasure (exercise) to maintain lean body mass and muscle strength. The objectives are: 1) to determine whether microgravity effects the metabolic utilization of pyridoxine and 2) to quantitate changes in B-6 vitamer distribution in tissue and excreta relative to loss of lean body tissue. The rationale for this study encompasses the unique challenge to control biochemical mechanisms effected during space travel and the significance of pyridoxine to maintain and counter muscle integrity for EVA activities. This experiment will begin to elucidate the importance of biochemical interactions between micronutrients and the homeostasis condition of biological processes in the space environment. To address this research topic a simulated microgravity model has been developed. The experiment uses radioisotopically labelled pyridoxine administered as an oral dose to rats which are maintained by tail suspension to simulate a microgravity environment. At the termination of the study, liver, muscle, blood and urine are collected and analyzed by reverse phase high pressure liquid chromatography to determine the quantity and distribution of the B-6 vitamers in tissue and excreta relative to lean body tissue loss. Earlier studies, published by this investigator, have shown that differences in vitamer distribution among samples from experimental versus control subjects indicate changes in metabolic utilization and storage of vitamin B-6.

Gilbert, Joyce A.↗

NASA NTRS1992

TREK - A cosmic-ray experiment on the Russian space station Mir

The goals of the TREK experiment, now in place on the Mir space station, are to resolve and measure the composition of both odd-Z and even-Z cosmic-ray nuclei up to uranium, to measure the isotopic composition of Fe-group nuclei, and to search for transuranic nuclei and exotic particles such as strangelets. To collect tracks of ultraheavy cosmic rays, exterior panels holding an array of BP-1 phosphate glass 1.2 sq m in area and 16 plates thick are now mounted outside the Kvant-2 module on Mir. Heaters and relays regulate the temperature of the glass at 25 +/- 5 C. The detectors will record about 1000 cosmic-ray tracks with Z greater than or equal to 50 during about 2.5 years. An interior panel consisting of an array 0.09 sq m in area and 32 plates thick and mounted on the inside wall of the Soyuz spacecraft will collect tracks of about 13,000 Fe and 500 Ni nuclei.

Price, P. B.↗