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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26

Simulation of Impedance Changes with Aging in Lithium Titanate-based Cells Using Physics-Based Dimensionless Modeling

Quantifying aging effects in lithium-ion cells with chemistries that have a flat open circuit potential is challenging. We implement a physics-based electrochemical model to track changes in the electrochemical impedance response of lithium titanate-based cells. Frequency domain equations of a pseudo two-dimensional model are made dimensionless, and the corresponding non-dimensional parameters are estimated using a Levenberg-Marquardt routine. The model weighs the relative contributions of changes in diffusion, ionic conduction within the electrolyte phase against solid phase electronic conduction towards cell aging. Solid-phase diffusion, charge transfer resistance and double layer capacitance at the solid-liquid interface are accounted for in the particle impedance. The estimation routine tracks dimensionless parameters using accelerated cycling data from full cells over 1000 cycles. The model can be deployed within a short time for state estimation using physics-based models without requiring prior knowledge of the battery chemistry, format, or capacity.

25 ENERGY STORAGE↗

Design and Implementation of a 1-3 MW th sCO 2 Support Loop for Gen3 CSP Primary Heat Exchangers

The generation 3 concentrating solar power, or Gen3CSP, campaign seeks to de-risk and deploy a CSP pilot plant through three parallel project tracks focused on solid, liquid, and gas-phase primary heat transfer fluids. Although the components between the sun and the primary heat exchanger from the thermal storage system differ with each track, the supercritical carbon dioxide (sCO 2 ) coolant system required to cool the primary heat exchanger in place of a complete power conversion system has very similar requirements regardless of the primary heat transfer fluid. In order to avoid duplicative efforts, this project will design, assemble, perform acceptance testing, and deploy a single sCO 2 coolant system design meeting the needs of any Gen3CSP topic 1 pathway pilot plant design.

14 SOLAR ENERGY↗

A Solar Fuels Nexus: Molecules and Materials for Light-Driven Catalysis

The American Chemical Society (ACS) selects two groups of graduate students each year to plan and host a one-day symposium at each national meeting (both fall and spring).This year our Graduate Student Symposium Planning Committee (GSSPC), composed of seven students from four universities, proposal entitled “A Solar Fuels Nexus: Molecules and Materials for Light-Driven Catalysis” was selected for the “Crossroads in Chemistry” ACS Meeting that will take place March 23-26, 2023 in Indianapolis, IN. All members of our GSSPC are affiliated with the DOE Fuels from Sunlight Energy Innovation Hub, with two from the Liquid Sunlight Alliance (LiSA) and five from the Center for Hybrid Approaches in Solar Energy to Liquid Fuels (CHASE). Here we request funds to support this symposium. This symposium will highlight research progress and perspectives in the solar fuels generation field and seeks to advance the four priority research objectives (PROs) established by the Department of Energy’s Office of Basic Energy Sciences (DOE-BES) Roundtable Report that are also central to many research goals within LiSA and CHASE. The symposium will consist of research presentations from 10 invited senior researcher speakers on topics such as molecular catalyst design, computational modeling of electron transfer systems, microenvironmental effects on CO2 reduction and H2O oxidation catalysis, and intelligent design of semiconductor interfaces with ample time for discussions. These research topics fit very well with the Solar Photochemistry supported research areas of “light-driven electron and energy transfer in condensed phase and interfacial molecular systems,” “electrocatalysis and photocatalysis of solar fuels reactions,” and “semiconductor photoelectrochemistry.” More broadly, this symposium seeks to advance the DOE-BES’s mission to: “support fundamental research to understand, predict, and ultimately control matter and energy at the level of electrons, atoms, and molecules” by providing a diverse atmosphere where such research will be disseminated, discussed, and debated. There will be a strong focus on Diversity, Equity, and Inclusivity (DEI) in our symposium. Of our 10 speakers, 7 will be from underrepresented demographics in STEM, including 5 who identify as women. Furthermore, we have representatives from academia accompanied by one national lab scientist and one officer from the Office of Fossil Energy and Carbon Management at the DOE. All speakers will be holding a short DEI moment ahead of their talks. In order to support the career development of attending early career scientists, we will also be hosting a luncheon specifically for graduate students and postdocs to provide them opportunities to network with the distinguished speakers and other attendees. DOE funds for this symposium will be used to support the attendance and participation of 15 graduate students from US institutions by defraying travel and registration costs. These funds will promote engagement and conversation between early career scientists in the solar fuels field, while disseminating solar fuels research funded by and relevant to the DOE.

30 DIRECT ENERGY CONVERSION↗

OH density and water vapor concentration gradients during plasma-droplet interactions

Plasma-droplet interactions significantly promote the reactivity transfer of gas phase species from the plasma to the liquid phase. Nonetheless, experimental studies on the impact of droplet evaporation on reactive species generation in such systems remain scarce. We report the spatial distribution of water vapor and OH radical densities around a droplet (∼41 μm in diameter) in He and He-Ar plasma using laser-induced fluorescence. The results reveal a significant gradient in both water vapor and OH radical concentrations near the droplets. Mutiple droplets present in the plasma can lead to a significant accumulation of water vapor and even local quenching of the discharge. The findings are critical for developing a quantitative understanding of plasma-liquid interactions for a broad range of plasma-enabled applications in the liquid phase often involving OH radicals.

42 ENGINEERING↗

Space shuttle: Heat transfer rate measurements of North American Rockwell orbiter (161B) at nominal Mach number of 8

Plots and tables which determine detailed heat transfer distributions on phase B space shuttle configurations are presented. A thin-skinned thermocouple was used to measure the reentry events of the delta wing orbiter. Data was obtained at a nominal Mach number of 8 and free stream Reynolds numbers ranging from 0.83 x 10 to the 6th power to 3.76 x 10 to the 6th power per foot. Angle of attack was varied from -5 to 50 degrees.

Warmbrod, J. D.↗

Heating and flow-field studies on a straight-wing hypersonic reentry vehicle at angles of attack from 20 to 80 deg with simulation of real-gas trends

Data are presented from a series of phase-change heat transfer and flow visualization tests at Mach 7.4, 8, and 10.3 in air, Mach 19.5 in nitrogen, Mach 20.3 in helium, and Mach 6 in tetrafluoromethane (CF4) on the windward surface of a straight wing hypersonic reentry configuration for angles of attack from 20 deg to 80 deg. The results indicate that: (1) for hypersonic stream Mach numbers, the flow field over the straight-wing configuration is essentially independent of Mach number, (2) transition Reynolds number decreases with increasing angle of attack, (3) at some critical angle of attack, the wing-shock standoff distance is greatly increased and the stagnation line moves downstream from the wing leading edge, (4) value of the critical angle of attack is very sensitive to the flow shock density ratio or effective gamma, and (5) at angles of attack above the critical value for all gases, the nondimensional level of heat transfer to the wing is higher for the higher shock density ratio flows.

Hunt, J. L.↗

Influence of mechanical properties on the combustion of propellants

Experimental study of the effects of minor compositional variables upon the combustion behavior of composite solid propellants. More specifically, it was attempted to determine the influence of ingredients that improve the mechanical properties upon the oscillatory combustion characteristics. Tests were carried out in the familiar Crawford bomb, a low-pressure L-star burner, and a high-pressure T-burner. Two families of propellants were investigated; each family consists of two propellants with a minor compositional variation between them. In the family that shows a decreasing (steady state) pressure index (n) with increasing pressures, all of the combustion characteristics are found to be very similar although the mechanical properties are widely different. In the other family, which shows an increasing n with increasing pressures, unmistakable differences are found between the two propellants in the low-pressure L-star instability behavior (along with the differences in the mechanical properties), while the other combustion characteristics are almost identical. The results are interpreted to be consistent with a theory that highlights the importance of condensed phase heat-transfer effects.

Kumar, R. N.↗

Effects of tidal distortion on binary-star velocity curves and ellipsoidal variation

Radial velocity curves for the more massive components of binaries with extreme mass ratios can show a large distortion due to tides, as first recognized by Sterne. Binaries in which the effect is large should be rare because nearly all such binaries would be in the rapid phase of mass transfer. However, the optical counterparts of some X-ray binaries may show the effect, which would then serve as a new means of extracting considerable information from the observations. The essential parts of the computational procedure are given. Light curves for ellipsoidal variables with extreme mass ratios were also computed, and were found to be less sinusoidal than those with normal mass ratios.

Wilson, R. E.↗

Combustor fluctuating pressure measurements in-engine and in a component test facility - A preliminary comparison

Combustor internal fluctuating pressure and far-field noise generated in a YF-102 turbofan engine are investigated; combustor internal measurements are also made in a duct-component test facility operating over a range of conditions encompassing those characteristic of the aircraft engine. Although directly measured spectra for the engine and the duct-component test facility show discrepancies, the results of coherence function, transfer function and phase relationship comparisons suggest that the internal dynamics of the combustor as an acoustic source may be preserved in a component test facility.

Reshotko, M.↗

A note on the statistics of early-type close binaries

A degree of contact index (I sub c) is defined, and its frequency diagram is given for 16 early-type close binaries. The objective is to determine whether the numbers of such systems are continuous or discontinuous across marginal contact. Data for four of the systems (TU Mus, V499 Sco, Delta Pic, and SZ Cam) derive from new photometric analyses, the results of which are also given. Present results indicate that there is continuity in frequency across marginal contact, although it would be desirable to include more binaries as further observations become available. It is noted that the only two systems in the bin of largest I sub c are known to be in the rapid phase of mass transfer.

Wilson, R. E.↗

Effects of a rough boundary surface on polarization of the scattered field from an inhomogeneous medium

A combination of the standard Kirchhoff method for rough surface scattering with the Rayleigh phase function radiative transfer method for volume scattering is employed in the present study of the effect of surface roughness on the polarization of the scattered field. It is found that for pure surface scattering, the polarization ratio between zero and 20 deg incidence angles is sensitive to surface roughness change. When both surface and volume scattering are present, however, copolarization nulls by colatitude or degree of polarization at zero to 15 deg incidence angle, and copolarization or crosspolarization nulls by longitude at large incidence angles, are better indicators of surface roughness changes. It is noted that degree of polarization and copolarization nulls by colatitude vary monotonously with incidence angle, while in combined surface and volume scattering these have, respectively, a minimum and a maximum. This characteristic allows the separation of combined surface and volume scattering from pure surface or volume scattering.

Fung, A. K.↗

Space station propulsion requirements study

Propulsion system requirements to support Low Earth Orbit (LEO) manned space station development and evolution over a wide range of potential capabilities and for a variety of STS servicing and space station operating strategies are described. The term space station and the overall space station configuration refers, for the purpose of this report, to a group of potential LEO spacecraft that support the overall space station mission. The group consisted of the central space station at 28.5 deg or 90 deg inclinations, unmanned free-flying spacecraft that are both tethered and untethered, a short-range servicing vehicle, and a longer range servicing vehicle capable of GEO payload transfer. The time phasing for preferred propulsion technology approaches is also investigated, as well as the high-leverage, state-of-the-art advancements needed, and the qualitative and quantitative benefits of these advancements on STS/space station operations. The time frame of propulsion technologies applicable to this study is the early 1990's to approximately the year 2000.

Wilkinson, C. L.↗

Orbital transfer vehicle concept definition and system analysis study. Volume 1A: Executive summary. Phase 2

The objectives of the Phase 2 study were to improve the orbit transfer vehicle (OTV) concept definition by focusing on the following issues: the impact of mission requirements on OTV system design; OTV basing concepts on the Space Shuttle, separate platforms, and/or remote locations; cost reduction of an OTV program to improve its economic benefits and support its acquisition. The OTV mission scenario includes a wide range of missions the main drivers of which are manned GEO servicing, mid-inclination/polar DOD, and lunar/planetary projects. A mission model is presented which includes the type and number of missions per year and the estimated propellant requirements. To accomplish the missions, many OTV concepts were defined including ground-based OTVs launched either in the STS orbiter, the aft cargo carrier, or a heavy lift launch vehicle, and a space-based OTV. System and program trade studies were conducted using performance, cost, safety/risk, and operations/growth criteria. The study shows that mission requirements and substantial economic benefits justify a reusable, cryogenic (H2/O2) space-based OTV. Such a system would not be subjected to Earth-to-orbit launch loads and would not be constained in size or weight. Safety is enhanced by the fact that the system components are launched unfueled. Its inherent reusability and ability to be refueled in space make the space-based OTV very economical to operate.

Ketchum, W. J.↗

System technology analysis of aeroassisted orbital transfer vehicles: Moderate lift/drag (0.75-1.5). Volume 3: Cost estimates and work breakdown structure/dictionary, phase 1 and 2

Technology payoffs of representative ground based (Phase 1) and space based (Phase 2) mid lift/drag ratio aeroassisted orbit transfer vehicles (AOTV) were assessed and prioritized. A narrative summary of the cost estimates and work breakdown structure/dictionary for both study phases is presented. Costs were estimated using the Grumman Space Programs Algorithm for Cost Estimating (SPACE) computer program and results are given for four AOTV configurations. The work breakdown structure follows the standard of the joint government/industry Space Systems Cost Analysis Group (SSCAG). A table is provided which shows cost estimates for each work breakdown structure element.

Source record↗

Single Electrode Would Control Charge-Coupled Device

Space saved and interelectrode short circuits eliminated. Proposed virtual-phase, interline-transfer, charge-couple device uses single gate electrode to control both interline and intraline transfer of charge. Voltage on single control electrode varied to transfer charge from photosites to shift register, or else along sift register. Two kinds of transfer independent of each other. Charge transferred along shift register when voltage on control electrode alternated between gate potentials.

Wadsworth, Mark↗

Gas dynamics, accretion, and evolution of Algols: Initial results for three representative systems

IUE (International Ultraviolet Explorer) observations were made around the orbits of three Algol-type binaries: R Arae, U Cephei and Algol. These stars were selected to represent, respectively, the rapid, moderate and slow phases of mass transfer and mass loss in Algols. The data was obtained to derive maps of gas flow and mass loss, to study accretion processes and kinetic heating, and to investigate the importance of magnetic fields in these systems. Continuous observations were made from GSFC and VILSPA over 4 1/3 consecutive days during 10 to 14 Sep. 1989. A total of 100 spectra are obtained. This is the first time that Algol systems are observed continuously over their orbits with IUE. Initial results from this program are discussed.

Gimenez, A.↗

Microgravity fluid physics research in the Space Station Freedom era

Microgravity fluid physics covers an exciting range of established and potential fields of scientific research. Areas in which the Microgravity Science and Applications Division of NASA's Office of Space Science and Applications is currently supporting research include: multiphase flow and phase change heat transfer, behavior of granular media and colloids; and interface dynamics, morphological stability, and contact line phenomena. As they contribute to our knowledge of fluid behavior, advances in these areas will enhance our understanding of materials processing on Earth and in space, and will contribute to technologies as diverse as chemical extraction, the prediction of soil behavior in earthquakes, and the production of oil reservoirs. NASA' s primary platform for research in microgravity fluid physics will soon be the Fluid Physics/Dynamics Facility on Space Station Freedom. This facility shares a rack for control and utilities with the Modular Combustion Facility, and has one rack for experiment-unique instruments. It is planned to change out the content of the experiment-unique rack at intervals on the order of one year. In order to obtain a maximum return on the operation of the facility during these intervals, the research community must carefully plan and coordinate an effort that brings the efforts of many investigators to bear on problems of particular importance. NASA is currently working with the community to identify research areas in which microgravity can make a unique and valuable contribution, and to build a balanced program of research around these areas or thrusts. Selections will soon be made from our first solicitation for research in fluid dynamics and transport phenomena. These solicitations will build the research community that will make Space Station Freedom a catalyst for scientific and technological discovery, and offer U.S. scientists in many disciplines a unique opportunity to participate in space science.

Carpenter, Bradley M.↗