Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “particle improvement”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Searches for New Long-Lived Particles and Upgrade to the ATLAS Inner Detector (Final Technical Report)

The search for new fundamental particles is one of the defining goals of the Large Hadron Collider (LHC). The discovery of the Higgs Boson by the ATLAS and CMS collaborations provided the capstone of the Standard Model of particle physics, but outstanding questions remain. Why does the Higgs boson have a mass of 125 GeV when its natural mass would be many orders of magnitude larger? Is there a universal symmetry which unites all three forces described by the Standard Model? Can that symmetry be extended to include gravity? Is dark matter, evidenced by astronomical observations, made of a particle that interacts via Standard Model forces with the rest of matter? Together, these motivations provide compelling arguments that new physical processes await discovery. This project addressed some outstanding questions about the fundamental particles and their interactions with the ATLAS experiment at the Large Hadron Collider. In particular, the project improved the discovery potential for new, long- lived particles produced via electroweak processes in proton-proton collisions and set world-leading limits on their existence for certain values of their potential mass and lifetime. To achieve this, the project developed new data analysis methods, developed new triggers to select events with new long-lived particles during data-taking of the ATLAS experiment, and analyzed the largest proton–proton collision dataset ever produced. The project also supported significant development of the data acquisition software for the upgrade to the ATLAS inner detector, the Inner TracKer (ITk). The upgrade of the ATLAS inner detector is essential to the success of the entire Phase II physics program on ATLAS. Personnel supported by the project provided support for integration, assembly, and testing of the inner two layers of the ITk pixel system during its prototype and pre-production phase. Four PhD students and two post-doctoral scholars were supported by the grant and received invaluable scientific training as part of the research endeavor. The students and postdocs gained essential professional skills in the areas of advanced data analysis techniques, statistical analysis of data and simulation, programming in C++ and Python, hardware and instrumentation development, and presentation and collaboration skills. Additionally, approximately ten undergraduate students supported through other funding sources participated in research activities synergistic with the goals of this project, receiving essential mentorship from the personnel supported by this project.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Role of Fluorine in Chemomechanics of Cation-Disordered Rocksalt Cathodes

The role of nanoscale chemomechanical behavior in the macroscopic performance of functional materials is well recognized. For lithium-ion battery cathodes, tremendous effort has been devoted to the development of new chemistry and structure, yet fundamental understanding of the correlation between redox processes and mechanical properties of the novel materials lags behind. In the present study, we prepare large discrete single grains of Li-excess cation-disordered rocksalts (DRX) and investigate their chemomechanical behavior at the particle level, using nanoresolution X-ray and electron-based spectro-imaging and chemical mapping techniques. While irregular cracking upon lithium extraction leads to the eventual breakdown of the baseline DRX oxide (Li 1.2 Ti 0.4 Mn 0.4 O 2 ) particles at a high delithiation state, the fluorinated-DRX (Li 1.3 Ti 0.3 Mn 0.4 O 1.7 F 0.3 ) clearly displays aligned cracking along the <001> direction. The resulting periodicity in the cracking pattern enables the particles to retain their integrity and, consequently, improved electrochemical stability. Density functional theory (DFT) calculations showed that fluorination leads to increased concentration of Li+ on the (001) planes and preferential Li movements along the <001>-family directions, revealing the underlying mechanism for directional cracking. Overall, our study demonstrates the unique role of fluorine in modulating nanoscale chemomechanics, which in turn influences the evolution of charge and strain heterogeneity at the particle level. These insights provide important design guidelines in further improving DRX cathode materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2019

Analysis of the Global Microwave Polarization Data of Clouds

Information about the characteristics of ice particles in clouds is necessary for improving our understanding of the states, processes, and subsequent modeling of clouds and precipitation for numerical weather prediction and climate analysis. Two NASA passive microwave radiometers, the satellite-borne Global Precipitation Measurement (GPM) Microwave Imager (GMI) and the aircraft-borne Conical Scanning Millimeter-Wave Imaging Radiometer (CoSMIR), measure vertically and horizontally polarized microwaves emitted by clouds (including precipitating particles) and Earth’s surface below. In this paper, GMI (or CoSMIR) data are analyzed with CloudSat (or aircraft-borne radar) data to find polarized difference (PD) signals not affected by the surface, thereby obtaining the information on ice particles. Statistical analysis of 4 years of GMI and CloudSat data, for the first time, reveals that optically thick clouds contribute positively to GMI PD at 166GHz over all the latitudes and their positive magnitude of 166-GHz GMI PD varies little with latitude. This result suggests that horizontally oriented ice crystals in thick clouds are common from the tropics to high latitudes, which contrasts the result of Cloud–Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) that horizontally oriented ice crystals are rare in optically thin ice clouds.

Xiping Zeng↗
DOE OSTI2023

Forward Pixel Detector for the Phase 2 Upgrade of CMS And Module Testing at UIC

High-Luminosity Large Hadron Collider (HL-LHC) upgrade aims to increase performance. In order to efficiently handle the larger particle flux and increased radiation, an upgrade is planned for the inner Tracker of the Compact Muon Solenoid (CMS) detector, which is located at the innermost part of the CMS. To efficiently reconstruct and track particles, the existing pixel tracker will be upgraded with novel sensors, readout chips, and front-end electronics designed to handle increased data rates. These improvements will allow the detector to track particles more precisely. In the United States, we are working on assembling new sensor modules to be inserted into disks, referred to as TFPX, for installation in the CMS detector for the HL-LHC era. We are currently testing the prototype of TFPX modules to ensure the upgrade is carried out in the best way possible. The University of Ilinois Chicago has been tasked with testing the final versions of the TFPX sensor modules before they are sent to CERN to be installed into the CMS detector. This work is supported by NSF.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2003

Shields for Enhanced Protection Against High-Speed Debris

A report describes improvements over the conventional Whipple shield (two thin, spaced aluminum walls) for protecting spacecraft against high-speed impacts of orbiting debris. The debris in question arise mainly from breakup of older spacecraft. The improved shields include exterior bumper layers composed of hybrid fabrics woven from combinations of ceramic fibers and high-density metallic wires or, alternatively, completely metallic outer layers composed of high-strength steel or copper wires. These shields are designed to be light in weight, yet capable of protecting against orbital debris with mass densities up to about 9 g/cm3, without generating damaging secondary debris particles. As yet another design option, improved shields can include sparsely distributed wires made of shape-memory metals that can be thermally activated from compact storage containers to form shields of predetermined shape upon arrival in orbit. The improved shields could also be used to augment shields installed previously.

Christiansen, Eric L.↗
NASA NTRS1995

Viking Lander image analysis of Martian atmospheric dust

We have reanalyzed three sets of Viking Lander 1 and 2 (VL1 and VL2) images of the Martian atmosphere to better evaluate the radiative properties of the atmospheric dust particles. The properties of interest are the first two moments of the size distribution, the single-scattering albedo, the dust single-scattering phase function, and the imaginary index of refraction. These properties provide a good definition of the influence that the atmospheric dust has on heating of the atmosphere. Our analysis represents a significant improvement over past analyses (Pollack et al. 1977, 1979) by deriving more accurate brightness closer to the sun, by carrying out more precise analyses of the data to acquire the quantities of interest, and by using a better representation of scattering by nonspherical particles. The improvements allow us to better define the diffraction peak and hence the size distribution of the particles. For a lognormal particle size distribution, the first two moments of the size distribution, weighted by the geometric cross section, are found. The geometric cross-section weighted mean radius r(sub eff) is found to be 1.85 +/- 0.3 micrometers at VL2 during northern summer when dust loading was low and 1.52 +/- 0.3 micrometers at VL1 during the first dust storm. In both cases the best cross-section weighted mean variance nu(sub eff) of the size distribution is equal to 0.5 +/- 0.2 micrometers. The changes in size distribution, and thus radiative properties, do not represent a substantial change in solar energy deposition in the atmosphere over the Pollak et al. (1977, 1979) estimates.

Pollack, James B.↗
NASA NTRS1995

Viking Lander image analysis of Martian atmospheric dust

We have reanalyzed three sets of Viking Lander 1 and 2 (VL1 and VL2) images of the Martian atmosphere to better evaluate the radiative properties of the atmospheric dust particles. The properties of interest are the first two moments of the size distribution, the single-scattering albedo, the dust single-scattering phase function, and the imaginary index of refraction. These properties provide a good definition of the influence that the atmospheric dust has on heating of the atmosphere. Our analysis represents a significant improvement over past analyses (Pollack et al. 1977,1979) by deriving more accurate brightnesses closer to the sun, by carrying out more precise analyses of the data to acquire the quantities of interest, and by using a better representation of scattering by nonspherical particles. The improvements allow us to better define the diffraction peak and hence the size distribution of the particles. For a lognormal particle size distribution, the first two moments of the size distribution, weighted by the geometric cross section, are found. The geometric cross-section weighted mean radius (r(sub eff)) is found to be 1.85 +/- 0.3 microns at VL2 during northern summer when dust loading was low and 1.52 +/- 0.3 microns at VL1 during the first dust storm. In both cases the best cross-section weighted mean variance (nu(eff)) of the size distribution is equal to 0.5 +/- 0.2 microns. The changes in size distribution, and thus radiative properties, do not represent a substantial change in solar energy deposition in the atmosphere over the Pollack et al. (1977,1979) estimates.

Pollack, James B.↗
NASA NTRS2003

Shields for Enhanced Protection Against High-Speed Debris

A report describes improvements over the conventional Whipple shield (two thin, spaced aluminum walls) for protecting spacecraft against high-speed impacts of orbiting debris. The debris in question arises mainly from breakup of older spacecraft. The improved shields include exterior "bumper" layers composed of hybrid fabrics woven from combinations of ceramic fibers and high-density metallic wires or, alternatively, completely metallic outer layers composed of high-strength steel or copper wires. These shields are designed to be light in weight, yet capable of protecting against orbital debris with mass densities up to about 9 g/cubic cm, without generating damaging secondary debris particles. As yet another design option, improved shields can include sparsely distributed wires made of shape memory metals that can be thermally activated from compact storage containers to form shields of predetermined shape upon arrival in orbit. The improved shields could also be used to augment shields installed previously.

Christiansen, Eric L.↗
DOE OSTI2025

The scintillator surface detector of the Pierre Auger observatory

Data collected so far by the Pierre Auger Observatory have enabled major advances in ultra-high energy cosmic ray physics and demonstrated that improved determination of masses of primary cosmic-ray particles, preferably on an event-by-event basis, is necessary for understanding their origin and nature. Improvement in primary mass measurements was the main motivation for the upgrade of the Pierre Auger Observatory, called AugerPrime. As part of this upgrade, scintillator detectors are added to the existing water-Cherenkov surface detector stations. By making use of the differences in detector response to the electromagnetic particles and muons between scintillator and water-Cherenkov detectors, the electromagnetic and muonic components of cosmic-ray air showers can be disentangled. Since the muonic component is sensitive to the primary mass, such combination of detectors provides a powerful way to improve primary mass composition measurements over the original Auger surface detector design. In this paper, the so-called Scintillator Surface Detectors are discussed, including their design characteristics, production process, testing procedure and deployment in the field.

Detector design and construction technologies and ↗
DOE OSTI2020

First observation of the production of three massive vector bosons and search for long-lived particles using delayed photons in pp collisions at $\sqrt{s}=13\text{ TeV}$

This thesis presents the first observation of the production of three massive vector bosons (VVV with V = W, Z) in proton-proton collisions at the LHC at $\sqrt{s}=13\text{ TeV}$. The search was performed in final states with two same-sign charged leptons (electrons or muons) plus one or two jets, and three, four, five, or six leptons from WWW, WWZ, WZZ and ZZZ decays, with a data sample corresponding to an integrated luminosity of 137 fb -1 collected by the CMS experiment during 2016-2018. The observed (expected) significance of the combined VVV production is 5.7 (5.9) standard deviations, and the production cross section is measured to be 1010$^{+210}_{-200}$(stat) $^{+150}_{-120}$(syst) fb, corresponding to a signal strength of 1.02$^{+0.26}_{-0.23}$. We also found evidence for WWW and for WWZ production, with observed significances of 3.3 and 3.4 standard deviations, respectively. The measured production cross sections for individual VVV processes are also reported. The establishment of VVV production opens a new program of many standard model studies (such as gauge-gauge and Higgs-gauge couplings), and provides a new tool for many new physics searches (such as anomalous gauge coupling searches, new resonance searches). This thesis also reports a search for long-lived supersymmetry particles decaying to photons in proton-proton collisions at the LHC at $\sqrt{s} = 13 TeV$, with a data sample corresponding to an integrated luminosity of 77.4 fb -1 collected by CMS during 2016-2017. Results are interpreted with a gauge-mediated supersymmetry breaking model, where the long-lived particle is a neutralino and the lightest supersymmetry particle is a gravitino. For neutralino proper decay lengths of 0.1, 1, 10, and 100 m, masses up to 320, 525, 360, and 215 GeV are excluded at 95% confidence level, respectively. This result extends the limits from previous searches by one order of magnitude for the neutralino proper decay length and up to 100 GeV more for the neutralino mass. Motivated by the need for precision timing measurements for long-lived particle searches, as well as for improvements in general object reconstruction performance, the timing performance of two types of sensors are studied in this thesis: one with a Cerium doped Lutetium Yttrium Orthosilicate (LYSO:Ce) crystal as the scintillator and a silicon photomultiplier (SiPM) as the photodetector, another with a Cadmium-Telluride sensor as the active material for a sampling calorimeter. Both setups have been demonstrated with test beams to be able to provide timing measurements of particles with a resolution below 30 ps.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Track reconstruction as a service for collider physics

Optimizing charged-particle track reconstruction algorithms is crucial for efficient event reconstruction in Large Hadron Collider (LHC) experiments due to their significant computational demands. Existing track reconstruction algorithms have been adapted to run on massively parallel coprocessors, such as graphics processing units (GPUs), to reduce processing time. Nevertheless, challenges remain in fully harnessing the computational capacity of coprocessors in a scalable and non-disruptive manner. This paper proposes an inference-as-a-service approach for particle tracking in high energy physics experiments. To evaluate the efficacy of this approach, two distinct tracking algorithms are tested: Patatrack, a rule-based algorithm, and Exa.TrkX, a machine learning-based algorithm. The as-a-service implementations show enhanced GPU utilization and can process requests from multiple CPU cores concurrently without increasing per-request latency. The impact of data transfer is minimal and insignificant compared to running on local coprocessors. This approach greatly improves the computational efficiency of charged particle tracking, providing a solution to the computing challenges anticipated in the High-Luminosity LHC era.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Development of Precipitation-Strengthened Al 0.8 NbTiVM (M = Co, Ni) Light-Weight Refractory High-Entropy Alloys

Single-phase solid-solution refractory high-entropy alloys (RHEAs) have been receiving significant attention due to their excellent mechanical properties and phase stability at elevated temperatures. Recently, many studies have been reported regarding the precipitation-enhanced alloy design strategy to further improve the mechanical properties of RHEAs at elevated temperatures. In this study, we attempted to develop precipitation-hardened light-weight RHEAs via addition of Ni or Co into Al 0.8 NbTiV HEA. The added elements were selected due to their smaller atomic radius and larger mixing enthalpy, which is known to stimulate the formation of precipitates. The addition of the Ni or Co leads to the formation of the sigma precipitates with homogeneous distribution. The formation and homogeneous distribution of sigma particles plays a critical role in improvement of yield strength. Furthermore, the Al 0.8 NbTiVM 0.2 (M = Co, Ni) HEAs show excellent specific yield strength compared to single-phase AlNbTiV and NbTiVZr RHEA alloys and conventional Ni-based superalloy (Inconel 718) at elevated temperatures.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Deuterium retention characteristics in Li film by coating and during flowing liquid Li limiter operation in experimental advanced superconducting tokamak

Lithium (Li) is a promising low-Z material for particle recycling and impurity control to improve plasma performance in fusion devices. In the experimental advanced superconducting tokamak (EAST), Li coating has become a routine method for wall conditioning, and a flowing liquid Li (FLiLi) limiter has been successfully tested several times. Deuterium retention characteristics in the Li film coated on the international thermonuclear experimental reactor-like tungsten divertor and FLiLi during plasma discharges, which is important for the utilization of Li in future fusion devices, were investigated in EAST. It is found that the absorption of the fuel particles by Li coatings decreases gradually, and recycling gradually increases over a series of discharges. The maximum net amount of deuterium retained reached ~0.8 g, corresponding to 12% deuterium in the Li. Furthermore, this corresponds to a whole day's worth of shots with a total of 87 plasma discharges and a total of ~640s plasma time after 11.75 g Li was deposited. Compared to the Li coating, it is shown that FLiLi continuously traps fuel particles and achieves a higher deuterium retention ratio over both the short- and long-term, leading to lower recycling. Meanwhile, it is also observed that the fuel particle retention ratio increases when FLiLi is closer to the plasma. This result is likely due to higher plasma heating power and limiter temperature, which cause an increased Li efflux from FLiLi due to a higher limiter temperature, which then redeposits on the other plasma-facing surfaces and increases fuel particle absorption. It is estimated that ≥ 80% of the retained D particles are captured by the continual renewal of the Li redeposition film during the FLiLi operation. This investigation would also be useful for D/T retention in future fusion devices if Li is used as a plasma-facing component.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2021

Evaluation of Higher-order Quadrature Schemes in Improving Computational Efficiency for Orientation-averaged Single-Scattering Properties of Nonspherical Ice Particles

We evaluate several high-order quadrature schemes for accuracy and efficacy in obtaining orientation-averaged single-scattering properties (SSPs). We use the highly efficient MIDAS to perform electromagnetic scattering calculations to evaluate the gain in efficiency from these schemes. MIDAS is shown to be superior to DDSCAT, a popular discrete dipole approximation (DDA) method. This study is motivated by the fact that quality physical precipitation retrievals rely on using accurate orientation-averaged SSPs derived from realistic hydrometeors as input to radiative transfer Models (RTMs). The DDA has been a popular choice for single-scattering calculations, due to its versatility with respect to target geometry. However, being iterative-solver-based (ISB), the most used DDA codes, e.g. DDSCAT and ADDA, must solve the scattering problem for each orientation of the target separately. As the size parameter and geometric anisotropy of the hydrometeor increase, the number of orientations needed to obtain accurate orientation-averages can increase drastically and so does the computation cost incurred by the ISB-DDA methods. MIDAS is a Direct-Solver-Based (DSB) code, its decomposition of the original large matrix with a high rank into multiple more manageable smaller matrices of lower ranks makes it much more computationally efficient while maintaining excellent accuracy. In addition, direct solvers consider all requested orientations at once, giving MIDAS further advantage over popular ISB-DDA methods. MIDAS, when combined with high-order quadrature for orientation averaging, can be greater than three orders of magnitude more efficient in obtaining RTM-ready SSPs of complex-shaped hydrometeors than existing ISB-DDA methods, with the native quadrature schemes they offer.

Ines Fenni↗
DOE OSTI2023

Low-energy physics in neutrino LArTPCs

Here, in this paper, we review scientific opportunities and challenges related to detection and reconstruction of low-energy (less than 100 MeV) signatures in liquid argon time-projection chamber (LArTPC) neutrino detectors. LArTPC neutrino detectors designed for performing precise long-baseline oscillation measurements with GeV-scale accelerator neutrino beams also have unique sensitivity to a range of physics and astrophysics signatures via detection of event features at and below the few tens of MeV range. In addition, low-energy signatures are an integral part of GeV-scale accelerator neutrino interaction final-states, and their reconstruction can enhance the oscillation physics sensitivities of LArTPC experiments. New physics signals from accelerator and natural sources also generate diverse signatures in the low-energy range, and reconstruction of these signatures can increase the breadth of Beyond the Standard Model scenarios accessible in LArTPC-based searches. A variety of experimental and theory-related challenges remain to realizing this full range of potential benefits. Neutrino interaction cross-sections and other nuclear physics processes in argon relevant to sub-hundred-MeV LArTPC signatures are poorly understood, and improved theory and experimental measurements are needed; pion decay-at-rest sources and charged particle and neutron test beams are ideal facilities for improving this understanding. There are specific calibration needs in the low-energy range, as well as specific needs for control and understanding of radiological and cosmogenic backgrounds. Low-energy signatures, whether steady-state or part of a supernova burst or larger GeV-scale event topology, have specific triggering, DAQ and reconstruction requirements that must be addressed outside the scope of conventional GeV-scale data collection and analysis pathways. Novel concepts for future LArTPC technology that enhance low-energy capabilities should also be explored to help address these challenges.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Bioaerosols are the dominant source of warm-temperature immersion-mode INPs and drive uncertainties in INP predictability

Ice-nucleating particles (INPs) are rare atmospheric aerosols that initiate primary ice formation, but accurately simulating their concentrations and variability in large-scale climate models remains a challenge. Doing so requires both simulating major particle sources and parameterizing their ice nucleation (IN) efficiency. Validating and improving model predictions of INP concentrations requires measuring their concentrations delineated by particle type. We present a method to speciate INP concentrations into contributions from dust, sea spray aerosol (SSA), and bioaerosol. Field campaign data from Bodega Bay, California, showed that bioaerosols were the primary source of INPs between –12° and –20°C, while dust was a minor source and SSA had little impact. We found that recent parameterizations for dust and SSA accurately predicted ambient INP concentrations. However, the model did not skillfully simulate bioaerosol INPs, suggesting a need for further research to identify major factors controlling their emissions and INP efficiency for improved representation in models.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2022

Advancing Solar Energetic Particle Forecasting

With growing interest from the aviation and satellite industries, and for NASA’s upcoming Artemis lunar missions, the need for improved scientific understanding and accurate forecasting of solar energetic particle events has never been stronger. In this paper we discuss the observational, validation and model transition support required to achieve these goals. Well-calibrated, high-quality energetic electron, proton, and ion measurements are essential. Expansions to the fields of view offered by current X-ray, extreme ultraviolet and coronagraph instruments, to obtain increased coverage of the solar corona and heliosphere, from vantage points off the Sun-Earth line, are desired for model input. New observations of suprathermal particles are needed to characterize seed particle distributions and low latency space-based observations of solar radio emissions are also desired. Together, this observational suite should offer high cadence, low latency, reliable and accurate space weather data streams. Consistent, extensive and quantitative model validation is required to assess scientific advancements and pave the way for models transitioning to real-time forecast operations. Model performance and skill should be compared to observations and to current operational forecasting baselines. Finally, resources are required to support the significant effort of transitioning mature models into forecast operations.

solar energetic particles↗
DOE OSTI2023

Calorimetric Energies and Chemical Potentials of Metal Atoms in Catalytic Nanoparticles on Oxide and Carbon Supports: Improved Size Dependencies and Adhesion Energies

The chemical potential of metal atoms, μM, in supported metal nanoparticles is an important descriptor related to both the catalytic activity and the stability of the nanoparticles. Here, we derive an expression relating μM to the radius of the particle’s contact area with the support and the adhesion energy at the metal/support interface (E adh ) that assumes the particles have the shape of spherical caps but of arbitrary contact angle with the support (θ c ) and includes an empirical correction for the increase in metal surface energy and adhesion energy with decreasing radius of curvature. We then show that, at any assumed contact angle, we can simultaneously fit previously reported measurements of both calorimetric μ M (from heats of metal vapor adsorption during nanoparticle growth by vapor deposition) versus metal coverage data and the He + low-energy ion scattering (LEIS) intensities for the metal and/or support versus metal coverage (using our recently developed spherical cap model for quantitative LEIS intensities), to determine the particle size versus coverage and E adh . Only one choice of contact angle gives a pair of values for contact angle and E adh , which is consistent with the Young–Dupré equation for the equilibrium shape of a spherical particle. At this equilibrium shape, we then applied this spherical cap model (SCM) to reanalyze microcalorimetric metal chemical potentials and LEIS signals versus coverage data for nine metal/support combinations that were previously analyzed by assuming that the particles had the shape of hemispherical caps, i.e., with a contact angle of 90°. We show that this revised approach gives close agreement with the calorimetric and LEIS data; the best-fit contact angles vary from 64 to 84°, correcting the earlier assumption of 90°. Furthermore, these results provide significant accuracy improvements in particle size versus coverage, metal chemical potential versus size and coverage, metal/support adhesion energies and contact angles for Cu, Ag and Au on CeO 2 (111), Ni on MgO(100), Ag on Fe 3 O 4 (111) and TiO 2 (100), and Ag, Ni and Pd on Ni-supported graphene. This revised approach is much more broadly applicable than the earlier hemispherical cap model (HCM).

99 GENERAL AND MISCELLANEOUS↗