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At least 469 records · Page 26

A high transmission tender X-ray monochromator employing a matched pair of multilayer grating and mirror

It is now well established that multilayer coated gratings may offer high diffraction efficiencies over the tender X-ray range, from about 1 keV to 5 keV, covering the gap between single layer coated grating monochromators and crystal monochromators. Nevertheless, few beamlines in the world are using such gratings in their monochromator. The successful implementation of a multilayer grating monochromator requires producing a matched pair of a multilayer grating and a multilayer mirror, and this matching is not straightforward as it must account for different incidence angles and refraction effects on each element. Here we review the realization of the multilayer grating monochromator of the SIRIUS beamline which has been successfully in service for several years. We show how, by alternating computer simulation with our diffraction code and measurements, we could optimize the monochromator transmission on a very wide energy range. After the grating was coated, it was found that the angle of optimal efficiency versus photon energy was significantly different from what was predicted by a simple conformal model of binary layers. Layer interdiffusion and profile smoothing during the deposition process must be added to the multilayer model to reproduce the measured data. The critical adjustment of the mirror multilayer period is achieved by the lateral translation of the mirror, which was given a small transverse period gradient. The monochromator is thus providing high transmission efficiency in the 1 to 5 keV energy range, more than 30% over 2.5 keV and up to 46% at 4.6 keV.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Electronic structure and dynamics of confined atoms

Confined atomic systems are of great importance owing a multitude of possible applications in various areas of science and technology. Of particular interest are atoms encaged in the C 60 molecule, A@C 60 , since the near-spherical symmetry of C 60 simplifies theoretical studies, and the stability of C 60 renders it amenable to experimental examination. Herein a review of investigations of the electronic structure and dynamics of A@C 60 is presented in this manuscript focusing on developments in the last decade. Addressed mainly are how the confinement affects electronic structure properties such as ionization potentials, localization of atomic electrons, Shannon entropy, correlation effects, relativistic interactions, and others. In the area of dynamics, photoionization and e-A@C 60 scattering are reviewed and summarized, and the major effects of confinement on the dynamical properties, e.g., confinement resonances, hybridization, Wigner time delay, are delineated.

74 ATOMIC AND MOLECULAR PHYSICS↗

Maximal nighttime electrical power generation via optimal radiative cooling

We present a systematic optimization of nighttime thermoelectric power generation system utilizing radiative cooling. We show that an electrical power density >2 W/m 2 , two orders of magnitude higher than the previously reported experimental result, is achievable using existing technologies. This system combines radiative cooling and thermoelectric power generation and operates at night when solar energy harvesting is unavailable. The thermoelectric power generator (TEG) itself covers less than 1 percent of the system footprint area when achieving this optimal power generation, showing economic feasibility. We study the influence of emissivity spectra, thermal convection, thermoelectric figure of merit and the area ratio between the TEG and the radiative cooler on the power generation performance. We optimize the thermal radiation emitter attached to the cold side and propose practical material implementation. The importance of the optimal emitter is elucidated by the gain of 153% in power density compared to regular blackbody emitters.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Scattering of an utlrashort laser pulse by a spherical air bubble

The scattering of an ultrashort laser pulse by an air bubble in water is investigated by means of the Lorenz-Mie theory and the Debye expansion. A 70 fs, 800 nm pulse is considered as a plane wave with a Gaussian temporal envelope. The transient response is treated with the theory derived from Gouesbet and Gréhan [ Part. Part. Syst. Charact. 17 , 213 –224 ( 2000 ) ], taking now into account chromatic dispersion and absorption of water. It is observed that contrary to the case of water droplet in air, the Debye modes p ≥ 1 start their transient scattering at the same time and the same angle (≈90 ° ) and for a large size parameter, they differentiate as time elapses. A parametric study on the size parameter and the spatial extension of the pulse is performed to identify regimes where the different Debye mode are distinguishable in time. Dependence on the scattering angle is also treated. Finally, by considering pulse chirp, it is shown that the laser/bubble distance has an influence on the separability of modes p = 0 and p = 1.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗