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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

A new technique for ground simulation of hypervelocity debris

A series of hypervelocity damage experiments were preformed on spacecraft materials. These experiments employed a technique which accelerates micro flyer plates simulating space debris traveling at 3 to 8 km/sec. The apparatus used to propel the micro flyer plates was compact and fit well into a space environmental chamber equipped with instrumentation capable of analyzing the vapor ejected from the sample. Mechanical damage to the sample was also characterized using optical and scanning electron microscpopy. Data for this work was obtained from hypervelocity impacts on a polysulfone resin and a graphite polysulfone composite. Polysulfone was selected because it was flown on the Long Duration Exposure Facility (LDEF) which spent several years in low earth orbit (LEO). Chemistry of the vapor produced by the impact was analyzed with a time of flight mass spectrometer, (TOFMS). This represents the first time that ejected vapors from hypervelocity collisions were trapped and analyzed with a mass spectrometer. With this approach we are able to study changes in the vapor chemistry as a function of time after impact, obtain a velocity measurement of the vapor, and estimate a temperature of the surface at time of impact using dynamic gas equations. Samples of the vapor plume may be captured and examined by transmission electron microscopy. Studies were also conducted to determine mechanical damage to a graphite polysulfone composite and a polysulfone resin. Impact craters were examined under optical and scanning electron microscopes. The collision craters in the matrix were typical of those shown in conventional shock experiments. However, the hypervelocity collisions with the graphite polysulfone composite were remarkably different than those with the resin.

Roybal, R.↗
NASA NTRS1995

Silicon Micromachined Sensor for Broadband Vibration Analysis

The development of a family of silicon based integrated vibration sensors capable of sensing mechanical resonances over a broad range of frequencies with minimal signal processing requirements is presented. Two basic general embodiments of the concept were designed and fabricated. The first design was structured around an array of cantilever beams and fabricated using the ARPA sponsored multi-user MEMS processing system (MUMPS) process at the Microelectronics Center of North Carolina (MCNC). As part of the design process for this first sensor, a comprehensive finite elements analysis of the resonant modes and stress distribution was performed using PATRAN. The dependence of strain distribution and resonant frequency response as a function of Young's modulus in the Poly-Si structural material was studied. Analytical models were also studied. In-house experimental characterization using optical interferometry techniques were performed under controlled low pressure conditions. A second design, intended to operate in a non-resonant mode and capable of broadband frequency response, was proposed and developed around the concept of a cantilever beam integrated with a feedback control loop to produce a null mode vibration sensor. A proprietary process was used to integrat a metal-oxide semiconductor (MOS) sensing device, with actuators and a cantilever beam, as part of a compatible process. Both devices, once incorporated as part of multifunction data acquisition and telemetry systems will constitute a useful system for NASA launch vibration monitoring operations. Satellite and other space structures can benefit from the sensor for mechanical condition monitoring functions.

Gutierrez, Adolfo↗
NASA NTRS1997

Atomic Oxygen Treatment Technique for Removal of Smoke Damage from Paintings

Soot deposits that can accumulate on surfaces of a painting during a fire can be difficult to clean from some types of paintings without damaging the underlying paint layers. A non-contact technique has been developed which can remove the soot by allowing a gas containing atomic oxygen to flow over the surface and chemically react with the soot to form carbon monoxide and carbon dioxide. The reaction is limited to the surface, so the underlying paint is not touched. The process can be controlled so that the cleaning can be stopped once the paint surface is reached. This paper describes the smoke exposure and cleaning of untreated canvas, acrylic gesso, and sections of an oil painting using this technique. The samples were characterized by optical microscopy and reflectance spectroscopy.

Rutledge, S. K.↗
NASA NTRS1995

Electro-Optically Active Monomers: Synthesis and Characterization of Thin Films of Liquid Crystalline Substituted Polyacetylenes

The overall objective of this study was the description of the behavior of mesogen substituted acetylene monomers and polymers in monolayer films at the air/water interface and as multilayer films including the formation of such films. Fundamental knowledge to be gained would include the effect of balancing hydrophilic and hydrophobic tendencies in a molecule more complex than the classical fatty acids or lipids. The effect of molecular shape on the packing and thus the ultimate stability of monolayers formed from these new molecules was explored. The work takes on the challenge of preorienting monomers in well-ordered arrays prior to attempting polymerization with the hope that order would be preserved in any resulting polymer. New knowledge gained with regard to the acetylenic monomers includes processing of the acetylene monomer into multi-layer films, followed by the design and synthesis of a second generation of improved monomer structure for superior LBK film transfer properties. A third generation of acetylenic monomer was synthesized which approaches more closely the goal of solid state polymerization of these materials. A parallel study took a different approach. The materials are pre-formed poly(phenylene-acetylene) polymers so questions about reactivity are mute. The materials are a variation on the well-known hairy-rod polymers with regard to their Langmuir film-forming properties. Overall, the goal was to demonstrate that these polymers could be processed into NLO materials with novel polar order.

Duran, R. S.↗
NASA NTRS1997

Remote Marine Aerosol: A Characterization of Physical, Chemical and Optical Properties and their Relation to Radiative Transfer in the Troposphere

Our research effort is focused on improving our understanding of aerosol properties needed for optical models for remote marine regions. This includes in-situ and vertical column optical closure and involves a redundancy of approaches to measure and model optical properties that must be self consistent. The model is based upon measured in-situ aerosol properties and will be tested and constrained by the vertically measured spectral differential optical depth of the marine boundary layer, MBL. Both measured and modeled column optical properties for the boundary layer, when added to the free-troposphere and stratospheric optical depth, will be used to establish spectral optical depth over the entire atmospheric column for comparison to and validation of satellite derived radiances (AVHRR).

Clarke, Antony D.↗
NASA NTRS1998

Filler/ Polycarbosilane Systems as CMC Matrix Precursors

Pyrolytic conversion of polymeric precursors to ceramics is accompanied by loss of volatiles and large volume changes. Infiltration of a low viscosity polymer into a fiber preform will fill small spaces within fiber tows by capillary forces, but create large matrix cracks within large, intertow areas. One approach to minimizing shrinkage and reducing the number of required infiltration cycles is to use particulate fillers. In this study, Starfire allylhydridopolycarbosilane (AHPCS) was blended with a silicon carbide powder, with and without dispersant, using shear mixing. The polymer and polymer/particle interactions were characterized using nuclear magnetic resonance, differential scanning calorimetry, thermogravimetric analysis and rheometry. Polymer/particulate slurries and suspensions were used to infiltrate a figidized preform of an eight ply five harness satin CG Nicalon fiber having a dual layer BN/SiC interface coating, and the resulting composites characterized by optical and scanning electron microscopy.

Hurwitz, Frances I.↗
NASA NTRS1998

Particle Engulfment and Pushing by Solidification Interfaces: Ground Experiments - Part 1

Directional solidification experiments have been carried out to determine the pushing/engulfment transition for two different metal/particle systems. The systems chosen were aluminum/zirconia particles and zinc/zirconia particles. Pure metals (99.999% Al and 99.95% Zn) and spherical particles (500 microns in diameter) were used. The particles were non-reactive with the matrices within the temperature range of interest. The experiments were conducted such as to insure a planar solid/liquid interface during solidification. Particle location before and after processing was evaluated by X-ray transmission microscopy for the Al/ZrO2 samples. All samples were characterized by optical metallography after processing. A clear methodology for the experiment evaluation was developed to unambiguously interpret the occurrence of the pushing/engulfment transition. It was found that the critical velocity for engulfment ranges from 1.9 to 2.4 micron/s for Al/ZrO2 and from 1.9 to 2.9 microns/s for Zn/ZrO2.

Juretzko, Frank R.↗
NASA NTRS1998

Purification and Crystal Growth of Lead Iodide by Physical Vapor Transport Method

Lead iodide (PbI2) is a layered compound semiconductor being developed as room temperature x- and gamma-ray detector. Compared to the more studied material, mercuric iodide, PbI2 has a higher melting temperature and no phase transition until liquid phase which are indications of better mechanical properties. In this study, the source material was purified by the zone-refining process, and the purest section was extracted from center of the the zone-refined ingot to be grown by physical vapor transport (PVT) method. The zone-refined material and as-grown crystals were characterized by optical microscopy and differential scanning calorimetry (DSC) to reveal the surface morphology, purity and stoichiometry. The results shows that both materials are near-stoichiometric composition, with the purity of the as-grown crystals higher than zone-refined materials. The resistivity of the as-grown crystal (10" Omega-cm) was derived from current-voltage (I-V) measurement, and is 10 times higher than the zone-refined materials. Detail results will be presented and discussed.

Wright, G. W.↗
NASA NTRS1997

Optical and Atomic Force Microscopy Characterization of PbI2 Quantum Dots

Lead iodide (PbI2) clusters were synthesized from the chemical reaction of NaI (or KI) with Pb(NO3)2 in H2O, D2O, CH3OH, and C3H7OH media. The observation of the absorption features above 350 nm with the help of integrating sphere accessory strongly suggests the quantum dot formation of PbI2 in solution. Spectral comparison between the synthesized PbI2 clusters in solution and PbI2 nanophase by impregnation of PbI2 in four different pore-sized porous silica indicates that the PbI2 cluster size in solution is less than 2.5 nm in lateral dimension. Atomic force microscopy (AFM) measurements show that the PbL clusters deposited onto three different molecularly flat surfaces are single-layered. The measured height is 1.0 - 0.1 nm. The swollen layer thickness can be attributed to the intralayer contraction from the strong lateral interaction among PbI2 molecules, which is supported by ab initio calculation. Raman scattering measurement of LO and TO modes of PbI2 in bulk and in the confined state were also conducted in 50-150 cu cm region. The observed three bands at 74, %, 106 1/cm are assigned to TO2, LO2, and LO, mode, respectively. The relatively small red-shift in LO modes may be caused by the surface phonon polaritons of PbI2 nanophase in the porous silica.

Mu, R.↗
NASA NTRS1998

Analytical and Experimental Characterization of a Linear-Array Thermopile Scanning Radiometer for Geo-Synchronous Earth Radiation Budget Applications

The Thermal Radiation Group, a laboratory in the department of Mechanical Engineering at Virginia Polytechnic Institute and State University, is currently working towards the development of a new technology for cavity-based radiometers. The radiometer consists of a 256-element linear-array thermopile detector mounted on the wall of a mirrored wedgeshaped cavity. The objective of this research is to provide analytical and experimental characterization of the proposed radiometer. A dynamic end-to-end opto-electrothermal model is developed to simulate the performance of the radiometer. Experimental results for prototype thermopile detectors are included. Also presented is the concept of the discrete Green's function to characterize the optical scattering of radiant energy in the cavity, along with a data-processing algorithm to correct for the scattering. Finally, a parametric study of the sensitivity of the discrete Green's function to uncertainties in the surface properties of the cavity is presented.

Sorensen, Ira J.↗
NASA NTRS2002

Toward an Improved Single-Particle Model for Large Irregular Grains

To interpret remote spectral observations, scattering and absorption in a particulate surface are simulated via radiative transfer models. The standard model for this purpose among the planetary science community is the Hapke model. This model (like many others) uses two parameters to characterize the optical behavior of individual grains in a particulate surface, the single-scattering albedo omega and phase function p(g). These terms describe, respectively, the quantity and the angular distribution of light scattered by an individual grain. Unfortunately, these parameters are strictly optical. They can be rather difficult to interpret in terms of more interesting particle properties such as grain sizes, shapes, and compositions, that a remote sensing experiment might seek to discover. An equivalent slab approximation is typically used to relate omega to the grain size and optical constants of the material. This approach can mimic the wavelength-dependent absorption behavior of irregular grains, as long as the imaginary index kappa is much less than 1, the shape is equant, and the grain size D is much larger than the wavelength lambda. Unfortunately, the equivalent slab approach provides no information about p(g), which also has a strong dependence on optical constants and particle form.

Grundy, W. M.↗
NASA NTRS2005

Compositions of Partly Altered Olivine and Replacement Serpentine in the CM2 Chondrite QUE93005

Some phyllosilicates in CM carbonaceous chondrites formed by aqueous alteration of anhydrous precursor phases. Although broad trends in the compositions of hydrous phyllosilicates are recognized and believed to be related to trends in degree of aqueous alteration, details of the reactions that formed specific secondary minerals remain obscure. This paper reports compositional relationships between remnants of partially pseudomorphically (or alteromorphically) replaced silicates and their alteration products (serpentine) in the CM2 chondrite QUE93005 and compares it with previously published results for ALH81002. Reactants and products were characterized by optical petrography, backscattered scanning electron microscopy (BSEM), and electron microprobe. By focusing on serpentine formed from known reactants (olivines), and on only those instances in which some of the reactant silicate remains, direct compositional relationships between reactants and products, and the elemental mobility required by the reactions, can be established. Additional information is included in the original extended abstract.

Velbel, M. A.↗
NASA NTRS2000

Portable Infrared Reflectometer Designed and Manufactured for Evaluating Emittance in the Laboratory or in the Field

The optical properties of materials play a key role in spacecraft thermal control. In space, radiant heat transfer is the only mode of heat transfer that can reject heat from a spacecraft. One of the key properties for defining radiant heat transfer is emittance, a measure of how efficiently a surface can reject heat in comparison to a perfect black body emitter. Heat rejection occurs in the infrared region of the spectrum, nominally in the range of 2 to 25 mm. To calculate emittance, one obtains the reflectance over this spectral range, calculates spectral absorptance by difference, and then uses Kirchhoff s Law and the Stefan-Boltzmann equation to calculate emittance. A new portable infrared reflectometer, the SOC 400t, was designed and manufactured to evaluate the emittance of surfaces and coatings in the laboratory or in the field. It was developed by Surface Optics Corporation under a contract with the NASA Glenn Research Center at Lewis Field to replace the Center s aging Gier-Dunkle DB-100 infrared reflectometer. The specifications for the new instrument include a wavelength range of 2 to 25 mm; reflectance repeatability of +/-1 percent; self-calibrating, near-normal spectral reflectance measurements; a full scan measurement time of 3.5 min, a sample size of 1.27 cm (0.5 in.); a spectral resolution selectable from 4, 8, 16, or 32/cm; and optical property characterization utilizing an automatic integration to calculate total emittance in a selectable temperature range.

Jaworske, Donald A.↗
NASA NTRS2003

Synthesis and Characterization of Chalcopyrite (CuInS2 and CuhInSe2) Colloidal Nanoparticles for Optoelectronic Applications via Low-Temperature Pyrolysis of Single-Source Precursors

Nanocrystalline (or quantum dot) materials hold potential as components of next-generation photovoltaic (PV) devices. The inclusion of quantum dots in PV devices has been proposed as a means to improve the efficiency of photon conversion (quantum dot solar cell), enable low-cost deposition of thin-films, provide sites for exciton dissociation, and pathways for electron transport. Quantum dots are also expected to be more resistant to degradation from electron, proton, and alpha particle radiation than the corresponding bulk material, a requirement for use in space solar ~sells. Chalcopyrite nanocrystals can be produced by low-temperature thermal decomposition of single-source precursors such as (PR3)2CuIn(ER')4 (R = Ph, R' = Et, E = S; R = R' = Ph, E = Se). Single-source precursors are molecules which contain all the necessary elements for synthesis of a desired material. Thermal decomposition of the precursor results in the formation of material with the correct stoichiometry as a nanocrystalline powder or a thin film, often at significantly lower temperatures than those typically employed for thin-film deposition by multi-source evaporation techniques, typically less than 500 C. We show that CuInSz and CuInSe2 nanocrystals can be synthesized from the precursors at temperatures as low as 250 C. The nanocrystals are characterized by optical spectroscopy, X-ray diffraction, and electron microscopy.

Castro, S. L.↗
NASA NTRS2005

Experimental Investigation of Magnesium Powder Combustion With C02 for Mars Ascent Applications

Combustion of metals with CO2 has been identified as a possible propellant for Mars ascent applications. CO2 could be condensed from the Martian atmosphere, reducing the amount of propellant that must be transported from Earth. An attractive feature of this approach compared to other in situ propellant concepts is that no chemical processing on Mars is required. Magnesium has been identified as the most promising metal for this application because it ignites and burns easily in CO2. Preliminary systems studies indicate a 2 to 1 delivered mass advantage for Mg ascent propulsion using in situ C02, as compared to a conventional storable propellant system. The Propulsion Research Center at MSFC is undertaking an experimental investigation of magnesium powder combustion with CO2 in order to provide fundamental data on the combustion performance of Mg powder + CO2 mixtures needed to assess the feasibility of developing a practical Mg powder + CO2 rocket engine. Initial combustion experiments will be carried out in a small scale atmospheric pressure dump combustor. Effects of varying the Mg particle size, firing rate and O/F ratio on combustion stability and efficiency will be investigated. The combustion process will be characterized by optical flame measurements and extraction of combustion product samples. The experimental facility is currently being prepared and combustion experiments will begin during the first quarter of 2005. The final paper will describe the test facility and initial experimental results.

Foote, John P.↗
NASA NTRS2006

Processing and Properties of a Phenolic Composite System

Phenolic resin systems generate water as a reaction by-product via condensation reactions during curing at elevated temperatures. In the fabrication of fiber reinforced phenolic resin matrix composites, volatile management is crucial in producing void-free quality laminates. A commercial vacuum-bag moldable phenolic prepreg system was selected for this study. The traditional single-vacuum-bag (SVB) process was unable to manage the volatiles effectively, resulting in inferior voidy laminates. However, a double vacuum bag (DVB) process was shown to afford superior volatile management and consistently yielded void-free quality parts. The DVB process cure cycle (temperature /pressure profiles) for the selected composite system was designed, with the vacuum pressure application point carefully selected, to avoid excessive resin squeeze-outs and achieve the net shape and target resin content in the final consolidated laminate parts. Laminate consolidation quality was characterized by optical photomicrography for the cross sections and measurements of mechanical properties. A 40% increase in short beam shear strength, 30% greater flexural strength, 10% higher tensile and 18% higher compression strengths were obtained in composite laminates fabricated by the DVB process.

Hou, Tan-Hung↗
NASA NTRS2008

Oxygen Plasma Modification of Poss-Coated Kapton(Registered TradeMark) HN Films

The surface energy of a material depends on both surface composition and topographic features. In an effort to modify the surface topography of Kapton(Registered TradeMark) HN film, organic solutions of a polyhedral oligomeric silsesquioxane, octakis(dimethylsilyloxy)silsesquioxane (POSS), were spray-coated onto the Kapton(Registered TradeMark) HN surface. Prior to POSS application, the Kapton(Registered TradeMark) HN film was activated by exposure to radio frequency (RF)-generated oxygen plasma. After POSS deposition and solvent evaporation, the films were exposed to various durations of RF-generated oxygen plasma to create a topographically rich surface. The modified films were characterized using optical microscopy, attenuated total reflection infrared (ATR-IR) spectroscopy, and high-resolution scanning electron microscopy (HRSEM). The physical properties of the modified films will be presented.

Wohl, C. J.↗
NASA NTRS2006

Wave-Optics Analysis of Pupil Imaging

Pupil imaging performance is analyzed from the perspective of physical optics. A multi-plane diffraction model is constructed by propagating the scalar electromagnetic field, surface by surface, along the optical path comprising the pupil imaging optical system. Modeling results are compared with pupil images collected in the laboratory. The experimental setup, although generic for pupil imaging systems in general, has application to the James Webb Space Telescope (JWST) optical system characterization where the pupil images are used as a constraint to the wavefront sensing and control process. Practical design considerations follow from the diffraction modeling which are discussed in the context of the JWST Observatory.

Dean, Bruce H.↗