Materials and Platforms for the Optical Detection of Rare Earth Elements
Poster describing sensing materials and platforms for detection economically critical metals from unconventional sources such as acid mine drainage.
photoluminescence↗
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Results for “materials for optics”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Dynamic Interplay of Nonlocal Recombination Pathways in Quantum Emitters in Hexagonal Boron Nitride
Not Available
36 MATERIALS SCIENCE↗
Signatures of nonthermal carriers in nonlinear photoluminescence
Ultrafast light emission from plasmonic nanostructures provides a sensitive probe of the energetic electrons generated by intense optical excitation. The way this emission scales with excitation intensity has long been read through the lens of heated electron populations at an elevated temperature, yet this picture cannot reconcile the variety of behaviors seen across different materials and experiments. We argue that transient nonthermal electrons play a far larger role than has been appreciated. We present a unified description that reproduces emission behavior across diverse systems and outline experiments needed to resolve their signatures.
nanoscale materials↗
Inverse design of photonic surfaces via multi fidelity ensemble framework and femtosecond laser processing
We demonstrate a multi-fidelity (MF) machine learning ensemble framework for the inverse design of photonic surfaces, trained on a dataset of 11,759 samples that we fabricate using high throughput femtosecond laser processing. The MF ensemble combines an initial low fidelity model for generating design solutions, with a high fidelity model that refines these solutions through local optimization. The combined MF ensemble can generate multiple disparate sets of laser-processing parameters that can each produce the same target input spectral emissivity with high accuracy (root mean squared errors < 2%). SHapley Additive exPlanations analysis shows transparent model interpretability of the complex relationship between laser parameters and spectral emissivity. Finally, the MF ensemble is experimentally validated by fabricating and evaluating photonic surface designs that it generates for improved efficiency energy harvesting devices. Our approach provides a powerful tool for advancing the inverse design of photonic surfaces in energy harvesting applications.
97 MATHEMATICS AND COMPUTING↗
Optically thin gas in the broad-line region of Seyfert galaxies
Profile comparisons between the H-alpha and O I 8446 emission lines in Seyfert galaxies are used to search for the presence of optically thin material in the broad-line region. In a sample of 12 objects with detected O I 8446, only four show significant profile differences. In the two clearest cases with profile differences, these can be explained as arising from an outflow of optically thin material. Also presented are high-resolutions spectra of a feature at 9210 A. It is suggested that Mg II pumped by a fluorescence with Ly-beta may be a significant contributor.
Morris, Simon L.↗
Optical, electrical, and EPR studies of polycrystalline Al:Cr:ZnSe gain elements
Transition metal-doped II-VI (TM:II-VI) chalcogenides are well-known laser materials for optically pumped middle-infrared lasers. Cr:ZnSe is a key representative of this class of transition metal doped II-VI gain media and is arguably considered the material of choice for optically pumped middle-infrared lasers. In addition to effective mid-IR lasing under optical excitation, these crystals, being wide-band semiconductors, hold the potential for direct electrical excitation. One way to form n-type conductivity in ZnSe crystals is by annealing them in a melt of Zn-Al alloy. However, this annealing of Cr:ZnSe crystals results in their purification and transfer of chromium to the melt of Zn-Al alloy. In this article, we report on optimizing the doping technique for providing n-type conductivity in Al:Cr:ZnSe crystals while preserving the chromium concentration. Al:Cr:ZnSe samples with resistivities ranging from 10.8 to 992 Ω-cm were fabricated. While the 2 + valence state of Cr is typically dominant in Cr:ZnSe, both Cr 2+ and Cr + were detected in Al:Cr:ZnSe samples. The maximum level of Cr + concentration was measured to be 4 × 10 18 cm -3 .
36 MATERIALS SCIENCE↗
Cosmological implications of ROSAT observations of groups and clusters of galaxies
We have combined ROSAT Position Sensitive Proportional Counter (PSPC) and optical observations of a sample of groups and clusters of galaxies to determine the fundamental parameters of these systems (e.g., the dark matter distribution, gas mass fraction, baryon mass fraction, mass-to-light ratio, and the ratio of total-to-luminous mass). Imaging X-ray spectroscopy of groups and clusters show that the gas is essentially isothermal beyond the central region, indicating that the total mass density (mostly dark matter) scales as rho(sub dark) varies as 1/r squared. The density profile of the hot X-ray emitting gas is fairly flat in groups with rho(sub gas) varies as 1/r and becomes progressively steeper in hotter richer systems, with rho(sub gas) varies as 1/r squared in the richest clusters. These results show, that in general, the hot X-ray-emitting gas is the most extended mass component in groups and clusters, the galaxies are the most centrally concentrated component, and the dark matter is intermediate between the two. The flatter density rofile of the hot gas compared to the dark matter produces a gas mass fraction that increases with radius within each object. There is also a clear trend of increasing gas mass fraction (from 2% to 30%) between elliptical galaxies and rich clusters due to the greater detectable extent of the X-ray emission in richer systems. For the few systems in which the X-ray emission can be traced to the virial radius (where the overdensity delta is approximately equal 200), the gas mass fraction (essentially the baryon mass fraction) approaches a roughly constant value of 30%, suggesting that this is the true primordial value. Based on standard big bang nucleosynthesis, the large baryon mass fraction implies that Omega = 0.1 - 0.2. The antibiased gas distribution suggests that feedback from galaxy formation and hydrodynamics play important roles in the formation of structure on the scale of galaxies to rich clusters. All the groups and clusters in our sample have mass-to-light ratios of M/L(sub V) approximately 100 - 150 solar mass/solar luminosity, which strongly contrasts with the traditional view that the mass-to-light ratio of rich clusters is significantly greater than individual galaxies or groups with M/L(sub V) approximately 250 - 300 solar mass/solar luminosity. We also show that M/L(sub V is essentially constant within the virial radius of clusters (where delta is greater than or approximately 200), which is consistent with the peaks formalism of biased galaxy formation. While the mass-to-light ratios of groups and clusters are comparable (indicating a constant mass fraction of optically luminous material), the ratio of the total mass-to-luminous mass (gas plus stars) monotonically decreases between galaxies and clusters. The decrease in M(sub total)/M(sub lum) arises from two factors: (1) the composition of baryonic matter varies from a predominance of optically luminous material (stars) on the scale of galaxies (approximately 10 kpc) to a predominance of X-ray luminous material (hot gas) on the scale of rich clusters (approximately 1 Mpc), and (2) the hot gas has a more extended spatial distribution than the gravitating matter. The observed decrease M(sub total)/M(sub lum) between galaxies and clusters indicates that the universe actually becomes `brighter' on mass scales between 10(exp 12) and 10(exp 15) solar mass, in the sense that a greater fraction of the gravitating mass is observable.
David, Laurence P.↗
Diverse Electron-Induced Optical Emissions from Space Observatory Materials at Low Temperatures
Electron irradiation experiments have investigated the diverse electron-induced optical and electrical signatures observed in ground-based tests of various space observatory materials at low temperature. Three types of light emission were observed: (i); long-duration cathodoluminescence which persisted as long as the electron beam was on (ii) short-duration (<1 s) arcing, resulting from electrostatic discharge; and (iii) intermediate-duration (~100 s) glow-termed "flares". We discuss how the electron currents and arcing-as well as light emission absolute intensity and frequency-depend on electron beam energy, power, and flux and the temperature and thickness of different bulk (polyimides, epoxy resins, and silica glasses) and composite dielectric materials (disordered SiO2 thin films, carbon- and fiberglass-epoxy composites, and macroscopically-conductive carbon-loaded polyimides). We conclude that electron-induced optical emissions resulting from interactions between observatory materials and the space environment electron flux can, in specific circumstances, make significant contributions to the stray light background that could possibly adversely affect the performance of space-based observatories.
long-duration cathodoluminescence↗
Rapid sensing of hidden objects and defects using a single-pixel diffractive terahertz sensor
Abstract Terahertz waves offer advantages for nondestructive detection of hidden objects/defects in materials, as they can penetrate most optically-opaque materials. However, existing terahertz inspection systems face throughput and accuracy restrictions due to their limited imaging speed and resolution. Furthermore, machine-vision-based systems using large-pixel-count imaging encounter bottlenecks due to their data storage, transmission and processing requirements. Here, we report a diffractive sensor that rapidly detects hidden defects/objects within a 3D sample using a single-pixel terahertz detector, eliminating sample scanning or image formation/processing. Leveraging deep-learning-optimized diffractive layers, this diffractive sensor can all-optically probe the 3D structural information of samples by outputting a spectrum, directly indicating the presence/absence of hidden structures or defects. We experimentally validated this framework using a single-pixel terahertz time-domain spectroscopy set-up and 3D-printed diffractive layers, successfully detecting unknown hidden defects inside silicon samples. This technique is valuable for applications including security screening, biomedical sensing and industrial quality control.
Li, Jingxi (ORCID:0000000165958680)↗
Methods for Determining the Infrared Complex Refractive Indices n (λ) and k (λ) from Organic Solid Powders: Comparison of a Sucrose Single Crystal and a Pressed Pellet
There exists a need to measure optical constants n and k for many materials, especially organic solids in the infrared spectral region, but at present, there are only two established methods for making such measurements: single-angle (SA) reflectance and infrared spectroscopic ellipsometry (IRSE). The former derives the n/k vectors via measurement of the change in the amplitude of light reflected from the sample and then uses the Kramers–Kronig transform, while the latter measures the change in polarization of the reflected light from the sample to derive n/k. Here we make a direct comparison between the n/k vectors derived from SA measurements of a sucrose single crystal and the n/k values obtained after the crystal had been crushed, ground to powder, and pressed into a pellet form. The pellet was measured not only by SA but also via the IRSE method, and we found that pressing specular-quality pellets was critical, especially for the SA data. The n/k values of this typical organic molecule all agree to within 0.04 root-mean-square error, confirming that a pressed pellet can be used instead of a crystal to derive the intrinsic n/k vectors. In conclusion, this result is important for the many organic materials that, unlike sugar, do not have centimeter-sized crystals readily available.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
A graphical approach to the efficiency of flat-plate collectors
A nomogram is described which can be used to determine the thermal performance of flat plate solar collectors, resulting in two performance factors: the net absorptance and the net heat loss coefficient. The nomogram takes into account angle of incidence, collector slope, absorber plate design, insulating materials, thicknesses, optical properties of absorbing surfaces and glazing materials, and flow factors. A case example is given to illustrate the use of the nomogram.
Selcuk, M. K.↗
Syntheses of Octasubstituted Metal Phthalocyanines for Nonlinear Optics
Many organic materials can be used as nonlinear optical media. Phthalocyanines are of special interest because they show an unusually large third order nonlinear response, they are thermally and photochemically stable and they can be formed into oriented thin films (Langmuir-Blodgett films). They also can be easily complexed by a large variety of metals, which place them at the interface between organics and organometallics, and allows for fine tuning of the macro cycle electronic properties by the coordinated metal and substituent groups. A series of 1,4,8,11,15,18,22,25-octaalkoxy metal-free and metal phthalocyanines and 2,3,9,10,16,17,23,24-octaalkoxy metal phthalocyanines has been synthesized. Their nonlinear optical properties have been measured. The physical properties of all the phthalocyanines synthesized in this work are subject to both acid and solvent effects.
Guo, Huaisong↗
The Role of Solar Wind Hydrogen in Space Weathering: Insights from Laboratory-Irradiated Northwest Africa 12008
Micrometeoroid impacts, solar wind plasma interactions, and regolith gardening drive the complicated and nuanced mechanism of space weathering (or optical maturation); a process by which a material’s optical properties are changed as a result of chemical and physical alterations at the surface of grains on airless bodies. Reddened slopes, attenuated absorption bands, and an overall reduction in albedo in the visible and near-IR wavelength ranges are primarily the result of native iron nanoparticle (npFe0) production within glassy rims that form from sputtering and vaporization. The sizes and abundance of these particles provide information about the relative surface exposure age of a particular grain. In addition, many studies have indicated that composition greatly affects the rate at which optical maturation occurs. Despite our understanding of how npFe0 affects optical signatures, the relative roles of micrometeoroid bombardment and solar wind interactions remains undetermined. To simulate the early effects of weathering by the solar wind and to determine thresholds for optical change with respect to a given mineral phase, we irradiated a fine-grained lunar basalt with 1 keV H+ to a fluence of 6.4 x 1016 H+ per sq.cm. Surface alterations within four phases have been evaluated using transmission electron microscopy (TEM). We found that for a given fluence of H+, the extent of damage acquired by each grain was dependent on its composition. No npFe(0) was produced in any of the phases evaluated in this study. These results are consistent with many previous studies conducted using ions of similar energy, but they also provide valuable information about the onset of space weathering and the role of the solar wind during the early stages of optical maturation.
Shusterman, M. L.↗
Integrating collapsible plasmonic gaps on near-field probes for polarization-resolved mapping of plasmon-enhanced emission in 2D material
Scanning near-field optical microscopy (SNOM) is an important technique used to study the optical properties of material systems at the nanoscale. In previous work, we reported on the use of nanoimprinting to improve the reproducibility and throughput of near-field probes including complicated optical antenna structures such as the ‘campanile’ probe. However, precise control over the plasmonic gap size, which determines the near-field enhancement and spatial resolution, remains a challenge. Here, we present a novel approach to fabricating a sub-20 nm plasmonic gap in a near-field plasmonic probe through the controlled collapse of imprinted nanostructures using atomic layer deposition (ALD) coatings to define the gap width. The resulting ultranarrow gap at the apex of the probe provides a strong polarization-sensitive near-field optical response, which results in an enhancement of the optical transmission in a broad wavelength range from 620 to 820 nm, enabling tip-enhanced photoluminescence (TEPL) mapping of 2-dimensional (2D) materials. We demonstrate the potential of this near-field probe by mapping a 2D exciton coupled to a linearly polarized plasmonic resonance with below 30 nm spatial resolution. This work proposes a novel approach for integrating a plasmonic antenna at the apex of the near-field probe, paving the way for the fundamental study of light-matter interactions at the nanoscale.
Zhou, Junze (ORCID:000000020682767X)↗
Plasmonics in argentene
Merging concepts from the fields of ab initio materials science and nanophotonics, there is now an opportunity to engineer new photonic materials whose optical, transport, and scattering properties are tailored to attain thermodynamic and quantum limits. Here we present first-principles calculations predicting that Argentene, a single-crystalline hexagonal close-packed monolayer of Ag, can dramatically surpass the optical properties and electrical conductivity of conventional plasmonic materials. In the low-frequency limit, we show that the scattering rate and resistivity reduce by a factor of 3 compared to the bulk three-dimensional metal. Most importantly, the low scattering rate extends to optical frequencies in sharp contrast to, e.g., graphene, whose scattering rate increase drastically in the near-infrared range due to optical-phonon scattering. Combined with an intrinsically high carrier density, this facilitates highly confined surface plasmons extending to visible frequencies. We evaluate Argentene across three distinct figures of merit, in each outperforming the state-of-the-art, making it a valuable addition to the two-dimensional heterostructure toolkit for quantum optoelectronics.
36 MATERIALS SCIENCE↗
Fiber Optic Sensors for Smart Materials and Structures
In this paper we describe recently developed fiber sensors which are capable of monitoring the health of smart-structures. The unobstrusive geometry of these sensors make them an excellent choice for embedding the sensor in composite materials to measure internal states of strain in structures and materials. Some of these sensors have gage lengths that can be tailored from tens of microns to many meters. We will describe various demodulation schemes (Pseudo-Heterodyne, Synthetic-Heterodyne, Homodyne, Differential-Cross Multiplier, and Single Channel Phase-Tracker) to obtain high bandwidth measurements, enabling measurement of static to high frequency impact generated strains with a dynamic response exceeding tens of thousands of microstrains. In addition, we will show that we can tailor the fiber sensor to either measure only strain and reject temperature response or measure only the temperature, or measure both temperature and strain simultaneously. We will also demonstrate the ability to measure multiple strain components inside a host simultaneously using a single fiber sensor embedded in the host using a certain sensor type and transverse strain immunity using another sensor type. Additionally we will show the ability to measure temperature up to 100 C using fiber optic sensors.
Singh, H.↗
Advances in optical property measurements of spacecraft materials
Some of the instruments and experimental approaches, used for measuring the optical properties of thermal control systems, are presented. The instruments' use in studies concerning the effects of combined contaminants and space environment on these materials, and in the qualification of hardware for spacecraft, are described. Instruments for measuring the solar absorptance and infrared emittance offer improved speed, accuracy and data handling. A transient method for directly measuring material infrared emittance is described. It is shown that oxygen exposure before measuring the solar absorptance should be avoided.
Smith, Charles A.↗
Highly Saturated Glassy Liquid Crystal Films Having Nano- and Microscale Thicknesses for High-Power Laser Applications
The optical properties of glassy liquid crystals (GLC’s) designed to provide high resistance to laser-induced damage are explored. GLC’s readily enable freezing of the anisotropic ordering of liquid crystals into the glassy state. This solidity avoids issues of fluid leakage while providing mechanical robustness and the promise of single-substrate coatings or stand-alone films of nanometer to micron thicknesses. A series of three increasingly saturated GLC’s was synthesized and tested for their thin-film (hundreds of nanometers to tens of micrometers) high-peak-power laser-damage resistance with nanosecond pulses at 1053 nm, 532 nm, and 351 nm, as well as their durability under continuous-wave, broadband ultraviolet illumination. As a result, the GLC’s with higher degrees of saturation demonstrated high resistance to laser-induced damage, extending from the near infrared to the ultraviolet spectral region.
36 MATERIALS SCIENCE↗