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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

The meteorological structure of the mesosphere including seasonal and latitudinal variations.

Evaluation of a large number of meteorological sounding of the mesosphere performed by the acoustic grenade technique and the pitot probe technique. An attempt is made to produce a climatology of observed values of temperature, pressure, density, and wind at various latitudes and seasons which will update and supplement the standard atmospheres and provide realistic inputs for computations involving neutral and ion composition, energy propagation, and transport processes. Temperature-time cross sections over the various observation stations are presented, as well as quasi-meridional cross sections of temperature, pressure, and density, maps of mean zonal and mean meridional winds, and maps of mean winter and mean summer circulation at various levels.

Theon, J. S.↗
DOE OSTI2020

Measurement and microscopic description of odd–even staggering of charge radii of exotic copper isotopes

Nuclear charge radii globally scale with atomic mass number A as A 1/3 , and isotopes with an odd number of neutrons are usually slightly smaller in size than their even-neutron neighbours. This odd–even staggering, ubiquitous throughout the nuclear landscape1, varies with the number of protons and neutrons, and poses a substantial challenge for nuclear theory. Here, we report measurements of the charge radii of short-lived copper isotopes up to the very exotic 78 Cu (with proton number Z = 29 and neutron number N = 49), produced at only 20 ions s –1 , using the collinear resonance ionization spectroscopy method at the Isotope Mass Separator On-Line Device facility (ISOLDE) at CERN. We observe an unexpected reduction in the odd–even staggering for isotopes approaching the N = 50 shell gap. To describe the data, we applied models based on nuclear density functional theory and A-body valence-space in-medium similarity renormalization group theory. Through these comparisons, we demonstrate a relation between the global behaviour of charge radii and the saturation density of nuclear matter, and show that the local charge radii variations, which reflect the many-body polarization effects, naturally emerge from A-body calculations fitted to properties of A ≤ 4 nuclei.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1982

A multi-fluid model of an H2O-dominated dusty cometary atmosphere

The solution of the simultaneous set of differential equations representing conservation of number density, momentum, and energy, together with solar radiation transfer in streams that are responsible for major photolytic processes and nucleus heating, yields a self-consistent multifluid solution for the thermal and dynamical structure of an H2O-dominated, two-phase dusty gas cometary atmosphere, whose validity is restricted to the collision-dominated region where ions and neutrals are assumed to achieve a common temperature and velocity. The model is transonic, due to the dust in the inner coma, and involves the subsonic expansion of the ions and neutrals from the nucleus until, in the outermost part of the collision-dominated coma, temperatures of 300-400 K are reached due to UV pyrolytic heating.

Marconi, M. L.↗
NASA NTRS2016

Impacts of Spontaneous Hot Flow Anomalies on the Magnetosheath and Magnetopause

Spacecraft observations and global hybrid (kinetic ions and fluid electrons) simulations have demonstrated that ion dissipation processes at the quasi-parallel bow shock are associated with the formation of structures called spontaneous hot flow anomalies (SHFAs). Previous simulations and recent spacecraft observations have also established that SHFAs result in the formation of magnetosheath filamentary structures(MFS). In this paper we demonstrate that in addition to MFS, SHFAs also result in the formation of magnetos heath cavities that are associated with decreases in density, velocity, and magnetic field and enhancements in temperature. We use the results of a global MHD run to determine the change in the magnetosheath properties associated with cavities due to ion kinetic effects. The results also show the formation of regions of high flow speed called magnetosheath jets whose properties as a function of solar wind Mach number are described in this study. Comparing the properties of the simulated magnetosheath cavities and jets to past spacecraft observations provides good agreement in both cases. We also demonstrate that pressure variations associated with cavities and SHFAs in the sheath result in a continuous sunward and anti sunward magnetopause motion. This result is consistent with previous suggestions that SHFAs may be responsible for the generation of ion cyclotron waves and precipitation of ring current protons in the outer magnetosphere.

Omidi, N.↗
NASA NTRS1983

Density drift instabilities and weak collisions

A model is developed which describes the effects of weak collisions on the linear kinetic theory of electrostatic density drift instabilities. A dispersion equation valid at all frequencies and wave numbers is derived using the assumptions of a weak, uniform density gradient; a uniform magnetic field; and the BGK collision operator with a modification of the local approximation. The properties of the universal and collisional density drift instabilities at maximum growth rates are examined in detail. The thresholds of the instabilities are examined for an ionospheric model which includes ion-neutral, electron-neutral, and electron-ion collisions, and are compared with the threshold of the lower hybrid density drift instability. It is concluded that the k to the -5th short wavelength density power spectra observed above 280 km in the PLUMEX experiment are due to the effects of the universal density drift instability.

Gary, S. P.↗
NASA NTRS1992

A reconsideration of the effects of terminator ionopause height on the nightward ion transport at Venus

The ionopause altitude near the terminator is a crucial parameter for studies dealing with the maintenance of the nightside ionosphere of Venus. It is generally thought that, during high solar wind dynamic pressures (P(SW)) or during solar minimum conditions, the ionopause comes down to very low altitudes so that the dayside ionosphere is not able to supply sufficient plasma to maintain the observed nightside densities. However, there are a number of workable definitions of the ionopause. Near the terminator, the altitude of the ionopause differs considerably depending upon the definition. The ionopause deduced from the radio occultation experiment as well as the pressure ionopause can be significantly lower than the density ionopause deduced from the Langmuir probe at these locations. The latter refers to the altitude where the electron density falls to 100/cu cm. Using in situ data from the Pioneer Venus Orbiter, it is shown that the density ionopause remains fairly high even for high P(SW) conditions. Simple quantitative estimates indicate that significant flow of plasma is still possible under these conditions. Thus, nightward transport of plasma during high P(SW) conditions may be more efficient than has been assumed so far. Since such conditions are more prevalent during solar cycle minimum, it is argued that transport may be relevant in the maintenance of nightside ionosphere at that time also.

Kar, J.↗
DOE OSTI2023

Magic Numbers and Stabilities of Photoionized Water Clusters: Computational and Experimental Characterization of the Nanosolvated Hydronium Ion

The stability and distributions of small water clusters generated in a supersonic beam expansion are interrogated by tunable vacuum ultraviolet (VUV) radiation generated at a synchrotron. Time-of-flight mass spectrometry reveals enhanced population of various protonated water clusters (H + (H 2 O) $n$ ) based upon ionization energy and photoionization distance from source, suggesting there are "magic" numbers below the traditional $n$ = 21 that predominates in the literature. These intensity distributions suggest that VUV threshold photoionization (11.0-11.5 eV) of neutral water clusters close to the nozzle exit leads to a different nonequilibrium state compared to a skimmed molecular beam. This results in the appearance of a new magic number at 14. Metadynamics conformer searches coupled with modern density functional calculations are used to identify the global minimum energy structures of protonated water clusters between $n$ = 2 and 21, as well as the manifold of low-lying metastable minima. New lowest energy structures are reported for the cases of $n$ = 5, 6, 11, 12, 16, and 18, and special stability is identified by several measures. These theoretical results are in agreement with the experiments performed in this work in that $n$ = 14 is shown to exhibit additional stability, based on the computed second-order stabilization energy relative to most cluster sizes, though not to the extent of the well-known $n$ = 21 cluster. Other cluster sizes that show some additional energetic stability are $n$ = 7, 9, 12, 17, and 19. To gain insight into the balance between ion-water and water-water interactions as a function of the cluster size, an analysis of the effective two-body interactions (which sum exactly to the total interaction energy) was performed. In conclusion, this analysis reveals a crossover as a function of cluster size between a water-hydronium-dominated regime for small clusters and a water-water-dominated regime for larger clusters around $n$ = 17.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2011

DMSP Spacecraft Charging in Auroral Environments

The Defense Meteorological Satellite Program (DMSP) spacecraft are a series of low-earth orbit (LEO) satellites whose mission is to observe the space environment using the precipitating energetic particle spectrometer (SSJ/4-5). DMSP satellites fly in a geosynchronous orbit at approx.840 km altitude which passes through Earth s ionosphere. The ionosphere is a region of partially ionized gas (plasma) formed by the photoionization of neutral atoms and molecules in the upper atmosphere of Earth. For satellites in LEO, such as DMSP, the plasma density is usually high and the main contributors to the currents to the spacecraft are the precipitating auroral electrons and ions from the magnetosphere as well as the cold plasma that constitutes the ionosphere. It is important to understand how the ionosphere and auroral electrons can accumulate surface charges on satellites because spacecraft charging has been the cause of a number of significant anomalies for on-board instrumentation on high altitude spacecraft. These range from limiting the sensitivity of measurements to instrument malfunction depending on the magnitude of the potential difference over the spacecraft surface. Interactive Data Language (IDL) software was developed to process SSJ/4-5 electron and ion data and to create a spectrogram of the particles number and energy fluxes. The purpose of this study is to identify DMSP spacecraft charging events and to present a preliminary statistical analysis. Nomenclature

Colson, Andrew↗
NASA NTRS1980

Radiative cooling efficiencies and predicted spectra of species of the Io plasma torus

Calculations of the physical condition of the Io plasma torus have been made based on the recent Voyager EUV observations. The calculations represent an assumed thin plasma collisional ionization equilibrium among the states within each species. The observations of the torus are all consistent with this condition. The major energy loss mechanism is radiative cooling in discrete transitions. Calculations of radiative cooling efficiencies of the identified species leads to an estimated energy loss rate of at least 1.5 x 10 to the 12th watts. The mean electron temperature and density of the plasma are estimated to be 100,000 K and 2100/cu cm. The estimated number densities of S III, S IV, and O III are roughly 95, 80, and 190-740/cu cm. Upper limits have been placed on a number of other species based on the first published Voyager EUV spectrum of the torus. The assumption that energy is supplied to the torus through injection of neutral particles from Io leads to the conclusion that ion loss rates are controlled by diffusion, and relative species abundances consequently are not controlled by collisional ionization equilibrium.

Shemansky, D. E.↗
NASA NTRS1981

Tearing at the dayside magnetopause

Initial observations of the dayside magnetopause thickness using magnetometers on board ISEE 1 (International Sun-Earth Explorer) and ISEE 2 indicate that this boundary may only be a few ion gyro-radii thick during periods of observed southward interplanetary magnetic field (IMF). Such a thin current layer can destabilize the collisionless tearing mode, a probable first step in the reconnection sequence. The linear growth rate is calculated assuming typical magnetopause parameters and it is found that it is a sensitive function of IMF orientation, magnetopause thickness, and electron number density. It is also shown that the finite size of the dayside magnetopause necessitates the existence of a two-dimensional tearing mode wave vector spectrum, a consequence of the inability of a thermal electron to maintain Landau resonance with the wave for a growth period. Implications regarding reconnection are discussed.

Quest, K. B.↗
NASA NTRS2007

Potential Fluctuations and Energetic Ion Production in Hollow Cathode Discharges

Ions with energies significantly in excess of the applied discharge voltage have been reported for many years in hollow cathode discharges. Models of dc potential hills downstream of the cathode and instabilities in postulated double layers in the cathode orifice have been proposed to explain this, but have not been substantiated. Measurements of the dc and rf plasma density and potential profiles near the exit of hollow cathodes by miniature fast-scanning probes suggests that turbulent ion acoustic fluctuations and ionization instabilities in the cathode plume significantly increase the energy of the ions that flow from this region. Increases in the discharge current and/or decreases in the cathode gas flow enhance the amplitude of the fluctuations and increase the number and energy of the energetic ions, which increases the erosion rate of the cathode electrodes. The transition from the quiescent 'spot mode' to the noisy 'plume mode' characteristic of these discharges is found to be a gradual transition of increasing fluctuation amplitudes.

keeper↗
NASA NTRS1985

Material interactions with the low earth orbital environment Accurate reaction rate measurements

Interactions between spacecraft surfaces and atomic oxygen within the low earth orbital (LEO) environment have been observed and measured during Space Shuttle flights over the past 3 yr. The results of these experiments have demonstrated that interaction rates for many materials proposed for spacecraft applications are high and that protective coatings must be developed to enable long-lived operation of spacecraft structures in the LEO environment. A flight experiment discussed herein uses the Space Shuttle as an orbiting exposure laboratory to obtain accurate reaction rate measurements for materials typically used in spacecraft construction. An ion-neutral mass spectrometer, installed in the Orbiter cargo bay, will measure diurnal ambient oxygen densities while material samples are exposed at low altitude (222 km) to the orbital environment. From in situ atomic oxygen density information and postflight material recession measurements, accurate reaction rates can be derived to update the Space Station materials interaction data base. Additionally, gases evolved from a limited number of material surfaces subjected to direct oxygen impingement will be identified using the mass spectrometer. These measurements will aid in mechanistic definitions of chemical reactions which cause atom-surface interactions and in validating results of upcoming degradation studies conducted in ground-based neutral beam laboratories.

Visentine, J. T.↗
DOE OSTI2024

Electrochemical leaching of spent LIBs: Kinetics, novel reactor, and modeling

The use of electrons as main reagent for the recovery and recycling of critical metals from spent lithium-ion batteries (LIBs) is a process electrification strategy that can be used to close the life-cycle loop of LIBs through more sustainable methods. Electrochemical leaching, a process that uses a reductant that is constantly regenerated electrochemically for the leaching of lithium-ion battery black mass (LIBBM), has shown high extraction efficiencies and sustainable scores. However, slow kinetics, reactor design challenges and lack of deeper understanding of the underlying processes are barriers to the optimization, scale-up, and market adoption of this technology. In this paper, a kinetic study and mathematical model for dissolving LIBBM is presented to better understand the underlying mechanisms aiming to reduce the processing time and make predictions for future design and scale-up. The effect of acid and electrochemically mediated reductant concentrations, LIBBM loading, and cathode/reactor designs were explored. As a result, the leaching time was reduced from 7h to under 1h at a pulp density of 73 g/L, without external heating. A novel reactor with parallel baffle electrodes (PBE) was developed, which significantly reduced the leaching time by improving convection in a stirred slurry electrochemical reactor. Dimensionless numbers were deduced from an unsteady state model, which can be used in dimensional analysis for future process design and scale-up.

25 ENERGY STORAGE↗
NASA NTRS1977

Boundary-value problem for plasma centrifuge at arbitrary magnetic Reynolds numbers

We solve in closed form the boundary-value problem for the partial differential equations which describe the (azimuthal) rotation velocity and induced magnetic fields in a cylindrical plasma centrifuge with ring electrodes of different radii and an external, axial magnetic field. The electric field, current density, and velocity distributions are discussed in terms of the Hartmann number H and the magnetic Reynolds number R. For small Hall coefficients, the induced magnetic field does not affect the plasma rotation. As a result of the Lorentz forces, the plasma rotates with speeds as high as 100,000 cm/sec around its axis of symmetry at typical conditions, so that the lighter (heavier) ion and atom components are enriched at (off) the center of the discharge cylinder.

Wilhelm, H. E.↗
DOE OSTI2025

A Novel Solid Form of Erlotinib: Synthesis by Heterogeneous Complexation and Characterization by NMR Crystallography

We describe the synthesis of a novel complex of the anticancer "active pharmaceutical ingredient erlotinib (ERL) via heterogeneous nucleation on polished zinc tiles. The resulting product, ERL 2 ·ZnCl 2 , is characterized by single-crystal X-ray diffraction, multinuclear solid-state NMR (ssNMR) spectroscopy, and density functional theory (DFT) calculations. Also characterized are the hydrochloride salt (ERL·HCl) and monohydrate free base (ERL·H 2 O) forms of erlotinib. 13 C ssNMR spectroscopy is useful for site-by-site assignment and rapid fingerprinting, while also providing preliminary structural interpretations, such as the number of molecules in the asymmetric unit. 35 Cl ssNMR can readily differentiate between the chloride ions in ERL·HCl and the covalently bonded chlorine in ERL 2 ·ZnCl 2 . 15 N ssNMR proves to be critical here because of the large isotropic chemical shift differences between ERL·H 2 O, ERL·HCl, and ERL 2 ·ZnCl 2 . The 15 N chemical shift tensors are linked directly to differences in structure and bonding with the aid of DFT calculations. Together, these results demonstrate the utility of multinuclear NMR crystallography for the characterization of solid forms of APIs, especially when other analytical techniques face significant challenges.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1996

Study of Analytic Statistical Model for Decay of Light and Medium Mass Nuclei in Nuclear Fragmentation

The angular momentum independent statistical decay model is often applied using a Monte-Carlo simulation to describe the decay of prefragment nuclei in heavy ion reactions. This paper presents an analytical approach to the decay problem of nuclei with mass number less than 60, which is important for galactic cosmic ray (GCR) studies. This decay problem of nuclei with mass number less than 60 incorporates well-known levels of the lightest nuclei (A less than 11) to improve convergence and accuracy. A sensitivity study of the model level density function is used to determine the impact on mass and charge distributions in nuclear fragmentation. This angular momentum independent statistical decay model also describes the momentum and energy distribution of emitted particles (n, p, d, t, h, and a) from a prefragment nucleus.

Cucinotta, Francis A.↗
NASA NTRS1977

Plasma rotation by electric and magnetic fields in a discharge cylinder

A theoretical model for an electric discharge consisting of a spatially diverging plasma sustained electrically between a small ring cathode and a larger ring anode in a cylindrical chamber with an axial magnetic field is developed to study the rotation of the discharge plasma in the crossed electric and magnetic fields. The associated boundary-value problem for the coupled partial differential equations which describe the electric potential and the plasma velocity fields is solved in closed form. The electric field, current density, and velocity distributions are discussed in terms of the Hartmann number and the Hall coefficient. As a result of Lorentz forces, the plasma rotates with speeds as high as 1 million cm/sec around its axis of symmetry at typical conditions. As an application, it is noted that rotating discharges of this type could be used to develop a high-density plasma-ultracentrifuge driven by j x B forces, in which the lighter (heavier) ion and atom components would be enriched in (off) the center of the discharge cylinder.

Wilhelm, H. E.↗
NASA NTRS1990

Gravity-dependent polarity of cytoplasmic streaming in Nitellopsis

The internodal cells of the characean alga Nitellopsis obtusa were chosen to investigate the effect of gravity on cytoplasmic streaming. Horizontal cells exhibit streaming with equal velocities in both directions, whereas in vertically oriented cells, the downward-streaming cytoplasm flows ca. 10% faster than the upward-streaming cytoplasm. These results are independent of the orientation of the morphological top and bottom of the cell. We define the ratio of the velocity of the downward- to the upward-streaming cytoplasm as the polar ratio (PR). The normal polarity of a cell can be reversed (PR < 1) by treatment with neutral red (NR). The NR effect may be the result of membrane hyperpolarization, caused by the opening of K+ channels. The K+ channel blocker TEA Cl- inhibits the NR effect. External Ca2+ is required for normal graviresponsiveness. The [Ca2+] of the medium determines the polarity of cytoplasmic streaming. Less than 1 micromole Ca2+ resulted in a PR < 1 while greater than 1 micromole Ca2+ resulted in the normal gravity response. The voltage-dependent Ca(2+)-channel blocker, nifedipine, inhibited the gravity response in a reversible manner, while treatment with LaCl3 resulted in a PR < 1, indicating the presence of two types of Ca2+ channels. A new model for graviperception is presented in which the whole cell acts as the gravity sensor, and the plasma membrane acts as the gravireceptor. This is supported by ligation and UV irradiation experiments which indicate that the membranes at both ends of the cell are required for graviperception. The density of the external medium also affects the PR of Nitellopsis. Calculations are presented that indicate that the weight of the protoplasm may provide enough potential energy to open ion channels.

NASA Discipline Plant Biology↗