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At least 469 records · Page 26

Progress in High-Dielectric Constant Materials

The relative permittivity of a material is a scaling factor for capacitors and the devices based upon them; the larger the relative permittivity, the greater the degree of miniaturization, or potential for energy storage. Materials with a relative permittivity than that of silicon nitride (approximately 7) are referred to as high-dielectric constant materials. Values of about 100 are typical in titanium dioxide rutile. Values of about 10,000 are observed in barium titanate in the region of the ferroelectric transition, which while impressive, is not very useful due to the strong temperature dependence. The observation of a relative permittivity of over 100,000 in the calcium copper titanate material sparked considerable interest because it showed little temperature dependence between 100 and 600 K over most of the radio-frequency range. Further investigation revealed that this material appears to be naturally nanotextured and that the colossal permittivity was likely due to the surface and/or internal barrier layer capacitance effect, although the issue is not settled. Unfortunately, the dielectric losses in this class materials are relatively high. A new strategy to achieve high dielectric permittivity with low loss involves using localized lattice defect states through ambipolar co-doping; these intrinsic defect complexes give rise to strong dipoles that are responsible for a relative permittivity of 10,000 with exceptionally low dielectric losses over most of the radio frequency range and excellent thermal stability.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Interferometric bunch length measurements of 3 MeV picocoulomb electron beams

We report picosecond bunch length measurements using an interferometric method for a 3 MeV electron beam having bunch charge ranging from 1 to 14 pC. The method senses the single-cycle sub-terahertz (THz) pulse emitted by each electron bunch as coherent transition radiation which, in turn, is analyzed using a Michelson-type interferometer, forming an interferogram that is then processed to yield the nominal electron bunch length. This sub-THz coherent radiation intensity was measured using a quasi-optical detector (QOD) operated at room temperature. This experiment was quite challenging since the divergence angle of the sub-THz pulse emitted by the low-energy electron bunch exceeds ±10°, and its pulse energy at the entrance to the detector was as low as 100 pJ. When compared to a conventional helium-cooled silicon composite bolometer designed for frequencies above 0.5 THz, the QOD provided much better signal-to-noise ratio in the ~80 GHz frequency range, which was critical for the successful measurement of the bunch length.

36 MATERIALS SCIENCE↗

Ultra-thin on-chip ALD LiPON capacitors for high frequency application

Multi-layer ceramic capacitors have been used for high frequency decoupling application due to a lower overall impedance leading to fast current response. However, high parasitic inductance limits the application of these capacitors in ultra-high frequency domain. Thus, Multlayer Ceramic Capacitors (MLCCs) are placed close to the IC to improve circuit efficiency and reduce inductance. With next generation applications, the demand for frequency range has further increased which not only requires enhanced capacitor material but improved manufacturing techniques to limit the inductive path. Here, we demonstrate ALD of two different polymorphs of ultra-thin film lithium phosphorus oxynitride (LiPON) as an inorganic solid state electrolyte (SSE) for on chip capacitors for decoupling application. Both the LiPON capacitors shows an electric double layer behavior with a capacitance of 15 μF/cm 2 and a low leakage current (<20 nA/cm 2 ) at 2V. The LiPON shows EDLC behavior up to 10 kHz and beyond, both the polymorphs show an electrostatic behavior with a high dielectric constant (14). Furthermore, this dual frequency behavior along with low parasitic inductance and on chip integration allows for operation in extended frequency ranges.

25 ENERGY STORAGE↗

Microfluidic Extraction of Biomarkers using Water as Solvent

A proposed device, denoted a miniature microfluidic biomarker extractor (mu-EX), would extract trace amounts of chemicals of interest from samples, such as soils and rocks. Traditionally, such extractions are performed on a large scale with hazardous organic solvents; each solvent capable of dissolving only those molecules lying within narrow ranges of specific chemical and physical characteristics that notably include volatility, electric charge, and polarity. In contrast, in the mu-EX, extractions could be performed by use of small amounts (typically between 0.1 and 100 L) of water as a universal solvent. As a rule of thumb, in order to enable solvation and extraction of molecules, it is necessary to use solvents that have polarity sufficiently close to the polarity of the target molecules. The mu-EX would make selection of specific organic solvents unnecessary, because mu-EX would exploit a unique property of liquid water: the possibility of tuning its polarity to match the polarity of organic solvents appropriate for extraction of molecules of interest. The change of the permittivity of water would be achieved by exploiting interactions between the translational states of water molecules and an imposed electromagnetic field in the frequency range of 300 to 600 GHz. On a molecular level, these interactions would result in disruption of the three-dimensional hydrogen-bonding network among liquid-water molecules and subsequent solvation and hydrolysis of target molecules. The mu-EX is expected to be an efficient means of hydrolyzing chemical bonds in complex macromolecules as well and, thus, enabling analysis of the building blocks of these complex chemical systems. The mu-EX device would include a microfluidic channel, part of which would lie within a waveguide coupled to an electronically tuned source of broad-band electromagnetic radiation in the frequency range from 300 to 600 GHz (see figure). The part of the microfluidic channel lying in the waveguide would constitute an interaction volume. The dimensions of the interaction volume would be chosen in accordance with the anticipated amount of solid sample material needed to ensure extraction of sufficient amount of target molecules for detection and analysis. By means that were not specified at the time of reporting the information for this article, the solid sample material would be placed in the interaction volume. Then the electromagnetic field would be imposed within the waveguide and water would be pumped through the interaction volume to effect the extraction.

Amashukeli, Xenia↗

Search for 1-10 Hz Modulations in Coronal Emission with SECIS During the August 11, 1999 Eclipse

Results of the search of the periodic changes of the 530.3 nm line intensity emitted by selected structures of the solar corona in the frequency range 1-10 Hz are presented. A set of 12728 images of the section of the solar corona extending from near the north pole to the south-west were taken simultaneously in the 530.3 nm ('green') line and white-light with the Solar Eclipse Coronal Imaging System (SECIS) during the 143-seconds-long totality of the 1999 August 11 solar eclipse observed in Shabla, Bulgaria. The time resolution of the collected data is better than 0.05-s and the pixel size is approximately 4 arcsecs. Using classical Fourier spectral analysis tools, we investigated temporal changes of the local 530.3 nm coronal line brightness in the frequency range 1-10 Hz of thousands of points within the field of view. The various photometric and instrumental effects have been extensively considered. We did not find any indisputable, statistically significant evidence of periodicities in any of the investigated points (at significance level alpha = 0.05 or better).

Rudawy, P.↗

Low loss factor Co{sub 2}Z ferrite composites with equivalent permittivity and permeability for ultra-high frequency applications

Ferrite composites of nominal composition Ba{sub 3}Co{sub 2+x}Ir{sub x}Fe{sub 24−2x}O{sub 41} were studied in order to achieve low magnetic and dielectric losses and equivalent permittivity and permeability over a frequency range of 0.3–1 GHz. Crystallographic structure was characterized by X-ray diffraction, which revealed a Z-type phase accompanied by increasing amounts of Y-type phase as the iridium amount was increased. The measured microwave dielectric and magnetic properties showed that the loss tan δ{sub ε} and loss tan δ{sub μ} decreased by 80% and 90% at 0.8 GHz with the addition of iridium of x = 0.12 and 0.15, respectively. An effective medium approximation was adopted to analyze the composite ferrites having mixed phase structures. Moreover, adding Bi{sub 2}O{sub 3} enabled equivalent values of real permittivity and real permeability over the studied frequency range. The resultant data give rise to low loss factors, i.e., tan δ{sub ε}/ε′ = 0.008 and tan δ{sub μ}/μ′ = 0.037 at 0.8 GHz, while characteristic impedance was the same as that of free space.

36 MATERIALS SCIENCE↗

Simulation of the TAEs’ saturation phase in the Large Helical Device: MHD burst

Here, the aim of the present study is to analyze the saturation regime of the toroidal Alfven eigenmodes (TAE) in the Large Helical Device plasma, particularly the MHD burst. The linear and nonlinear evolution of the TAEs are simulated by the FAR3d code that uses a reduced MHD model for the thermal plasma coupled with a gyrofluid model for the energetic particle (EP) species. The linear simulations indicate the overlapping of 1/2–1/1, 2/3–2/4 and 3/5–3/6 TAEs in the inner-middle plasma region and frequency range of 45–75 kHz, triggered by EPs with an energy of T f = 45 keV and EP β = 0.022. The nonlinear simulations show that 2/3–2/4 and 3/4–3/5 TAEs are further destabilized due to the energy transfer from the 1/1–1/2 TAE, leading to broad TAE radial overlapping and triggering of the MHD burst. The energy of the 1/1–1/2 TAE is also nonlinearly transferred to the thermal plasma destabilizing the 0/0 and 0/1 modes, inducing the generation of shear flows and zonal currents, as well as large deformations in the thermal pressure and EP density radial profiles. The nonlinear simulation reproduces the same succession of instabilities and the same frequency range with respect to the experiment. The instability propagates outward during the bursting phase, showing a large decrease of the EP density profile between the middle-outer plasma, indicating the loss of part of the EP population that explains the decrease in the plasma heating efficiency observed during the MHD burst.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Active Vibration Isolation of Microgravity Experiments with Spring Umbilicals Using an Electrodynamic Actuator

Microgravity experiments will require active vibration isolation in the low to mid frequency range of 0.1 Hz to 10 Hz. Approximately two orders of acceleration reduction (40 dB) will be required. Previous works have reported results for accelerations transmitted through the umbilical. This paper describes experimental and theoretical results for vibration isolation in one dimension (horizontal) where the simulated experiment is connected to the spacecraft by a spring umbilical. The experiment consisted of a spacecraft (shaker), experiment (mass), umbilical, accelerometer, control electronics, and Lorentz actuator. The experiment mass was supported in magnetic bearings to avoid any stiction problems. Acceleration feedback control was employed to obtain the vibration isolation. Three different spring umbilicals were employed. Acceleration reductions on the order of 40 dB were obtained over the frequency range of 0.1 Hz to 10 Hz. Good agreement was obtained between theory and experiment.

Banerjee, B. B.↗

Photonic-magnonic crystals: Multifunctional periodic structures for magnonic and photonic applications

We investigate the properties of a photonic-magnonic crystal, a complex multifunctional one-dimensional structure with magnonic and photonic band gaps in the GHz and PHz frequency ranges for spin waves and light, respectively. The system consists of periodically distributed dielectric magnetic slabs of yttrium iron garnet and nonmagnetic spacers with an internal structure of alternating TiO{sub 2} and SiO{sub 2} layers which form finite-size dielectric photonic crystals. We show that the spin-wave coupling between the magnetic layers, and thus the formation of the magnonic band structure, necessitates a nonzero in-plane component of the spin-wave wave vector. A more complex structure perceived by light is evidenced by the photonic miniband structure and the transmission spectra in which we have observed transmission peaks related to the repetition of the magnetic slabs in the frequency ranges corresponding to the photonic band gaps of the TiO{sub 2}/SiO{sub 2} stack. Moreover, we show that these modes split to very high sharp (a few THz wide) subpeaks in the transmittance spectra. The proposed novel multifunctional artificial crystals can have interesting applications and be used for creating common resonant cavities for spin waves and light to enhance the mutual influence between them.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Influence of Fabrication Methods on Structure and Microwave Absorption Property of Fe{sub 3}O{sub 4}/rGO Composites

In this study, flake graphite is used as raw material and oxidized to produce graphene oxide (GO), and then two kinds of ferroferric oxide/reduced graphene oxide (Fe{sub 3}O{sub 4}/rGO) composites are fabricated with one-step and two-step methods, respectively. The influence of composite methods on structure and performance is investigated by FT-IR, XRD, SEM, TEM, and testing of electromagnetic parameters. The results show that there are many advantages in the one-step method for fabrication of Fe{sub 3}O{sub 4}/rGO composite, such as the composite process is simplified, the time is shortened, and the Fe{sub 3}O{sub 4}/rGO composite fabricated with the one-step method has the best microwave impedance matching property in the frequency range of 2.5–6 GHz. At the same time, it can be found that there is the Fe–O–C bond in Fe{sub 3}O{sub 4}/rGO composites fabricated with the one-step method, which results in two ways of physical recombination and chemical bonding between Fe{sub 3}O{sub 4} and rGO sheet particulates. In addition, when the mass ratio of GO and FeCl{sub 3} is 1:10, the R{sub L} value of the Fe{sub 3}O{sub 4}/rGO composite fabricated with the one-step method is minimum, and the increase of sample thickness is beneficial to improve the impedance matching property of Fe{sub 3}O{sub 4}/rGO composite in the frequency range of 2.5–6 GHz.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Relaxation dynamics of water in the vicinity of cellulose nanocrystals

Water molecules near cellulose nanocrystals (CNCs; produced via the sulfuric acid-catalyzed hydrolysis of wood pulp) are believed to relax slower than those in the bulk liquid, which may result in unique properties of CNC aqueous dispersions. Herein this study analyzed the polarization behavior of water molecules in CNC aqueous dispersions and other reference samples using a dielectric relaxation spectroscopy (DRS) technique in the microwave frequency range (0.2–20 GHz). As the CNC concentration increases, two slow relaxation components become prominent. The comparison with DRS data of aqueous dispersions of nanoporous silica, polyvinyl alcohol (PVA), and hairy CNC (HCNC) with amorphous chains protruding from both ends suggested that these slow relaxation modes of water near CNC surfaces cannot be attributed to direct hydrogen bonding interactions with the hydroxyl (OH) groups exposed and immobilized at the solid surface. Instead, they are similar to the water molecules interacting with OH groups attached to flexible polymer chains. Molecular dynamics (MD) simulations of the polarization behavior of water near the (110) facet of cellulose Iβ crystals confirmed that the interactions of water molecules with the cellulose crystal surface do not cause slower relaxations in the frequency range studied via the DRS. These results indicated that the CNC surface cannot be depicted with the crystallographic facets of cellulose Iβ; instead, it resembles a polymer-brush surface on which the short glucan residues or fragments of the strong acid-catalyzed hydrolysis process are swollen and extended into the aqueous phase.

59 BASIC BIOLOGICAL SCIENCES↗

Piezoelectrically Tuned, Multimode Cavity Search for Axion Dark Matter

The eV axion is a well-motivated extension to the standard model. The Axion Dark Matter 27 eXperiment (ADMX) collaboration seeks to discover this particle by looking for the resonant con28 version of dark-matter axions to microwave photons in a strong magnetic eld. In this paper we 29 report results from an ADMX pathnder experiment, the ADMX \Sidecar", which is designed to 30 pave the way for future, higher mass, searches. The Sidecar experiment excludes masses in three 31 widely spaced frequency ranges (4202-4249 MHz, 5086-5799 MHz and 7173-7203 MHz), correspond32 ing to masses favored by some cosmic string simulations. In addition, Sidecar demonstrates the 33 successful use of piezoelectric actuators for both cavity tuning and antenna coupling. Finally, this publication is the rst to report data taken on both the TM010 and TM020 modes.

Boutan, Christian R.↗

Electrical conductivity studies of Bi{sub 2}O{sub 3}-Li{sub 2}O-ZnO-B{sub 2}O{sub 3} glasses

Highlights: Black-Right-Pointing-Pointer Ac conductivity measurements and its analysis has been performed on Bi{sub 2}O{sub 3}-Li{sub 2}O-ZnO-B{sub 2}O{sub 3} glasses in the temperature range 30-300 Degree-Sign C and a frequency range of 100 Hz to 1 MHz. Black-Right-Pointing-Pointer The dc conductivity increased and the activation energy decreased with lithium content. Black-Right-Pointing-Pointer The frequency dependent conductivity has been analyzed employing conductivity and modulus formalisms. Black-Right-Pointing-Pointer The onset of conductivity relaxation shifts towards higher frequencies with temperature. Black-Right-Pointing-Pointer The Almond-West conductivity formalism is used to explain the scaling behavior, and the relaxation mechanism is independent of temperature. -- Abstract: Ac conductivity measurements and its analysis has been performed on xBi{sub 2}O{sub 3}-(65-x)Li{sub 2}O-20ZnO-15B{sub 2}O{sub 3} (0 {<=} x {<=} 20) glasses in the temperature range 30-300 Degree-Sign C and a frequency range of 100 Hz to 1 MHz. The dc conductivity increased and the activation energy decreased with lithium content. The frequency dependent conductivity has been analyzed employing conductivity and modulus formalisms. The onset of conductivity relaxation shifts towards higher frequencies with temperature. The Almond-West conductivity formalism is used to explain the scaling behavior, and the relaxation mechanism is independent of temperature.

36 MATERIALS SCIENCE↗

Binary pseudo-random patterned structures for modulation transfer function calibration and resolution characterization of a full-field transmission soft x-ray microscope

We present a modulation transfer function (MTF) calibration method based on binary pseudo-random (BPR) one-dimensional sequences and two-dimensional arrays as an effective method for spectral characterization in the spatial frequency domain of a broad variety of metrology instrumentation, including interferometric microscopes, scatterometers, phase shifting Fizeau interferometers, scanning and transmission electron microscopes, and at this time, x-ray microscopes. The inherent power spectral density of BPR gratings and arrays, which has a deterministic white-noise-like character, allows a direct determination of the MTF with a uniform sensitivity over the entire spatial frequency range and field of view of an instrument. We demonstrate the MTF calibration and resolution characterization over the full field of a transmission soft x-ray microscope using a BPR multilayer (ML) test sample with 2.8 nm fundamental layer thickness. We show that beyond providing a direct measurement of the microscope’s MTF, tests with the BPRML sample can be used to fine tune the instrument’s focal distance. Our results confirm the universality of the method that makes it applicable to a large variety of metrology instrumentation with spatial wavelength bandwidths from a few nanometers to hundreds of millimeters.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Rupture Dynamics Simulations of Shallow Crustal Earthquakes on Reverse Slip Faults

The main goal of this study was to perform dynamic rupture simulations in order constrain the characterization of kinematic rupture models implemented in techniques for simulating strong ground motion for crustal earthquakes. First, we investigated the rupture process of the 2008 Iwate-Miyagi Nairiku earthquake by developing a dynamic rupture model on a reverse fault using a trial-and-error technique that produced a slip distribution and near-fault ground motion that matched the recorded ones. The simulations were performed in the frequency range 0-2 Hz, using a 3D staggered grid finite-difference method and a linear slip weakening friction law. Constrained by the observed slip distribution and consistent with dynamic rupture models, the derived kinematic rupture model of the Iwate-Miyagi Nairiku earthquake contains areas with relatively large slip rate, representing strong motion generation areas, set against lower amplitude heterogeneous background slip, and a relatively low slip rate in the weak zone of the top-most crust (upper 3km). Second, we performed rupture dynamics modeling to constrain shallow slip characterization in rupture models for strike-slip crustal earthquakes. The objective was to establish general rules about the characterization of slip rate function and slip at shallow depths and in the strong motion generation areas (SMGAs). The simulations of spontaneous rupture were performed in the frequency range 0-2.0Hz, using a 3D staggered-grid finite-difference method and a layer over half-space 1D crustal velocity model with a minimum shear-wave velocity of 2.8 km/s. In order to account for changes in material ductility and reduction of stress drop, observed in the shallow crust (upper 3-5 km), and the transition from ductile state to brittle state in the upper seismogenic zone, in our stress models we included a shallow weak zone (<4km). In this zone the stress drop was set to zero at the free surface and gradually increased with depth, while the slip weakening distance was set to 75 cm at the free surface and decreased to 50 cm at the base of the weak zone. As in the case of reverse faulting during the Iwate-Miyagi Nairiku earthquake, from these computations we found a systematic change in the shape of the slip-rate function, from Kostrov-type in the deeper part of the fault to a more symmetric cosine-type in the upper few kilometers, near the free-surface. Moreover, the average slip duration in the weak zone, with respect to slip duration in the deeper parts of the fault, increases by at most a factor of 1.5. We found a systematic and gradual change in the shape of the slip-rate function from Kostrov-type in the asperity areas (SMGAs), to more symmetric cosine-type in the upper few km near the free-surface, on the long period motion generation area (LMGA). The effective rise time in the LMGA, with respect to that in the SMGAs, increases by at most a factor of 2. Effective rise time is the time difference between the time at which the slip rate drops to a level that is equal to 25% of its peak and the onset time of the signal. In addition, the slip in the LMGA located above the SMGAs is almost the same as the one in the SMGAs, and about 1.5 times larger than the average slip.

58 GEOSCIENCES↗

Vibrations measured in the passenger cabins of two jet transport aircraft

Accelerations in the lateral and vertical directions were measured at two locations on the floor of a three-jet-engine aircraft and at two locations on the floor of a two-jet-engine aircraft during a total of 13 flights, each of which included taxiing, takeoff, ascent, cruise, descent, and landing. Accelerations over the frequency range 0 to 25 Hz were recorded continuously on magnetic tape and were synchronized with the VGH recorders in the aircraft so that vibratory accelerations could be correlated with the operating conditions of the aircraft. From the results it was indicated that the methodology used in segmenting the data, which were obtained in a continuous and repetitive manner, contributes to establishing baseline data representative of the flight characteristics of aircraft. Significant differences among flight conductions were found to occur. The lateral accelerations were approximately 15 percent of the vertical accelerations during flight but as much as 50 to 100 percent of the vertical accelerations during ground operations. The variation between the responses of the two aircraft was not statistically significant. The results also showed that more than 90 percent of the vibratory energy measured during flight occurred in the 0- to 3.0-Hz frequency range. Generally, the vibration amplitudes were normally distributed.

Catherines, J. J.↗

A dynamic pressure calibration standard

A dynamic pressure calibration standard has been developed for calibrating flush diaphragm mounted pressure transducers. Pressures up to 20 kPa (3 psi) have been accurately generated over a frequency range of 50 to 1800 hz. The uncertainty of the standard is +/-5 pct to 5kPa (.75 psi) and +/-10 pct from 5 kPa (.75 psi) to 20 kPa (3 psi). The system consists of two conically shaped, aluminum columns, one 5 cm (2 in.) high for low pressures and another 11 cm (4.3 in.) high for higher pressures, each filled with a viscous fluid. A column is mounted on the armature of a vibration exciter which imparts a sinusoidally varying acceleration to the fluid column. Two pressure transducers mounted at the base of the column sense the sinusoidally varying pressure. This pressure is determined from measurements of the density of the fluid, the height of the fluid, and the acceleration of the column. A section of the taller column is filled with steel balls to control the damping of the fluid to extend its useful frequency range.

Schutte, P. C.↗

Novel high-gain, improved-bandwidth, finned-ladder V-band Traveling-Wave Tube slow-wave circuit design

The V-band frequency range of 59-64 GHz is a region of the millimeter-wave spectrum that has been designated for inter-satellite communications. As a first effort to develop a high-efficiency V-band Traveling-Wave Tube (TWT), variations on a ring-plane slow-wave circuit were computationally investigated to develop an alternative to the more conventional ferruled coupled-cavity circuit. The ring-plane circuit was chosen because of its high interaction impedance, large beam aperture, and excellent thermal dissipation properties. Despite these advantages, however, low bandwidth and high voltage requirements have, until now, prevented its acceptance outside the laboratory. In this paper, the three-dimensional electrodynamic simulation code MAFIA (solution of MAxwell's Equation by the Finite-Integration-Algorithm) is used to investigate methods of increasing the bandwidth and lowering the operating voltage of the ring-plane circuit. Calculations of frequency-phase dispersion, beam on-axis interaction impedance, attenuation and small-signal gain per wavelength were performed for various geometric variations and loading distributions of the ring-plane TWT slow-wave circuit. Based on the results of the variations, a circuit termed the finned-ladder TWT slow-wave circuit was designed and is compared here to the scaled prototype ring-plane and a conventional ferruled coupled-cavity TWT circuit over the V-band frequency range. The simulation results indicate that this circuit has a much higher gain, significantly wider bandwidth, and a much lower voltage requirement than the scaled ring-plane prototype circuit, while retaining its excellent thermal dissipation properties. The finned-ladder circuit has a much larger small-signal gain per wavelength than the ferruled coupled-cavity circuit, but with a moderate sacrifice in bandwidth.

Kory, Carol L.↗