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At least 469 records · Page 26

The vapor pressures of explosives

The vapor pressures of many explosive compounds are extremely low and thus determining accurate values proves difficult. Many researchers, using a variety of methods, have measured and reported the vapor pressures of explosives compounds at single temperatures, or as a function of temperature using vapor pressure equations. There are large variations in reported vapor pressures for many of these compounds, and some errors exist within individual papers. This article provides a review of explosive vapor pressures and describes the methods used to determine them. We have compiled primary vapor pressure relationships traceable to the original citations and include the temperature ranges for which they have been determined. Corrected values are reported as needed and described in the text. In addition, after critically examining the available data, we calculate and tabulate vapor pressures at 25 °C.

explosive, vapor pressure, NG, TNT, PETN, RDX↗

Improved explosive collection and detection with rationally assembled surface sampling materials

Sampling and detection of trace explosives is a key analytical process in modern transportation safety. In this work we have explored some of the fundamental analytical processes for collection and detection of trace level explosive on surfaces with the most widely utilized system, thermal desorption IMS. The performance of the standard muslin swipe material was compared with chemically modified fiberglass cloth. The fiberglass surface was modified to include phenyl functional groups. When compared to standard muslin, the phenyl functionalized fiberglass sampling material showed better analyte release from the sampling material as well as improved response and repeatability from multiple uses of the same swipe. The improved sample release of the functionalized fiberglass swipes resulted in a significant increase in sensitivity. Various physical and chemical properties were systematically explored to determine optimal performance. The results herein have relevance to improving the detection of other explosive compounds and potentially to a wide range of other chemical sampling and field detection challenges.

Explosive detection↗

Shocks, explosions, and vortices in two-dimensional homogeneous quantum magnetoplasma

Using the quantum hydrodynamic model for a uniform quantum magnetoplasma, and considering that the collision between ions and neutrals is dominant, a two-dimensional nonlinear system is derived. The linear dispersion relation is obtained and thus the variations of the dispersion relation with the obliqueness angle and density are discussed in detail. Shock, explosion, and vortex solutions of the nonlinear system are obtained. It is found that increasing the plasma density may enhance the strength of the shock and the width of the explosion. However, the higher the collision frequency is, the weaker the shock and the narrower the explosion will be. The temporal and spatial distributions for the vortex potential are studied. Spatially, it forms a periodic vortex street. Temporally, the vortex street may evolve in various ways owing to the arbitrary function of time.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

MESOSCALE MODELING OF DEFLAGRATION-INDUCED DECONSOLIDATION IN POLYMER-BONDED EXPLOSIVES

Initially undamaged polymer-bonded explosives can transition from conductive burning to more violent convective burning via rapid deconsolidation at higher pressures. The pressure-dependent infiltration of cracks and pores, i.e., damage, by product gases at the burn-front is a key step in the transition to convective burning. However, the relative influence of pre-existing damage and the evolution of deflagration-induced damage during the transition to convective burning is not well understood. The objective of this study is to investigate the role of microstructure and initial pressurization on deconsolidation. We performed simulations using the multi-physics hydrocode, ALE3D. HMX-Viton A served as our model explosive. A Prout-Tompkins chemical kinetic model, Vielle's Law pressure-dependent burning, Gruneisen equation-of-state, and simplified strength model were used for the HMX. The propensity for deconsolidation increased with increasing defect size and decreasing initial pressurization, as measured by the increase in burning surface area. These studies are important because they enable the development of continuum-scale damage models and the design of inherently safer explosives.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dust cluster explosion

A model for the dust cluster explosion where micron/sub-micron sized particles are accelerated at the expense of plasma thermal energy, in the afterglow phase of a complex plasma discharge is proposed. The model is tested by molecular dynamics simulations of dust particles in a confining potential. The nature of the explosion (caused by switching off the discharge) and the concomitant dust acceleration is found to depend critically on the pressure of the background neutral gas. At low gas pressure, the explosion is due to unshielded Coulomb repulsion between dust particles and yields maximum acceleration, while in the high pressure regime it is due to shielded Yukawa repulsion and yields much feebler acceleration. These results are in agreement with experimental findings. Our simulations also confirm a recently proposed electrostatic (ES) isothermal scaling relation, P{sub E}{proportional_to}V{sub d}{sup -2} (where P{sub E} is the ES pressure of the dust particles and V{sub d} is the confining volume).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Explosively driven air blast in a conical shock tube

Explosively driven shock tubes present challenges in terms of safety concerns and expensive upkeep of test facilities but provide more realistic approximations to the air blast resulting from free-field detonations than those provided by gas-driven shock tubes. Likewise, the geometry of conical shock tubes can naturally approximate a sector cut from a spherically symmetric blast, leading to a better agreement with the blast profiles of free-field detonations when compared to those provided by shock tubes employing constant cross sections. The work presented in this article documents the design, fabrication, and testing of an explosively driven conical shock tube whose goal was to closely replicate the blast profile seen from a larger, free-field detonation. By constraining the blast through a finite area, large blasts (which can add significant damage and safety constraints) can be simulated using smaller explosive charges. The experimental data presented herein show that a close approximation to the free-field air blast profile due to a 1.5 lb charge of C4 at 76 in. can be achieved by using a 0.032 lb charge in a 76-in.-long conical shock tube (which translates to an amplification factor of nearly 50). Modeling and simulation tools were used extensively in designing this shock tube to minimize expensive fabrication costs.

42 ENGINEERING↗

Generation of ultra-fast cumulative water jets by sub-microsecond underwater electrical explosion of conical wire arrays

The results of experiments with underwater electrical explosion of modified conical arrays of copper and aluminum wires are presented. A pulsed generator producing a 550 kA-amplitude current with a 400 ns rise time was used in the explosion of the arrays. The array explosion generates water flows converging at the axis of the cone. This flow generates a fast-moving water jet with a velocity exceeding 1.8 × 10{sup 5 }cm/s, which was observed being ejected from the surface of the water covering the array. The positions of the water jet were measured by multiple-exposure fast framing imaging. In experiments, the apex angle of the array, the thickness of the water layer above the arrays, or the material of the wires was altered, which changed the resulting velocities and shapes of the emitted jets. A model that considers the converging stationary flow of a slightly compressible fluid is suggested. The velocities and shapes of the jets obtained by this model agree well with the experimentally measured jet velocities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Atomistic modelling of evaporation and explosive boiling of thin film liquid argon over internally recessed nanostructured surface

Molecular dynamics (MD) simulations have been carried out to investigate evaporation and explosive boiling phenomena of thin film liquid argon on nanostructured solid surface with emphasis on the effect of solid-liquid interfacial wettability. The nanostructured surface considered herein consists of trapezoidal internal recesses of the solid platinum wall. The wetting conditions of the solid surface were assumed such that it covers both the hydrophilic and hydrophobic conditions and hence effect of interfacial wettability on resulting evaporation and boiling phenomena was the main focus of this study. The initial configuration of the simulation domain comprised of a three phase system (solid platinum, liquid argon and vapor argon) on which equilibrium molecular dynamics (EMD) was performed to reach equilibrium state at 90 K. After equilibrium of the three-phase system was established, the wall was set to different temperatures (130 K and 250 K for the case of evaporation and explosive boiling respectively) to perform non-equilibrium molecular dynamics (NEMD). The variation of temperature and density as well as the variation of system pressure with respect to time were closely monitored for each case. The heat flux normal to the solid surface was also calculated to illustrate the effectiveness of heat transfer for hydrophilic and hydrophobic surfaces in cases of both nanostructured surface and flat surface. The results obtained show that both the wetting condition of the surface and the presence of internal recesses have significant effect on normal evaporation and explosive boiling of the thin liquid film. The heat transfer from solid to liquid in cases of surface with recesses are higher compared to flat surface without recesses. Also the surface with higher wettability (hydrophilic) provides more favorable conditions for boiling than the low-wetting surface (hydrophobic) and therefore, liquid argon responds quickly and shifts from liquid to vapor phase faster in case of hydrophilic surface. The heat transfer rate is also much higher in case of hydrophilic surface.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Coulomb explosion of “hot spot”

The study presented in this paper has shown that the generation of hard x rays and high-energy ions, which are detected in pinch implosion experiments, may be associated with the Coulomb explosion of the hot spot that is formed due to the outflow of the material from the pinch cross point. During the process of material outflow, the temperature of the hot spot plasma increases, and conditions arise for the plasma electrons to become continuously accelerated. The runaway of electrons from the hot spot region results in the buildup of positive space charge in this region followed by a Coulomb explosion. The conditions for the hot spot plasma electrons to become continuously accelerated have been revealed, and the estimates have been obtained for the kinetic energy of the ions generated by the Coulomb explosion.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Numerical parameter optimizations of the Ignition and Growth model for a HMX plastic bonded explosive

We present here a novel method for optimizing parameters of the Ignition and Growth (I&G) reactive flow model for high explosives. The I&G model predicts the shock initiation response of explosives subjected to dynamic loading. However, calibrating the model is a time-consuming process because it has several parameters, typically requires multiple data sets, and there are no direct correlations between parameters and data. In this study, we couple a scalable optimization algorithm to simulations of shock initiation experiments in the multi-physics code ALE3D. We develop four I&G model parameter sets for the HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocane)-based explosive LX-07 [90 wt. % HMX, 10 wt. % Viton A] based on minimizing the difference between calculations and measurements at the embedded pressure gauges in 1D gun shock experiments. Our study shows that a cost function based on both shock time of arrival and pressure pulse shape demonstrates the best agreement with experimental data.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A reactive flow model for the 3,3'-diamino-4,4'-azoxyfurazan based plastic bonded explosive (PBX 9701)

Here, this paper describes the calibration of the Arrhenius Wescott–Stewart–Davis (AWSD) reactive flow model for the recently developed high explosive PBX 9701, which consists of 97% 3,3'-diamino-4,4'-azoxyfurazan (DAAF) and 3% FK-800 binder by weight. DAAF-based explosive formulations have several desirable qualities as they are relatively insensitive to non-shock insults but have higher performance than triaminotrinitrobenzene based formulations. Equations of state for the explosive reactants and products are calibrated using a combination of existing and new experimental data and theoretical calculations. The AWSD rate law calibration utilizes both one-dimensional shock-to-detonation and multidimensional rate stick experiments to capture the shock initiation and propagating detonation regimes. Validation of the calibrated model is demonstrated through comparison with recent gas-gun experiments.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Explosively driven Richtmyer–Meshkov instability jet suppression and enhancement via coupling machine learning and additive manufacturing

The ability to control the behavior of fluid instabilities at material interfaces, such as the shock-driven Richtmyer–Meshkov instability, is a grand technological challenge with a broad number of applications ranging from inertial confinement fusion experiments to explosively driven shaped charges. In this work, we use a linear-geometry shaped charge as a means of studying methods for controlling material jetting that results from the Richtmyer–Meshkov instability. A shaped charge produces a high-velocity jet by focusing the energy from the detonation of high explosives. The interaction of the resulting detonation wave with a hollowed cavity lined with a thin metal layer produces the unstable jetting effect. By modifying the characteristics of the detonation wave prior to striking the lined cavity, the kinetic energy of the jet can be enhanced or reduced. Modifying the geometry of the liner material can also be used to alter jetting properties. We apply optimization methods to investigate several design parameterizations for both enhancing or suppressing the shaped-charge jet. This is accomplished using 2D and 3D hydrodynamic simulations to investigate the design space that we consider. We also apply new additive manufacturing methods for producing the shaped-charge assemblies, which allow for the experimental testing of complicated design geometries obtained through computational optimization. We present a direct comparison of our optimized designs with experimental results carried out at the High Explosives Application Facility at Lawrence Livermore National Laboratory.

36 MATERIALS SCIENCE↗

Verification and validation of detonation-shock-dynamics relations for explosives described by general equation of state and chemical reaction models

Detonation shock dynamics is a powerful method to model the behaviour of High Explosives (HE). However in order to use this method, the underlying relationship between the local radius of curvature and the detonation speed must be known. Previous work has developed methods to calculate this effect using simple, single-step Arrhenius and polytropic gas, models for the chemical reaction and the equation of state, respectively. In recent years, more complex models for both reaction rates and equations of state have been developed which show better agreement with experimental data than these simple models, especially when considering condensed phase explosives.. This work presents the governing equations for solving these problems in a way that is generalised to use arbitrary equations of state as well as reaction models which may have more than a single step and multiple product species. This implementation is verified against exact solutions, demonstrating that the equations were implemented properly. The verified algorithm is then validated against experimental data and high fidelity simulations, showing that it is able to make accurate predictions in a regime where the underlying assumptions of the governing equations are valid. Importantly, this approach has many applications: from creating equivalent detonation shock dynamics models for existing reactive burn calibrations for HE; to developing new functional forms and calibrations of reactive burn models for condensed phase high explosives.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

INTEGRAL FIELD SPECTROSCOPY OF SUPERNOVA EXPLOSION SITES: CONSTRAINING THE MASS AND METALLICITY OF THE PROGENITORS. I. TYPE Ib AND Ic SUPERNOVAE

Integral field spectroscopy of 11 Type Ib/Ic supernova (SN Ib/Ic) explosion sites in nearby galaxies has been obtained using UH88/SNIFS and Gemini-N/GMOS. The use of integral field spectroscopy enables us to obtain both spatial and spectral information about the explosion site, enabling the identification of the parent stellar population of the SN progenitor star. The spectrum of the parent population provides metallicity determination via strong-line method and age estimation obtained via comparison with simple stellar population models. We adopt this information as the metallicity and age of the SN progenitor, under the assumption that it was coeval with the parent stellar population. The age of the star corresponds to its lifetime, which in turn gives the estimate of its initial mass. With this method we were able to determine both the metallicity and initial (zero-age main sequence) mass of the progenitor stars of SNe Ib and Ic. We found that on average SN Ic explosion sites are more metal-rich and younger than SN Ib sites. The initial mass of the progenitors derived from parent stellar population age suggests that SN Ic has more massive progenitors than SN Ib. In addition, we also found indication that some of our SN progenitors are less massive than {approx}25 M{sub Sun }, indicating that they may have been stars in a close binary system that have lost their outer envelope via binary interactions to produce SNe Ib/Ic, instead of single Wolf-Rayet stars. These findings support the current suggestions that both binary and single progenitor channels are in effect in producing SNe Ib/Ic. This work also demonstrates the power of integral field spectroscopy in investigating SN environments and active star-forming regions.

79 ASTRONOMY AND ASTROPHYSICS↗

RADIO AND X-RAY OBSERVATIONS OF THE TYPE Ic SN 2007gr REVEAL AN ORDINARY, NON-RELATIVISTIC EXPLOSION

We present extensive radio and X-ray observations of the nearby Type Ic SN 2007gr in NGC 1058 obtained with the Very Large Array (VLA) and the Chandra X-ray Observatory and spanning 5 to 150 days after explosion. Through our detailed modeling of these data, we estimate the properties of the blast wave and the circumstellar environment. We find evidence for a freely expanding and non-relativistic explosion with an average blast wave velocity, v-bar {approx}0.2c, and a total internal energy for the radio emitting material of E {approx} 2 x 10{sup 46} erg assuming equipartition of energy between electrons and magnetic fields ({epsilon}{sub e} = {epsilon}{sub B} = 0.1). The temporal and spectral evolution of the radio emission points to a stellar wind-blown environment shaped by a steady progenitor mass loss rate of M-dot {approx}6x10{sup -7} M{sub sun} yr{sup -1} (wind velocity, v{sub w} = 10{sup 3} km s{sup -1}). These parameters are fully consistent with those inferred for other SNe Ibc and are in line with the expectations for an ordinary, homologous SN explosion. Our results are at odds with those of Paragi et al. who recently reported evidence for a relativistic blast wave in SN 2007gr based on their claim that the radio emission was resolved away in a low signal-to-noise Very Long Baseline Interferometry (VLBI) observation. Here we show that the exotic physical scenarios required to explain the claimed relativistic velocity-extreme departures from equipartition and/or a highly collimated outflow-are excluded by our detailed VLA radio observations. Moreover, we present an independent analysis of the VLBI data and propose that a modest loss of phase coherence provides a more natural explanation for the apparent flux density loss which is evident on both short and long baselines. We conclude that SN 2007gr is an ordinary Type Ibc supernova.

79 ASTRONOMY AND ASTROPHYSICS↗

DUSTY EXPLOSIONS FROM DUSTY PROGENITORS: THE PHYSICS OF SN 2008S AND THE 2008 NGC 300-OT

SN 2008S and the 2008 NGC 300-OT were explosive transients of stars self-obscured by very dense, dusty stellar winds. An explosive transient with an unobserved shock breakout luminosity of order 10{sup 10} L{sub sun} is required to render the transients little obscured and visible in the optical at their peaks. Such a large breakout luminosity then implies that the progenitor stars were cool, red supergiants, most probably {approx}9 M{sub sun} extreme asymptotic giant branch stars. As the shocks generated by the explosions propagate outward through the dense wind, they produce a shock luminosity in soft X-rays that powers the long-lived luminosity of the transients. Unlike typical cases of transients exploding into a surrounding circumstellar medium, the progenitor winds in these systems are optically thick to soft X-rays, easily absorb radio emission, and rapidly reform dust destroyed by the peak luminosity of the transients. As a result, X-rays are absorbed by the gas and the energy is ultimately radiated by the reformed dust. Three years post-peak, both systems are still significantly more luminous than their progenitor stars, but they are again fully shrouded by the reformed dust and only visible in the mid-IR. The high luminosity and heavy obscuration may make it difficult to determine the survival of the progenitor stars for {approx}10 years. However, our model indicates that SN 2008S, but not the NGC 300-OT, should now be a detectable X-ray source. SN 2008S has a higher estimated shock velocity and a lower density wind, so the X-rays begin to escape at a much earlier phase.

79 ASTRONOMY AND ASTROPHYSICS↗

GENERIC MODEL FOR MAGNETIC EXPLOSIONS APPLIED TO SOLAR FLARES

An accepted model for magnetospheric substorms is proposed as the basis for a generic model for magnetic explosions and is applied to solar flares. The model involves widely separated energy-release and particle-acceleration regions, with energy transported Alfvenically between them. On a global scale, these regions are coupled by a large-scale current that is set up during the explosion by redirection of pre-existing current associated with the stored magnetic energy. The explosion-related current is driven by an electromotive force (EMF) due to the changing magnetic flux enclosed by this current. The current path and the EMF are identified for an idealized quadrupolar model for a flare.

79 ASTRONOMY AND ASTROPHYSICS↗

A NEW MULTI-DIMENSIONAL GENERAL RELATIVISTIC NEUTRINO HYDRODYNAMICS CODE OF CORE-COLLAPSE SUPERNOVAE. III. GRAVITATIONAL WAVE SIGNALS FROM SUPERNOVA EXPLOSION MODELS

We present a detailed theoretical analysis of the gravitational wave (GW) signal of the post-bounce evolution of core-collapse supernovae (SNe), employing for the first time relativistic, two-dimensional explosion models with multi-group, three-flavor neutrino transport based on the ray-by-ray-plus approximation. The waveforms reflect the accelerated mass motions associated with the characteristic evolutionary stages that were also identified in previous works: a quasi-periodic modulation by prompt post-shock convection is followed by a phase of relative quiescence before growing amplitudes signal violent hydrodynamical activity due to convection and the standing accretion shock instability during the accretion period of the stalled shock. Finally, a high-frequency, low-amplitude variation from proto-neutron star (PNS) convection below the neutrinosphere appears superimposed on the low-frequency trend associated with the aspherical expansion of the SN shock after the onset of the explosion. Relativistic effects in combination with detailed neutrino transport are shown to be essential for quantitative predictions of the GW frequency evolution and energy spectrum, because they determine the structure of the PNS surface layer and its characteristic g-mode frequency. Burst-like high-frequency activity phases, correlated with sudden luminosity increase and spectral hardening of electron (anti-)neutrino emission for some 10 ms, are discovered as new features after the onset of the explosion. They correspond to intermittent episodes of anisotropic accretion by the PNS in the case of fallback SNe. We find stronger signals for more massive progenitors with large accretion rates. The typical frequencies are higher for massive PNSs, though the time-integrated spectrum also strongly depends on the model dynamics.

79 ASTRONOMY AND ASTROPHYSICS↗