Low Cost Hydrogen Monitor for Continuous Quantification of Facility Emissions
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54 ENVIRONMENTAL SCIENCES↗
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OES-Environmental 2024 State of the Science Report: Environmental Effects of Marine Renewable Energy Development Around the World
This report summarizes the state of the science of environmental effects of marine renewable energy (MRE) and serves as an update and a complement to the 2020 State of the Science report. The 2024 State of the Science report was produced by the Ocean Energy Systems (OES)-Environmental initiative, under the International Energy Agency’s OES collaboration. Under OES-Environmental, 16 countries have collaborated to evaluate the “state of the science” of potential environmental effects of MRE development and to understand how they may affect consenting/permitting (hereafter consenting) of MRE devices. This report has brought together the most up-to-date information on potential environmental effects of MRE development, using information that is publicly available as well as from expert inputs. The OES-Environmental analysts from the 16 participating countries helped to scope the entirety of the report and provided valuable contributions to all chapters. The input from these contributors and reviewers has resulted in the most complete compendium of research and monitoring findings possible. This report encompasses an introduction and look ahead, as well as nine chapters that provide details of research and monitoring findings around the world on environmental effects of MRE.
16 TIDAL AND WAVE POWER↗
Tonopah Test Range Air Monitoring: Meteorological, Radiological, and Wind Transported Particulate Observations (CY 2019)
In 1963, the U.S. Department of Energy (DOE) (formerly the Atomic Energy Commission [AEC]), implemented Operation Roller Coaster on the Tonopah Test Range (TTR) and an adjacent area of the Nevada Test and Training Range (NTTR) (formerly the Nellis Air Force Range). This operation resulted in radionuclide-contaminated soils at the Double Tracks site and Clean Slate I, II, and III sites. This report documents observations made during ongoing monitoring of radiological, meteorological, and dust conditions at stations installed adjacent to the Clean Slate sites and at the TTR Sandia National Laboratories (SNL) Range Operations Center (ROC). The main objectives of the monitoring effort are to support the DOE Environmental Management Nevada Program (EM NV) in the safe remediation of the environmental legacy of nuclear device development and testing by determining if wind blowing across the Clean Slate sites is transporting particles of radionuclide-contaminated soil beyond the physical and administrative boundaries of the sites, and providing information for designing long-term monitoring of the sites. The monitoring program in 2019 included five stations. Station 400, located within TTR Area 3 and near the ROC, monitors conditions near the local workforce center. Stations 401 and 403 are located on the northern and southeastern perimeter fence lines, respectively, of the Clean Slate III site. Stations 404 and 405 are along the northern and eastern boundary fence, respectively, at Clean Slate II. The stations are generally downwind of the contaminated areas during either northwesterly or southerly winds, which are the predominant wind directions.
54 ENVIRONMENTAL SCIENCES↗
Actions to Evaluate Tritium in ATR Complex Perched Water Well 12
On April 23, 2019, elevated tritium concentrations in monitoring well PW-12 were reported to the Advanced Test Reactor (ATR) Complex environmental manager by the Fluor Idaho Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) lead. The monitoring well is one of a series of wells located in and around the ATR Complex that are sampled on an annual basis as part of the CERCLA monitoring program. The Fluor Idaho CERCLA lead indicated the elevated concentrations had been trending upward from Fiscal Year (FY) 2017 through FY 2019. The tritium levels went from 1,880 pCi/L in October 2016 to 7,890 pCi/L in October 2017 and increased to 13,000 pCi/L in October 2018. In order to identify a baseline, the safe drinking water level (e.g. 20,000 pCi/L) can be used as a reference point for comparison only, as PW-12 is a perched water well and does not penetrate the aquifer. Although well below safe drinking water levels, an investigation was initiated to identify the source of tritium.
99 GENERAL AND MISCELLANEOUS↗
Calibration and Uncertainty Estimation Using the Ensemble Kalman Filter with a Large Subsurface Flow and Transport Model - 20321
At routinely monitored groundwater contamination sites, periodically measured environmental conditions such as groundwater levels and contaminant concentrations are used to inform and confirm a conceptual site model (CSM) and guide the development and calibration of a numerical groundwater flow and transport model. The calibration of groundwater flow and transport models after each measurement (sampling) event can illuminate deficiencies in a CSM, identify areas where additional monitoring is warranted, and predict the behavior of the system to guide decision making. However, manual and automated (e.g. PEST) model calibration tools can be time-consuming and computationally expensive to implement after each sampling event. Perhaps as a result, such calibration tools generally utilize all available monitoring data simultaneously rather than sequentially assimilating monitoring data one sampling event at a time as the results from sampling become available. A more real-time data assimilation approach may reduce parameter uncertainty, quantify the value of additional monitoring data, and produce a usable model more quickly and with less effort. To mitigate the potential time-consuming aspects of manual and widely applied automated calibration techniques, a data assimilation algorithm called the ensemble Kalman filter (EnKF) was evaluated as a relatively efficient method of model calibration and uncertainty assessment via the sequential integration of monitoring data into a model. The EnKF was able to successfully and efficiently assimilate monitoring and modeling data to calibrate a complex flow and transport model at a real-world site with significant subsurface heterogeneity, uncertainty, and 12 years of monitoring data (over 4,000 individual measurements of groundwater levels and over 2,500 measurements of contaminant concentrations). Starting with an uncalibrated model data from annual sampling events were sequentially assimilated, and the resultant predication errors and estimated parameter uncertainties were tracked. After all monitoring data were assimilated, both flow and transport residuals at the end of the EnKF process were comparable to those produced via a concurrent PEST calibration effort but required fewer model simulations. Both uncertainty and prediction errors decreased over time. In a real-time application, the adequacy of the model could be assessed after each sampling event. The benefits of such a real-time approach to utilizing monitoring data include reduced costs (in the form of model updates or site characterization efforts), early flagging of possible errors in the CSM, and a reduced risk of overfitting and corresponding increased confidence in model predictions. This tool may be particularly useful compared to other calibration techniques (e.g. manual, PEST) when model runtimes are long, calibration parameters are many, or parameter uncertainty is large. (authors)
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
Design of an AIM Network for Monitoring Carbon Storage Projects
Conference poster presented at Carbon Capture, Utilization, and Storage (CCUS) Conference 2024, Houston, Texas, March 11–13, 2024. The Energy & Environmental Research Center (EERC) is researching novel carbon storage-monitoring techniques at an approved North Dakota geologic carbon storage site. One of the research objectives is to design an autonomous, integrated, and modular (AIM) monitoring network that is compliant with monitoring requirements across multiple carbon capture and storage (CCS) policy frameworks, such as the U.S. Environmental Protection Agency’s (EPA) underground injection control (UIC) Class VI permitting program.
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Townsend’s Ground Squirrel Conservation on the Hanford Site for Calendar Year 2022: Translocation to Support At-Risk Ground Squirrel Populations
The U.S. Department of Energy, Richland Operations Office (DOE-RL) conducts ecological monitoring on the Hanford Site to collect and track data needed to ensure compliance with an array of environmental laws, regulations, and policies governing DOE-RL activities. Ecological monitoring data provide baseline information about the plants, animals, and habitat under DOE-RL stewardship at the Hanford Site required for accurate ecological impact assessment decision-making under the National Environmental Policy Act (NEPA) and Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). In addition, ecological monitoring helps ensure that DOE-RL, its contractors and other entities conducting activities on the Hanford Site are in compliance with the Hanford Site Comprehensive Land Use Plan (DOE/EIS-0222-F). DOE-RL places priority on monitoring those plant and animal species or habitats with specific regulatory protections or requirements; or that are rare and/or declining (federal or state listed endangered, threatened, or sensitive species); or of significant interest to federal, state, or tribal governments or the public.
54 ENVIRONMENTAL SCIENCES↗
Camera facing SW to monitor ocean from AERI at kcg:M1 (a1-level)
Camera facing SW to monitor ocean from AERI at kcg:M1
54 ENVIRONMENTAL SCIENCES↗
Camera facing NW to monitor ocean from AERI at kcg:M1 (a1-level)
Camera facing NW to monitor ocean from AERI at kcg:M1
54 ENVIRONMENTAL SCIENCES↗
Y-12 Groundwater Protection Program Monitoring Well Inspection and Maintenance Plan
This plan describes the systematic approach for: inspecting the physical condition of monitoring wells at Y-12, determining maintenance needs that extend the life of a well, and identifying those wells that no longer meet acceptable monitoring well design or well construction standards and require plugging and abandonment. The inspection and maintenance of groundwater monitoring wells is one of the primary management strategies of the Y-12 Groundwater Protection Program (GWPP) Management Plan, that is, the “proactive stewardship of the extensive monitoring well network at Y-12" (Consolidated Nuclear Security, L.L.C. [CNS], 2018). Effective stewardship, and a program of routine inspections of the physical condition of each monitoring well, ensures that representative water-quality samples and hydrologic data are obtained from the well network and protects the subsurface environment. In accordance with the Y-12 GWPP Monitoring Optimization Plan (MOP) for Groundwater Monitoring Wells at the Y-12 National Security Complex, Oak Ridge, Tennessee (CNS, 2017), the status designation (active or inactive) for each well determines the scope and extent of well inspections and maintenance activities. This plan, in conjunction with the above document, formalizes the GWPP approach to focus available resources on monitoring wells which provide the most useful data, and for that reason the GWPP inspects and performs maintenance on the wells sampled by the GWPP. This plan applies to groundwater monitoring wells installed at Y-12 and the related waste management facilities located within the three hydrogeologic regimes: (1) the Bear Creek Hydrogeologic Regime (Bear Creek Regime), (2) the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and (3) the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek Regime encompasses the section of Bear Creek Valley (BCV) immediately west of Y-12. The East Fork Regime encompasses most of the Y-12 process, operations, and support facilities in BCV west of Scarboro Road. The Chestnut Ridge Regime is directly south of Y-12 and encompasses a section of Chestnut Ridge that is bounded to the west by a surface drainage feature (Dunaway Branch, located immediately west of Industrial Landfill II) and by Scarboro Road to the east. The GWPP maintains an extensive database of geographic and construction details and related information for the monitoring wells in each hydrogeologic regime in the Updated Subsurface Database for Bear Creek Valley, Chestnut Ridge, and Parts of Bethel Valley on the U.S. DOE Oak Ridge Reservation (CNS, 2019). A detailed description of the hydrogeologic framework at Y-12 can be found in the GWPP Management Plan (CNS, 2018).
54 ENVIRONMENTAL SCIENCES↗
Hanford Site Freshwater Mussel Monitoring Report for Calendar Year 2022
The U.S. Department of Energy, Richland Operations Office (DOE-RL) conducts ecological monitoring on the Hanford Site to collect and maintain data needed to ensure compliance with an array of environmental laws, regulations, and policies governing DOE-RL activities. Ecological monitoring data provides baseline information about the plants, animals, and habitats under DOE-RL stewardship at the Hanford Site that is required for decision making under the National Environmental Policy Act of 1969 and Comprehensive Environmental Response, Compensation, and Liability Act of 1980. In addition, ecological monitoring helps ensure that DOE-RL, its contractors, and other entities conducting activities on the Hanford Site are in compliance with the Hanford Site Comprehensive Land Use Plan (DOE/EIS-0222-F). DOE-RL places priority on monitoring those plant and animal species or habitats with specific regulatory protections or requirements that are rare and/or declining (federal or state listed endangered, threatened, or sensitive species) or are of significant interest to federal, state, or tribal governments or the public.
54 ENVIRONMENTAL SCIENCES↗
Corrective Action Unit 98: Frenchman Flat Five-Year Evaluation Nevada National Security Site, Nevada (Revision 1)
The Corrective Action Unit (CAU) 98, Frenchman Flat (FF) Closure Report (CR) (NNSA/NFO, 2016) and its ensuing Records of Technical Change (ROTCs) (compiled in DOE/EMNV, 2019) required the U.S. Department of Energy (DOE), Environmental Management (EM) Nevada Program’s Underground Test Area (UGTA) Activity to collect data for five years to establish triggers for the monitoring network and analyze the monitoring points for viability in long-term monitoring. This document provides the results of the five-year evaluation and presents recommendations for future monitoring of CAU 98.
54 ENVIRONMENTAL SCIENCES↗
Absolute Band Intensity of the Iodine Monochloride Fundamental Mode for Infrared Sensing and Quantitative Analysis
Iodine monochloride (ICl) is a gaseous off-product of molten salt reactors; monitoring this heteronuclear diatomic is of great interest for both environmental and safety purposes. In this paper we investigate the possibility of infrared monitoring of ICl by measuring the far-infrared absorption cross section of its fundamental band near 381 cm -1 . We have performed quantitative studies of the neat gas in a 20 cm cell at 25, 35, 50 and 70 oC at multiple pressures up to ~ 9 Torr and investigated the temperature and pressure dependence of the band’s infrared cross section. Quantitative measurements were problematic due to sample adhesion to the cell walls and windows as well as reactions/possible hydrolysis of ICl to form HCl gas. Effects were mitigated by measuring only the neat gas, using short measurement times and subtracting out the partial pressure of the HCl(g). The integrated band strength is shown to be temperature independent and was found to be equal to 9.1 x 10 -19 (cm 2 /molecule) cm-1. As expected, the temperature dependence of the band profile showed only a small effect over this limited temperature range. Furthermore, we have also investigated using the absorption data along with inverse least squares multivariate methods for the quantitative monitoring of ICl effluent concentrations under different scenarios using infrared (standoff) sensing and compare these results with traditional Beer’s Law (univariate) techniques.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Hanford Reach Fall Chinook Salmon Redd Monitoring Report for Calendar Year 2024
The U.S. Department of Energy, Hanford Field Office (HFO) conducts ecological monitoring on the Hanford Site to collect and track data needed to ensure compliance with an array of environmental laws, regulations, and policies governing HFO activities. Ecological monitoring data provide baseline information about the plants, animals, and habitats under HFO stewardship at the Hanford Site required for decision making under the National Environmental Policy Act (NEPA) and Comprehensive Environmental Response, Compensation, and Liability Act. DOE/EIS-0222, Final Hanford Comprehensive Land-Use Plan Environmental Impact Statement, (CLUP) evaluates the potential environmental impacts associated with implementing a comprehensive land-use plan for the Hanford Site for at least the next 50 years, and ensures that HFO, its contractors, and other entities conduct activities on the Hanford Site in compliance with NEPA.
54 ENVIRONMENTAL SCIENCES↗
Hanford Reach Fall Chinook Salmon Redd Monitoring Report for Calendar Year 2023
The U.S. Department of Energy, Hanford Field Office (HFO) conducts ecological monitoring on the Hanford Site to collect and track data needed to ensure compliance with an array of environmental laws, regulations, and policies governing HFO activities. Ecological monitoring data provide baseline information about the plants, animals, and habitats under HFO stewardship at the Hanford Site required for decision making under the National Environmental Policy Act (NEPA) and Comprehensive Environmental Response, Compensation, and Liability Act. DOE/EIS-0222, Final Hanford Comprehensive Land-Use Plan Environmental Impact Statement, (CLUP) evaluates the potential environmental impacts associated with implementing a comprehensive land-use plan for the Hanford Site for at least the next 50 years, and ensures that HFO, its contractors, and other entities conduct activities on the Hanford Site in compliance with NEPA.
54 ENVIRONMENTAL SCIENCES↗
Hanford Site Roadside Bird Surveys Report for Calendar Years 2021-2023
The U.S. Department of Energy, Hanford Field Office (HFO) conducts ecological monitoring on the Hanford Site to collect and track data needed to ensure compliance with an array of environmental laws, regulations, and policies governing HFO activities. Ecological monitoring data provide baseline information about the plants, animals, and habitats under HFO stewardship at Hanford which is required for decision-making under the National Environmental Policy Act (NEPA) and Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). The Hanford Site Comprehensive Land Use Plan (CLUP, DOE/EIS-0222-F), which is the Environmental Impact Statement for Hanford Site activities, helps ensure that HFO, its contractors, and other entities conducting activities on the Hanford Site are in compliance with NEPA.
54 ENVIRONMENTAL SCIENCES↗
Adaptation to the dietary sugar D-tagatose via genome instability in polyploid Candida albicans cells
The opportunistic fungal pathogen Candida albicans undergoes an unusual parasexual cycle wherein diploid cells mate to form tetraploid cells that can generate genetically diverse progeny via a nonmeiotic program of chromosome loss. The genetic diversity afforded by parasex impacts clinically relevant features including drug resistance and virulence, and yet the factors influencing genome instability in C. albicans are not well defined. To understand how environmental cues impact genome instability, we monitored ploidy change following tetraploid cell growth in a panel of different carbon sources. We found that growth in one carbon source, D-tagatose, led to high levels of genomic instability and chromosome loss in tetraploid cells. This sugar is a stereoisomer of L-sorbose which was previously shown to promote karyotypic changes in C. albicans. However, while expression of the SOU1 gene enabled utilization of L-sorbose, overexpression of this gene did not promote growth in D-tagatose, indicating differences in assimilation of the two sugars. In addition, genome sequencing of multiple progenies recovered from D-tagatose cultures revealed increased relative copy numbers of chromosome 4, suggestive of chromosome-level regulation of D-tagatose metabolism. Together, these studies identify a novel environmental cue that induces genome instability in C. albicans, and further implicate chromosomal changes in supporting metabolic adaptation in this species.
59 BASIC BIOLOGICAL SCIENCES↗
Deep Neural Network Assisted Distributed Strain and Temperature Fiber Sensor System for Natural Gas Pipeline Monitoring
Natural gas pipeline integrity monitoring is crucial to detect potential leaks, find structural issues, and prevent environmental damage. This article presents a system of natural gas pipeline monitoring that uses a specialized double Brillouin peak sensing fiber along with the Brillouin optical time domain analysis (BOTDAs) technique. The calibrated sensing fiber coefficients for strain and temperature are 41.8 kHz/ με and 0.9 MHz/°C for peak 1; and 47.2 kHz/ με , and 1.11 MHz/°C for peak 2, respectively. Initially, lab tests were performed by installing a short section of double Brillouin peak fiber (DBPF) on a 1-in steel pipe under pressure up to 1000 per square inch (psi) at elevated temperatures. Simultaneous distributed measurements of temperature and pressure-induced hoop strain were successfully measured. Considering the long processing speed to extract Brillouin frequency shift (BFS), we employ a novel probabilistic deep neural network (PDNN) framework for rapid BFS prediction. Additionally, using the Finite Element Method, the effects of the pipeline pressure on hoop strain were modeled and compared to the experimental hoop strain under the same set of pipeline conditions. Finally, an actual 4-in outer diameter steel natural gas pipeline was used for pilot-scale tests, where hoop strain was measured at various pressure levels. Leaks were simulated to demonstrate accurate pipeline integrity monitoring. At an internal pipe pressure of 1000 psi, hoop strain of approximately 300 με was observed, and the sensitivity was calculated as 0.28 με /psi. The results of this pilot-scale study demonstrated that the system is capable of performing distributed monitoring sufficient to detect pipeline pressure and the presence of leaks to ensure the safe operation of gas pipelines in the field.
03 NATURAL GAS↗