Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “carbonyls”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

Mass spectrometry in structural and stereochemical problems. CXCIX.

Electron-impact induced fragmentations of o-, m-, and p-hydroxyalkylphenones and their trimethylsilyl (TMS) ethers are studied by means of high-resolution mass spectrometry, metastable defocusing, and deuterium labeling of the TMS ether derivatives. A markedly increased methyl radical loss from the o-TMS ether is attributed to a proximity effect. Minor fragmentation was observed with m- and p-isomers. Significantly intense doubly-charged ions were formed from ketonic cleavage and by the loss of a TMS methyl radical. The sequence of fragmentation was found to depend on the size of the alkyl group attached to the ketone carbonyl.

Smith, G. G.↗
NASA NTRS1973

Characteristics of capacitor-type micrometeoroid flux detectors when impacted with simulated micrometeoroids

A series of impact tests are described and data presented which characterize the operation of the capacitor-type micrometeoroid flux detectors used on the Meteoroid Technology Satellite (MTS). Capacitor-type detectors with silicon dioxide dielectric thickness of 0.4 and 1.0 microns were tested in the micrometeoroid impact simulator at the Langley Research Center, a 4-MV Van de Graaff electrostatic accelerator. The carbonyl iron projectiles were from 0.5 to 5.0 microns in diameter with velocities from 4 to 10.0 km/sec. The detector bias voltage was varied from -20 to -60 V; some tests were at detector temperatures of 90 C to -100 C; and the angle of impact varied from 0 deg to 75 deg from the normal to the detector. These tests showed that: (1) the detector operation is reliable when the bias voltage is greater than 30 V; (2) after an impact the detector returns to its original condition with an insignificant loss of active area; and (3) the sensitivity of the detector is inversely proportional to the detector thickness. The test results suggest a theoretical model in which the signal is an arc triggered by the impacting projectile, and the detector bias voltage must be high enough to insure that an arc will form.

Kassel, P. C., Jr.↗
NASA NTRS1974

The vapor pressure of iron pentacarbonyl

Vapor pressure measurements have been made on pure iron pentacarbonyl between +31 and -19 C. The experimental results may be expressed by the logarithm of pressure (mm Hg) to the base 10 equals -(2096.7 K/T) + 8.4959, which corresponds to a heat of vaporization for the liquid carbonyl of delta H ? (9.588 plus or minus 0.12) kcal/mole. This result confirms and extends the earlier measurements made by Trautz and Badstuebner between 0 and 140 C. The need for careful purification of commercially available iron pentacarbonyl is emphasized, particularly for establishing the correct vapor pressure below 45 C.

Gilbert, A. G.↗
NASA NTRS1974

A flash photolysis-resonance fluorescence kinetics study of the reaction S/3P/ + OCS

Using the technique of flash photolysis-resonance fluorescence, the reaction of ground-state atomic sulfur with carbonyl sulfide has been investigated over the temperature range from 233 to 445 K. Over this temperature range, the experimental data were fitted to an Arrhenius equation of the form k sub 1 = (1.52 plus or minus 0.20) x 10 to the minus 12th power exp(-3.63 plus or minus 0.12 kcal/mol/RT) cu cm/molecule/sec. A comparison of these results with previous investigations on this reaction system is presented.

Klemm, R. B.↗
NASA NTRS1973

Photochemistry of interstellar molecules

The role of photochemistry in determining the lifetime of interstellar molecules is considered. The probability of photodecomposition depends on three factors, including the absorption cross section, the quantum yield or probability of dissociation following photon absorption, and the interstellar radiation field. A more detailed discussion of the photochemistry of five molecules is presented, giving attention to carbonyl sulfide, methyl acetylene, nitric oxide, acetylene, and benzene. Lifetimes of interstellar molecules in unobscured regions are in the range from 5 to 100 years. It is concluded that polyatomic molecules can exist only in dense clouds which protect them from the full interstellar radiation field.

Stief, L. J.↗
NASA NTRS1975

Analytical study of spacecraft deposition contamination by internal reflection spectroscopy

The in-situ vacuum chamber designed around the IRE was tested under vacuum. The contamination analyzer system was tested using two liquid contaminant materials. The analysis of the contaminants on the SL-4 rendezvous window shows that the material has methyl silicone, hydroxyl, and carbonyl radicals. The analysis of the outgassing material from Shuttle TPS shows silicone as the primary product.

Mookherji, T. K.↗
NASA NTRS1977

New diamine hardeners for epoxies

Stronger amine-cured polyepoxides can be obtained by using those diaminobenzophenones and diaminodiphenylmethanes that have amine groups located at ortho or meta positions to carbonyl or methylene groups joining two benzene rings.

Bell, V. L.↗
NASA NTRS1975

PMR polyimides with improved high temperature performance

Studies were performed to investigate the effect of substituting a hexafluoro isopropyl idene connecting group for a carbonyl group of a PMR polyimide monomeric reactant on the thermo-mechanical properties processability of graphite fiber reinforced PMR polyimide composites. Composites were fabricated utilizing PMR methodology. Monomeric reactant solutions of various stoichiometric ratios were used to impregnate Hercules HTS graphite fiber. The processing characteristics and elevated temperature (600 F) mechanical properties of the composites are described.

Vannucci, R. D.↗
NASA NTRS1975

Research investigation of the physical interactions and phenomena associated with hypervelocity sub-micron particles

Signals from impact ionization plasmas were studied as a means of performing microparticle composition analysis. Impact ionization signal response was measured in a time-of-flight (TOF) system for lanthanum hexaboride, carbonyl iron, and aluminum microparticle impacts on a tantalum target, primarily in the 1 - 8 km/s velocity range. Oscilloscope photographs of representative ion TOF signal response are given for each material studied. Graphs and histograms are presented of the total charge collected as well as the charge collected in each observed ion mass group. Data show that ion signals consist primarily of the lower ionization potential elements over the 1 - 8 km/s range.

Roy, N. L.↗
NASA NTRS1979

Application of a coupled aerosol formation: Radiative transfer model to climatic studies of aerosols

A sophisticated one dimensional physical-chemical model of the formation and evolution of stratospheric aerosols was used to predict the size and number concentration of the stratospheric aerosols as functions of time and altitude following: a large volcanic eruption; increased addition of carbonyl sulfide (OCS) or sulfur dioxide (SO2) to the troposphere; increased supersonic aircraft (SST) flights in the stratosphere; and, large numbers of space shuttle (SS) flights through the stratosphere. A radiative-convective one dimensional climate sensitivity study, using the results of the aerosol formation model, was performed to assess the ground level climatic significance of these perturbations to the stratospheric aerosol layer. Volcanic eruptions and large OCS or SO2 increases could cause significant climatic changes. Currently projected SS launches and moderate fleets of SST's are unlikely to upset the stratospheric aerosol layer enough to significantly impact climate.

Toon, O. B.↗
NASA NTRS1979

Prebiotic coordination chemistry: The potential role of transition-metal complexes in the chemical evolution

In approaching the extremely involved and complex problem of the origin of life, consideration of the coordination chemistry appeared not only as a possibility but as a necessity. The first model experiments appear to be promising because of prebiotic-type synthesis by means of transition-metal complexes. It is especially significant that in some instances various types of vitally important substances (nucleic bases, amino acids) are formed simultaneously. There is ground to hope that systematic studies in this field will clarify the role of transition-metal complexes in the organizatorial phase of chemical evolution. It is obvious that researchers working in the fields of the chemistry of cyano and carbonyl complexes, and of the catalytic effect of transition-metal complexes are best suited to study these aspects of the attractive and interesting problem of the origin of life.

Beck, M.↗
NASA NTRS1979

COS in the stratosphere

Carbonyl sulfide (COS) has been detected in the stratosphere, and mixing ratio measurements are reported for altitudes of 15.2 to 31.2 km. A large volume, cryogenic sampling system mounted on board a U-2 aircraft has been used for lower stratosphere measurements and a balloon platform for measurement at 31.2 km. These observations and measurements strongly support the concept that stratospheric COS is an important precursor in the formation of sulfuric acid aerosols.

Inn, E. C. Y.↗
NASA NTRS1978

Measurement requirements and techniques for degradation studies and lifetime prediction testing of photovoltaic modules

Tests of weathering and aging behavior are being developed to characterize the degradation and predict the lifetimes of low-cost photovoltaic arrays. Environmental factors which affect array performance include UV radiation, thermal energy, water, oxygen (generally involved in synergistic effects with UV radiation or high temperatures), physical stress, pollutants (oxides of nitrogen, sulfur dioxide and ozone), abrasives and dirt. A survey of photovoltaic array testing has shown the need to establish quantitative correlations between certain measurable properties (carbonyl formation, glass transition temperature, and molecular weight change) and modes of degradation and failure.

Noel, G. T.↗
NASA NTRS1979

The 4-8 micron spectrum of the infrared source W33 A

The spectrum of the highly obscured infrared source W33 A from 4.5 to 8 microns is measured in order to investigate the intervening cold, dense interstellar material. Spectrophotometry at a relative spectral resolution of about 0.015 by an airborne filter-wheel infrared spectrometer reveals strong absorption features at 4.61, 5.99 and 6.78 microns. The absorption at 4.61 microns is attributed primarily to the fundamental vibration-rotation band of CO at a column density (at least 10 to the 19th/sq cm) which is 10% of the carbon inferred from silicate abundances. The strengths and line widths of the absorption agt 5.99 and 6.78 microns are interpreted as evidence of absorption in the resonance bands of carbonyl, carbon-carbon double, methyl and methylene bonds of hydrocarbons associated with interstellar dust.

Soifer, B. T.↗
NASA NTRS1979

Method of purifying metallurgical grade silicon employing reduced pressure atmospheric control

A method in which a quartz tube is charged with chunks of metallurgical grade silicon and/or a mixture of such chunks and high purity quartz sand, and impurities from a class including aluminum, boron, as well as certain transition metals including nickel, iron, and manganese is described. The tube is then evacuated and heated to a temperature within a range of 800 C to 1400 C. A stream of gas comprising a reactant, such as silicon tetrafluoride, is continuously delivered at low pressures through the charge for causing a metathetical reaction of impurities of the silicon and the reactant to occur for forming a volatile halide and leaving a residue of silicon of an improved purity. The reactant which included carbon monoxide gas and impurities such as iron and nickel react to form volatile carbonyls.

Ingle, W. M.↗
NASA NTRS1980

The stratospheric sulfate aerosol layer - Processes, models, observations, and simulations

After briefly reviewing the observational data on the stratospheric sulfate aerosol layer, the chemical and physical processes that are likely to fix the properties of the layer are discussed. We present appropriate continuity equations for aerosol particles, and show how to solve the equations on a digital computer. Simulations of the unperturbed aerosol layer by various published models are discussed and the sensitivity of layer characteristics to variations in several aerosol model parameters is studied. We discuss model applications to anthropogenic pollution problems and demonstrate that moderate levels of aerospace activity (supersonic transport and Space Shuttle operations) will probably have only a negligible effect on global climate. Finally, we evaluate the possible climatic effect of a ten-fold increase in the atmospheric abundance of carbonyl sulfide.

Whitten, R. C.↗
NASA NTRS1981

Gaseous constituents in the plume from eruptions of Mount St. Helens

Measurements in the stratosphere of gaseous constituents in the plume of Mount St. Helens were obtained during five flights of the NASA U-2 aircraft between 19 May and 17 June 1980. Mixing ratios from gas chromatographic measurements on samples acquired about 24 hours after the initial eruption show considerable enhancement over nonvolcanic concentrations for sulfur dioxide (more than 1000 times), methyl chloride (about 10 times), and carbon disulfide (more than 3 times). The mixing ratio of carbonyl sulfide was comparable to nonvolcanic mixing ratios although 3 days later it was enhanced two to three times. Ion chromatography measurements on water-soluble constituents are also reported. Very large concentrations of chloride, nitrate, and sulfate ions were measured, implying large mixing ratios for the water-soluble gaseous constituents from which the anions are derived. Measurements of radon-222 present in the plume are also reported.

Inn, E. C. Y.↗
NASA NTRS1982

Rate constant for the reaction between OH and CS2 at 298 and 520 K

In an attempt to resolve discrepancies between published values of the rate constant for the reaction between the hydroxyl radical and carbon disulfide, the reaction has been studied in a discharge flow system by using resonance fluorescence for kinetic measurements and mass spectrometry for product analysis. On the basis of the measured rate constant for disappearance of OH, and measurements of the amount of carbonyl sulfide formed, it was estimated that for the reaction HO + CS2 yields HS + OCS, rate constant values are not greater than 3 x 10 to the -15th/cu cm per sec at 520 K and not greater than 7 x 10 to the -15th/cu cm per sec at 298 K, upper limits are specified because of the inability to isolate exclusively this reaction channel, and because of possible involvement of wall reactions. These results confirm the low values found for this rate constant in two very recent studies.

Leu, M.-T.↗