Reduction and analysis of data from OGO-4 experiment 15 Final report, 1 Nov. 1969 - 30 Nov. 1970
Procedures for processing atmospheric composition data obtained through use of sweeping quadrupole mass spectrometer on OGO-4 satellite
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Procedures for processing atmospheric composition data obtained through use of sweeping quadrupole mass spectrometer on OGO-4 satellite
Discussion of the opportunity that the new wide-bodied commercial jet aircraft hold forth as platforms for a global monitoring system that could provide the atmospheric baseline and tropical meteorological data for which there is a pressing need. It is argued that there is no immutable technological impediment to the implementation of such a monitoring program, and that its realization could enhance our knowledge of atmospheric processes at an enormous saving in costs.
A small parameter model of circulation in a homogeneous baroclinic ocean is presented. The principles common to the construction of small parameter models and certain energetic principles developed in connection with atmospheric processes are made use of. These principles were applied in the study of processes in a baroclinic ocean.
The use of active microwave systems to study atmospheric phenomena is studied. Atmospheric pollution, weather prediction, climate and weather modification, weather danger and disaster warning, and atmospheric processes and interactions are covered.
Tests of the ability of numerical general circulation models to simulate the atmosphere have focussed so far on simulations of the January climatology. These models generally present boundary conditions such as sea surface temperature, but this does not prevent testing their ability to simulate seasonal changes in atmospheric processes that accompany presented seasonal changes in boundary conditions. Experiments to simulate changes in the zonally averaged heat balance are discussed since many simplified models of climatic processes are based solely on this balance.
A tutoral background of radar capabilities and its potential for insect research is provided. The basic principles and concepts of radar were reviewed. Information on current radar equipment was examined. Specific issues related to insect research included; target cross-section, radar frequency, tracking target recognition and false alarms, clutter reduction, radar transmitter power, and ascertained atmospheric processes.
A discussion of freshwater and marine systems is presented including areas of the classification of lakes, identification and quantification of major functional groups of phytoplankton, sources and sinks of biochemical factors, and temporal and regional variability of surface features. Atmospheric processes linked to hydrospheric process through the transfer of matter via aerosols and gases are discussed. Particle fluxes to the aquatic environment and global geochemical problems are examined.
Experimental methods in planetary astronomy are discussed using a comparison of the advantages and disadvantages in the astronomical methods of ground based, Earth-orbit, and deep space missions. Problem areas in planetary astronomy which demonstrate the utility and power of the space telescope (ST) over other methods are delineated. These include utilizing the ST for studying the atmospheric dynamics, stratospheric and upper atmospheric processes, and circumplanetary nebulae of the planets. The capability of the ST for solar system observations is summarized with a discussion of the increases in resolution and sensitivity of the ST over other Earth-orbiting telescopes highlighted.
The paper describes an experimental study of the title reaction that uses the discharge-flow technique, laser-induced-fluorescence detection of OH and simultaneous monitoring of O and H atoms in the 250-459 K range. The reaction is normal and free from surface effect interference in Teflon or halocarbon wax-coated tube, but not in clean Pyrex. OH radicals are generated in three ways and at low concentrations to eliminate side reactions. The rate constants were determined at 298 K and over the 250-459 K range, with a factor of two higher at 298 K and factors of 3 to 5 higher at 10 to 30 km altitude in the terrestrial atmosphere than previous studies have indicated. The effect of the higher rate constant on atmospheric processes and on recent laboratory measurements of other reactions is also discussed.
Progress in the study of the intensity of the urban heat island is reported. The intensity of the heat island is commonly defined as the temperature difference between the center of the city and the surrounding suburban and rural regions. The intensity is considered as a function of changes in the season and changes in meteorological conditions in order to derive various parameters which may be used in numerical models for urban climate. Twelve case studies were selected and CCT's were ordered. In situ data was obtained from sixteen stations scattered about the city of St. Louis. Upper-air meteorological data were obtained and the water vapor and the temperature data were processed. Atmospheric transmissivities were computed for each of the case studies.
To examine chemical transformation within stagnant air masses and the atmospheric processes acting upon such air masses, the United States EPA sponsored a study in the summer of 1980 in the northeastern region of the country. Ten research aircraft and several mobile and stationary surface monitoring platforms participated in an intensive measurement program between 16 July and 15 August 1980. Pollutants of interest included SO2, NO, NO(x), HC, O3, sulfate, nitrate, and aerosols in general. This paper summarizes the activities of these research aircraft. Three aircraft and one helicopter logged a total of 353 flight hours during 100 missions in the program. The flight patterns and data collected for each mission are documented. This summary will allow scientists who are interested in this data base to identify subsets of the data for model development.
A description is presented of the first application of an airborne optical radar (lidar) to measurements of ozone and aerosol profiles in regional and global tropospheric investigations. It is pointed out that high spatial resolution measurements of ozone and aerosols are important in studying the relative contribution of chemistry and transport in large scale atmospheric processes. The investigation makes use of an airborne differential absorption optical radar system, which has been developed for the remote profiling of O3 and aerosols in the troposphere. Attention is given to lower tropospheric measurements and upper tropospheric measurements. The obtained results demonstrate the capability of the considered system to measure O3 and aerosol profiles in the troposphere and lower stratosphere.
The new edition of the AFGL trace gas compilation is described. The latest version provides the necessary parameters for the computation of absorption or emission spectra of major bands of twenty-one gases in the region from 0 to 10,000 per cm. Emphasis in this edition has been on the addition of numerous millimeter and submillimeter transitions, the inclusion of bands of significance in upper atmospheric processes, and strong IR bands of trace constituents likely to be used for remote detection. The sources for the additions and modifications of the absorption parameters are summarized.
A series of cosmic ray neutron monitor data which were used in three analyses: (1) solar activity influence on ionization of the upper troposphere and tropopause; (2) solar activity influence on Canadian high stratus in winter; and (3) the S3-4 satellite study of IMF/GMF magnetic coupling effects are reported. The magnetic coupling model of solar activity influence on atmospheric processes were investigated. The magnetic coupling model is used to explain a number of seemingly diverse studies lightning incidence is emphasized.
The near-zero G environment of Spacelab is the basis of a true spherical experimental model of synoptic scale baroclinic atmospheric processes, using a radial dielectric body force analogous to gravity over a volume of liquid within two concentric spheres. The baroclinic motions are generated by corotating the spheres and imposing thermal boundary conditions, such that the liquid is subjected to a stable radial gradient and a latitudinal gradient. Owing to mathematical difficulties associated with the spherical geometry, quantitative design criteria can be acquired only by means of numerical models. The procedure adopted required the development of two computer codes based on the Navier-Stokes equations. The codes, of which the first calculates axisymmetric steady flow solutions and the second determines the growth or decay rates of linear wave perturbations with different wave numbers, are combined to generate marginal stability curves.
There have been major efforts in measuring extraterrestrial solar irradiance for use in atmospheric studies. The quantity of immediate relevance to theoretical studies is the number of photons which reach a given altitude in the middle atmosphere. Current models compute the attenuated radiation field but the cross sections available for the major absorbers, O2 and O3, often come from experiments that are now quite old. Balloon measurements show some significant differences between the predicted and observed ultraviolet radiation field between 30 and 40 km. The wavelength region to be studied includes Lyman alpha plus the range 175 nm to the visible. Specific topics to be addressed are as follows: (1) the cross sections of the major absorbers, O2 and O3 including the Schumann-Runge bands as a subset; (2) comparison of the in situ measurements of the attenuated radiation field with calculations; and (3) the relevance of the scattered and reflected radiation fields for middle atmospheric processes.
Eight doublet and eight quartet states of ClOO were investigated by ab initio CI techniques. The potential energy surfaces of the four lowest energy doublet states of both A-double-prime and A-prime symmetry indicate that only the 1 2A-double-prime state is bound. In contrast to the model provided by the HO2 radical, all of the excited doublet states investigated were repulsive with respect to dissociation to Cl + O2 and metastable or bound with respect to dissociation to ClO + O. The transitions to the excited states investigated span the visible and near UV spectral regions, but the transition moments indicate that they are very weak. Since the photolysis products are the same as those of the rapid thermal dissociation, photolysis is not expected to be an important atmospheric process. The soft bending potential for the 1 2A-prime state and the shape of the 1 4A-double-prime state in the entrance channel of the ClO + O yields Cl + O2 reaction provide a qualitative explanation for the underprediction of the low temperature reaction rate by previous trajectory calculations.
This paper reports the first results of an experimental program established to provide cross section data for use in modeling various atmospheric processes. Absolute cross sections, differential in the scattering angle, have been measured for collisions of 0.5-, 1.5-, and 5.0-keV helium atoms with He, H2, N2, and O2 at laboratory scattering angles between 0.1 deg and 5 deg. The results are the sums of cross sections for elastic and inelastic scattering of helium atoms; charged collision products are not detected. Integration of the differential cross section data yields integral cross sections consistent with measurements by other workers. The apparatus employs a position-sensitive detector for both primary and scattered particles and uses a short target cell with a large exit aperture to ensure a simple and well-defined apparatus geometry.