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NASA NTRS2002

A geostatistical analysis of small-scale spatial variability in bacterial abundance and community structure in salt marsh creek bank sediments

Small-scale variations in bacterial abundance and community structure were examined in salt marsh sediments from Virginia's eastern shore. Samples were collected at 5 cm intervals (horizontally) along a 50 cm elevation gradient, over a 215 cm horizontal transect. For each sample, bacterial abundance was determined using acridine orange direct counts and community structure was analyzed using randomly amplified polymorphic DNA fingerprinting of whole-community DNA extracts. A geostatistical analysis was used to determine the degree of spatial autocorrelation among the samples, for each variable and each direction (horizontal and vertical). The proportion of variance in bacterial abundance that could be accounted for by the spatial model was quite high (vertical: 60%, horizontal: 73%); significant autocorrelation was found among samples separated by 25 cm in the vertical direction and up to 115 cm horizontally. In contrast, most of the variability in community structure was not accounted for by simply considering the spatial separation of samples (vertical: 11%, horizontal: 22%), and must reflect variability from other parameters (e.g., variation at other spatial scales, experimental error, or environmental heterogeneity). Microbial community patch size based upon overall similarity in community structure varied between 17 cm (vertical) and 35 cm (horizontal). Overall, variability due to horizontal position (distance from the creek bank) was much smaller than that due to vertical position (elevation) for both community properties assayed. This suggests that processes more correlated with elevation (e.g., drainage and redox potential) vary at a smaller scale (therefore producing smaller patch sizes) than processes controlled by distance from the creek bank. c2002 Federation of European Microbiological Societies. Published by Elsevier Science B.V. All rights reserved.

Non-NASA Center↗
NASA NTRS2004

Fossil Signatures Using Elemental Abundance Distributions and Bayesian Probabilistic Classification

Elemental abundances (C6, N7, O8, Na11, Mg12, Al3, P15, S16, Cl17, K19, Ca20, Ti22, Mn25, Fe26, and Ni28) were obtained for a set of terrestrial fossils and the rock matrix surrounding them. Principal Component Analysis extracted five factors accounting for the 92.5% of the data variance, i.e. information content, of the elemental abundance data. Hierarchical Cluster Analysis provided unsupervised sample classification distinguishing fossil from matrix samples on the basis of either raw abundances or PCA input that agreed strongly with visual classification. A stochastic, non-linear Artificial Neural Network produced a Bayesian probability of correct sample classification. The results provide a quantitative probabilistic methodology for discriminating terrestrial fossils from the surrounding rock matrix using chemical information. To demonstrate the applicability of these techniques to the assessment of meteoritic samples or in situ extraterrestrial exploration, we present preliminary data on samples of the Orgueil meteorite. In both systems an elemental signature produces target classification decisions remarkably consistent with morphological classification by a human expert using only structural (visual) information. We discuss the possibility of implementing a complexity analysis metric capable of automating certain image analysis and pattern recognition abilities of the human eye using low magnification optical microscopy images and discuss the extension of this technique across multiple scales.

Hoover, Richard B.↗
NASA NTRS2005

Distribution and Abundance of Mars' Atmospheric Argon

One and one half Mars years (MY 26 and 27) of atmospheric Argon measurements are described and studied in the context of understanding how Argon, a minor constituent of Mars atmosphere that does not condense at Mars temperatures, can be used to study martian circulation and dynamics. Argon data are from the 2001 Mars Odyssey Gamma Subsystem (GS) of the suite of three instruments comprising the Gamma Ray Spectrometer (GRS). A comprehensive data analysis including gamma-ray production and attenuation by the atmosphere is included. Of particular interest is the enhanced abundance of Ar over the observed Ar abundance at lower latitudes at south (up to a factor of 10) and north (up to a factor of 4) polar regions during winter. Calibration of the measurements to actual Ar abundance is possible because GS measurements cover the same latitude and season as measurements made by the gas chromatograph mass spectrometer (GCMS) on Viking Landers 1 and 2 (VL1 and VL2). [2].

Sprague, A. L.↗
NASA NTRS2005

How Does Abundance Affect the Strength of UV Emission in Elliptical Galaxies?

This program used the Far Ultraviolet Spectroscopic Explorer (FUSE) to observe elliptical galaxies with the intention of measuring the chemical abundances in their hot stellar populations. It was designed to complement an earlier FUSE program that observed elliptical galaxies with strong UV emission. The current program originally planned observations of two ellipticals with weak UV emission (M32 and M49). Once FUSE encountered pointing control problems in certain regions of the sky (particularly Virgo, which is very unfortunate for the study of ellipticals in general), M49 was replaced with the bulge of M31, which has a similar UV-to-optical flux ratio as the center of M49. As the closest elliptical galaxy and the one with the weakest UV-to-optical flux ratio, M32 was an obvious choice of target, but M49 was the ideal complementary target, because it has a very low reddening (unlike M32). With the inability of FUSE to point at Virgo, nearly all of the best elliptical galaxies (bright galaxies with low foreground extinction) were also lost, and this severely hampered three FUSE programs of the PI, all focused on the hot stellar populations of ellipticals. M31 was the best replacement for M49, but like M32, it suffers from significant foreground reddening. Strong Galactic ISM lines heavily contaminate the FUSE spectra of M31 and M32. These ISM lines are coincident with the photospheric lines from the stellar populations (whereas M49, with little foreground ISM and significant redshift, would not have suffered from this problem). We have reduced the faint (and thus difficult) data for M31 and M32, producing final co-added spectra representing all of the exposures, but we have not yet finished our analysis, due to the complication of the contaminating ISM. The silver lining here is the set of CHI lines at 1175 Angstroms, which are not significantly contaminated by the ISM. A comparison of the M31 spectrum with other galaxies observed by FEE showed a surprising result: the hot stars in M31 seem to have a similar carbon abundance to those stars in galaxies with much brighter UV emission. The fraction of these hot stars in a population should be a strong function of chemical abundances, so this finding warrants further exploration, and we are proceeding with our analysis. Because the UV emission in these galaxies comes from a population of extreme horizontal branch stars, the PI (Brown) presented this result at a June 2003 conference on such stars.

Sonneborn, George↗
NASA NTRS2007

Stellar Evolutionary Effects on the Abundance of PAHS and SN-Condensed Dust in Galaxies

Spectral aid photometric observations of nearby galaxies show a correlation between the strength of their mid-IR aromatic features and their metal abundance, and a deficiency of these features in low-metallicity galaxies. The aromatic features are most commonly attributed to emission from PAH molecules. In this paper, we suggest that the observed correlation represents a trend of PAH abundance with galactic age, reflecting the delayed injection of PAHs and carbon dust into the ISM, by AGB stars in their final, post-AGB phase of their evolution. These AGB stars are the primary sources of PAHs and carbon dust in galaxies, and recycle their ejecta back to the interstellar medium only after a few hundred million years of evolution on the main sequence. In contrast, more massive stars that explode as Type II supernovae inject their metals and dust almost instantaneously after their formation. After determining the PAH abundances in 35 nearby galaxies, we use a chemical evolution model to show that the delayed injection of carbon dust by AGB stars provides a natural explanation to the dependence of the PAH content, in galaxies with metallicity. We also show that larger dust particles giving rise to the far-IR emission follow a distinct evolutionary trend closely related to the injection of dust by massive stars into the ISM.

Dwek, Eli↗
NASA NTRS2006

On the Discovery of CO Nighttime Emissions on Titan by Cassini/VIMS: Derived Stratospheric Abundances and Geological Implications

We present a quantitative analysis of CO thermal emissions discovered on the nightside of Titan by Baines et al. [2005. The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/VIMS. Earth, Moon, and Planets, 96, 119-147] in Cassini/VIMS spectral imagery. We identify these emission features as the P and R branches of the 1-0 vibrational band of carbon monoxide (CO) near 4.65 microns. For CH3D, the prominent Q branch of the nu(2) fundamental band of CH3D near 4.55 microns is apparent. CO2 emissions from the strong nu(3) vibrational band are virtually absent, indicating a CO2 abundance several orders of magnitude less than CO, in agreement with previous investigations. Analysis of CO emission spectra obtained over a variety of altitudes on Titan's nightside limb indicates that the stratospheric abundance of CO is 32 +/- 15 ppm, and together with other recent determinations, suggests a vertical distribution of CO nearly constant at this value from the surface throughout the troposphere to at least the stratopause near 300 km altitude. The corresponding total atmospheric content of CO in Titan is similar to 2.9 +/- 1.5 x 10(exp 14) kg. Given the long lifetime of CO in the oxygen-poor Titan atmosphere (similar to 0.5-1.0 Gyr), we find a mean CO atmospheric production rate of 6 +/- 3 x 10(exp 5) kg yr(exp -1). Given the lack of primordial heavy noble gases observed by Huygens [Niemann et al., 2005. The abundances of constituents of Titan's atmosphere from the GCMS on the Huygens probe. Nature, 438, 779-784], the primary source of atmospheric CO is likely surface emissions. The implied CO/CH4 mixing ratio of near-surface material is 1.8 +/- 0.9 x 10(exp -4), based on an average methane surface emission rate over the past 0.5 Gyr of 1.3 x 10(exp -13) gm cm(exp -2) s(exp -1) as required to balance hydrocarbon haze production via methane photolysis [Wilson and Atreya, 2004. Current state of modeling the photochemistry of Titan's mutually dependent atmosphere and ionosphere. J. Geophys. Res. 109, E06002 Doi: 10.1029/2003JE002181]. This low CO/CH4 ratio is much lower than expected for the sub-nebular formation region of Titan and supports the hypothesis [e.g., Atreya et al., 2005. Methane on Titan: photochemical-meteorological-hydrogeochemical cycle. Bull. Am. Astron. Soc. 37, 735] that the conversion of primordial CO and other carbon-bearing materials into CH4-enriched clathrate-hydrates occurs within the deep interior of Titan via the release of hydrogen through the serpentinization process followed by Fischer-Tropsch catalysis. The time-averaged predicted emission rate of methane-rich surface materials is approximately 0.02 km(exp 3) yr (exp -1), a value significantly lower than the rate of silicate lava production for the Earth and Venus, but nonetheless indicative of significant geological processes reshaping the surface of Titan.

carbon compounds↗
NASA NTRS2009

Chlorine Abundances in Martian Meteorites

Chlorine measurements made in martian surface rocks by robotic spacecraft typically give Chlorine (Cl) abundances of approximately 0.1-0.8%. In contrast, Cl abundances in martian meteorites appear lower, although data is limited, and martian nakhlites were also subjected to Cl contamination by Mars surface brines. Chlorine abundances reported by one lab for whole rock (WR) samples of Shergotty, ALH77005, and EET79001 range 108-14 ppm, whereas Cl in nakhlites range 73-1900 ppm. Measurements of Cl in various martian weathering phases of nakhlites varied 0.04-4.7% and reveal significant concentration of Cl by martian brines Martian meteorites contain much lower Chlorine than those measured in martian surface rocks and give further confirmation that Cl in these surface rocks was introduced by brines and weathering. It has been argued that Cl is twice as effective as water in lowering the melting point and promoting melting at shallower martian depths, and that significant Cl in the shergottite source region would negate any need for significant water. However, this conclusion was based on experiments that utilized Cl concentrations more analogous to martian surface rocks than to shergottite meteorites, and may not be applicable to shergottites.

Bogard, D.D.↗
NASA NTRS2010

Particle Size and Abundance of HC3N Ice in Titan's Lower Stratosphere at High Northern Latitudes

Up to now, there has been no corroboration from Cassini CIRS of the Voyager IRIS-discovery of cyanoacetylene (HC3N) ice in Titan's thermal infrared spectrum. We report the first compelling spectral evidence from CIRS for the v6 HC3N ice feature at 506 per centimeter at latitudes 62 deg. N and 70 deg. N, from which we derive particle sizes and column abundances in Titan's lower stratosphere. We find mean particle radii of 3.0 micrometers and 2.3 micrometers for condensed HC3N at 62 deg. N and 70 deg. N, respectively, and corresponding ice phase molecular column abundances in the range 1-10 x 10(exp 16) mol per square centimeter. Only upper limits for cloud abundances can be established at latitudes of 85 deg. N, 55 deg. N, 30 deg. N, 10 deg. N, and 15 deg. S. Under the assumption that cloud tops coincide with the uppermost levels at which HC3N vapor saturates, we infer geometric thicknesses for the clouds equivalent to 10-20 km or so, with tops at 165 km and 150 km at 70 deg. N and 62 Deg. N, respectively.

Anderson, C. M.↗
NASA NTRS2011

Temporal Variability of Ion Acceleration and Abundances in Solar Flares

Solar flares accelerate both ions and electrons to high energies, and their X-ray and gamma-ray signatures not only probe the relationship between their respective acceleration, but also allow for the measurement of accelerated and ambient abundances. RHESSI observations have shown a striking close linear correlation of gamma-ray line fluence from accelerated ions greater than approximately 20 MeV and bremsstrahlung emission from relativistic accelerated electrons greater than 300 keV, when integrated over complete flares, suggesting a common acceleration mechanism. SMM/GRS observations, however, show a weaker correlation, and this discrepancy might be associated with previously observed electron-rich episodes within flares and/or temporal variability of gamma-ray line fluxes over the course of flares. We use the latest RHESSI gamma-ray analysis techniques to study the temporal behavior of the RHESSI flares, and determine what changes can be attributed to an evolving acceleration mechanism or to evolving abundances. We also discuss possible explanations for changing abundances.

Shih, Albert↗
NASA NTRS2011

Iron Abundance in the Prototype PG 1159 Star, GW Vir Pulsator PG 1159-035, and Related Objects

We performed an iron abundance determination of the hot, hydrogen deficient post-AGB star PG 1159-035. which is the prototype of the PG 1159 spectral class and the GW Vir pulsators, and of two related objects (PG 1520+525, PG 1144+005), based on the first detection of Fe VIII lines in stellar photospheres. In another PG 1159 star. PG 1424+535. we detect Fe VII lines. In all four stars, each within T(sub eff) = 110,000-150,000 K, we find a solar iron abundance. This result agrees with our recent abundance analysis of the hottest PG 1159 stars (T(sub eff) = 150,000-200,000 K) that exhibit Fe x lines. On the whole, we find that the PG 1159 stars are not significantly iron deficient, in contrast to previous notions.

Werner, K.↗
NASA NTRS2012

Derivation of FEO Abundances in Lunar Pyroclastic Deposits Using Diviner

Telescopic observations and orbital images of the Moon reveal at least 75 lunar pyroclastic deposits (LPDs), interpreted as the products of explosive volcanic eruptions [1]. The deposits are understood to be composed primarily of sub-millimeter beads of basaltic composition, ranging from glassy to partially-crystallized [2]. Delano [3] documented 25 distinct pyroclastic bead compositions in lunar soil samples, with a range of FeO abundances from 16.5 - 24.7 wt%. Green glasses generally have lower FeO abundances and red, yellow, and orange glasses generally have higher FeO abundances. The current study employs data from the Diviner Lunar Radiometer Experiment onboard the Lunar Reconnaissance Orbiter (LRO) to derive the FeO compositions of glasses from unsampled lunar pyroclastic deposits. The pyroclastic glasses are the deepest-sourced and most primitive basalts on the Moon [4]. Recent analyses have documented the presence of water in these glasses, demonstrating that the lunar interior is considerably more volatile-rich than previously understood [5]. Experiments have shown that the iron-rich pyroclastic glasses release the highest percentage of oxygen of any Apollo soils, making these deposits promising lunar resources [6].

Allen, Carlton C.↗
NASA NTRS2012

Temporal Variability of Ion Acceleration and Abundances in Solar Flares

solar flares accelerate both ions and electrons to high energies, and their x-ray and gamma-ray signatures not only probe the relationship between their respective acceleration, but also allow for the measurement of accelerated and ambient abundances. RHESSI observations have shown a striking close linear correlation of gamma-ray line fluence from accelerated ions > approx 20 MeV and bremsstrahlung emission from relativistic accelerated electrons >300 kev, when integrated over complete flares, suggesting a common acceleration mechanism. SMM/GRS observations, however, show a weaker correlation, and this discrepancy might be associated with previously observed electron-rich episodes within flares and/or temporal variability of gamma-ray line fluxes over the course of flares. We use the latest RHESSI gamma-ray analysis techniques to study the temporal behavior of the RHESSI flares, and determine what changes can be attributed to an evolving acceleration mechanism or to evolving abundances. We also discuss possible explanations for changing abundances.

Shih, Albert Y.↗
NASA NTRS2012

An In-Depth Study of the Abundance Pattern in the Hot Interstellar Medium in NGC 4649

We present our X-ray imaging spectroscopic analysis of data from deep Suzuku and XMM-Newton Observatory exposures of the Virgo Cluster elliptical galaxy NGC 4649 (M60), focusing on the abundance pattern in the hot interstellar medium (ISM). All measured elements show a radial decline in abundance, with the possible exception of O. We construct steady state solutions to the chemical evolution equations that include infall in addition to stellar mass return and SNIa enrichment, and consider recently published SNIa yields. By adjusting a single model parameter to obtain a match to the global abundance pattern in NGC 4649 we infer that accretion of subsolar metallicity external gas has reduced the overall ISM metallicity and diluted the effectiveness of SNIa to skew the pattern towards low alpha/Fe ratios, and estimate the combination of SNIa rate and level of dilution. Evidently, newly-introduced gas is heated as it is integrated into. and interacts with, the hot gas that is already present. These results indicate a complex flow and enrichment history for NGC 4649, reflecting the continual evolution of elliptical galaxies beyond the formation epoch. The heating and circulation of accreted gas may help reconcile this dynamic history with the mostly passive evolution of elliptical stellar populations. In an appendix we examine the effects of the recent updated atomic database AtomDB in spectral fitting of thermal plasmas with hot ISM temperatures in the elliptical galaxy range.

Lowenstein, Michael↗
NASA NTRS2012

Characterizing Abundances of Volatiles in Comets Through Multiwavelength Observations

Recently, there have been complimentary observations from multiple facilities to try to unravel the chemical complexity of comets. Incorporating results from various techniques, including: single-dish millimeter wavelength observations, interferometers, and/or IR spectroscopy, one can gain further insight into the abundances, production rates, distributions, and formation mechanisms of molecules in these objects [I]. Such studies have provided great detail towards molecules with a-typical chemistries, such as H2CO [2]. We report spectral observations of C/2007 N3 (Lulin), C/2009 R1 (McNaught), 103P/Hartley 2, and C/2009 P1 (Garradd) with the Arizona Radio Observatory's SMT and 12-m telescopes, as well as the NRAO Greenbank telescope and IRTF-CSHELL. Multiple parent volatiles (HCN, CH3OH, CO, CH4, C2H6, and H2O) as well as a number of daughter products (CS and OH) have been detected in these objects. We will present a comparison of molecular abundances in these comets to those observed in others, supporting a long-term effort of building a comet taxonomy based on composition. Previous work has revealed a range of abundances of parent species (from "organics-poor" to "organics-rich") with respect to water among comets [3,4,5], however the statistics are still poorly constrained and interpretations of the observed compositional diversity are uncertain. We gratefully acknowledge support from the NSF Astronomy and Astrophysics Program, the NASA Planetary Astronomy Program, NASA Planetary Atmospheres Program, and the NASA Astrobiology Program.

Milam, Stefanie N.↗
NASA NTRS2012

Interstellar Abundances Toward X Per, Revisited

The nearby X-ray binary X Per (HD 24534) provides a useful beacon with which to measure elemental abundances in the local ISM. We examine absorption features of O, Mg, and Si along this line of sight using spectra from the Chandra Observatory's LETG/ACIS-S and XMM-Newton's RGS instruments. In general, we find that the abundances and their ratios are similar to those of young F and G stars and the most recent solar values. We compare our results with abundances required by dust grain models.

Valencic, Lynne A.↗
NASA NTRS2012

An In-Depth Study of the Abundance Pattern in the Hot Interstellar Medium in NGC 4649

We present our X-ray imaging spectroscopic analysis of data from deep Suzaku and XMM-Newton Observatory exposures of the Virgo Cluster elliptical galaxy NGC 4649 (M60), focusing on the abundance pattern in the hot interstellar medium (ISM). All measured elements show a radial decline in abundance, with the possible exception of Oxygen. We construct steady state solutions to the chemical evolution equations that include infall in addition to stellar mass return and Type Ia supernovae (SNIa) enrichment, and consider recently published SNIa yields. By adjusting a single model parameter to obtain a match to the global abundance pattern in NGC 4649 we infer that introduction of subsolar metallicity external gas has reduced the overall ISM metallicity and diluted the effectiveness of SNIa to skew the pattern towards low alpha/Fe ratios, and estimate the combination of SNIa rate and level of dilution. Evidently, newly-introduced gas is heated as it is integrated into, and interacts with, the hot gas that is already present. These results indicate a complex flow and enrichment history for NGC 4649, reflecting the continual evolution of elliptical galaxies beyond the formation epoch. The heating and circulation of accreted gas may help reconcile this dynamic history with the mostly passive evolution of elliptical stellar populations. In an appendix we examine the effects of the recent updated atomic database AtomDB in spectral fitting of thermal plasmas with hot ISM temperatures in the elliptical galaxy range.

Loewenstein, Michael↗
NASA NTRS2013

Variability of a Stellar Corona on a Time Scale of Days: Evidence for Abundance Fractionation in an Emerging Coronal Active Region

Elemental abundance effects in active coronae have eluded our understanding for almost three decades, since the discovery of the first ionization potential (FIP) effect on the sun. The goal of this paper is to monitor the same coronal structures over a time interval of six days and resolve active regions on a stellar corona through rotational modulation. We report on four iso-phase X-ray spectroscopic observations of the RS CVn binary EI Eri with XMM-Newton, carried out approximately every two days, to match the rotation period of EI Eri. We present an analysis of the thermal and chemical structure of the EI Eri corona as it evolves over the six days. Although the corona is rather steady in its temperature distribution, the emission measure and FIP bias both vary and seem to be correlated. An active region, predating the beginning of the campaign, repeatedly enters into our view at the same phase as it rotates from beyond the stellar limb. As a result, the abundances tend slightly, but consistently, to increase for high FIP elements (an inverse FIP effect) with phase. We estimate the abundance increase of high FIP elements in the active region to be of about 75% over the coronal mean. This observed fractionation of elements in an active region on time scales of days provides circumstantial clues regarding the element enrichment mechanism of non-flaring stellar coronae.

Nordon, R.↗
NASA NTRS2017

The Composition of Comet C 2012 K1 (PanSTARRS) and the Distribution of Primary Volatile Abundances Among Comets

On 2014 May 22 and 24 we characterized the volatile composition of the dynamically new Oort cloud comet C2012 K1 (PanSTARRS) using the long-slit, high resolution ( lambda/delta lambda is approximately or equal to 25,000) near-infrared echelle spectrograph (NIRSPEC) at the 10 m Keck II telescope on Maunakea, Hawaii. We detected fluorescent emission from six primary volatiles (H2O, HCN, CH4, C2H6, CH3OH, and CO). Upper limits were derived for C2H2, NH3, and H2CO. We report rotational temperatures, production rates, and mixing ratios (relative to water). Compared with median abundance ratios for primary volatiles in other sampled Oort cloud comets, trace gas abundance ratios in C2012 K1 (PanSTARRS) for CO and HCN are consistent, but CH3OH and C2H6 are enriched while H2CO, CH4, and possibly C2H2 are depleted. When placed in context with comets observed in the near- infrared to date, the data suggest a continuous distribution of abundances of some organic volatiles (HCN, C2H6, CH3OH, CH4) among the comet population. The level of enrichment or depletion in a given comet does not necessarily correlate across all molecules sampled, suggesting that chemical diversity among comets may be more complex than the simple organics-enriched, organics-normal, and organics-depleted framework.

Roth, Nathan X.↗