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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Ordinary chondrites - Multivariate statistical analysis of trace element contents

The contents of mobile trace elements (Co, Au, Sb, Ga, Se, Rb, Cs, Te, Bi, Ag, In, Tl, Zn, and Cd) in Antarctic and non-Antarctic populations of H4-6 and L4-6 chondrites, were compared using standard multivariate discriminant functions borrowed from linear discriminant analysis and logistic regression. A nonstandard randomization-simulation method was developed, making it possible to carry out probability assignments on a distribution-free basis. Compositional differences were found both between the Antarctic and non-Antarctic H4-6 chondrite populations and between two L4-6 chondrite populations. It is shown that, for various types of meteorites (in particular, for the H4-6 chondrites), the Antarctic/non-Antarctic compositional difference is due to preterrestrial differences in the genesis of their parent materials.

Lipschutz, Michael E.↗
NASA NTRS1991

Grain boundary sliding behaviour of copper and alpha brass at intermediate temperatures

The role of grain boundary sliding in copper and Cu-30 pct Zn in the temperature range 0.50-0.72 Tm, where Tm is the absolute melting point of the material, is examined. First, sliding data obtained on these materials are presented. The results indicate that the stress exponent for sliding is similar to that for lattice deformation, while the activation energy for sliding varies between 0.5 and 1.6 of the activation energy for creep. Several models proposed for grain boundary sliding are discussed, and it is shown that they do not account for the observed results on copper and alpha brass. A phenomenological model is proposed, where it is assumed that grain boundary sliding results from the glide of dislocations on secondary slip planes.

Raj, S. V.↗
NASA NTRS1990

Pyroclastic deposits as sites for lunar bases

Ilmenite-rich pyroclastic deposits may prove to be excellent sites for the establishment of a permanent lunar base for mining purposes. A wide variety of potentially useful by-products could be produced (e.g., Fe, Ti, H, N, C, S, Cu, Zn, Cd, Bi, and Pb). A number of ilmenite-rich pyroclastic deposits of regional extent has been studied. The physical properties of the regional pyroclastic units have important implications for lunar construction. These extensive, deep deposits of ilmenite-rich pyroclastic material are block-free and uncontaminated; they could be easily excavated and would be ideal for lunar mining operations. These deep, loose pyroclastic deposits would also be ideal for rapidly covering base modules with an adequate thickness of shielding.

Hawke, B. Ray↗
NASA NTRS1990

Life testing of secondary silver-zinc cells for the orbiting maneuvering vehicle

Over the past 5 years, extensive testing has been performed at the Marshall Space Flight Center (MSFC) on a variety of secondary (rechargeable) silver-zinc (Ag-Zn) cells for the Orbital Maneuvering Vehicle (OMV). The first tests performed were to determine the feasibility of using such a cell in a long-life (18-month), low-Earth-orbit (LEO) application. Results from these tests were promising, so testing continued with a 250-Ah cell that was specifically designed for this type of application. Once again, results from the tests were promising. Following a review of the data from these previous tests, slight modifications to the 250-Ah design were necessary to alleviate problem areas. Currently, MSFC is testing a 350-Ah design that has incorporated these changes and is the baseline design for the OMV. This test began in mid-November, 1989, and will be complete in the spring of 1991, barring any substantial offline time. A report is presented on the preliminary results from the first few months of this test and they are compared to results obtained in previous tests done at MFSC.

Brewer, Jeffrey C.↗
NASA NTRS1990

Study of surface passivation as a function of InP closed-ampoule solar cell fabrication processing variables

The effects of various surface preparation procedures, including chemical treatment and anodic or chemical oxidation, closed-ampoule diffusion conditions, and post-diffusion surface preparation and annealing conditions, on the passivating properties of InP have been investigated in order to optimize the fabrication procedures of n(+)p InP solar cells made by closed-ampoule diffusion of sulfur into p-type InP. The InP substrates used were p-type Cd-doped to a level of 1.7 x 10 to the 16th/cu cm, Zn-doped to levels of 2.2 x 10 to the 16th and 1.2 x 10 to the 18th/cu cm, and n-type S-doped to 4.4 x 10 to the 18th/cu cm. The passivating properties have been evaluated from photoluminescence (PL) and conductance-voltage (G-V) data. Good agreement was found between the level of surface passivation and the composition of different surface layers as revealed by X-ray photoelectron spectroscopy (XPS) analysis.

Faur, Mircea↗
NASA NTRS1991

Directional solidification of HgCdTe and HgZnTe in a transverse magnetic field

Hg(0.80)Cd(0.20)Te crystals were grown vertically in a transverse magnetic field by directional solidification. The effect of a magnetic field on the nature of fluid flow in the melts was investigated by measuring compositional variations along the axial and radial directions of the grown ingots. Magnetic field effects were shown to be significant over the entire field range employed (i.e., 2 to 5 kG). The axial compositional profiles (determined by precision density measurements) showed an abrupt decrease in the mole fraction of CdTe when the field was applied. Radial compositional mapping by IR transmission and X-ray energy dispersion spectrometry indicated that the solid-liquid interface evolved through three stages when the field was applied (i.e., from a radially symmetric concave interface to an off-center concave shape when the field was initially applied, then to a tilted plane, and, finally, to an off-center concave interface). The axial compositional profile of an Hg(0.84)Zn(0.16)Te ingot showed similar field effects.

Su, Ching-Hua↗
NASA NTRS1991

First results from the Goddard High-Resolution Spectrograph - Element abundances as a function of velocity in the neutral gas toward Xi Persei

Observations of ultraviolet interstellar absorption lines toward Xi Persei obtained with the echelle mode of the Goddard High-Resolution Spectrograph (GHRS) aboard the HST at a resolution of 3.5 km/s are presented. The data for O I, C II, Mg II, S II, Fe II, Si II, Mn II, and Zn II are converted into representations of apparent column density per unit velocity, Na(v), over the velocity range from -30 to +40 km/s. The profiles for ions that are the dominant state of ionization in neutral clouds permit a study of the variation of element abundance with velocity caused by changes in the gas phase depletion in the different absorbing regions situated toward Xi Per. In the denser portions of the diffuse clouds, heavy element depletions are very large. However, in absorbing components near -5 and +25 km/s, the depletions are less severe, with a nearly solar gas phase abundance ratio being found for the gas in the +25 km/s component. The measurements confirm that the GHRS is well suited for diagnostic spectroscopy of interstellar gas.

Savage, Blair D.↗
NASA NTRS1990

Universal energy relations and metal/ceramic interfaces

Known general relationships between pertinent variables are applied to investigate metal-ceramic interfaces. The adhesive energy is determined. The electronic exchange-correlation energy is found to be the dominant attractive term in the total energy. Results for the adhesive energy are obtained for junctions of all combinations of the low index surfaces of Al,Na, Mg, and Zn. This leads to a variety of curves, all with a single minimum of separation and equilibrium binding energy. Scaling results for 10 contacts fall closely onto a single curve, a universal energy relation for adhesion. The scaled chemisorption curves fall accurately on the same universal form that was found for adhesion. For the case of cohesion, all-first principle results are scaled and again all scaled curves for a variety of metals fall accurately on the universal form for adhesion and chemisorption. An intimate relationship between the energetics of solids and molecules is inferred.

Smith, John R.↗
NASA NTRS1991

Chemical studies of H chondrites. III - Regolith evolution of the Fayetteville chondrite parent

Radiochemical neutron concentration analysis was used to determine Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Sb, Se, Te, Tl, and Zn contents in consortium samples of solar gas and track-rich dark matrix. Data obtained confirmed that the matrix is chemically homogeneous. Most dark clasts had similar mean trace element concentrations as the matrix but were compositionally much more heterogeneous. It is concluded that material incorporated with soil and compacted to form the dark portion of Fayetteville included soil-melt, the odd C2M fragment, and dark and light clasts which escaped comminution.

Xiao, Xiaoyue↗
NASA NTRS1990

The Advanced Composition Explorer

The Advanced Composition Explorer (ACE) was recently selected as one of two new Explorer-class missions to be developed for launch during the mid-1990s. ACE will observe particles of solar, interplanetary, interstellar, and Galactic origins, spanning the energy range from that of the solar wind to Galactic cosmic ray energies. Definitive studies will be made of the abundance of nearly all isotopes from H to Zn, with exploratory isotope studies extending to Zr. The scientific objectives, instrumentation, spacecraft, and mission approach that were defined for ACE during the Phase-A study period are summarized.

Stone, E. C.↗
NASA NTRS1992

Mineralization on the moon? Theoretical considerations of Apollo 16 'rusty rocks', sulfide replacement in 67016, and surface-correlated volatiles on lunar volcanic glass

Theoretical considerations of vapor-rock interactions in the lunar environment are a useful supplement to petrologic studies of mineralization or alteration in rocks from the moon. They also provide insights into the potential for the existence of more extensive mineralization on the moon than is found in the limited sample set. Discussed in this paper are the coexistence and textural association in 66095 of the phases lawrencite, troilite, schreibersite, iron metal, and sphalerite; the replacement of olivine in certain clasts of 67016 by troilite and enstatite; and the existence of Zn + S deposits on the surfaces of volcanic glass beads. Particular attention is given in each case to whether the observed mineralization implies that metals, as well as S, P, or Cl, have been mobilized in the vapor. Vapor species that might mobilize metals in the absence of H2O are considered. Most importantly, the suggestion is made that in the dry lunar environment carbonyl species may be important carriers of S and metals. The implications of this possibility are discussed.

Colson, Russell O.↗
NASA NTRS1992

Mathematical modeling of a primary zinc/air battery

The mathematical model developed by Sunu and Bennion has been extended to include the separator, precipitation of both solid ZnO and K2Zn(OH)4, and the air electrode, and has been used to investigate the behavior of a primary Zn-Air battery with respect to battery design features. Predictions obtained from the model indicate that anode material utilization is predominantly limited by depletion of the concentration of hydroxide ions. The effect of electrode thickness on anode material utilization is insignificant, whereas material loading per unit volume has a great effect on anode material utilization; a higher loading lowers both the anode material utilization and delivered capacity. Use of a thick separator will increase the anode material utilization, but may reduce the cell voltage.

Mao, Z.↗
NASA NTRS1992

Labile trace elements in carbonaceous chondrites - A survey

Data are presented on 14 trace elements, including Co, Au, Ga, Rb, Sb, Ag, Se, Cs, Te, Zn, Cd, Bi, Tl, and In (nearly all of which are moderately or highly labile in meteorites), obtained by radiochemical neutron activation analyses of 42 C2-C6 chondrites, all but three from Antarctica. The data indicate that carbonaceous chondrites of petrographic types 2-6 define compositional continua. It is suggested that carbonaceous C2-C6 chondrites may reflect a mixture of material that formed at low temperatures and that contained cosmic levels of highly labile elements, with material that was devoid of them.

Xiao, Xiaoyue↗
NASA NTRS1991

Life testing of secondary silver-zinc cells

Testing on a variety of secondary silver-zinc (Ag-Zn) cells has been in progress at the Marshall Space Flight Center (MSFC) for over six years. The latest test involves a 350-Ah cell design that has been cycled at 10 C for 16 months. This design has achieved over 7200 low-earth-orbit (LEO) cycles as well as 17 deep discharges at an 85 percent depth of discharge. This test not only is a life test on these cells but also addresses different methods of storing these cells between the deep discharges. As the test is approaching completion, some interesting results are being seen. In particular, two of the four packs currently on test have failed to meet the 35-h (295-Ah) deep discharge requirement that was arbitrarily set at the beginning of the test. This capacity loss failure is likely a result of the storage method used on these two packs between deep discharges. The two packs are LEO cycled in such a way as to minimize overcharge in an attempt to prolong life.

Brewer, Jeffrey C.↗
NASA NTRS1991

High voltage thermally diffused p(+)n solar cells

The possibility of fabricating thermally diffused p(+)n InP solar-cells with high open-circuit voltage without sacrificing the short circuit current is discussed. The p(+)n InP junctions were formed by Cd and Zn diffusion through a 3-5-nm-thick anodic or chemical phosphorus-rich oxide cap layer grown on n:InP:S (with ND-NA = 3.5 x 10 exp 16 and 4.5 x 10 exp 17/cu cm) Czochralski LEC-grown substrates. After thinning the emitter from its initial thickness of 1 to 2.5 micron down to 0.06-0.15 micron, the maximum efficiency was found when the emitter was 0.2 to 0.3 micron thick. Typical AM0, 25 C values of 854-860 mV were achieved for Voc, Jsc values were from 25.9 to 29.1 mA/sq cm using only the P-rich passivating layer left after the thinning process as an antireflection coating.

Faur, M.↗
NASA NTRS1992

Four space application material coatings on the long-duration exposure flight (LDEF)

Four material coatings of different thickness were flown on the LDEF to determine their ability to perform in the harsh space environment. The coatings, located in the ram direction of the spacecraft, were exposed for 10 months to the low-Earth orbit (LEO) environment experienced by the LDEF at an orbit of 260 nautical miles. They consisted of indium oxide (In2O3), silicon oxide (SiO(x)), clear RTV silicone, and silicone with silicate-treated zinc oxide (ZnO). These coatings were flown to assess their behavior when exposed to atomic oxygen and to confirm their good radiative properties, stability, electrical conductivity, and resistance to UV exposure. The flown samples were checked and compared with the reference unflown samples using high-magnification optical inspection, ESCA analysis, weight changes and dimensional changes. These comparisons indicated the following: The 1000 A SiO(x) coating eroded uniformly, with minor changes in its radiative properties. The 100 A of In2O3 coating eroded completely down to the Kapton backing, with resultant losses of reflectance. The RTV-615 showed erosion, with carbon (C) content losses, while the Si remained constant, with a doubling of the oxygen (O) concentration. The RTV-615 silicone with K2SiO3-treated ZnO changed from flat to glossy white in appearance. It lost C, was etched, and increased its O content. The upper layers showed no remaining Zn or K. Losses of reflectance occurred within certain wavelength bands. It was not possible to evaluate the experimental oxygen reaction rate using the calculated atomic oxygen fluence of 2.6 x 10(exp 20) atoms/cm(exp 2) for the exposure of these coatings during the flight. The bakeout of the coatings was not carried out prior to the flight. Hence, the coating weight and dimensional losses included losses by outgassing products.

Scialdone, John J.↗
NASA NTRS1992

Morphology and composition of condensates on Apollo 17 orange and black glass

Lunar soil sample 74220 and core samples 74001/2 consist mainly of orange glass droplets, droplet fragments, and their crystallized equivalents. These samples are now generally accepted to be pyroclastic ejecta from early lunar volcanic eruptions. It has been known since early examination of these samples that they contain surface coatings and material rich in volatile condensible phases, including S, Zn, F, Cl, and many volatile metals. The volatiles associated with these orange and black glasses (and the Apollo 15 green glasses) may provide important clues in understanding the differentiation and volcanic history of the Moon. In addition, condensible volatiles can be mobilized and concentrated by volcanic processes. We have reviewed many of our existing photomicrographs and energy dispersive analysis (EDXA) of grain surfaces and have reexamined some of our older SEM mounts using an improved EDXA system capable of light-element detection and analysis (oxygen, nitrogen, and carbon). The results from these investigations are presented.

Mckay, David S.↗
NASA NTRS1993

Thermodynamic data for fifty reference elements

This report is a compilation of thermodynamic functions of 50 elements in their standard reference state. The functions are C(sub p)(sup 0), (H(sup 0)(T) - H(sup 0)(0)), S(sup 0)(T), and -(G(sup 0)(T) - H(sup 0)(O)) for the elements Ag, Al, Ar, B, Ba, Be, Br2, C, Ca, Cd, Cl2, Co, Cr, Cs, Cu, F2, Fe, Ge, H2, He, Hg, I2, K, Kr, Li, Mg, Mn, Mo, N2, Na, Nb, Ne, Ni, O2, P, Pb, Rb, S, Si, Sn, Sr, Ta, Th, Ti, U, V, W, Xe, Zn, and Zr. Deuterium D2 and electron gas e(sup -) are also included. The data are tabulated as functions of temperature as well as given in the form of least-squares coefficients for two functional forms for C(sub p)(sup 0) with integration constants for enthalpy and entropy. One functional form for C(sub p)(sup 0) is a fourth-order polynomial and the other has two additional terms, one with T(exp -1) and the other with T(exp -2). The gases Ar, D2, e(sup -), H2, He, Kr, N2, Ne, O2, and Xe are tabulated for temperatures from 100 to 20,000 K. The remaining gases Cl2 and F2 are tabulated from 100 to 6000 K and 1000 to 6000 K. The second functional form for C(sub p)(sup 0) has an additional interval from 6000 to 20,000 K for the gases tabulated to 20,000 K. The fits are constrained so that the match at the common temperature endpoints. The temperature ranges for the condensed species vary with range of the data, phase changes, and shapes of the C(sub p)(sup 0) curves.

Mcbride, Bonnie J.↗