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At least 469 records · Page 26

Thermal energy storage material thermophysical property measurement and heat transfer impact

The thermophysical properties of salts having potential for thermal energy storage to provide peaking energy in conventional electric utility power plants were investigated. The power plants studied were the pressurized water reactor, boiling water reactor, supercritical steam reactor, and high temperature gas reactor. The salts considered were LiNO3, 63LiOH/37 LiCl eutectic, LiOH, and Na2B4O7. The thermal conductivity, specific heat (including latent heat of fusion), and density of each salt were measured for a temperature range of at least + or - 100 K of the measured melting point. Measurements were made with both reagent and commercial grades of each salt.

Tye, R. P.↗

DEMO-FTES: Development, Monitoring, and Control of Fracture Thermal Energy Storage in Crystalline Rock Formations (CRADA Final Report)

The DEMO-FTES project investigated the feasibility of Fracture Thermal Energy Storage (FTES) as a seasonal energy storage solution in crystalline rock formations. FTES leverages hydraulically induced fractures to exchange heat between circulating fluids and the surrounding rock mass, enabling long-term thermal energy retention due to the high specific heat and low thermal conductivity of rock. This approach has the potential to reduce heating and cooling energy demands and enhance building energy resilience. The project combined dimensional analysis, numerical modeling, laboratory experiments, and meso-scale field tests to evaluate FTES performance and advance its technology readiness level from 3 to 5. Scaling analysis identified key dimensionless parameters governing heat transfer and fluid flow, ensuring laboratory and field tests were representative of larger-scale systems. Numerical simulations using TOUGH and iTOUGH2 frameworks supported experiment design and interpretation, modeling fracture geometry, thermal-hydraulic behavior, and thermo-mechanical coupling. Laboratory tests at EPFL involved creating single and multiple fractures in 25 cm cubic samples of Gabbro and Granite under true triaxial stress.

25 ENERGY STORAGE↗

Large-scale thermal energy storage using sodium hydroxide /NaOH/

A technique employing NaOH phase change material for large-scale thermal energy storage to 900 F (482 C) is described; the concept consists of 12-foot diameter by 60-foot long cylindrical steel shell with closely spaced internal tubes similar to a shell and tube heat exchanger. The NaOH heat storage medium fills the space between the tubes and outer shell. To charge the system, superheated steam flowing through the tubes melts and raises the temperature of NaOH; for discharge, pressurized water flows through the same tube bundle. A technique for system design and cost estimation is shown. General technical and economic properties of the storage unit integrated into a solar power plant are discussed.

Turner, R. H.↗

Use of pure nickel and LiOH for thermal energy storage

The solid to liquid phase transformation of LiOH has been proposed as an ideal candidate thermal energy storage media for a Rankine Cycle powered electrical generation unit envisioned in Space Station based solar dynamic systems. Due to the corrosive nature of molten hydroxides, long term containment of LiOH is of concern. Pure nickel is thought to be a suitably resistant material, and a program has been instituted to measure the effects of prolonged exposure of liquid and gaseous LiOH on the mechanical properties of pure nickel alloys. Results to date indicate that negligible weight and thickness changes occurred in Ni alloys exposed to LiOH for as long as 2500 hr at 775 K, and essentially no difference in 77-900 K tensile properties could be detected between LiOH exposed and vacuum annealed Ni specimens. Although there was little sign of outward damage, microstructural examination revealed that all hydroxide contaminated tensile test specimens had surface connected intergranular cracks along the gage lengths. Two other potential problems, which have strong implications with respect to a LiOH/Ni energy storage system, were also noted during the corrosion experiments. In particular stress corrosion cracking of weld joints in pressurized vessel and permeation of hydrogen through nickel were observed.

Whittenberger, J. D.↗

Development and Validation of a Simulation Testbed for the Intelligent Building Agents Laboratory (IBAL) Using TRNSYS

This paper documents the development and validation of a dynamic primary cooling and thermal storage system simulation testbed. The system simulation testbed, sIBAL, is based on the Intelligent Building Agents Laboratory (IBAL) at the National Institute of Standards and Technology (NIST), which is a research infrastructure and testbed for the development, evaluation, and demonstration of intelligent control algorithms. The sIBAL testbed developed in this project will serve as a virtual twin of the real facility for future control algorithm development. The details of the methodologies used to develop and validate the simulation testbed, which replicates the dynamic behaviors of the primary cooling and ice storage system in the IBAL facility, are presented. The simulation testbed was developed in TRNSYS using built-in component models and MATLAB functions to replicate the two water-cooled chillers, a thermal storage tank, pumps, valves and other components for four different operation modes. Experiments on IBAL components were designed and executed to generate experimental data for model development and verification of the simulation platform. The validation of the simulation results was carried out in two phases: 1) independent component simulations for the chillers and thermal storage tank, and 2) a combined testbed simulation of the entire hydronic system. Comparison of simulation results to the experimental data obtained from the IBAL facility showed errors within 1 °C for the temperatures outputs of both the chiller and the thermal storage model. The error is within an acceptable range for further intelligent control algorithms development. The findings from the study are summarized and presented along with areas where additional research is needed. In addition, data filtering procedures and model refinement measures utilized to improve the accuracy and accelerate the computation time of the simulation are presented.

cooling systems↗

Addressing Data Center Cooling Needs through the Use of Subsurface Thermal Energy Storage Systems

This study aims to evaluate the feasibility of addressing the cooling needs for information technology (IT) equipment in data centers by using reservoir thermal energy storage (RTES) to provide reliable and sustainable low-temperature fluid. This project focuses on the technical viability of operating such a system in Houston, Texas, which is a representative location for crypto mining data centers. An analysis has been performed to investigate the technical feasibility with climate data for Houston. Results show that data centers on the scale of 30 MW, and operating at a temperature of 27 degrees C, can be reliably cooled by a combined RTES and dry coolers setup. A techno-economic analysis will be performed and energy/water saving benefits will be quantified in the future. In addition, the study will be extended to other representative data center locations with different climates and geographical locations.

cooling↗

Thermal energy storage for industrial waste heat recovery

The potential is examined for waste heat recovery and reuse through thermal energy storage in five specific industrial categories: (1) primary aluminum, (2) cement, (3) food processing, (4) paper and pulp, and (5) iron and steel. Preliminary results from Phase 1 feasibility studies suggest energy savings through fossil fuel displacement approaching 0.1 quad/yr in the 1985 period. Early implementation of recovery technologies with minimal development appears likely in the food processing and paper and pulp industries; development of the other three categories, though equally desirable, will probably require a greater investment in time and dollars.

Hoffman, H. W.↗

Thermal energy storage systems using fluidized bed heat exchangers

The viability of using fluidized bed heat exchangers (FBHX) for thermal energy storage (TES) in applications with potential for waste heat recovery was investigated. Of the candidate applications screened, cement plant rotary kilns and steel plant electric arc furnaces were identified, via the chosen selection criteria, as having the best potential for successful use of FBHX/TES system. A computer model of the FBHX/TES systems was developed and the technical feasibility of the two selected applications was verified. Economic and tradeoff evaluations in progress for final optimization of the systems and selection of the most promising system for further concept validation are described.

Ramanathan, V.↗

Thermal energy storage effort at JPL

The technical, operational, and economic readiness of parabolic dish systems for electric and thermal applications was investigated. A parabolic dish system was then developed to the point at which subsequent commercialization activities can lead to successful market penetration. The immediate possible applications of the dish system to thermal energy storage are discussed.

Young, D. L.↗

Advanced Materials and Additive Manufacturing for Phase Change Thermal Energy Storage and Management: A Review

Abstract Phase change materials (PCMs) can enhance the performance of energy systems by time shifting or reducing peak thermal loads. The effectiveness of a PCM is defined by its energy and power density—the total available storage capacity (kWh m −3 ) and how fast it can be accessed (kW m −3 ). These are influenced by both material properties as well as geometry of the energy systems; however, prior efforts have primarily focused on improving material properties, namely, maximizing latent heat of fusion and increasing thermal conductivity. The latter is often at the expense of the former. Advanced manufacturing techniques hold tremendous potential to enable co‐optimization of material properties and device geometry, while potentially reducing material waste and manufacturing time. There is an emerging body of research focused on additive manufacturing of PCM composites and devices for thermal energy storage (TES) and thermal management. In this article, the fundamentals and applications of PCMs are reviewed and recent additive manufacturing advances in latent heat TES for both the PCM composite and associated heat exchanger are discussed. A forward‐looking perspective on the future and potential of PCM additive manufacturing for TES and thermal management is provided.

25 ENERGY STORAGE↗

Study of thermal energy storage using fluidized bed heat exchangers

The technical and economic feasibility of fluid bed heat exchangers (FBHX) for thermal energy storage (TES) in waste heat recovery applications is assessed by analysis of two selected conceptual systems, the rotary cement kiln and the electric arc furnace. It is shown that the inclusion of TES in the energy recovery system requires that the difference in off-peak and on-peak energy rates be large enough so that the value of the recovered energy exceeds the value of the stored energy by a wide enough margin to offset parasitic power and thermal losses. Escalation of on-peak energy rates due to fuel shortages could make the FBHX/TES applications economically attractive in the future.

Weast, T. E.↗

Geologic Thermal Energy Storage of Solar Heat to Provide a Source of Dispatchable Renewable Power and Seasonal Energy Storage Capacity

This paper concludes that there is a cost-effective strategy for seasonal storage of heat that will provide firm, but dispatchable, electrical generating capacity in times when other renewable energy is not available to meet demand. Deployment of the technology appears to require no new technology, but instead combines solar, geothermal, and conventional oil and gas drilling technologies in a novel way. The study basis is the use of sedimentary geologic formations as a medium for thermal energy storage (TES), specifically for heat collected in concentrating solar collectors.

40 EE - Geothermal Technologies Office (EE-4G)↗

Concrete Thermal Energy Storage Enabling Flexible Operation without Coal Plant Cycling

The work described in this report is responsive to the Office of Fossil Energy program “Energy Storage for Fossil Power Generation.” The pilot plant built as a result of this project demonstrated the feasibility and performance of a concrete thermal energy storage (CTES) system integrated with a supercritical coal power plant. The 10 MWh electrical (>25 MWh thermal) CTES unit, developed by Storworks Power, was designed to enable flexible operation of coal plants without cycling damage. The project's key technical achievements showcase a significant advancement in energy storage technology. A modular CTES system using 42 “Bolderblocs” units was successfully designed and constructed at Alabama Power’s Plant Gaston Unit 5, with each block containing embedded stainless-steel coils in specialized, cost-effective high-temperature concrete. The system interfaced seamlessly with the plant's 3500 psig (241 barg), 1000°F (538°C) supercritical steam, demonstrating operational flexibility. Over 86 full cycles, the CTES exhibited rapid charging and discharging capabilities, effectively mimicking steam turbine feed conditions and handling varying load profiles and storage durations. Performance validation confirmed the system's ability to consistently meet design target steam conditions of 75 bar-a and ~400°C for nominal baseline discharge. The concrete material withstood repeated thermal cycling without degradation, validating earlier lab-scale tests. Integration of balance of plant components, including a condensate management system with storage tank and air-cooled condenser, minimized plant interfaces and water consumption. A robust control scheme ensured safe, automated operation across various scenarios. Key learnings from the project were invaluable: 1. Initial concrete drying and commissioning procedures were refined for future deployments, enhancing efficiency in subsequent installations. 2. System flexibility exceeded expectations, with rapid response to changing conditions. 3. Design improvements were identified including optimized insulation and piping that will enhance overall system efficiency in future deployments 4. Full cycle thermal roundtrip efficiencies exceeded 88%. While the roundtrip electrical efficiency was somewhat limited by known challenges using input steam, such constraints may be mitigated by swapping steam for hot air as thermal input. 5. A summary of key performance parameters for the pilot test and predicted performance of a full scale commercial system with specified improvements determined from the pilot are shown in Section 8. The project faced challenges, including COVID-19 delays and host plant availability constraints. However, these were overcome through adaptive planning and execution. The successful management of these obstacles demonstrated the resilience and adaptability of the project team and the robustness of the CTES technology. This successful pilot demonstrates the potential for CTES to enhance coal plant flexibility, supporting grid stability as renewable penetration increases. The validated design and operational data provide a solid foundation for scaling up to utility-scale implementations, potentially transforming how thermal plants operate in evolving energy landscapes. The system's ability to rapidly respond to changing grid conditions while maintaining high efficiency makes it a promising solution for balancing intermittent renewable energy sources. Furthermore, the project highlighted the potential for even greater efficiencies in future iterations. The use of air as an input medium could potentially eliminate the limitations observed with steam input, opening new possibilities for energy storage applications beyond coal plant integration. In conclusion, this pilot project not only achieved its primary goals but also uncovered additional benefits and potential applications of the CTES technology. It represents a significant step forward in addressing the challenges of grid stability and flexibility in an increasingly renewable-driven energy landscape.

01 COAL, LIGNITE, AND PEAT↗

High Density Thermal Energy Storage by Highly Stable Glauber’s Salt Composites with Low Supercooling for Building-Scale Application

Phase change materials (PCM) are a promising candidate for thermal energy storage in building infrastructure, enabling grid-integrated peak load shaving by utilizing energy production in off-peak hours. Glauber’s salt (Na2SO4.10H2O, Sodium sulfate hydrate) are highly attractive due to their high energy storage capacity and low cost but Glauber’s salt suffers from long-standing challenges including high supercooling ( > 15oC) and low thermal cyclic stability, which is a major setback for practical building-scale energy storage applications. Here, we developed a unique ionic molecular nucleating agent for Glauber’s salt which reduced the supercooling temperature to less than 5oC. By combining this nucleated SSD with a polymer, phase segregation of salt hydrate for over 100 thermal cycles without degradation was achieved. Key was that the polymer confined the SSD crystals, preventing phase separation. In addition, we applied our stable Glauber’s salt composite in a miniatured building model and demonstrate that our PCM composite can be utilized for real-world building infrastructure.

additives↗

Influence of Thermal Energy Storage Integration Strategy on System Performance and Refrigerant Charge for Small-Scale R290 Heat Pumps

As small-scale (2.5 – 5 kW) heat pumps across the US increase straining the grid during peak hours, integrated heat pump thermal energy storage (HP-TES) systems can assist by load shifting. However, challenges arise when assembling these systems, as direct refrigerant-phase change material (PCM) heat exchangers (HXs) increase refrigerant charge, and indirect secondary loops degrade HP-TES performance. In this work, direct and indirect HP-TES configurations were sized using commercially available HXs to compare the available load shift time and performance at similar refrigerant charges. For the same indirect 5 kW HP-TES refrigerant charge, directly HP-TES can operate up to 72 and 145 minutes in cooling and heating modes, respectively, using small diameter tubes. Using Modelica, COP increases for direct and indirect HP-TES were 22% and 9%, respectively, given the parasitic losses in the indirect HP-TES. Overall, small-scale direct HP-TES can have comparable refrigerant charges with indirect HP-TES maximizing COP improvements.

25 ENERGY STORAGE↗

Operational Parameter Database for Molten Salt Thermal Energy Storage Tank Modeling

The second generation of concentrated solar power (CSP) plants is characterized by the use of a central receiver (either cavity or external), two molten nitrate salt tanks (60 wt.% NaNO 3 and 40 wt.% KNO 3 ), and a steam Rankine power-generation cycle connected through a primary heat exchanger. Molten salt thermal energy storage (TES) tanks have been widely deployed in commercial CSP plants worldwide and have been essential for increasing plant dispatchability and capacity factor, while also reducing the levelized cost of electricity (LCOE). These systems enable energy storage at the gigawatt-hour scale, typically providing 6 to 17 hours of storage duration. Despite being a commercial technology, the multiple failures observed after only a few months or years of operation in plants around the world demonstrate the technology's relative infancy and highlight the need for further research to improve its reliability. The National Laboratory of the Rockies (NLR), in collaboration with industry partners and academic and research institutions, has been leading multiple projects funded by the U.S. Department of Energy (DOE). These projects focus on addressing molten salt tank failures by improving tank design and welding fabrication practices, evaluating new alloys and weld fillers, and providing guidelines for tank commissioning and safe operation. In particular, this report presents modeling results on the effect of key tank operation parameters during 60 minutes of operation, including the mass flow rate and temperature of the salt inflow, tank salt inventory temperature, and inventory level for a representative molten salt tank design. These results form a database of tank operation behaviors that captures the effects of each specific parameter during charging, charging/discharging, and discharging processes.

14 SOLAR ENERGY↗

An assessment of existing barriers to market adoption of thermal energy storage in buildings based on interviews with stakeholders

The United States administration recently established a goal of reducing greenhouse gas emissions by half below 2005 levels by 2030 and becoming a carbon-neutral economy by 2050. The transition to renewable energy sources may be significantly aided by energy storage. Energy storage could smooth the delivery of variable or intermittent renewable energy sources such as wind, hydro, and sun by storing excess renewable energy when it’s available and delivering it back when renewable energy production is low. Thermal energy storage (TES) is a way that stores thermal energy by heating or cooling a storage medium, which is then used for space heating and cooling, industrial processes, or power generation purposes later. This TES operation could lessen the demand for electricity in both the winter's and the summer's peak hours of electricity. While there are various studies that focus on the advancements and successes of TES technology, less attention is placed on its market adoption. Therefore, the current study undertakes survey-based interview research to understand the existing market barriers hindering TES application in buildings. A series of interviews were performed in this study with individuals from various backgrounds, ranging from homeowners to market specialists who work for TES manufacturers and utility companies. According to the responses obtained during the interviews, they strongly believe that TES has a high potential to contribute to the nation's grid stability and decarbonization goals, however, there are several barriers that prevent homeowners and heat pump manufacturers from investing in TES applications. The current study divided the responses from various background groups into categories to better understand the current challenges for TES applications in buildings. These responses range from payback concerns from homeowners to the need to develop a new metric to represent the benefits of TES from the heat pump and TES manufacturers. The findings from this study can be used by policymakers, utility companies, and manufacturers to better understand present obstacles and develop strategies to overcome them.

Prem Anand Jayaprabha, Jyothis Anand↗