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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Manipulating the Second Coordination Shell of Single-Atom Fe for Enhanced Fenton Reaction

While current methods use oxidizable metals as electron donors to effectively reduce Fe 3+ , they suffer from the irreversible oxidation of these metals, ultimately compromising the catalyst’s longevity. To address this challenge, we engineered the second coordination shell of a single-atom Fe center by doping boron (B) onto a graphene-based support (Fe 1 /B-graphene) and utilized H 2 O 2 as the electron source for efficient Fe 2+ regeneration. Experimental results, supported by theoretical calculations, revealed that the Fe–O–B motif functions like a micro galvanic cell, with intermediary O atoms facilitating electron transfer between electrodes. Specifically, electrons consumed during H 2 O 2 activation at Fe 1 sites (positive electrode) are replenished by electrons extracted from H 2 O 2 at B atoms (negative electrode), where the activation energy for H 2 O 2 oxidation is significantly lower than that at Fe 1 sites. This study offers inspirational insights into the design of Fenton catalysts through precise regulation of the second coordination shell, demonstrating the potential of tailoring the outer coordination environment of single-atom catalysts to enhance catalytic performance across various reactions.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Measurement of the Neutron Magnetic Form Factor at Large Momentum Transfer Using the Super-Bigbite Apparatus in Jefferson Lab Hall-A

The nucleon elastic electromagnetic form factors help us study the electromagnetic structure of the nucleon, benchmark theoretical models, and improve our understanding of non-perturbative quantum chromodynamics and confinement. The Nobel Prize-winning electron-nucleon scattering experiments by Robert Hofstadter and collaborators in the 1950s at Stanford High Energy Physics Lab were the first nucleon form factor measurements performed using leptonic probes. The Super Bigbite Spectrometer (SBS) program at Hall-A of Jefferson Lab represents the latest efforts to measure nucleon form factors. This ambitious program aims to significantly extend the current data set in terms of square momentum transfer (Q2) with high precision. The advent of novel detector technologies, like Gas Electron Multipliers (GEM), which provide excellent position resolution (< 100 ?m) while withstanding high background particle rates (several hundred MHz/cm2) over a large active area, has paved the way for open-geometry, moderate solid angle spectrometers, which are central to all form factor experiments in the SBS program. The first experimental run group in SBS ran successfully between September 2021 and February 2022, collecting data for the measurement of the magnetic form factor of the neutron Gn M at five squared momentum-transfer values: 3.0, 4.5, 7.5, 9.8, and 13.5 (GeV /c)2. This extends the existing high-precision data for Gn M by about a factor of four. The ratio technique was used, which involved the simultaneous measurement of exclusive quasielastic scattering of D(e,e?n)p and D(e,e?p)n from a deuterium target. Pre-preliminary results for D(e,e?n)p and D(e,e?p)n quasi-elastic ratio, and the neutron magnetic form factor Gn M , for Q2 points 3.0, 9.8, and 13.5 (GeV /c)2 are presented.

Mudiyanselage, Anuruddha Rathnayake↗
NASA NTRS2004

Cluster observations of quasi-periodic impulsive signatures in the dayside northern lobe: High-latitude flux transfer events?

We report on a series of quasi-periodic reversals in GSM B(sub Z) observed by the four Cluster spacecraft in the northern dayside lobe poleward of the cusp on 23 February 2001. During an interval of about 35 min, multiple reversals (negative to positive) in B(sub Z) of approximately 1-min duration with an approximate 8-min recurrence time were observed. The individual structures do not resemble low-latitude flux transfer events (FTE) [Russell and Elphic, 1979] but the 8-min recurrence frequency suggests that intermittent reconnection may be occurring .Measurements (appropriately lagged) of the solar wind at ACE show that the IMF was southward-oriented with a strong B(sub X) and that a modest dynamic pressure increased as the events started. The multi-point observations afforded by the Cluster spacecraft were used to infer the motion (direction and speed) of the observed magnetic field reversals. The associated currents were also calculated and they are consistent with the spatial confinement of the observed magnetic field reversals. We propose that the observed reversals are due to flux tubes reconnecting with closed field lines on the dayside. Ancillary data from the Cluster Ion Spectrometry (CIS) and Plasma Electron And Current Experiment (PEACE) instruments were used to develop a physical picture of the reversals.

Thompson, S. M.↗
DOE OSTI2023

A Computational Investigation of Engine Heat Transfer with Ducted Fuel Injection

Ducted fuel injection (DFI) is an innovative method that curtails or prevents soot formation in direct-injection compression-ignition engines. DFI uses a simple duct, positioned outside each injector hole, facilitating the fuel/charge gas mixing before ignition. This reduces the equivalence ratio below two, in the autoignition zone, which in turn decreases soot formation. But this method also reduces fuel-conversion efficiency. This study investigates the effects of DFI on in-cylinder heat transfer. Experiments with conventional diesel combustion (CDC) and DFI were performed at four different dilution levels. Computational fluid dynamics (CFD) simulations were carried out at conditions matching those of the experiments, and the simulations were validated by the experimental data. The CFD simulations enabled to examine of in-cylinder heat release and temperature distributions. The heat transfer to the piston, head, and cylinder was investigated. The results show that DFI increased the heat transfer to the walls compared to CDC under the same conditions. This could help explain why DFI has been observed to reduce fuel-conversion efficiency by approximately 1% (absolute) relative to CDC under certain conditions. The efficiency loss typically decreases with dilution, such that DFI can improve fuel-conversion efficiencies relative to CDC at higher dilution levels.

Şener, Ramazan↗
DOE OSTI2025

High-resolution X-ray structure of Gln143Asn manganese superoxide dismutase captures multiple hydrogen peroxide-binding sites

Human mitochondrial manganese superoxide dismutase (MnSOD) converts superoxide into hydrogen peroxide and molecular oxygen, serving as a key defence against oxidative damage. Despite extensive studies, the full structural characterization of H 2 O 2 -binding sites in MnSOD remains largely unexplored. Previous H 2 O 2 -soaked MnSOD structures have identified two distinct H 2 O 2 -binding sites: one directly ligated to the catalytic manganese (LIG position) and another at the active-site gateway (PEO position) between the second-shell residues Tyr34 and His30. In this study, a kinetically impaired Gln143Asn MnSOD variant is used to trap and explore additional H 2 O 2 -binding sites beyond the second-shell solvent gate. In the wild-type enzyme, Gln143 mediates proton transfers with the manganese-bound solvent (WAT1) to drive redox cycling of the metal, which is necessary for effective superoxide dismutation. Substitution with Asn stalls catalysis because the increased distance from WAT1 disrupts critical proton-coupled electron-transfer (PCET) events, and the redox cycling of the active-site metal is impaired. This, in turn, stalls the electrostatic cycling of positive charge on the enzyme surface and enhances the likelihood of trapping transient H 2 O 2 -bound states in this variant. The results reveal several H 2 O 2 molecules leading up to the active site, in addition to the canonical LIG and PEO positions.

Dasgupta, Medhanjali [University of Nebraska Medic↗
NASA NTRS1976

Shock interference heat transfer to tank configurations mated to a straight-wing space shuttle orbiter at Mach number 10.3

Heat transfer was measured on a space shuttle-tank configuration with no mated orbiter in place and with the orbiter in 10 different mated positions. The orbiter-tank combination was tested at angles of attack of 0 deg and 5 deg, at a Mach number of 10.3, and at a free-stream Reynolds number of one million based on the length of the tank. Comparison of interference heat transfer with no-interference heat transfer shows that shock interference can increase the heat transfer to the tank by two orders of magnitude along the ray adjacent to the orbiter and can cause high temperature gradients along the tank skin. The relative axial location of the two mated vehicles determined the location of the sharp peaks of extreme heating as well as their magnitude. The other control variables (the angle of attack, the gap, and the cross-section shape) had significant effects that were not as consistent or as extreme.

Crawford, D. H.↗
DOE OSTI2025

Elucidation of Marcus Relationships for Hydride Transfer Reactions Involving Transition Metal Hydrides

The rate of hydride transfer from three Ir hydride complexes of the type Cp*Ir( R bpy)H + (Cp* = C 5 Me 5 ; R bpy = 4,4′-R-2,2′-bipyridine, R = OMe, H, CO 2 Me) to six N-methylacridinium ( R Acr + ) acceptors with electronically different substituents in the 2- or 2,7-positions were measured. Using the thermodynamic hydricity of the donors and the hydride affinity of the acceptors the thermodynamic driving forces for hydride transfer were determined. Brønsted plots, which correlate kinetic and thermodynamic hydricity, demonstrate distinct linear free energy relationships for each complex, with different Brønsted α values. Thus, at the same driving force hydride transfer from Cp*Ir( OMe bpy)H + is faster than for Cp*Ir(bpy)H + or Cp*Ir( CO2Me bpy)H + . Experimental and computational analyses are consistent with a concerted hydride transfer mechanism for all Ir complexes. As the thermodynamic driving force increases an earlier transition state is observed and all transition states also include π-stacking interactions between the donor and acceptor, which likely contribute to the different α values. The experimental data fits well to the Marcus model, enabling the determination of reorganization energies (λ) that range from 58 to 69 kcal mol -1 . These are lower than λ values for hydride transfer reactions involving organic donors and acceptors. This work provides a rare example of the correlation of kinetic and thermodynamic hydricity using only experimental data and shows that hydride transfer reactions involving metal hydrides can follow Marcus theory. Furthermore, the findings offer insight into controlling metal-catalyzed hydride transfer reactions, which is valuable for designing improved systems for a range of transformations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1980

Sodium heat pipe use in solar Stirling power conversion systems

Sodium heat pipes were selected for use as a thermal transport method in a focus-mounted, distributed concentrator solar Stirling power conversion system intended to produce 15-20 kWe per unit. Heat pipes were used both to receive thermal power in the solar receiver and to transmit it to a secondary heat pipe containing both latent heat salt (for up to 1.25 hours of thermal storage) and the heat exchanger of the Stirling engine. Experimental tests were performed on five solar receiver heat pipes with various internal wicking configurations. The performance of the heat pipes at various power levels and operating attitudes was investigated at temperatures near 1550 F; the unidirectional heat transfer in these heat pipes was demonstrated in normal operating attitudes and particularly in the inverted position required during overnight stowage of the concentrator.

Zimmerman, W. F.↗
NASA NTRS1983

A design procedure for active control of beam vibrations

The transverse vibrations of beams is discussed and a methodology for the design of an active damping device is given. The Bernoulli-Euler equation is used to derive a transcendental transfer function, which relates a torque applied at one end of the beam to the rotational position and velocity at that point. The active damping device consists of a wire, a linear actuator and a short torque arm attached to one end of the beam. The action of the actuator varies a tension in the wire and creates a torque which opposes the rotation of the beam and thus damps vibration. A design procedure for such an active damper is given. This procedure shows the relationships and trade-offs between the actuator stroke, power required, stress levels in the wire and beam and the geometry of the beam and wire. It is shown that by consideration of the frequency response at the beam natural frequencies, the aforementioned relationships can be greatly simplified. Similarly, a simple way of estimating the effective damping ratios and eigenvalue locations of actively controlled beams is presented.

Dickerson, S. L.↗
NASA NTRS1986

LANDSAT imagery of the Central Andes

The central Andes of South America extend from approximately 14 deg. S to 28 deg. S as an unbroken chain of mountains and volcanoes over 2000 km long. It is here that the Nazca plate dives under the South American plate at angles varying from 10 deg to 30 deg. Very little is known about the volcanoes comprising this classic, subduction-type plate margin. A catalogue of the volcanoes in the central Andes is being prepared by Dr. P.W. Francis and Dr. C.A. Wood at the NASA Lunar and Planetary Institute. At present, more than 800 volcanoes of Cenozoic age have been recognized in the chain, with an estimated 75-80 major, active Quarternary volcanoes. Approximately one hundred 1536 x 1536 pixel color composite Optronics positives were produced from six full LANDSAT Thermatic Mapper scenes and three partial TM scenes. These positives cover a large portion of the central Andes. The positives were produced from LANDSAT data using the VAX imaging package, LIPS. The scenes were first transferred from magnetic tape to disk. The LIPS package was then used to select volcanically interesting areas which were then electronically enhanced. Finally, the selected areas were transferred back to tape and printed on the Optronics equipment. The pictures are color composites using LANDSAT TM bands 7,4, and 2 in the red, green, and blue filters, respectively.

Komer, C. A.↗
NASA NTRS1992

Importance of numerosity and distribution of articulations within the digits, wrists, and arms of telemanipulators confronted with dextrous assembly tasks

This study was conducted to evaluate the impact of successive exclusion of degrees-of-freedom within digits (thumb and index finger) and wrist when performing tasks demanding varying degrees of end effector kinematic complexity. The analysis was performed by successive constraining articulations in the fingers (thumb and index) and wrists or human subjects via splints, and then timing performance of part movement, positioning, and assembly operations requiring different levels of kinematic freedom. Analysis of performance times showed that transferring degrees-of-freedom, or articulations, from the digits to the wrist and arm had little or no material affect upon manipulation performance times if wrist and arm kinematics were unrestricted. If wrist and arm kinematics are not constrained and are of high-quality, our findings show that transferring kinematic freedom from the digits to the wrist and arms or remote end effectors offers limited or no consequence in terms of remote assembly operations. The importance of such findings, in terms of development and implementation of commercially attractive telemanipulators, is discussed.

Wiker, Steven F.↗
NASA NTRS1991

Autonomous rendezvous targeting techniques for national launch system application

The rendezvous targeting techniques that can be utilized to achieve autonomous guidance for delivering a cargo to Space Station Freedom (SSF) using the National Launch System's (NLS) Heavy Lift Launch Vehicle (HLLV) and the on-orbit Cargo Transfer Vehicle (CTV) are described. This capability is made possible by advancements in autonomous navigation (Global Positioning System - GPS) on-board the CTV and SSF as well as the new generation flight computers. How the HLLV launch window can be decoupled from the CTV phasing window is described. The performance trades that have to be made to determine the length of the launch window and the phasing window between the CTV and SSF are identified and recommendations made that affect mission timelines.

Lomas, James J.↗
NASA NTRS1993

TAB interconnects for space concentrator solar cell arrays

The Boeing Company has evaluated the use of Tape Automated Bonding (TAB) and Surface Mount Technology (SMT) for a highly reliable, low cost interconnect for concentrator solar cell arrays. TAB and SMT are currently used in the electronics industry for chip interconnects and printed circuit board assembly. TAB tape consists of sixty-four 3-mil/1-oz tin-plated copper leads on 8-mil centers. The leads are thermocompression gang bonded to GaAs concentrator solar cell with silver contacts. This bond, known as an Inner Lead Bond (ILB), allows for pretesting and sorting capability via nondestruct wire bond pull and flash testing. Destructive wire pull tests resulted in preferred mid-span failures. Improvements in fill factor were attributed to decreased contact resistance on TAB bonded cells. Preliminary thermal cycling and aging tests were shown excellent bond strength and metallurgical results. Auger scans of bond sites reveals an Ag-Cu-Tin composition. Improper bonds are identified through flash testing as a performance degradation. On going testing of cells are underway at Lewis Research Center. SMT techniques are utilized to excise and form TAB leads post ILB. The formed leads' shape isolates thermal mismatches between the cells and the flex circuit they are mounted on. TABed cells are picked and placed with a gantry x-y-z positioning system with pattern recognition. Adhesives are selected to avoid thermal expansion mismatch and promote thermal transfer to the flex circuit. TAB outer lead bonds are parallel gap welded (PGW) to the flex circuit to finish the concentrator solar cell subassembly.

Avery, J.↗
NASA NTRS1993

Modeling and control for vibration suppression of a flexible smart structure

Theoretical and experimental results of the modeling and control of a flexible ribbed antenna are presented. The antenna consists of eight flexible ribs which constitutes a smart antenna in the sense that the actuator and sensors are an integral part of the structure. The antenna exhibits closely space and repeated modes, thus multi-input multi-output (MIMO) control is necessary for controllability and observability of the structure. The structure also exhibits mode localization phenomenon and contains post buckled members making an accurate finite element model of the structure difficult to obtain. An identified MIMO minimum order model of the antenna is synthesized from identified single-input single-output (SISO) transfer functions curve fit in the frequency domain. The identified model is used to design a positive position feedback (PPF) controller that increases damping in all of the modes in the targeted frequency range. Due to the accuracy of the open loop model of the antenna, the closed loop response predicted by the identified model correlates well wtih experimental results.

Dosch, J.↗
NASA NTRS1999

Gravitational Acceleration Effects on Macrosegregation: Experiment and Computational Modeling

Experiments were performed under terrestrial gravity (1g) and during parabolic flights (10-2 g) to study the solidification and macrosegregation patterns of Al-Cu alloys. Alloys having 2% and 5% Cu were solidified against a chill at two different cooling rates. Microscopic and Electron Microprobe characterization was used to produce microstructural and macrosegregation maps. In all cases positive segregation occurred next to the chill because shrinkage flow, as expected. This positive segregation was higher in the low-g samples, apparently because of the higher heat transfer coefficient. A 2-D computational model was used to explain the experimental results. The continuum formulation was employed to describe the macroscopic transports of mass, energy, and momentum, associated with the solidification phenomena, for a two-phase system. The model considers that liquid flow is driven by thermal and solutal buoyancy, and by solidification shrinkage. The solidification event was divided into two stages. In the first one, the liquid containing freely moving equiaxed grains was described through the relative viscosity concept. In the second stage, when a fixed dendritic network was formed after dendritic coherency, the mushy zone was treated as a porous medium. The macrosegregation maps and the cooling curves obtained during experiments were used for validation of the solidification and segregation model. The model can explain the solidification and macrosegregation patterns and the differences between low- and high-gravity results.

Leon-Torres, J.↗
NASA NTRS2018

Double Asteroid Redirection Test (DART) Mission Design and Navigation for Low Energy Escape

This paper describes the evolution of the NASA Double Asteroid Redirection Test (DART) mission design and navigation. Specifically, the mission has been conceived as (1) a hydrazine bus on a ballistic trajectory, (2) a low-thrust bus launching from a geostationary transfer orbit and spiraling to escape, and (3) a lowthrust bus that launches with a small positive escape energy. This paper discusses the rationale in favor of the third concept, low energy escape, and describes the key mission design and navigation studies. In an effort to be compatible with an unknown co-manifest partner, the trajectory design must account for a large range of launch energies, orientations, and dates. The navigation approach must account for sensitive regions in the trajectory and plan for both low-thrust and chemical phases of flight. These findings are relevant to other missions pursuing low-cost interplanetary rideshare concepts.

Grebow, Daniel↗
DOE OSTI2021

Adaptive cover for cooling pathway by additive manufacture

A hot gas path component of an industrial machine includes an adaptive cover for a cooling pathway. The component and adaptive cover are made by additive manufacturing. The component includes an outer surface exposed to a working fluid having a high temperature; an internal cooling circuit; and a cooling pathway in communication with the internal cooling circuit and extending towards the outer surface. The adaptive cover is positioned in the cooling pathway at the outer surface. The adaptive cover may include a heat transfer enhancing surface at the outer surface causing the adaptive cover to absorb heat faster than the outer surface.

Lacy, Benjamin Paul↗