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In this yeast, the study of trait variation at the population level led to the detection of distinct sets of GAL structural genes. Besides the reference version, present in most strains, alternative highly divergent alleles supporting faster growth on galactose were recently uncovered in strains associated with dairy products and also in some wild strains.
The Columbia CO survey of the first Galactic quadrant was used to determine the locations and physical properties of the largest molecular complexes in the inner Galaxy. Within the range of the survey (l = 12-60 deg), 26 complexes were detected with masses greater than 5 x 10 to the 5th solar masses, and roughly several hundred such complexes are deduced to exist throughout the Galaxy within the solar circle. These complexes are the parent objects of much of the Population I in the Galaxy. Distances to most of the complexes were determined kinematically, the distance ambiguity being resolved with the aid of associated H II regions, OB associations, masers, and other early Population I objects. The largest complexes are good tracers of spiral structure, the Sagittarius arm in particular being delineated with unprecedented clarity. A total of 17 large complexes are distributed rather uniformly along a 15 kpc stretch of the arm with a spacing comparable to that of the strings of regularly spaced H Ii regions observed in external galaxies. Power-law relations exist between the line widths and sizes of the complexes and between their densities and sizes. The forms of these relations are in good agreement with those found previously and are extended by roughly an order of magnitude in cloud mass.
We present results from two four-frequency observations centered near the stars Sigma Herculis and Iota Draconis during the fourth flight of the Millimeter-wave Anisotropy eXperiment (MAX). The observations were made of 6 deg x 0.6 deg strips of the sky with a 1.4 deg peak to peak sinusoidal chop in all bands. The full width at half maximum (FWHM) beam sizes were calculated 0.55 deg +/- 0.05 deg at 3.5/cm and a 0.75 deg +/- 0.05 deg at 6, 9, and 14/cm. Significant correlated structures were observed at 3.5, 6, and 9/cm. The spectra of these signals are inconsistent with thermal emission from known interstellar dust populations. The extrapolated amplitudes of synchrotron and free-free emission are too small to account for the amplitude of the observed structures. If the observed structures are attributed to cosmic microwave background (CMB) anisotropy with a Gaussian autocorrelation function and a coherence angle of 25 min, then the most probable values at Delta T/T(sub CMB) = 3.1 (sup +1.7 sub -1.3) x 10(exp -5) for the Sigma Herculis scan, and Delta T/T(sub CMB) = 3.3(sup +1.1 sub -1.1) x 10(exp -5) for the Iota Draconis scan (95% confidence upper, lower limits).
How many of us have worked in organizations where the discipline was so rigid and unyielding that it would send even a Marine Corps Drill Instructor screaming into the night? How many of us have worked in organizations where sightings of senior management were sporadic and rare, and any other interactions were by appointment only? Or, how many of us have worked in organizations where your role, absent specific direction, was to be seldom seen and rarely heard? And how many of us have worked in organizations where seemingly light itself was not permitted to escape without the acquiescence and approval of the director? Sadly, there are organizations that embody some of these conditions, and the resultant adverse effects on employee productivity, creativity and morale are profound. But what if you could work in an organization in which there was little hierarchy, where rank and seniority played no part, where there were no closed meetings or doors, where everyone knows what was expected of them, and where creativity was not only tolerated but encouraged and celebrated? Was there ever such a place? There was, and it was known as NASA's Space Station Task Force. I was fortunate enough to work there for a time, and I would like to tell you how this organization with few apparent rules led to incredibly high levels of employee satisfaction and fulfillment, and yielded work products of enduring quality. On May 20, 1982, NASA Administrator James M. Beggs established the Space Station Task Force under the direction of John D. Hodge. The Task Force was charged with the responsibility for "the development of the programmatic aspects of a Space Station as they evolve, including mission analysis, requirements definition and program management," and was authorized to draw on Space Station activities at the NASA Program Offices and Field Centers. No additional conditions or directions were provided. Hodge knew that in order to accomplish the job he had been given, he was going to have to obtain the services of the "best and the brightest" and facilitate the unleashing of the full force of their creative capabilities. In order to avoid the stultifying effects of a typical hierarchical organization, he set up a loosely structured, horizontal organization with only one supervisor of record - himself. He populated this organization with detailees from Headquarters, the field Centers and the Jet Propulsion Lab, thereby assuring himself of the political and technical expertise with which to deal with Congress and the bureaucracy, and conduct the required engineering studies and analyses.
The Space Life Sciences directorate (SLSD) and Human Research Program (HRP) at NASA Johnson Space Center has implemented a system for managing human systems risks. These risks are defined as the health and performance risks posed to crew during and after spaceflight. Identification and evaluation of these risks has led to the identification of gaps in knowledge about the risks as well as gaps in technology needed to mitigate them. Traditional routes of closing technology gaps have, in some cases, proven to be too slow when a solution was required quickly. Therefore, certain gaps were used to drive the development of "challenges" for the scientific community. Partnering with open innovation service providers such as InnoCentive and Yet2.com, SLSD and HRP have decreased the amount of time from identification of a need to the evaluation of a solution. Although not all proposed solutions will result in a risk mitigation strategy or tool, the process has allowed faster evaluation of proposed solutions providing the researcher the ability to move to another possible solution if the first does not sufficiently address the problem. Moreover, this process engages the community outside of NASA and broadens the population from which to draw solutions. In the traditional grant funding structure, only those in the specific field will apply for the grant. However, using open innovation, solutions can come from individuals in many different fields. This can expand the general view of a field (way of thinking within a field) and the application of solutions form new fields while providing a pathway for the acquisition of novel solutions or refinements of current mitigations. Identification of the human systems risks has helped drive the development and evaluation of innovative solutions as well as engaging a broader scientific audience in working with NASA.
Capitalizing on optical data products and applying them to generate a more complete understanding of orbital space objects, is a key objective of NASA's Optical Measurement Program, and a primary objective for the creation of the Optical Measurements Center(OMC). The OMC attempts to emulate space-based illumination conditions using equipment and techniques that parallel telescopic observations and source-target-sensor orientations. The data acquired in the OMC are a function of known shape, size, and material. These three physical parameters are key to understanding the orbital debris environment in more depth. For optical observations, one must rely on spectroscopic or photometric measurements to ascertain an object's material type. Determination of an object s shape using remote observations is more complicated due to the various light scattering properties each object present and is a subject that requires more study. It is much easier to look at the periodicity of the light curve and analyze its structure for rotation. In order to best simulate the orbital debris population, three main sources were used as test fragments for optical measurements: flight-ready materials, destructive hypervelocity testing (simulating on-orbit collisions) and destructive pressure testing (simulating on-orbit explosions). Laboratory optical characteristics of fragments were measured, including light curve shape, phase angle dependence, and photometric and spectroscopic color indices. These characteristics were then compared with similar optical measurements acquired from telescopic observations in order to correlate remote and laboratory properties with the intent of ascertaining the intrinsic properties of the observed orbital debris
The Geospace Dynamics Constellation (GDC), with an anticipated launch by the end of thedecade, can provide a unique dataset and modeling effort to support heterogeneousdistributed studies of auroral electrodynamics. On its own, GDC will fully characterize thelarger scale context for auroral electrodynamics, including the electric Meld/ion drift, plasmawaves and irregularities/small-scale structure, Meld-aligned and horizontal current, andenergetic electron and ion populations, with multipoint measurements that can assesslongitudinal gradients on scales of 300+ km, and in-track/latitudinal scales of approximately10 km, on timescales ranging from seconds to tens of minutes. In addition, GDC will fullycharacterize the thermosphere and ionosphere populations, including new capabilities likemeasurements of 3-d neutral wind, and detailed assessment of the neutral and ioncomposition and the plasma density proMles.When added to other space-based and ground-based assets, which may provide Mne-scaleelectrodynamics, time history of energy inputs and forcing, or altitude proMles of plasma driftsand density, the combined heterogeneous dataset will represent a groundbreaking opportunityto advance the science of auroral electrodynamics. GDC is particularly well suited as a'strategic hub' that can be leveraged by other observation campaigns with focus on GDC-adjacent science. For example, constellations of satellites able to measure Mne-scalestructure, or sounding rocket missions, or dedicated ground-based observing campaigns, inconjunction with advanced local-scale and regional-scale modeling show great promise incoordination with GDC.We will present the current status of GDC, its sampling scheme, measurement parameters,and a summary of instrumentation, in addition to several potential sampling scenarios thatmay be of particular interest for studies of auroral electrodynamics.
The microscopic understanding of probing and controlling molecular chirality is of considerable interest. Numerous spectroscopic techniques are capable of monitoring molecular asymmetry and its consequences, ranging from the infrared to the X-ray regime. Resonant X-rays have long been used to investigate local atomic sites within molecules thanks to the localized nature of core electronic transitions. These techniques can be used to determine the extent to which chirality is a local versus a delocalized property. However, how to systematically partition dichroic contributions from the point of view of electronic structure simulations remains an open question. Here, we introduce the concept of chiral population analysis that connects chirality to the atomic orbital picture. In analogy with Mulliken population analysis, which assigns charges to atomic orbitals, chiral populations allow the dichroic response to be distributed among the participating atomic orbitals. This decomposition can be further visualized in real space by representing it in terms of isosurface plots, providing an intuitive way to connect the dichroic response to its origins. Thus chiral population analysis can be particularly useful to assess the extent to which a given electronic transition is sensitive to chirality as a local or global feature of the molecular geometry.
We explore dynamic interactions between the crystal lattice and magnetic degrees of freedom in a frustrated magnetic system using the example of a pyrochlore quantum spin-ice candidate Pr 2 Zr 2 O 7 . Using Raman scattering spectroscopy we demonstrate that crystal electric field excitations of Pr3+, which define the magnetic properties of Pr 2 Zr 2 O 7 , cannot be understood within a model of a static lattice. We identify vibronic interactions with a phonon which lead to a splitting of a doublet crystal field excitation at around 55 meV. We also observe an unconventional behavior of a splitting of the non-Kramers ground state doublet of Pr 3+ , revealed by observing excitations to the first excited singlet state $E$$^{0}_{g}$ → A 1 g at around 10 meV. The splitting has a strong temperature dependence, where the doublet structure is most prominent between 50 and 100 K, and the weight of one of the components strongly decreases on cooling contrary to simple thermal population tendency. Furthermore, we suggest a static or dynamic deviation of Pr 3+ from the position in the ideal crystal structure can be the origin of the effect, with the deviation strongly decreasing at low temperatures.
Significance Landscapes are spatially heterogeneous, and the measurement of spatial pattern is dependent upon observation scale. Understanding plant populations requires assessing their extrinsic interactions with the environment as well as intrinsic biological processes and has been difficult because of the inability to track both plant abundance and health on appropriate scales. We introduce remote sensing observations that assess the abundance and health of giant kelp, an important ecosystem-structuring species, over regional and local scales. We find that both extrinsic nutrient availability and intrinsic senescence processes regulate population dynamics but on regional and local scales, respectively. This suggests that future satellite missions will be able to assess plant abundance and health and their interactions with the environment on local to global scales.
Smectite-based adsorbents are increasingly being studied as sustainable packaging materials for scavenging ethylene, a plant hormone that accelerates fruit ripening. However, the mechanisms governing their uptake and retention remain poorly understood. Here, to tackle this question we systematically investigate ethylene gas-solid interactions in pristine, acid-activated, and choline-functionalized montmorillonites using a complementary combination of structural, gravimetric, and spectroscopic techniques, including inelastic neutron scattering. We experimentally distinguish ethylene populations associated with interlayer confinement, mesopore, and external surface adsorption. We show that chemical functionalization distinctly controls adsorption pathways: acid activation enhances total uptake by generating mesoporous adsorption sites and promoting partial interlayer intercalation, yielding capacities comparable to those of leading smectite-based adsorbents, while choline functionalization promotes preferential confinement and stabilization of guest molecules within the interlayer galleries. Advanced spectroscopic analysis provides molecular-level insight into confinement environments and interaction strengths. We also establish clear structure-property relationships by correlating uptake values derived from independent techniques, linking chemical modification, accessible adsorption domains, and retention behavior. These findings provide general design principles for tuning gas-solid interactions in functionalized layered silicates and highlight their potential as adaptable platforms for sustainable ethylene gas capture and selective adsorption technologies.
The ability to tie structural features to a fuel candidate’s ignition properties provides a path for rational design of advantaged fuels that facilitate higher-efficiency, lower-emitting combustion in engines. The time evolution of a fuel’s radical population directly correlates with global combustion parameters, and because the generated radicals depend on the initial structure and reaction pathways of the fuel molecule, it follows that the molecular structure of a fuel has a direct impact on this cascade, and therefore salient ignition-tied fuel properties. This work aims to understand the impact of structural features in the context of global combustion properties for direct application to emerging engine technologies. Specifically, we highlight the ability to identify potential fuel blendstocks for specific engine strategies by examining and elucidating the radical cascade tied to ignition. A representative subset of alcohols possessing a variety of structural features (e.g. branching, chain length) was selected for study using a robust combination of experimental and computational methods. The approach begins with identifying short-lived radicals and likely abstraction sites upon pyrolysis in a microreactor coupled with photoionization mass spectrometry for direct detection of product species. In tandem, electronic structure calculations were performed to calculate the relevant potential energy surfaces for fuel pyrolysis as well as the subsequent O2 addition-isomerization reactions, which govern ignition behavior. Furthermore, the theoretical energetic and ro-vibrational data are used to calculate rate constants for direct ignition modeling to explore how structural effects impact NTC behavior. The microreactor data combined with electronic structure theory calculations provide a well-informed picture of the reactions relevant to ignition for each fuel in this study, as well as the most likely radicals generated under engine conditions. This thorough fundamental picture of fuel decomposition and ignition chemistry is used to correlate the observed ignition behavior to molecular structural effects.
The globular cluster omega Centauri contains the largest known population of very hot horizontal branch (HB) stars. We have used the Hubble Space Telescope to obtain a far-UV/optical color-magnitude diagram of three fields in omega Cen. We find that over 30% of the HB objects are "extreme" HB or hot post-HB stars. A wide gap in the color distribution of the hot HB stars may correspond to gaps found earlier in several other clusters, which argues for a common mass loss mechanism. The diagram contains a significant population of hot sub-HB stars, which we interpret as the "blue-hook" objects predicted by D'Cruz (1996a). These are produced by late He-flashes in stars which have undergone unusually large giant branch mass loss. Omega Cen has a well-known spread of metal abundance, and the diagram is consistent with a giant branch mass loss efficiency which increases with metallicity. There is no evidence for a dynamical origin of the hot HB stars.
Application of a mild (60 mT), uniform magnetic field during short-term thermal treatment of kinetically retained, atomically disordered (paramagnetic) ε-MnAl was found to deliver a significant ~50 % increase in the formation of L1 0 atomically ordered (ferromagnetic) τ-MnAl product phase, compared to that produced by conventional (i.e., zero-field) annealing under identical thermal conditions. The magnetic field, applied in a passive closed-circuit configuration during annealing, induced significant changes in the structural, magnetic, and phase evolution of the material. Computational results based on electronic structure calculations demonstrate that the effective magnetic susceptibility of τ-MnAl is sensitive to the orientation, rather than the magnitude, of an applied magnetic field in the vicinity of the Curie temperature. The uniaxial magnetocrystalline anisotropy of the L1 0 structure is proposed to act as a filter for selective propagation of the population of τ-MnAl variants that are favorably aligned with the applied field. In this manner, crystallographic “gridlock” is alleviated that would otherwise arise from the coexistence of multiple, energetically equivalent τ-phase variants within the parent ε-phase matrix. These results confirm that static, low-magnitude magnetic field annealing is able to accelerate L1 0 atomic ordering in the MnAl system and likely can exert similar influences in relevant magnetic systems, facilitating efficient tailoring of structure-sensitive magnetic properties for the manufacture of magnetic materials.
Organic C has many benefits for soil, but it is depleted by tillage and crop harvest, and especially so for biofuel crops. Accordingly, strategies such as partially retaining stover or planting a cover crop can help ameliorate the negative effect of C removal. We used a long-term field experiment to study the impacts of stover retention and planting cover crop on soil organic matter (SOM), its extractable components and the soil microbial community. SOM chemical composition characterization was determined by electrospray ionization (ESI) coupled with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) in sequential water, methanol (MeOH), and chloroform (CHCl3) extracts. The characteristics of the soil bacterial community were measured by phospholipid fatty acid (PLFA), real-time quantitative PCR, and 16S rRNA gene sequence. The variations in total SOM content, total microbial biomass, and bacterial population were slight among treatments, but SOM chemical compounds, arbuscular mycorrhizal fungi (AMF) biomass, and bacterial structure changed significantly, and especially so in the coupled application of stover retention and cover crop. Specifically, stover retention enriched more lignin-like compounds in soil, whereas cover crop enriched more condensed hydrocarbons, and had more compounds with an aromaticity index (AI) >0.5. The bacterial community was not altered by the cover crop, but the corn stover retention increased the relative abundances of Myxococcales (Deltaproteobacteria) and decreased that of Actinobacteria. Redundancy analysis (RDA) further unveiled that the bacterial community in the stover treatments had significantly positive association with CHCl3-extracted chemical classes, i.e. unsaturated hydrocarbon and lipid with the coupled application (stover and cover crop), and lignin and protein with the single corn stover treatment. Taken together, our study shows how different C addition practices influence the molecular composition of SOM and the structure of soil microbial communities.
Electronic spin superposition states enable nanoscale sensing through their sensitivity to the local environment, yet their sensitivity to vibrational motion also limits their coherence times. In molecular spin systems, chemical tunability and atomicscale resolution are accompanied by a dense, thermally accessible phonon spectrum that introduces efficient spin relaxation pathways. Despite extensive theoretical work, there is little experimental consensus on which vibrational energies dominate spin relaxation or how molecular structure controls spin−phonon coupling (SPC). We present a fully experimental method to quantify SPC coefficients by combining temperature-dependent vibrational spectra from inelastic neutron scattering with spin relaxation rates measured by electron paramagnetic resonance. We apply this framework to two model S = 1/2 systems, copper(II) phthalocyanine (CuPc) and copper(II) octaethylporphyrin (CuOEP). Two distinct relaxation regimes emerge: below 40 K, weakly coupled lattice modes below 50 cm −1 dominate, whereas above 40 K, optical phonons above ∼185 cm −1 become thermally populated and drive relaxation with SPC coefficients nearly 3 orders of magnitude larger. Structural distortions in CuOEP that break planar symmetry soften the crystal lattice and enhance anharmonic scattering but also raise the energy of stretching modes at the molecular core where the spins reside. This redistributes vibrational energy toward the molecular periphery and out of plane, ultimately reducing SPC relative to CuPc and enabling room-temperature spin coherence in CuOEP. Although our method does not provide mode-specific SPC coefficients, it quantifies contributions from distinct spectral regions and establishes a broadly applicable, fully experimental link between crystal structure, lattice dynamics, and spin relaxation.
During the Winter and Fall 2001 observing campaigns, we obtained multifilter photometry using the Quest camera on the 1mt Schmidt of the Venezuelan National Observatory, to continue the survey of the Orion clouds. In the Winter 2001 season, we obtained photometry for 9 scans at DEC=+5, 3 scans at DEC=-5, and 2 scans at DEC=-3, while 2 additional scans at DEC=-3 were obtained during the Fall 2001 observing campaign (the width of each scan is 2.3 arc minutes). The photometric survey has not been completed this season because the instrument was damaged by lightening on Sep 2001 and operations were suspended until Dec 2001. Observations are still under way. Nonetheless, we have enough scans at -3 and +5 to start selecting candidates for spectroscopic follow up on the next season. Spectra of more than 300 objects was obtained with the FAST spectrograph on the Mt Hopkins 48 inch telescope during observing campaigns Jan-March 2001, and Oct-Dec 2001. Bad weather prevented observations with Hydra on the WIYN telescope on KPNO in Jan 2001. The FAST spectra are been analyzed to select the young population of the regions. Observations in the JHKL bands were obtained for a sample of 20-30 objects in Ori Ia and Ib from scan centered at DEC=-l, with the StellIRCam on the Mt Hopkins 48 inch telescope on Nov 2001. L band observations will be effective for picking up objects surrounded by accretion disks, in which inner disk holes prevent having any excess at shorter wavelength bands. Observations at 10 micrometers and 18 micrometers were obtained in que mode for a sample of 20 objects in Ori Ia and Ib in the same regions as the near IR photometry with the Gemini-South telescope. These new data is presently been reduced and analyzed, together with data from the observing campaigns of 2000. Analysis of Hydra fields at strips centered at DEC=-1 and +1 have confirmed 105 more candidates as low mass pre-main sequence objects. In addition, every target was detected at 10 micrometers and a few at 18 micrometers. With these data, combined with our optical and JHKL photometry, we will construct spectral energy distributions. This will allow us to begin studying the structure of disks around low mass T Tauri stars in the distributed population of the Orion clouds, for direct comparison with that of Taurus. Ours is the first determination of the infrared emission of protoplanetary disks around low mass stars in the Orion region.