Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Organic LED”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Beyond Charge Balance: Counter-Cations in Polyoxometalate Chemistry

Polyoxometalates (POMs) are molecular metal-oxide anions applied in energy conversion and storage, manipulation of biomolecules, catalysis, as well as materials design and assembly. Although often overlooked, the interplay of intrinsically anionic POMs with organic and inorganic cations is crucial to control POM self-assembly, stabilization, solubility, and function. Beyond simple alkali metals and ammonium, chemically diverse cations including dendrimers, polyvalent metals, metal complexes, amphiphiles, and alkaloids allow tailoring properties for known applications, and those yet to be discovered. This review provides an overview of fundamental POM– cation interactions in solution, the resulting solid-state compounds, and behavior and properties that emerge from these POM–cation interactions. We will explore how application-inspired research has exploited cation-controlled design to discover new POM materials, which in turn has led to the quest for fundamental understanding of POM–cation interactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Structural study of Ca{sub 2}Gd{sub 2}Ge{sub 2}O{sub 9} and optical spectroscopy of the Eu{sup 3+} dopant ion

The new rare earth-based germanate compound Ca{sub 2}Gd{sub 2}Ge{sub 2}O{sub 9} (orthorhombic (Pnma) crystal structure), has been characterized and investigated for the first time, using synchrotron powder X-ray diffraction. From Rietveld refinement calculations on the collected powder pattern we observe an inhomogeneous distribution of the two available cationic sites by Gd{sup 3+} and Ca{sup 2+} ions. In particular, the former prefers the occupation (67.5%) of the site with 8-fold coordination. In addition, we observed a not negligible degree of distortion of the Ge{sub 2}O{sub 7}{sup 6−} unit. Finally, luminescence spectra and decay curves of Eu{sup 3+} doped Ca{sub 2}Gd{sub 2}Ge{sub 2}O{sub 9} were measured and analysed taking into account the structural features of the host. The results reveal that this material shows strong red luminescence upon excitation in the region where blue LEDs emit (470 nm). - Graphical abstract: The structural study on Ca{sub 2}Gd{sub 2}Ge{sub 2}O{sub 9} exploiting synchrotron X-ray diffraction, allows us to determine the detailed geometry of the metal coordination polyhedra, which is closely related to the emission luminescence spectroscopy of the Eu{sup 3+} dopant ion introduced as impurity in this host. - Highlights: • The crystal structure of the Ca{sub 2}Gd{sub 2}Ge{sub 2}O{sub 9} was determined. • Gd{sup 3+} ion is distributed on two crystal sites with different occupation. • A structural study focused on the metal coordination polyhedra was performed. • Two emitting sites are detected for Eu{sup 3+} dopant ion in Ca{sub 2}Gd{sub 2}Ge{sub 2}O{sub 9}. • Strong red luminescence by excitation in the region where blue LEDs emit was found.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Operating organic light-emitting diodes imaged by super-resolution spectroscopy

Super-resolution stimulated emission depletion microscopy is adapted here for materials characterization that would not otherwise be possible. With the example of organic lightemitting diodes (OLEDs), spectral imaging with pixel-by-pixel wavelength discrimination allows us to resolve local-chain environment encoded in the spectral response of the semiconducting polymer, and correlate chain packing with local electroluminescence by using externally applied current as the excitation source. We observe nanoscopic defects that would be unresolvable by traditional microscopy. They are revealed in electroluminescence maps in operating OLEDs with 50 nm spatial resolution. We find that brightest emission comes from regions with more densely packed chains. Conventional microscopy of an operating OLED would lack the resolution needed to discriminate these features, while traditional methods to resolve nanoscale features generally cannot be performed when the device is operating. Furthermore, this points the way towards real-time analysis of materials design principles in devices as they actually operate.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2022

Chemical crystallography by serial femtosecond X-ray diffraction

Abstract Inorganic–organic hybrid materials represent a large share of newly reported structures, owing to their simple synthetic routes and customizable properties 1 . This proliferation has led to a characterization bottleneck: many hybrid materials are obligate microcrystals with low symmetry and severe radiation sensitivity, interfering with the standard techniques of single-crystal X-ray diffraction 2,3 and electron microdiffraction 4–11 . Here we demonstrate small-molecule serial femtosecond X-ray crystallography (smSFX) for the determination of material crystal structures from microcrystals. We subjected microcrystalline suspensions to X-ray free-electron laser radiation 12,13 and obtained thousands of randomly oriented diffraction patterns. We determined unit cells by aggregating spot-finding results into high-resolution powder diffractograms. After indexing the sparse serial patterns by a graph theory approach 14 , the resulting datasets can be solved and refined using standard tools for single-crystal diffraction data 15–17 . We describe the ab initio structure solutions of mithrene (AgSePh) 18–20 , thiorene (AgSPh) and tethrene (AgTePh), of which the latter two were previously unknown structures. In thiorene, we identify a geometric change in the silver–silver bonding network that is linked to its divergent optoelectronic properties 20 . We demonstrate that smSFX can be applied as a general technique for structure determination of beam-sensitive microcrystalline materials at near-ambient temperature and pressure.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Radioiodine Biogeochemistry and Prevalence in Groundwater

129I is commonly either the top or among the top risk drivers, along with 99Tc, at radiological waste disposal sites and contaminated groundwater sites where nuclear material fabrication or reprocessing has occurred. The risk stems largely from 129I having a high toxicity, a high bioaccumulation factor (90% of all the body’s iodine concentrates in the thyroid), a high inventory at source terms (due to its high fission yield), an extremely long half-life (16M yr), and rapid mobility in the subsurface environment. Another important reason that 129I is a key risk driver is that there is the uncertainty regarding its biogeochemical fate and transport in the environment. We typically can define 129I mass balance and flux at sites, but cannot predict accurately its response to changes in the environment. As a consequence of some of these characteristics, 129I has a very low Drinking Water Standard, DWS, which is set at 1 pCi/L, the lowest of all radionuclides in the Federal Register. Recently, significant advancements have been made in detecting iodine species at ambient groundwater concentrations, defining the nature of the organic matter and iodine bond, and quantifying the role of naturally occurring sediment microbes to promote iodine oxidation and reduction. These recent studies have led to a more mechanistic understanding of radioiodine biogeochemistry. The objective of this review is to describe these advances and to provide a state of the science of radioiodine biogeochemistry relevant to its fate and transport in the terrestrial environment and provide information useful for making decisions regarding the stewardship and remediation of 129I contaminated sites. As part of this review, knowledge gaps were identified that would significantly advance the goals of basic and applied research programs for accelerating 129I environmental remediation and reducing uncertainty associated with disposal of 129I waste. Together the information gained from addressing these knowledge gaps will not alter the observation that 129I is primarily mobile, but it will likely permit demonstration that the entire 129I pool in the source term is not moving at the same rate and some may be tightly bound to the sediment, thereby “smearing” the modeled 129I peak and reducing maximum calculated risk.

Kaplan, Daniel I.↗
DOE OSTI2021

“Experimental investigation of the governing parameters of atmospheric ice nucleation using field-collected and laboratory generated aerosol particles and its application in cloud resolving models” (Final Report)

The objective of this research project is to improve our understanding of the role of aerosol particles acting as ice-nucleating particles (INPs) which in turn define the mixed-phase and cirrus cloud radiative properties and thus climate. The focus is placed on how the physicochemical particle population properties determine the particles’ ability to initiate ice nucleation. This research project combined micro-spectroscopic particle analysis, experimental ice nucleation studies, and model sensitivity studies to advance our predictive capability of the formation of mixed-phase and cirrus clouds. These project activities have led to new ice nucleation data from laboratory generated and ambient (authentic) aerosol particles furthering process-level understanding, insights in the role of organic aerosol in ice formation, and advancements in the interpretation and parameterization of ice nucleation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Toward Understanding Phage:Host Interactions in the Rumen; Complete Genome Sequences of Lytic Phages Infecting Rumen Bacteria

The rumen is known to harbor dense populations of bacteriophages (phages) predicted to be capable of infecting a diverse range of rumen bacteria. While bacterial genome sequencing projects are revealing the presence of phages which can integrate their DNA into the genome of their host to form stable, lysogenic associations, little is known of the genetics of phages which utilize lytic replication. These phages infect and replicate within the host, culminating in host lysis, and the release of progeny phage particles. While lytic phages for rumen bacteria have been previously isolated, their genomes have remained largely uncharacterized. Here we report the first complete genome sequences of lytic phage isolates specifically infecting three genera of rumen bacteria: Bacteroides , Ruminococcus , and Streptococcus . All phages were classified within the viral order Caudovirales and include two phage morphotypes, representative of the Siphoviridae and Podoviridae families. The phage genomes displayed modular organization and conserved viral genes were identified which enabled further classification and determination of closest phage relatives. Co-examination of bacterial host genomes led to the identification of several genes responsible for modulating phage:host interactions, including CRISPR/ Cas elements and restriction-modification phage defense systems. These findings provide new genetic information and insights into how lytic phages may interact with bacteria of the rumen microbiome.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Comparative Genomic Analysis of Ochratoxin A Biosynthetic Cluster in Producing Fungi: New Evidence of a Cyclase Gene Involvement

The widespread use of Next-Generation Sequencing has opened a new era in the study of biological systems by significantly increasing the catalog of fungal genomes sequences and identifying gene clusters for known secondary metabolites as well as novel cryptic ones. However, most of these clusters still need to be examined in detail to completely understand the pathway steps and the regulation of the biosynthesis of metabolites. Genome sequencing approach led to the identification of the biosynthetic genes cluster of ochratoxin A (OTA) in a number of producing fungal species. Ochratoxin A is a potent pentaketide nephrotoxin produced by Aspergillus and Penicillium species and found as widely contaminant in food, beverages and feed. The increasing availability of several new genome sequences of OTA producer species in JGI Mycocosm and/or GenBank databanks led us to analyze and update the gene cluster structure in 19 Aspergillus and 2 Penicillium OTA producing species, resulting in a well conserved organization of OTA core genes among the species. Furthermore, our comparative genome analyses evidenced the presence of an additional gene, previously undescribed, located between the polyketide and non-ribosomal synthase genes in the cluster of all the species analyzed. The presence of a SnoaL cyclase domain in the sequence of this gene supports its putative role in the polyketide cyclization reaction during the initial steps of the OTA biosynthesis pathway. The phylogenetic analysis showed a clustering of OTA SnoaL domains in accordance with the phylogeny of OTA producing species at species and section levels. The characterization of this new OTA gene, its putative role and its expression evidence in three important representative producing species, are reported here for the first time.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1980

Changes of the body functions during long-term hypokinesia

Prolonged hypokinesis (100-170 days) studied in 2000 rats kept in cages limiting their mobility provoked considerable changes in the gaseous and energetic metabolism: an elevation of the total gaseous metabolism and of the rate of O2 requirement by the muscles (in the late periods of hypokinesis) and a change in the intensity of tissue respiration of the liver and myocardium. There also proved to be a reduction in the level of phosphorylation and separation of oxidative phosphorylation in the myocardium, liver, and partially in the skeletal muscle. Prolonged hypokinesia led to changes in tissue metabolism: a disturbance of development of the animals, a marked delay and an increase in the weight of the organism and the muscular system, and disturbances of the mineral and protein metabolism. Prolonged hypokinesis also lead to exhaustion of the hypothalamus-hypophysis-adrenal cortex system.

Kovalenko, Y. A.↗
NASA NTRS1985

STS-8 atomic oxygen effects experiment

A flight experiment was performed on the eighth Space Shuttle mission to measure reaction of surfaces with atomic oxygen in the low earth orbital environment. More than 300 individual samples were exposed to ram (normal to surface) conditions for 41.75 hr leading to a total atomic oxygen fluence of 3.5 x 10 to the 20th atoms/sq cm. Reaction rates for surface recession measured primarily by mass change of several organic films were in the range of 3.0 x 10 to the -24th cu cm/atom, and less than 5 x 10 to the -26th cu cm/atom for Teflon. Effects of parameters such as temperature and solar radiation were assessed, as was the importance of atmospheric ionic species on surface recession. In an experiment performed on the fifth Space Shuttle flight, no temperature dependence of reaction rate for the organic films studied was found in the temperature range of 25 to 125 C. Preliminary findings indicate that the reactivity of organic films is not affected by temperature (in the range of 65 to 125 C), solar radiation, or ionic species. Significant surface morphology changes led to a carpet-like appearance also consistent with previous findings.

Visentine, J. T.↗
NASA NTRS2008

Software Archive Related Issues

With the archive opening of the major X-ray and Gamma ray missions, the school is intended to provide information on the resource available in the data archive and the public software. This talk reviews the archive content, the data format for the major active missions Chandra, XMM-Newton, Swift, RXTE, Integral and Suzaku and the available software for each of these missions. It will explain the FITS format in general and the specific layout for the most popular mission, explaining the role of keywords and how they fit in the multimission standard approach embrace by the High Energy Community. Specifically, it reviews : the difference data levels and the difference software applicable; the popular/standard method of analysis for high level products such as spectra, timing and images; the role of calibration in the multi mission approach; how to navigate the archive query databases. It will present also how the school is organized and how the information provided will be relevant to each of the afternoon science projects that will be proposed to the students and led by a project leader

Angelini, Lorella↗
NASA NTRS2010

Tracking Provenance of Earth Science Data

Tremendous volumes of data have been captured, archived and analyzed. Sensors, algorithms and processing systems for transforming and analyzing the data are evolving over time. Web Portals and Services can create transient data sets on-demand. Data are transferred from organization to organization with additional transformations at every stage. Provenance in this context refers to the source of data and a record of the process that led to its current state. It encompasses the documentation of a variety of artifacts related to particular data. Provenance is important for understanding and using scientific datasets, and critical for independent confirmation of scientific results. Managing provenance throughout scientific data processing has gained interest lately and there are a variety of approaches. Large scale scientific datasets consisting of thousands to millions of individual data files and processes offer particular challenges. This paper uses the analogy of art history provenance to explore some of the concerns of applying provenance tracking to earth science data. It also illustrates some of the provenance issues with examples drawn from the Ozone Monitoring Instrument (OMI) Data Processing System (OMIDAPS) run at NASA's Goddard Space Flight Center by the first author.

Tilmes, Curt↗
NASA NTRS2017

Search for Primitive Matter in the Solar System

Recent astronomical observations and theoretical modeling led to a consensus regarding the global scenario of the formation of young stellar objects (YSO) from a cold molecular cloud of interstellar dust (organics and minerals) and gas that, in some cases, leads to the formation of a planetary system. In the case of our Solar System, which has already evolved for approximately 4567 Ma, the quest is to access, through the investigation of planets, moons, cometary and asteroidal bodies, meteorites, micrometeorites, and interplanetary dust particles, the primitive material that contains the key information about the early Solar System processes and its evolution. However, laboratory analyses of extraterrestrial samples, astronomical observations and dynamical models of the Solar System evolution have not brought yet any conclusive evidence on the nature and location of primitive matter in the Solar System, preventing a clear understanding of its early stages.

Libourel, G.↗
DOE OSTI2013

Standards Increase Market Confidence in SSL Performance

Fact sheet that reviews current and future SSL standards developed by DOE and other standards-setting organizations to effectively measure and characterize SSL lighting products.

ssl, solid-state, lighting, standards, market, LED↗
DOE OSTI2021

Microbial seasonality promotes soil respiratory carbon emission in natural ecosystems: A modeling study

Seasonality is a key feature of the biosphere and the seasonal dynamics of soil carbon (C) emissions represent a fundamental mechanism regulating the terrestrial–climate interaction. We applied a microbial explicit model—CLM-Microbe—to evaluate the impacts of microbial seasonality on soil C cycling in terrestrial ecosystems. Additionally, the CLM-Microbe model was validated in simulating belowground respiratory fluxes, that is, microbial respiration, root respiration, and soil respiration at the site level. On average, the CLM-Microbe model explained 72% (n = 19, p < 0.0001), 65% (n = 19, p < 0.0001), and 71% (n = 18, p < 0.0001) of the variation in microbial respiration, root respiration, and soil respiration, respectively. We then compared the model simulations of soil respiratory fluxes and soil organic C content in top 1 m between the CLM-Microbe model with (CLM-Microbe) and without (CLM-Microbe_wos) seasonal dynamics of soil microbial biomass in natural biomes. Removing soil microbial seasonality reduced model performance in simulating microbial respiration and soil respiration, but led to slight differences in simulating root respiration. Compared with the CLM-Microbe, the CLM-Microbe_wos underestimated the annual flux of microbial respiration by 0.6%–32% and annual flux of soil respiration by 0.4%–29% in natural biomes. Correspondingly, the CLM-Microbe_wos estimated higher soil organic C content in top 1 m (0.2%–7%) except for the sites in Arctic and boreal regions. Our findings suggest that soil microbial seasonality enhances soil respiratory C emissions, leading to a decline in SOC storage. An explicit representation of soil microbial seasonality represents a critical improvement for projecting soil C decomposition and reducing the uncertainties in global C cycle projection under the changing climate.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2015

Composting of the solid fraction of digestate derived from pig slurry: Biological processes and compost properties

Highlights: • Anaerobic digestion leads to the production of a biologically stable digestate. • Solid–liquid separation produces a solid fraction having high fertilizer value. • Composting process shows low biological activity due to high biological stability of digestate. • Solid digestate fraction can be composted in a short time or used directly as organic fertilizer. - Abstract: The aim of this paper was to assess the characteristics of the solid fractions (SF) obtained by mechanical separation of digestate, their compostability and compost quality. To do so, the SF of digestates obtained from anaerobic digestion of pig slurry, energy crops and agro-industrial residues were sampled in five plants located in Northern Italy. Results obtained indicated that anaerobic digestion by itself promoted the high biological stability of biomasses with a Potential Dynamic Respiration Index (PDRI) close to 1000 mgO{sub 2} kg V S{sup −1} h{sup −1}. Subsequent composting of digestates, with an added bulking agent, did not give remarkably different results, and led only to a slight modification of the characteristics of the initial non-composted mixtures; the composts obtained fully respected the legal limits for high quality compost. Chemical studies of organic matter composition of the biomasses by using CP MAS {sup 13}C NMR, indicated that the compost was composed of a high relative content of O-alkyl-C (71.47% of total C) (cellulose and hemicelluloses) and a low alkyl-C (12.42%) (i.e. volatile fatty acids, steroid-like molecules, aliphatic biopolymers and proteins)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Nanoscale view of assisted ion transport across the liquid–liquid interface

During solvent extraction, amphiphilic extractants assist the transport of metal ions across the liquid–liquid interface between an aqueous ionic solution and an organic solvent. Investigations of the role of the interface in ion transport challenge our ability to probe fast molecular processes at liquid–liquid interfaces on nanometer-length scales. Recent development of a thermal switch for solvent extraction has addressed this challenge, which has led to the characterization by X-ray surface scattering of interfacial intermediate states in the extraction process. Here, we review and extend these earlier results. We find that trivalent rare earth ions, Y(III) and Er(III), combine with bis(hexadecyl) phosphoric acid (DHDP) extractants to form inverted bilayer structures at the interface; these appear to be condensed phases of small ion–extractant complexes. The stability of this unconventional interfacial structure is verified by molecular dynamics simulations. The ion–extractant complexes at the interface are an intermediate state in the extraction process, characterizing the moment at which ions have been transported across the aqueous–organic interface, but have not yet been dispersed in the organic phase. In contrast, divalent Sr(II) forms an ion–extractant complex with DHDP that leaves it exposed to the water phase; this result implies that a second process that transports Sr(II) across the interface has yet to be observed. Calculations demonstrate that the budding of reverse micelles formed from interfacial Sr(II) ion–extractant complexes could transport Sr(II) across the interface. Our results suggest a connection between the observed interfacial structures and the extraction mechanism, which ultimately affects the extraction selectivity and kinetics.

Liang, Zhu↗