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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Bayesian Integration and Characterization of Composition C-4 Plastic Explosives Based on Time-of-Flight Secondary Ion Mass Spectrometry and Laser Ablation-Inductively Coupled Plasma Mass Spectrometry
Key elements regarding the use of non-radioactive ionization sources will be presented as related to explosives detection by mass spectrometry and ion mobility spectrometry. Various non-radioactive ionization sources will be discussed along with associated ionization mechanisms pertaining to specific sample types.
Scalable Frontal Oligomerization: Insights from Advanced Mass Analysis
Linear oligomers of dicyclopentadiene (DCPD) are reactive precursors for thermoplastic and thermoset materials. Unlike the foul-smelling parent monomer, oligomers composed of DCPD are odorless. With appropriate modification of the end-group or backbone chemistry, telechelic DCPD oligomers have potential utility as cross-linkers and as macromonomer precursors for block and graft copolymers. Most existing methods to produce oligo-DCPD, however, require solvent, are relatively slow, and necessitate air-free techniques. Here we show that frontal ring-opening metathesis oligomerization (FROMO) of neat DCPD and other norbornene derivatives rapidly generates hundreds of grams of material in minutes with catalyst loadings of 0.5 mM. This energy-efficient catalytic process utilizes the heat generated by the reaction to self-propagate oligomerization throughout the liquid monomer. FROMO employs a terminal olefin (e.g., styrene) in which a cross-metathesis reaction (i.e., chain transfer) competes with ring-opening metathesis (i.e., propagation). Kendrick mass analysis enables rapid identification and assignment of all the chain-end types present and quantifies the degree of branching resulting from the infrequent cyclopentene ring-opening reaction. This analytical technique also detects oligomer species derived from trace impurities in the monomer or chain-transfer agent that are otherwise difficult to observe with other characterization methods. Here, the obtained oligomers possess well-defined chain-ends and molecular weight distributions.
Solid matrix transformation and tracer addition using molten ammonium bifluoride salt as a sample preparation method for laser ablation inductively coupled plasma mass spectrometry
Solid sampling and analysis methods, such as laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), are challenged by matrix effects and calibration difficulties. Matrix-matched standards for external calibration are seldom available and it is difficult to distribute spikes evenly into a solid matrix as internal standards. While isotopic ratios of the same element can be measured to high precision, matrix-dependent effects in the sampling and analysis process frustrate accurate quantification and elemental ratio determinations. Here we introduce a potentially general solid matrix transformation approach entailing chemical reactions in molten ammonium bifluoride (ABF) salt that enables the introduction of spikes as tracers or internal standards. Proof of principle experiments show that the decomposition of uranium ore in sealed PFA fluoropolymer vials at 230 °C yields, after cooling, new solids suitable for direct solid sampling by LA. When spikes are included in the molten salt reaction, subsequent LA-ICP-MS sampling at several spots indicate that the spikes are evenly distributed, and that U-235 tracer dramatically improves reproducibility in U-238 analysis. Precisions improved from 17% relative standard deviation for U-238 signals to 0.1% for the ratio of sample U-238 to spiked U-235, a factor of over two orders of magnitude. These results introduce the concept of solid matrix transformation (SMT) using ABF, and provide proof of principle for a new method of incorporating internal standards into a solid for LA-ICP-MS. This new approach, SMT-LA-ICP-MS, provides opportunities to improve calibration and quantification in solids based analysis. Finally, looking forward, tracer addition to transformed solids opens up LA-based methods to analytical methodologies such as standard addition, isotope dilution, preparation of matrix-matched solid standards, external calibration, and monitoring instrument drift against external calibration standard
The 2011 outburst of recurrent nova T PYX: Radio observations reveal the ejecta mass and hint at complex mass loss
Despite being the prototype of its class, T Pyx is arguably the most unusual and poorly understood recurrent nova. Here, we use radio observations from the Karl G. Jansky Very Large Array to trace the evolution of the ejecta over the course of the 2011 outburst of T Pyx. The radio emission is broadly consistent with thermal emission from the nova ejecta. However, the radio flux began rising surprisingly late in the outburst, indicating that the bulk of the radio-emitting material was either very cold, or expanding very slowly, for the first ∼50 days of the outburst. Considering a plausible range of volume filling factors and geometries for the ejecta, we find that the high peak flux densities of the radio emission require a massive ejection of (1-30) × 10{sup –5} M {sub ☉}. This ejecta mass is much higher than the values normally associated with recurrent novae, and is more consistent with a nova on a white dwarf well below the Chandrasekhar limit.
Starobinsky-like inflation and neutrino masses in a no-scale SO(10) model
Using a no-scale supergravity framework, we construct an SO(10) model that makes predictions for cosmic microwave background observables similar to those of the Starobinsky model of inflation, and incorporates a double-seesaw model for neutrino masses consistent with oscillation experiments and late-time cosmology. We pay particular attention to the behaviour of the scalar fields during inflation and the subsequent reheating.
Starobinsky-like inflation, supercosmology and neutrino masses in no-scale flipped SU(5)
We embed a flipped SU(5) × U(1) GUT model in a no-scale supergravity framework, and discuss its predictions for cosmic microwave background observables, which are similar to those of the Starobinsky model of inflation. Measurements of the tilt in the spectrum of scalar perturbations in the cosmic microwave background, n {sub s} , constrain significantly the model parameters. We also discuss the model's predictions for neutrino masses, and pay particular attention to the behaviours of scalar fields during and after inflation, reheating and the GUT phase transition. We argue in favor of strong reheating in order to avoid excessive entropy production which could dilute the generated baryon asymmetry.
String Theory Bounds on the Cosmological Constant, the Higgs Mass, and the Quark and Lepton Masses
In this paper, we elaborate on the new understanding of the cosmological constant and the gauge hierarchy problems in the context of string theory in its metastring formulation, based on the concepts of modular spacetime and Born geometry. The interplay of phase space (and Born geometry), the Bekenstein bound, the mixing between ultraviolet (UV) and infrared (IR) physics and modular invariance in string theory is emphasized. This new viewpoint is fundamentally rooted in quantum contextuality and not in statistical observer bias (anthropic principle). We also discuss the extension of this point of view to the problem of masses of quarks and leptons and their respective mixing matrices.
Characterizing K2 Candidate Planetary Systems Orbiting Low-mass Stars. I. Classifying Low-mass Host Stars Observed during Campaigns 1–7
We present near-infrared spectra for 144 candidate planetary systems identified during Campaigns 1–7 of the NASA K2 Mission. The goal of the survey was to characterize planets orbiting low-mass stars, but our Infrared Telescope Facility/SpeX and Palomar/TripleSpec spectroscopic observations revealed that 49% of our targets were actually giant stars or hotter dwarfs reddened by interstellar extinction. For the 72 stars with spectra consistent with classification as cool dwarfs (spectral types K3–M4), we refined their stellar properties by applying empirical relations based on stars with interferometric radius measurements. Although our revised temperatures are generally consistent with those reported in the Ecliptic Plane Input Catalog (EPIC), our revised stellar radii are typically 0.13 R{sub ⊙} (39%) larger than the EPIC values, which were based on model isochrones that have been shown to underestimate the radii of cool dwarfs. Our improved stellar characterizations will enable more efficient prioritization of K2 targets for follow-up studies.
Mass-spectrometric measurements on the distribution of he super plus, n super plus, no super plus, and o2 super plus ions in the earth's atmosphere up to an altitude of 430 km <mass-spektrometricheskiy izmereniya raspredeleniya ionov he super plus, n
Mass spectrometric measurements of atmospheric distribution of helium, nitrogen, oxygen and nitrogen oxide ions to 430 km altitude
A series of small mass spectrometers for investigating the composition of neutral and ionized gases in the upper layers of the atmosphere <seriya malogabaritnykh mass- spectrometrov dlya issledovaniya sostava neytralnykh iionizirovannykh gazov verkh
Mass spectrometer for investigating composition of neutral and ionized gases in upper layers of atmosphere
The Hyper-inflation Stage in the Coronal Mass Ejection Formation: A Missing Link That Connects Flares, Coronal Mass Ejections, and Shocks in the Low Corona
We analyze the formation and three-dimensional (3D) evolution of two coronal mass ejections (CMEs) and their associated waves in the low corona via a detailed multi-viewpoint analysis of extreme-ultraviolet observations. We analyze the kinematics in the radial and lateral directions and identify three stages in the early evolution of the CME: (1) a hyper-inflation stage, when the CME laterally expands at speeds of ∼1000 km/s, followed by (2) a shorter and slower expansion stage of a few minutes and ending with (3) a self-similar phase that carries the CME into the middle corona. The first two stages coincide with the impulsive phase of the accompanying flare, the formation and separation of an EUV wave from the CME, and the start of the metric type II radio burst. Our 3D analysis suggests that the hyper-inflation phase may be a crucial stage in the CME formation with wide-ranging implications for solar eruption research. It likely represents the formation stage of the magnetic structure that is eventually ejected into the corona, as the white-light CME. It appears to be driven by the injection of poloidal flux into the ejecting magnetic structure, which leads to the lateral (primarily) growth of the magnetic flux rope. The rapid growth results in the creation of EUV waves and eventually shocks at the CME flanks that are detected as metric type II radio bursts. In other words, the hyper-inflation stage in the early CME evolution may be the "missing" link between CMEs, flares, and coronal shocks.
Meeting Report on the 3rd Chinese American Society for Mass Spectrometry Conference—Advancing Biological and Pharmaceutical Mass Spectrometry
Following the highly successful Chinese American Society for Mass Spectrometry (CASMS) conferences in the previous 2 years, the 3rd CASMS Conference was held virtually on August 28–31, 2023, using the Gather. Town platform to bring together scientists in the MS field. The conference offered a 4-day agenda with a scientific program consisting of two plenary lectures, and 14 parallel symposia in which a total of 70 speakers presented technological innovations and their applications in proteomics and biological MS and metabo-lipidomics and pharmaceutical MS. In addition, 16 invited speakers/panelists presented at two research-focused and three career development workshops. Moreover, 86 posters, 12 lightning talks, 3 sponsored workshops, and 11 exhibitions were presented, from which 9 poster awards and 2 lightning talk awards were selected. Furthermore, the conference featured four young investigator awardees to highlight early-career achievements in MS from our society. In conclusion, the conference provided a unique scientific platform for young scientists (i.e. graduate students, postdocs, and junior faculty/investigators) to present their research, meet with prominent scientists, learn about career development, and job opportunities (http://casms.org).
Search for new resonances in mass distributions of jet pairs using 139 fb(-1) of pp collisions at root s=13TeV with the ATLAS detector
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Electron mass enhancement and magnetic phase separation near the Mott transition in double-layer ruthenates
Here, we present a detailed investigation of the specific heat of Ca 3 (Ru 1-x M x ) 2 O 7 (M = Ti, Fe, Mn) single crystals. Depending on the dopant and doping level, three distinct regions are present: a quasitwo-dimensional metallic state with antiferromagnetic (AFM) order formed by ferromagnetic bilayers (AFM-b), a Mott insulating state with G-type AFM order (G-AFM), and a localized state with a mixed AFM-b and G-AFM phase. Our specific heat data provide deep insights into the Mott transitions induced by Ti and Mn doping. We observed not only an anomalous large mass enhancement, but also an additional term in the specific heat, i.e., C ∝ T 2 , in the localized region. The C ∝ T 2 term is most likely due to long-wavelength excitations with both FM and AFM components. A decrease in the Debye temperature is observed in the G-type AFM region, indicating lattice softening associated with the Mott transition.