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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Hydrocarboxylation of C=C Bonds in Polycyclooctene: Progress Toward Valorization of Waste Polyolefins

Upcycling of waste polyolefins into higher-value functional polymers through chemical functionalization is a promising strategy to recover value and minimize their environmental impact. We report the hydrocarboxylation of polycyclooctene as a model for accessing ethylene acrylic acid copolymers (EAA) from waste polyethylene. The effects of various process parameters on the hydrocarboxylation were investigated. The relationship between carboxylic acid concentration and material properties, including crystallinity, melting temperature, glass transition temperature, adhesive properties, and wettability, was studied in comparison to an unfunctionalized polyethylene. Among the catalysts evaluated, Co 2 (CO) 8 exhibited relatively slow kinetics toward the hydrocarboxylation and was not compatible with 2,6-di-tert-butyl hydroxytoluene, a common additive present in commercial polyolefins. PdCl 2 (PPh 3 ) 2 exhibited a higher reactivity toward the hydrocarboxylation, though polymer gelation was observed with extended reaction times or high catalyst loadings. Carboxylic acid incorporation into the polymer was readily controlled by varying the reaction time. Altogether, the resultant COOH-functionalized polyolefins possessed properties analogous to commercial EAA.

36 MATERIALS SCIENCE↗
NASA NTRS1952

Preliminary Investigation of Flow Fluctuations During Surge and Blade Row Stall in Axial-flow Compressors / c Merle C. Huppert

A preliminary investigation of the flow fluctuations of surge and blade row stall was conducted with three single-stage axial-flow compressors with hub-tip ratios of 0.9,0.8, and 0.5 and with a multistage axial-flow compressor. Flow fluctuations of large amplitude associated with stall were detected in all compressors investigated. The fluctuations were caused by low flow regions affecting 25 to 40 percent of the annulus area and propagating in the direction of compressor rotation, but at a lower speed. Mild audible surge was obtained with the single-stage compressors with hub-tip ratios of 0.9 and 0.8. No audible surge was detected with the 0.5 hub-tip ratio stage. A severe audible surge was obtained with the multistage axial-flow compressor. The surge point was coincident with the sharp drop in pressure ratio due to stall.

ENGINES, TURBO-JET↗