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At least 469 records · Page 26

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NASA NTRS2009

Gadolinia-Doped Ceria Cathodes for Electrolysis of CO2

Gadolinia-doped ceria, or GDC, (Gd(0.4)Ce(0.6)O(2-delta), where the value of delta in this material varies, depending on the temperature and oxygen concentration in the atmosphere in which it is being used) has shown promise as a cathode material for high-temperature electrolysis of carbon dioxide in solid oxide electrolysis cells. The polarization resistance of a GDC electrode is significantly less than that of an otherwise equivalent electrode made of any of several other materials that are now in use or under consideration for use as cathodes for reduction of carbon dioxide. In addition, GDC shows no sign of deterioration under typical temperature and gas-mixture operating conditions of a high-temperature electrolyzer. Electrolysis of CO2 is of interest to NASA as a way of generating O2 from the CO2 in the Martian atmosphere. On Earth, a combination of electrolysis of CO2 and electrolysis of H2O might prove useful as a means of generating synthesis gas (syngas) from the exhaust gas of a coal- or natural-gas-fired power plant, thereby reducing the emission of CO2 into the atmosphere. The syngas a mixture of CO and H2 could be used as a raw material in the manufacture, via the Fisher-Tropsch process, of synthetic fuels, lubrication oils, and other hydrocarbon prod

Adler, Stuart B.↗

DOE OSTI2025

Silver(I) Supported Liquid Membranes for Selective Ethylene Recovery from Mixed-Gas Streams of Tandem CO 2 Electrolysis

Large-scale olefin separations from unreacted paraffins and other byproduct gases are primarily done by energy-intensive cryogenic distillation processes at refineries. Silver(I) supported liquid membranes (Ag SLMs) can be implemented at smaller production scales of ethylene (C 2 H 4 ), a critical industrial chemical, such as its electrocatalytic (EC) production from CO 2 . Challenges of EC C 2 H 4 production mainly stem from reducing gases like hydrogen (H 2 ), where the redox reactions pertinent to Ag(I) facilitators diminish olefin transport. Herein we report that aqueous Ag(I) solution in a composite Ag SLM can operate in mixed-gas conditions containing H 2 gas utilizing reduced titania compounds, such as titanium(III) oxide (Ti 2 O 3 ). Embedding Ti 2 O 3 in the polydimethylsiloxane layer of Ag SLM assisted in selectively separating C 2 H 4 from mixed-gas feed streams related to CO 2 electrolysis containing H 2 . The direct exposure of a mixed-gas stream containing C 2 H 4 , CO 2 , CO, N 2 , and CH 4 with as high as 50 vol % H 2 maintained excellent C 2 H 4 separations for 7 days of continuous operation. The Ag SLM provided effective separations of C 2 H 4 from CO (at detection limits), CH 4 (selectivity ratio (α) = 20–30), and H 2 (α = ∼20), but C 2 H 4 from CO 2 (α = 2–4) revealed a slightly lower separation. These data show that aqueous Ag(I) solution(s) used in the SLMs can separate C 2 H 4 for extended periods, even under highly reducing gas conditions. Also, we report C 2 H 4 recovery from the gas mixture produced in the EC CO 2 reduction process. In conclusion, the Ag SLM gave C 2 H 4 selective separation from a five-component complex mixed-gas stream, relevant to tandem CO 2 electrolysis.

37 - INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL C↗

DOE OSTI2021

The research into the propagation law of the shock wave of a gas explosion inside a building

Based on the dissipation rate conservation equations of turbulent kinetic energy in the k‐ ε turbulence model, a complicated three‐dimensional finite element model of a kitchen filled with gas mixture is developed by using the open source field operation and manipulation (OpenFOAM). Two representative kitchens were used to investigate the propagation law of the shock wave of a gas explosion inside a building by considering the key characteristics of the blast shock wave. The influence of some crucial parameters, such as initial conditions and kitchen parameters, on the properties of the blast shock wave is investigated. The basic steps to predict the peak pressure of the blast shock wave are given in consideration of the initial condition and the kitchen whilst the injury effect of the blast shock wave on the humans and animals is evaluated. The research results indicate that the pressure time history and the peak pressure space distribution are greatly influenced by the kitchen design layout. The coupled interaction between the initial temperature and gas volume concentration, especially at the upper and lower explosion limits of the gas, significantly affects the peak pressure. The peak pressure varies significantly with the opening and the buffer; however, it has little relation with the width, length, and height of the kitchen. The proposed method can accurately and effectively predict the peak pressure of the blast shock wave inside buildings. In terms of the peak pressure space distribution of the explosion shock wave, the peak pressure is much higher than the threshold of the killing pressure, which is unsafe for the humans and animals in the building.

Lin, Shu-Chao↗

DOE OSTI2025

Application of deep learning to single-shot gas-phase laser-induced breakdown spectroscopy

Single-shot fs laser-induced breakdown spectroscopy (LIBS) has the potential to capture ns-scale electrode desorption phenomena in pulsed power fusion drivers. However, the successful implementation of the diagnostic for this purpose is challenging, as it requires interpreting single-shot measurements collected from low-density gas mixtures. In this work, we demonstrate the efficacy of a Bayesian-optimized convolutional neural network (CNN) to interpret these measurements. We generated 256 distinct measurement conditions at relevant gas pressures ranging from 80–530 mTorr by mixing 100–250 sccm H 2 and 50–200 sccm CH 4 in increments of 10 sccm. Despite the considerable overlap between signals separated by 20 sccm, the CNN is able to predict the H 2 flow rate with a root-mean-square error (RMSE) of 15.9 sccm and the CH 4 flow rate with an RMSE of 12.0 sccm. The average relative prediction error is <9% for each gas and largely remains below or near 10%.

Brown, Nathan Parnell [Sandia National Lab. (SNL-N↗

NASA NTRS1989

Isothermal-Gas-Transfer Program

Isothermal Gas Transfer program (GASXFER) solves variety of problems in which gas or gas mixture transferred between two containers. Special features of program include ease of entering data and ease of obtaining output. Program displays, prints, or graphs complete pressure history of each gas as function of time. Written in Lotus Symphony macrolanguage.

Levine, Don I.↗

NASA NTRS2002

Direct-Drive Gas-Cooled Reactor Power System: Concept and Preliminary Testing

This paper describes the concept and preliminary component testing of a gas-cooled, UN-fueled, pin-type reactor which uses He/Xe gas that goes directly into a recuperated Brayton system to produce electricity for nuclear electric propulsion. This Direct-Drive Gas-Cooled Reactor (DDG) is designed to be subcritical under water or wet- sand immersion in case of a launch accident. Because the gas-cooled reactor can directly drive the Brayton turbomachinery, it is possible to configure the system such that there are no external surfaces or pressure boundaries that are refractory metal, even though the gas delivered to the turbine is 1144 K. The He/Xe gas mixture is a good heat transport medium when flowing, and a good insulator when stagnant. Judicious use of stagnant cavities as insulating regions allows transport of the 1144-K gas while keeping all external surfaces below 900 K. At this temperature super-alloys (Hastelloy or Inconel) can be used instead of refractory metals. Super-alloys reduce the technology risk because they are easier to fabricate than refractory metals, we have a much more extensive knowledge base on their characteristics, and, because they have a greater resistance to oxidation, system testing is eased. The system is also relatively simple in its design: no additional coolant pumps, heat exchanger, or freeze-thaw systems are required. Key to success of this concept is a good knowledge of the heat transfer between the fuel pins and the gas, as well as the pressure drop through the system. This paper describes preliminary testing to obtain this key information, as well as experience in demonstrating electrically heated testing of simulated reactor components.

Wright, S. A.↗

NASA NTRS2003

Thermally Simulated Testing of a Direct-Drive Gas-Cooled Nuclear Reactor

This paper describes the concept and preliminary component testing of a gas-cooled, UN-fueled, pin-type reactor which uses He/Xe gas that goes directly into a recuperated Brayton system to produce electricity for nuclear electric propulsion. This Direct-Drive Gas-Cooled Reactor (DDG) is designed to be subcritical under water or wet-sand immersion in case of a launch accident. Because the gas-cooled reactor can directly drive the Brayton turbomachinery, it is possible to configure the system such that there are no external surfaces or pressure boundaries that are refractory metal, even though the gas delivered to the turbine is 1144 K. The He/Xe gas mixture is a good heat transport medium when flowing, and a good insulator when stagnant. Judicious use of stagnant cavities as insulating regions allows transport of the 1144-K gas while keeping all external surfaces below 900 K. At this temperature super-alloys (Hastelloy or Inconel) can be used instead of refractory metals. Super-alloys reduce the technology risk because they are easier to fabricate than refractory metals, we have a much more extensive knowledge base on their characteristics, and, because they have a greater resistance to oxidation, system testing is eased. The system is also relatively simple in its design: no additional coolant pumps, heat exchanger, or freeze-thaw systems are required. Key to success of this concept is a good knowledge of the heat transfer between the fuel pins and the gas, as well as the pressure drop through the system. This paper describes preliminary testing to obtain this key information, as well as experience in demonstrating electrical thermal simulation of reactor components and concepts.

Godfroy, Thomas↗

DOE OSTI2022

Advanced Ceramic Membranes/Modules for Ultra Efficient Hydrogen (H2) Production/Carbon Dioxide (CO2) Capture for Coal-Based Polygeneration Plants: Fabrication, Testing, and CFD Modeling

Inorganic membrane-based systems are a promising technology for precombustion CO2 capture with simultaneous H2 production. State-of-the-art packages for high temperature and pressure service consist of multiple tube membrane bundles prepared in a "candle filter" configuration, in which the membrane tubes are open at one end and sealed at the other. This configuration is used for practical reasons, specifically the need to minimize problems due to thermal expansion mismatch between the ceramic tube bundle and the steel housing. However, the primary technical problem with the candle filter format for commercial-scale installations is the inability to purge the tube side (typically the permeate side), a feature that is crucial for high H2 recovery. In this study, the focus is to design and fabricate the first dual-end open full ceramic multiple tube membrane bundle that enables tube side (permeate) purge for gas separation applications. An additional key feature of this design is the simplified module layout, as the membrane bundles can be installed end-to-end with tube side (permeate) flow directly from one bundle to the next. This layout simplifies the membrane to housing seals and yields significant improvement in membrane packing density. Detailed focus areas in our studies include: (i) Materials development and preparation of the tube-to-tube sheet potting for the dual-ended bundle; (ii) the sealing and optimal module configuration design to minimize membrane stress upon module mounting; (iii) the demonstration, via the fabrication of CMS and Pd-alloy membranes supported on full-size, dual-ended ceramic support bundles, of the first example of a purgeable ceramic membrane and module; and (iv) development of a CFD model of the membrane module for calculation of feed flow distribution, and for use in scale-up, and capital cost estimating. The CFD model was validated using experimental data with the multi-tubular membrane system, employing He/N2 as a model gas mixture (surrogate for H2/CO2), and has been shown to be quite accurate. Employing the model, we are able to study the effects of operating pressure and temperature, feed and sweep gas flow rates, and the choice of membrane tube configuration on system performance.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2022

Advanced Ceramic Membranes/Modules for Ultra Efficient Hydrogen (H2) Production/Carbon Dioxide (CO2) Capture for Coal-Based Polygeneration Plants: Fabrication, Testing and CFD Modeling

20 FOSSIL-FUELED POWER PLANTS↗

NASA NTRS1999

Feature Profile Evolution of SiO2 Trenches In Fluorocarbon Plasmas

Etching of silicon microstructures for semiconductor manufacturing in chlorine plasmas has been well characterized. The etching proceeds in a two-part process, where the chlorine neutrals passivate the Si surface and then the ions etch away SiClx. However, etching in more complicated gas mixtures and materials, such as etching of SiO2 in Ar/C4F8, requires knowledge of the ion and neutral distribution functions as a function of angle and velocity, in addition to modeling the gas surface reactions. In order to address these needs, we have developed and integrated a suite of models to simulate the etching process from the plasma reactor level to the feature profile evolution level. This arrangement allows for a better understanding, control, and prediction of the influence of equipment level process parameters on feature profile evolution. We are currently using the HPEM (Hybrid Plasma Equipment Model) and PCMCM (Plasma Chemistry Monte Carlo Model) to generate plasma properties and ion and neutral distribution functions for argon/fluorocarbon discharges in a GEC Reference Cell. These quantities are then input to the feature scale model, Simulation of Profile Evolution by Level Sets (SPELS). A surface chemistry model is used to determine the interaction of the incoming species with the substrate material and simulate the evolution of the trench profile. The impact of change of gas pressure and inductive power on the relative flux of CFx and F to the wafer, the etch and polymerization rates, and feature profiles will be examined. Comparisons to experimental profiles will also be presented.

Hwang, Helen↗

NASA NTRS1974

Studies on disease transmission in spacecraft environments

The effects of the Skylab gas mixtures on general health and immunocompetence of mice and ferrets subjected to the Skylab space cabin environment (SCE) were initially studied in a stainless steel low pressure facility which was maintained at gas ratios of 30% nitrogen and 70% oxygen under 5 psia, and which consisted of two subchambers, that permitted mutual isolation of experimental groups and/or selective removal of animals without return of the entire cabin to ambient pressure was developed. The studies demonstrated that ferrets immunized with Brucella Strain 19 prior to being housed in SCE had decreased synthesis of IgG compared to their respective controls. The possibility of latent infections being responsible for stress-induced upper respiratory diseases of astronauts required that the role of neutralizing antibody as a function of antibody affinity/avidity be investigated. The model consisted of Aleutian disease virus (ADV) which infects ferrets and mink resulting in nonneutralized immune complexes. These studies demonstrated that early antibody to ADV had lower affinity/avidity than late antibody with respect to chronicity. These studies culminated in a description of antibody affinity, first isolation of ADV and its cultivation in vitro.

Kenyon, A. J.↗

NASA NTRS1977

Removal of ammonia from urine vapor by a dual-catalyst system

The feasibility of removing ammonia from urine vapor by a low-temperature dual-catalyst system has been demonstrated. The process is based on the catalytic oxidation of ammonia to a mixture of nitrogen, nitrous oxide, and water, followed by a catalytic decomposition of the nitrous oxide into its elements. Potential ammonia oxidation and nitrous oxide decomposition catalysts were first screened with artificial gas mixtures, then tested with the actual urine vapor produced by boiling untreated urine. A suitable dual-catalyst bed arrangement was found that achieved the removal of ammonia and also organic carbon, and recovered water of good quality from urine vapor.

Budininkas, P.↗

NASA NTRS1992

Rett syndrome - Stimulation of endogenous biogenic amines

Transient hypercapnic hyperoxemia was induced in two Rett syndrome children by the administration of a gaseous mixture of 80 percent O2 and 20 percent CO2. Time course studies of neurotransmitters and their metabolites showed an immediate and marked increase in central biogenic amine turnover following inhalation of the gas mixture. The increased turnover of biogenic amines was associated with improved clinical changes. This suggests a coupled relationship and provides further support for an etiological role of neurotransmitter dysfunction in Rett syndrome. In a complementary study, elevation of pulmonary CO2 by application of a simple rebreathing device resulted in improvement of abnormal blood gases and elimination of the Cheyne-Stokes-like respiratory pattern of the Rett syndrome. Near normalization of the EEG occurred when a normal respiratory pattern was imposed by means of a respirator. Taken together, these results lead to the preliminary conclusion that cerebral hypoxemia secondary to abnormal respiratory function may contribute to diminished production of biogenic amines in Rett syndrome.

Pelligra, R.↗

NASA NTRS2014

Evaluating the Adsorptive Capabilites of Chemsorb 1000 and Chemsorb 1425

The removal of trace contaminants from spacecraft cabin air is necessary for crew health and comfort during long duration space exploration missions. The air revitalization technologies used in these future exploration missions will evolve from current ISS ISS State-of-Art (SOA) and is being designed and tested by the Advanced Exploration Systems (AES) Program's Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project. The ARREM project is working to mature optimum atmosphere revitalization and environmental monitoring system architectures to enable exploration beyond Lower Earth Orbit (LEO). The Air Revitalization Lab at KSC is one of six NASA field centers participating in the ARREM that specializes in adsorbent and catalyst characterization with simulated spacecraft gas streams using combinations of pressure, O2 partial pressure, CO2 partial pressure, and humidity that are representative of a range of anticipated cabin atmospheric conditions and loads. On board ISS, the Trace Contaminant Control Subassembly (TCCS) provides active control of trace contaminants from the cabin atmosphere utilizing physical adsorption, thermal catalytic oxidation, and chemical adsorption processes. High molecular weight contaminants and ammonia (NH3) are removed a granular activated carbon treated with approx. 10% by weight phosphoric acid (H3PO4) (B-S Type 3032 4×6 mesh), which is expendable and is periodically refurbished. The Type 3032 granular activated carbon bed is no longer commercially available and therefore it is important to characterize the efficiency and capacity of commercially available NH3 sorbents. This paper describes the characterization of two Molecular Products LTD activated carbons: Chemsorb 1000 and Chemsorb 1425. Untreated activated carbons (e.g. Chemsorb 1000) remove contaminants by physisorption, which concentrates the contaminant within the pores of the carbon while letting air to pass through the sorbent4. Low molecular weight or polar gases (e.g. HCl, SO2, formaldehyde, and NH3) are not removed by physisorption and typically require chemisorption for removal. Treated activated carbons (e.g. Chemsorb 1425) are impregnated with a a chemical agent (e.g. phosphoric acid) that reacts with those gases, converting them to solids or salts within the carbon and removes them from the air stream. This process occurs via neutralization or catalysis reactions and adsorption capacity is exhaustedwhen the available impregnated chemicals are consumed. Moisture affects removal performance since adsorption sites within the pores are filled with water. The performance of impregnated carbons may be enhanced by moisture content because the mechanisms of contaminant removal are chemical reactions that occur in reagents contained within the pores. The adsorptive capacity data (mol/kg) of Chemsorb 1000 and 1425 for gas mixtures (ethanol, acetone, toluene, acetaldehyde, dichloromethane, and xylene) was measured with 40% relative humidity at 23 deg C air temperature. The adsorptive capacity data (mol/kg) of Chemsorb 1425 was measured using NH3 gas streams.

adsorptive capacities↗

NASA NTRS2018

Environmental Control System Development

Since before the first men landed on the moon, human beings have aspired to reach farther into space, to discover and answer the great mysteries that exist beyond imagination. To reach where no one has gone before. To able to see all the wonderful things that can be found in space and that only satellites have revealed to us during all this time. Considering the last trip to the moon, mankind has been evolving and improving their technology to reach destinations whose distances had been impossible to transit. To reach that goal, the National Aeronautics and Space Administration (NASA) has designed and developed the largest and most powerful rocket ever created by the human race, the Space Launch System - better known as the SLS. To be able to send this large rocket to space, Kennedy Space Center (KSC) is doing upgrades to their existing facilities and equipment. At Launch Pad 39B, they are setting up a new Environmental Control System (ECS) developed to supply the rocket with the correct gases and mixtures that will be needed for the rocket to launch. The ECS is similar to an air conditioning unit. The main functionality of it is to supply the SLS with the correct gas mixture for it to launch. Also the ECS has been required to reduce or eliminate the possibility of a complete system failure. The system is part of the Ground Support Equipment (GSE) for the SLS that will be going to the Moon and Mars.

Flores Arroyo, Elvin A.↗

NASA NTRS1971

The development of a sonic boom simulator with detonable gases

A sonic boom pressure profile was simulated in the far-field by detonation of a methane-oxygen mixture contained in a slender, shaped Mylar envelope. Ideal N-waves were synthesized with peak overpressures from two to five psf and durations of 30 to 75 milliseconds. The detonation of the gas mixture was initiated by a single Primacord strand running the length of balloon. The N-wave producing balloon was synthesized as a composite structure, utilizing experimental pressure profiles obtained from the detonations of slender, axisymmetric balloons with elementary, non-cylindrical shapes.

Strugielski, R. T.↗

NASA NTRS1977

Shock tube measurements of the optical absorption of triatomic carbon, C3

The spectral absorption of C3 has been measured in a shock tube using a test gas mixture of acetylene diluted with argon. The absorption of a pulsed xenon light source was measured by means of eight photomultiplier channels to a spectrograph and an accompanying drum camera. The postshock test gas temperature and pressure were varied over the range 3300-4300 K and 0.36 to 2.13 atmospheres, respectively. The results showed appreciable absorption from C3 for the wavelength range 300 to 540 nanometers. The computed electronic oscillator strength varied from 0.12 to 0.06 as a function of temperature.

Jones, J. J.↗

NASA NTRS1978

The optical absorption of triatomic carbon C3 for the wavelength range 260 to 560 nm

The spectral absorption properties of C3 have been measured in a shock tube containing a test gas mixture of acetylene diluted with argon. The absorption of a pulsed xenon light source was measured by means of eight photomultiplier channels to a spectrograph and an accompanying drum camera. The postshock test gas temperature and pressure were varied over the range 3240 to 4300 K and 37 to 229 kPa, respectively. The results showed appreciable absorption by C3 for the wavelength range 300 to 540 nm. The various reported measurements of the heat of formation of C3 which are available in the open literature were reviewed, and a value of 198 kcal/mol is recommended. This value, along with best available values for other species, was used to calculate the number density of C3 for the conditions of the present experiments in order to compute absorption cross section or electronic oscillator strength. The computed electronic oscillator strength varied from a high of 0.062 at 3300 K to a low of 0.036 at 3900 K.

Jones, J. J.↗