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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Renewable fatty acid ester production in Clostridium

Abstract Bioproduction of renewable chemicals is considered as an urgent solution for fossil energy crisis. However, despite tremendous efforts, it is still challenging to generate microbial strains that can produce target biochemical to high levels. Here, we report an example of biosynthesis of high-value and easy-recoverable derivatives built upon natural microbial pathways, leading to improvement in bioproduction efficiency. By leveraging pathways in solventogenic clostridia for co-producing acyl-CoAs, acids and alcohols as precursors, through rational screening for host strains and enzymes, systematic metabolic engineering-including elimination of putative prophages, we develop strains that can produce 20.3 g/L butyl acetate and 1.6 g/L butyl butyrate. Techno-economic analysis results suggest the economic competitiveness of our developed bioprocess. Our principles of selecting the most appropriate host for specific bioproduction and engineering microbial chassis to produce high-value and easy-separable end products may be applicable to other bioprocesses.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2024

Small, solubilized platinum nanocrystals consist of an ordered core surrounded by mobile surface atoms

In situ structures of Platinum (Pt) nanoparticles (NPs) can be determined with graphene liquid cell transmission electron microscopy. Atomic-scale three-dimensional structural information about their physiochemical properties in solution is critical for understanding their chemical function. We here analyze eight atomic-resolution maps of small (<3 nm) colloidal Pt NPs. Their structures are composed of an ordered crystalline core surrounded by surface atoms with comparatively high mobility. 3D reconstructions calculated from cumulative doses of 8500 and 17,000 electrons/pixel, respectively, are characterized in terms of loss of atomic densities and atomic displacements. Less than 5% of the total number of atoms are lost due to dissolution or knock-on damage in five of the structures analyzed, whereas 10–16% are lost in the remaining three. Less than 5% of the atomic positions are displaced due to the increased electron irradiation in all structures. The surface dynamics will play a critical role in the diverse catalytic function of Pt NPs and must be considered in efforts to model Pt NP function computationally.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Towards non-contact pollution monitoring in sewers with hyperspectral imaging

Monitoring water quality in sewers is challenging, particularly because state-of-the-art technologies require contact with the raw wastewater. The presence of fat, oil, grease, and solids makes automated grab sampling difficult and causes sensor fouling. To overcome these limitations, non-contact methods based on light reflectance, such as hyperspectral imaging (HSI), are gaining attention. However, HSI has never been tested for raw wastewater. To assess its accuracy for measuring pollution, we developed a laboratory setup and performed targeted experiments with a combination of raw and diluted wastewater, as well as synthetic turbidity stock solutions. We measured seven pollution variables: chemical oxygen demand, turbidity, dissolved organic compounds, ammonium, total nitrogen, phosphate, and sulphates. We used automated pixel selection and partial least squares regression to retrieve pollution information from the hyperspectral images. Our results, based on 144 samples, suggest that HSI can estimate pollution levels with a precision in the range of state-of-the-art absorbance spectrophotometric methods. Additionally, we found that the combination of pixel and wavelength selection, enabled by the hyperspectral data structure, significantly influences the performance of partial least square modelling. Overall, our findings indicate that HSI is a promising technology for non-contact monitoring of water quality in raw wastewater.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Multiple origins of extra electron diffractions in fcc metals

Diffuse intensities in the electron diffraction patterns of concentrated face-centered cubic solid solutions have been widely attributed to chemical short-range order, although this connection has been recently questioned. This article explores the many nonordering origins of commonly reported features using a combination of experimental electron microscopy and multislice diffraction simulations, which suggest that diffuse intensities largely represent thermal and static displacement scattering. A number of observations may reflect additional contributions from planar defects, surface terminations incommensurate with bulk periodicity, or weaker dynamical effects.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on a Hanford AP Tank Farm Exhauster Slipstream (Volume 1)

Washington River Protection Solutions (WRPS) tested four types of chemical cartridges for use in air-purifying respirators (APR) and powered air-purifying respirators (PAPR). These tests were undertaken to determine the period of time that the cartridges would provide adequate performance1 for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from vapors exiting the Hanford AP tank farm exhauster slipstream. The Occupational Safety and Health Administration (OSHA) considers cartridge testing to be a valid approach for establishing cartridge change schedules. Testing commonly is applied in situations where mixtures of COPCs exist and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate the cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Cartridge testing on a slipstream from the Hanford AP tank exhauster was conducted on March 23-24, 2018. This testing focused on both APR and PAPR cartridges. Previous testing of APR cartridges was conducted on the AP exhauster in June of 2016. However, an AP exhauster upgrade was completed in September 2016. In the most recent testing, slipstream vapors from the new AP exhauster were fed to two respirator cartridge test stands, one for the PAPR respirator cartridges and the other for the APR respirator cartridges. Both the APR and PAPR test stands were developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose APR cartridges—SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina)—were assessed on separate days using the APR cartridge test stand. Multipurpose PAPR cartridges—MSA OptiFilter TL (MSA Safety Inc., Pittsburgh, Pennsylvania) and 3M FR-57 (3M Company, Maplewood, Minnesota)—were also tested consecutively over the same two days as the APR cartridge tests, using the PAPR cartridge test stand. Sample media (i.e., sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridges, and the samples then were analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life. The key conclusions from the analysis are described below.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2022

Organic Evaporation and Oxidation Testing in Support of Hanford Sample-and-Send

The Hanford site has approximately 56 million gallons of radioactive mixed waste stored in 177 underground storage tanks. The Hanford Waste Treatment and Immobilization Plant (WTP) is being built to treat and immobilize the tank waste. The baseline method for immobilization of Low Activity Waste (LAW) through the WTP is vitrification, but additional immobilization capacity is needed to supplement the initial LAW melters. An alternative cementitious waste form is being investigated for that future immobilization method to supplement vitrification. However, one impediment to a cementitious waste form is the presence of Land Disposal Restricted (LDR) organic chemicals in tank waste. This work evaluates potential avenues to eliminate that impediment to permit possible use of a cementitious waste form and work towards a decision whether additional LDR organic pretreatment would be required. Savannah River National Laboratory (SRNL) performed testing using simulants to examine evaporation as a method to remove some prevalent organics from LAW. Spiking the caustic LAW simulant with selected regulated organic chemicals found one that clearly decomposes because of caustic instability. Oxidation testing of other organic chemicals found some LDR organics degrade as desired and others are stable in the presence of peroxide and permanganate. In addition to studies with simulants, a literature review was performed to evaluate radiological stability of LDR organics. Descriptions of the experimental details, equipment, and results are included in this report. Evaporation testing consisted of preparing the LAW simulant, spiking that simulant with organic chemicals, and evaporating the mixture via differential distillation. The apparatus was a laboratory-scale vacuum evaporator operated at 60 ±5 torr absolute (vacuum evaporation) and also at atmospheric pressure. The LAW simulant represented the liquid expected to be retrieved from the Hanford tank farms at approximately 4.0 M [Na + ] total sodium ion concentration. The concentration of the organic chemicals added was significantly higher than typically found in the tank waste samples since the higher levels were necessary to assist in analytical measurement and tracking of the spiked species. Organic chemicals were chosen for the work with a consideration of how their volatility compares with that of methanol. This was done by comparing the ratio of the pure water Henry’s law coefficient (K h ) of methanol to that of the compound in question (hereafter termed the K h ratio), where ratios above unity indicated less volatility than methanol. Methanol was chosen because it is a common regulated chemical with relatively low volatility but which has been removed by evaporation in previous laboratory work. While organic separation results depend on evaporator design, laboratory experiments verified that organic partitioning to the overhead condensate stream by evaporation is a practical process. The work reported here found difficulties in quantitative analysis of the organic chemicals in aqueous samples. Most of the time there was insufficient analysis to close a mass balance for evaporator runs, but qualitative evidence of carryover was obtained. The methods were also able to show whether organic chemicals were susceptible or resistant to solution oxidation in permanganate or hydrogen peroxide tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Analysis of Air-Purifying Respirator (APR) and Powered Air-Purifying Respirator (PAPR) Cartridge Performance Testing on Hanford Tanks BY-108 and BY-110 Volume 1

Washington River Protection Solutions (WRPS) tested four types of chemical cartridges for use in air-purifying respirators (APR) and powered air-purifying respirators (PAPR). These tests were undertaken to determine the period of time that the cartridges would provide adequate performance for APRs and PAPRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPC) from vapors exiting the headspaces of Hanford BY-108 and BY-110 waste storage tanks. The Occupational Safety and Health Administration (OSHA) considers cartridge testing to be a valid approach for establishing cartridge change schedules. Testing commonly is applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate the cartridge service life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Cartridge tests were conducted over two days from February 23-25, 2018, using headspace vapors from Hanford tanks BY-108 and BY-110. Headspace vapors from the BY-108 tank were fed to the PAPR respirator cartridge test stand, while vapors from the BY-110 headspace were fed to the APR respirator cartridge test stand. Both the APR and PAPR test stands were developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Two different cartridges were assessed on each tank. Multipurpose APR cartridges—SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina)—were assessed for vapors from BY-110 using the APR cartridge test stand. Multipurpose PAPR cartridges—MSA OptiFilter TL (MSA Safety Inc., Pittsburgh, Pennsylvania) and 3M FR-57 (3M Company, Maplewood, Minnesota)—also were assessed for vapors from BY-108 over the same two days using the PAPR cartridge test stand. Sample media (i.e., sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridges, and the samples then were analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life. The key conclusions from the analysis are described below.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Compact Superconducting RF Accelerators for Water Treatment

Jefferson Lab is actively exploring the environmental applications of compact irradiation facilities utilizing Superconducting Radio Frequency (SRF) accelerator technology ? a well-established technology primarily used in large research machines. Recent advancements, such as the application of thin films of superconducting alloys in radio frequency (RF) resonators and the development of high-capacity cryocoolers, have made it feasible to employ this key technology in compact, standalone irradiation facilities. The main advantage over conventional systems based on normal conducting technology is the significantly enhanced efficiency in beam power generation, enabling exposure to substantially higher radiation doses. In the realm of addressing contaminants in wastewater treatment, particularly concerning persistent substances known as "forever chemicals," this technology presents an attractive solution, given the required considerable effort i.e. dose to break them down. Experiment Numbers:

Vennekate, John↗
NASA NTRS1978

A note on the diurnal averaging of aeronomical models

An approximate technique for diurnally time-averaging atmospheric photochemical-dynamical models which eliminates the need for a detailed numerical resolution of sunrise and sunset transitions is developed. The scheme is equivalent to scaling certain chemical rate constants and photodissociation coefficients by appropriate aeronomical factors. To calculate the scaling factors, diurnal variations are parameterized with a step-function behavior, assuming that each species has a constant day-time and night-time concentration whose ratio can be determined by analyzing the chemical interactions occurring after sunset. The solution accounts for the effects of night-time reactions on the 24 h average values of species abundances, and on the average daily rates of the catalytic processes consuming ozone in the stratosphere. The accuracy of the technique is demonstrated by comparing its predictions to those of a full diurnal simulation; typically, the precision is better than 10%. By contrast, it is shown that the use of some other well-known computational schemes can result in significantly larger predictive errors.

Turco, R. P.↗
NASA NTRS1980

Photoelectrochemical cell with nondissolving anode

Improved electrolytic cells have efficiencies comparable to those of best silicon solar cells but are potentially less expensive to manufacture. Cells consist of light-sensitive n-type semiconductor anode and metallic cathode immersed in electrolytic solution. Reversible redox cells produce no chemical change in electrolyte and stabilize anode against dissolving. Cell can produce more than 500 mW of power per square centimeter of anode area at output voltage of 0.4 V.

Ellis, A. B.↗
NASA NTRS1980

Liquid chromatographic characterization of PMR-15 resin and prepreg

A liquid chromatographic method has been developed capable of providing a chemical fingerprint of PMR-15 resin solutions and prepreg. The amounts of two of the monomers can be quantified so their experimentally determined molar ratio can be compared to the formulated one. Only the monomers were detected in fresh resin solution, whereas several additional components, resulting from an association or reaction between the norbornenyl endcap and the amine, were detected in a resin solution aged for three days. Two commercial prepregs exhibited fingerprints similar to that of laboratory material, but three others contained additional components corresponding to higher esters and nadimides.

Reed, K. E.↗
NASA NTRS1984

High altitude chemically reacting gas particle mixtures. Volume 1: A theoretical analysis and development of the numerical solution

The overall contractual effort and the theory and numerical solution for the Reacting and Multi-Phase (RAMP2) computer code are described. The code can be used to model the dominant phenomena which affect the prediction of liquid and solid rocket nozzle and orbital plume flow fields. Fundamental equations for steady flow of reacting gas-particle mixtures, method of characteristics, mesh point construction, and numerical integration of the conservation equations are considered herein.

Smith, S. D.↗
NASA NTRS1988

A chemical/microwave technique for the measurement of bulk minority carrier lifetime in silicon wafers

A chemical/microwave technique for the measurement of bulk minority carrier lifetime in silicon wafers is described. This method consists of a wet chemical treatment (surface cleaning, oxidation in solution, and measurement in HF solution) to passivate the silicon surfaces, a laser diode array for carrier excitation, and a microwave bridge measuring system which is more sensitive than the microwave systems used previously for lifetime measurement. Representative experimental data are presented to demonstrate this technique. The result reveals that this method is useful for the determination of bulk lifetime of commercial silicon wafers.

Luke, Keung L.↗
NASA NTRS1988

Rapid solidification research at the NASA Lewis Research Center

This paper describes the research program initiated at the NASA Lewis Research Center for the study of rapid solidification of high temperature materials, with the major purpose for the development of advanced high-temperature and heat-flux materials for aircraft and aerosphace applications. Particular attention is given to the development of three alloys: Ni-aluminides, Nb-alloys, and Cu-alloys. Rapid solidification processing yielded alloys with novel microstructures, very fine grain sizes, reduced chemical segregation, and metastable extended solid solutions.

Locci, Ivan E.↗
NASA NTRS1989

Computation of hypersonic flow fields

The present discussion of the theory, solution methods, and development status of chemically reactive flow CFD codes pertaining to the flow field around a hypersonic vehicle encompasses the formulation of multicomponent viscous equations, grid-generation techniques, and finite-difference algorithms. The Navier-Stokes equations presented focus on such particularities of high speed vehicles as their aerodynamic configuration, lee and wake flow, bow shock, and chemistry and low density effects. Issues for which further development is desirable encompass boundary treatments, grid quality, shock capturing, and the decoupling of chemistry from flow variables.

Li, Chien-Peng↗
NASA NTRS1991

Combustion kinetics and sensitivity analysis computations

The stiff ordinary differential equation solution methods more commonly used for chemical kinetics problems are examined, and the efficiency and accuracy of several of the methods are compared by applying them to two combustion kinetics problems. The local sensitivity analysis methods developed to date are outlined, and their advantages and difficulties are briefly discussed. Examples are used to make comparisons among the different techniques.

Radhakrishnan, K.↗
NASA NTRS1996

TPS Sizing for Access-to-Space Vehicles

A study was carried out to identify, develop, and benchmark simulation techniques needed for optimum thermal protection system (TPS) material selection and sizing for reusable launch vehicles. Fully viscous, chemically reacting, Navier-Stokes flow solutions over the Langley wing-body single stage to orbit (SSTO) configuration were generated and coupled with an in-depth conduction code. Results from the study provide detailed TPS heat shield materials selection and thickness sizing for the wing-body SSTO. These results are the first ever achieved through the use of a complete, trajectory based hypersonic, Navier-Stokes solution database. TPS designs were obtained for both laminar and turbulent entry trajectories using the Access-to-Space baseline materials such as tailorable advanced blanket insulation. The TPS design effects (materials selection and thickness) of coupling material characteristics to the aerothermal environment are illustrated. Finally, a sample validation case using the shuttle flight database is included.

Henline, William↗
NASA NTRS1971

Techniques for Measurement of Nitrate Movement in Soils

Contamination of surface and ground waters with nitrate usually involves leaching through soil of nitrate produced by mineralization of soil organic matter, decomposition of animal wastes or plant residues, or derived from fertilizers. Nitrate concentrations in the soil solution may be measured by several chemical procedures or by the nitrate electrode. since nitrate is produced throughout the soil mass it is difficult to identify a source of nitrate contamination by conventional means. This problem can be solved by use of N-15-enriched or N-15-depleted materials as tracers. The latter is particularly attractive because of the negligible possibility of the tracer hazardous to health.

Broadbent, F. E.↗