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Closing the Cyan Gap Toward Full-Spectrum LED Lighting with NaMgBO[subscript 3]:Ce[superscript 3+]
Abstract not provided
Oxidative Dissolution of Lanthanide Metals Ce and Ho in Molten GaCl 3
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Enhancement of Crystal Growth in Molten Salts by a Cocrystallization Agent: Synthesis and Luminescent Properties of Ce 3+ - and Eu 2+ -Doped La 3 (SiS 4 ) 2 I
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Interlayer Ions Control Spin Canting in Low-Dimensional Manganese Trimers in 12R-Ba 4 M Mn 3 O 12 ( M = Ce, Pr) Layered Perovskites
Not Available
Effect of Nanoscale Ce 0.8 Gd 0.2 O 2–δ Infiltrant and Steam Content on Ni–(Y 2 O 3 ) 0.08 (ZrO 2 ) 0.92 Fuel Electrode Degradation during High-Temperature Electrolysis
Studies of Ni–yttria-stabilized zirconia (YSZ) fuel electrode degradation mechanisms in solid oxide electrolysis cells (SOECs) are complicated by the different possible Ni–YSZ microstructures and compositions, and the variations in the H 2 /H 2 O ratio encountered in an electrolysis stack. Here, in this study, we describe a life testing scheme aimed at providing survey results on degradation as a function of the H 2 O–H 2 composition, with life tests carried out at five different steam contents from 90% to 10%. A Ni–YSZ-supported symmetric cell geometry is employed both with and without infiltrated nanoscale gadolinia-doped ceria (GDC). Impedance spectroscopy is utilized to observe changes in electrochemical characteristics during the life test, and a transmission-line-based equivalent circuit is used to model the data. Post-test electrode microstructures were observed. The results suggest that the GDC infiltrant reduces the electrode polarization resistance and provides more stable electrode polarization over a range of conditions.
Enhancing Ce x Zr 1– x O 2 Activity for Methane Dry Reforming Using Subsurface Ni Dopants
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Actively Learned Optimal Sustainable Operation of Plasma-Catalyzed Methane Bireforming on La 0.7 Ce 0.3 NiO 3 Perovskite Catalyst
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A hydrolytically stable Ce( iv ) complex of glutarimide-dioxime
Glutarimide-dioxime, a proligand known for its strongly electron-donating properties that has been studied for applications in uranium-sequestration from seawater, is considered here for stabilization of the cerium( iv ) cation.
Facile benzene reduction promoted by a synergistically coupled Cu–Co–Ce ternary mixed oxide
Hydrogenation of aromatic rings promoted by earth-abundant metal composites under mild conditions is an attractive and challenging subject in the long term.
In situ investigation of the mechanochemically promoted Pd–Ce interaction under stoichiometric methane oxidation conditions
A stable Pd 0 /Pd 2+ arrangement generated on Pd/CeO 2 prepared by mechanochemistry enables high methane activation rates in the absence of excess oxygen being available.
Phase evolution and magnetic properties of (Ce,Nd)–Fe–B prepared using microwave-assisted approach
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Mott vs Kondo: Influence of various density functional based methods on the Ce isostructural phase transition mechanism
The cerium iso-structural phase transition (γ–α) is dominated by f-electron localization changes that results in a magnetic ordering change and a volume collapse. Generally, these physics are difficult to capture with ab initio and first principles methods. However, previous works have shown various methods to be successful in predicting at least some of the physics of the γ to α phase transition. Therefore, here, we perform a broad survey of density functional based methods across three levels of theory and types of functions [GGA (generalized gradient approximation), MetaGGA, and hybrid functionals] and compare the results, focusing on hydrostatic compression across the phase boundary at zero kelvin. For the methods that best reproduce experimental results, we directly probe the predicted mechanisms and frame the results in the Mott/Kondo debate, assessing how the underlying methods and assumptions of different functionals can assess the physical drivers in the phase transition, providing insight into the governing processes of this unique phase transition.