Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “CEOS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Non-adiabatic Excited State Molecule Dynamics Modeling of Photochemistry and Photophysics of Materials

Understanding and controlling excited state dynamics lies at the heart of all our efforts to design photoactive materials with desired functionality. This tailor-design approach has become the standard for many technological applications (e.g., solar energy harvesting) including the design of organic conjugated electronic materials with applications in photovoltaic and light-emitting devices. Over the years, our team has developed efficient LANL-based codes to model the relevant photophysical processes following photoexcitation (spatial energy transfer, excitation localization/delocalization, and/or charge separation). The developed approach allows the non-radiative relaxation to be followed on up to ~10 ps timescales for large realistic molecules (hundreds of atoms in size) in the realistic solvent dielectric environment. The Collective Electronic Oscillator (CEO) code is used to compute electronic excited states, and the Non-adiabatic Excited State Molecular Dynamics (NA-ESMD) code is used to follow the non-adiabatic dynamics on multiple coupled Born-Oppenheimer potential energy surfaces. Our preliminary NA-ESMD simulations have revealed key photoinduced mechanisms controlling competing interactions and relaxation pathways in complex materials, including organic conjugated polymer materials, and have provided a detailed understanding of photochemical products and intermediates and the internal conversion process during the initiation of energetic materials. This project will be using LANL-based CEO and NA-ESMD codes to model nonradiative relaxation in organic and energetic materials. The NA-ESMD and CEO codes belong to a class of electronic structure/quantum chemistry codes that require large memory, “long-queue-few-core” distribution of resources in order to make useful progress. The NA-ESMD simulations are trivially parallelizable requiring ~300 processors for up to one week runtime to reach a meaningful restart point.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Production of Creep-Resistant FeCrAl-ODS

Four ODS FeCrAl alloys with base alloy composition Fe-16Cr-4Al-2Mo-0.2Y (wt.%) were mechanically alloyed with minor additions of CeO 2 and Y 2 O 3 additions and were successfully extruded into rectangular-shaped bars. Two oxide compositions were explored, which were designated NC with oxide addition of 0.5CeO 2 plus 0.2Yin solution of the base alloy powder and PC with additions of 0.5CeO 2 and 0.7Y 2 O 3 to elevate the O level. The microstructure of both alloys revealed by SEM and EBSD to consist of very small grains with sizes of ~450-520 nm and weak texture components. Sub-size tensile specimens fabricated from both alloys were tensile tested from room temperature to 800ºC. The results for both alloys from room temperature to 400ºC showed very high strengths, but low ductilities, especially uniform strain. From 500ºC to 800ºC, the strengths decreased rapidly, and the ductilities increased significantly. The reason for the rapid decreases in tensile strengths above 500ºC for both alloys is not clear, but will require advanced characterization techniques including atom probe tomography, to determine the size and number density of the nano-size oxide particles, and TEM/EFTEM, for investigating the dispersion of nano-size oxide particles on grain boundaries to assess the Zener grain boundary pinning effect, which will hinder grain coarsening at high temperatures that may enhance the Hall Petch strengthening mechanism.

36 MATERIALS SCIENCE↗
NASA NTRS1998

Toward the Development of an Integrated Global Observing Strategy

In the current environment of stagnant or shrinking budgets for space research and exploration, nations can no longer afford to develop costly systems in a vacuum. Greater coordination of existing and planned systems, both among space agencies and between the space agencies and user communities, will enable the maximization of global investments in all areas of space-related research. In this manner, a group of space agencies has embarked on an initiative to link their activities in Earth observation with complementary observation programs. The goal of this initiative is to develop a comprehensive strategy for enhanced levels of support to scientific, operational and research communities. The space agencies, through the Committee on Earth Observation Satellites (CEOS), have embraced the concept of an Integrated Global Observing Strategy (IGOS), primarily in fulfillment of their own set of objectives and to derive greater benefit from both operating and planned Earth observing systems. Through working together, CEOS agencies are in a position to plan their Earth observation projects with the minimum of unnecessary overlap and to devise joint strategies for addressing serious gaps in their observation capabilities. Ultimately, an IGOS should be the joint product of all groups involved in the collection and analysis of both space-based and in-situ data. CEOS is actively seeking IGOS -related partnerships with the Global Climate, Global Ocean and Global Terrestrial Observing Systems, their intergovernmental Sponsors, the International Group of Funding Agencies for Global Change Research, and other scientific and user organizations including the International Geosphere-Biosphere Programme and the World Climate Research Programme.

Charles, Leslie Bermann↗
NASA NTRS2007

The International Space Station Supports International Polar Year (IPY)

Every day, ISS astronauts photograph designated sites and dynamic events on the Earth's surface using digital cameras equipped with a variety of lenses. Depending on observation parameters, astronauts can collect high resolution (4-6 m pixel size) or synoptic views (lower resolution but covering very large areas) digital data in 3 (red-green-blue) color bands. ISS crews have daily opportunities to document a variety of high-latitude phenomena. Although lighting conditions, ground track and other viewing parameters change with orbital precessions and season, the 51.6o orbital inclination and 400 km altitude of the ISS provide the crew an unique vantage point for collecting image-based data of polar phenomena, including surface observations to roughly 65o latitude, and upper atmospheric observations that reach nearly to the poles. During the 2007-2009 timeframe of the IPY, polar observations will become a scientific focus for the CEO experiment; the experiment is designated ISS-IPY. We solicit requests from scientists for observations from the ISS that are coordinated with or complement ground-based polar studies. The CEO imagery website for ISS-IPY provides an on-line form that allows IPY investigators to interact with CEO scientists and define their imagery requests. This information is integrated into daily communications with the ISS astronauts about their Earth Observations targets. All data collected are cataloged and posted on the website for downloading and assimilation into IPY projects. Examples of imagery and detailed information about scientific observations from the ISS can also be downloaded from the ISS-IPY web site.

Evans, Cynthia A.↗
NASA NTRS2009

Recent Progress on Cross-Comparison of Terra and Aqua MODIS Calibration Using Dome C

For the past few years, the MODIS Characterization Support Team (MCST) at NASA/GSFC has continued to evaluate the Terra and Aqua MODIS calibration long-term stability and their calibration consistency using sensor observations over the Dome Concordia, Antarctica. Early results from Dome C observations show that the calibration of bands I and 2 (0.65 and 0.86 micron) is consistent within 1-2% and bands 31 and 32 (11 and 12 micron) differences are less than a couple of tenths of Kelvin, demonstrating that this site can provide a useful calibration reference for a wide range of Earth-observing sensors from visible (VIS) to long-wave infrared (LWIR). Recently, the Dome C area has been endorsed by the CEOS as a reference standard site for sensor cross-comparison. This, as a result, has led to an invitation to the broad community to participate in a CEOS comparison of top-of-atmosphere (TOA) spectral radiance/reflectance over Dome C. In this paper, we provide a brief description of the methodologies and report our recent progress on cross-comparison of Terra and Aqua MODIS spectral bands using observations over this area, including data provided in support of the upcoming CEOS comparison. Emphasis of this paper is on the long-term data records of MODIS instruments, their calibration consistency, and challenging issues.

Xiong, X.↗
NASA NTRS2012

Crew Earth Observations: Twelve Years of Documenting Earth from the International Space Station

The Crew Earth Observations (CEO) payload was one of the initial experiments aboard the International Space Station, and has been continuously collecting data about the Earth since Expedition 1. The design of the experiment is simple: using state-of-the-art camera equipment, astronauts collect imagery of the Earth's surface over defined regions of scientific interest and also document dynamic events such as storms systems, floods, wild fires and volcanic eruptions. To date, CEO has provided roughly 600,000 images of Earth, capturing views of features and processes on land, the oceans, and the atmosphere. CEO data are less rigorously constrained than other remote sensing data, but the volume of data, and the unique attributes of the imagery provide a rich and understandable view of the Earth that is difficult to achieve from the classic remote sensing platforms. In addition, the length-of-record of the imagery dataset, especially when combined with astronaut photography from other NASA and Russian missions starting in the early 1960s, provides a valuable record of changes on the surface of the Earth over 50 years. This time period coincides with the rapid growth of human settlements and human infrastructure.

Evans, Cynthia A.↗
NASA NTRS2018

Public Engagement of Earth Science and Art Using Astronaut Photography

For over fifty years of crewed spaceflight missions, NASA astronauts have taken remarkable photographs of the Earth that offer various perspectives for viewing dynamic Earth processes. The International Space Station (ISS) today provides a unique platform to view and capture imagery of Earth at a variety of viewing angles, seasons, and times of day. Astronaut photos comprise a variable true-color (RGB - Red Green Blue) dataset taken with multiple handheld digital (and historically, film) cameras and lens types that differ from nadir-looking satellite-based remote sensing instruments with fixed temporal and spatial resolutions. The Crew Earth Observations (CEO) Facility within the Earth Science and Remote Sensing Unit at NASA’s Johnson Space Center supports the acquisition, analysis, and curation of astronaut photography of Earth’s surface and atmosphere. CEO’s website, the Gateway to Astronaut Photography of Earth (eol.jsc.nasa.gov), provides free public access to view, search, and download over three million images taken by astronauts from Mercury, Gemini, and Apollo missions to current ISS missions. Handheld images taken by astronauts from the ISS are used for scientific research and public engagement in STEM (Science, Technology, Engineering, Mathematics) fields, particularly earth science. While segments of the public are actively interested in STEM fields, there may be groups who are underexposed to and disinterested in earth science or are unaware of astronaut photography from the ISS. A broader public audience can be introduced to earth science, STEM fields, and ISS research through artistic or abstract photos of the Earth. Wide angle pictures taken of Earth have identifiable landforms and bodies of water, however zoomed in, very high resolution photos without obvious geographic reference can attract new viewing audiences on a purely aesthetic basis. The CEO Facility actively curates a collection of exceptional astronaut photos of Earth as art used to reach a wider population through increased digital products and outreach events. This continuously-updated collection feeds development of freely accessible and high-quality downloadable materials including scientific articles, videos, computer wallpapers, and social media content. These materials are presented with science-based information that augments the artistic qualities of the imagery, and facilitate connection between art-engaged or non-STEM audiences to the ISS research platform and the need for future innovative STEM research.

Meado, Andrea L.↗
NASA NTRS2018

Earth Science Engagement Through Art and Astronaut Photography

For over five decades of manned spaceflight missions, NASA astronauts have taken extraordinary photographs of Earth's surface and dynamic processes. Humans on board the International Space Station (ISS) have a unique platform to perform Earth observations at various viewing angles, seasons, and times of day. Astronaut photos taken from the ISS comprise a true‐color (RGB) dataset taken with multiple handheld digital cameras and lens types (prior to 2004, film cameras were in use). Earth observations through astronaut photography are an important and unique remote sensing method when monitoring natural disasters, urban growth, and environmental changes. While astronaut imagery can be used for earth science research, there is also an artistic aspect to the photography that fascinates a wide global population. A broader public audience can be introduced to earth science through high resolution, Earth art photos taken from the perspective of an astronaut. The Crew Earth Observations (CEO) Facility within the Earth Science and Remote Sensing Unit at NASA's Johnson Space Center supports the acquisition, analysis, and curation of astronaut photography of Earth's surface and atmosphere. CEO's website, the Gateway to Astronaut Photography of Earth (eol.jsc.nasa.gov), provides free public access to view, search, and download over three million images taken by astronauts throughout all of NASA's crewed spaceflight history, with an emphasis on current ISS imagery. The CEO Facility actively curates a digital collection of exceptional Earth art astronaut photos used for public engagement. Our new Downloadable Earth Art page focuses on broad earth science topics including: mountains, water, clouds, agriculture, as well as an "abstract" category. This continuously‐updated collection is comprised of freely accessible and high‐quality downloadable materials, such as single‐ and dual‐screen digital wallpapers. All Earth Art materials are presented with science‐based information that complements the artistic qualities of the imagery, and facilitate connections between general audiences and earth science from the International Space Station.

Meado, Andrea L.↗
NASA NTRS2014

Assessment of the Spectral Stability of Libya 4, Libya 1, and Mauritania 2 Sites Using Earth Observing One Hyperion

The objective of this paper is to formulate a methodology to assess the spectral stability of the Libya 4, Libya 1, and Mauritania 2 pseudo-invariant calibration sites (PICS) using Earth Observing One (EO-1) Hyperion sensor. All the available Hyperion collections, downloaded from the Earth Explorer website, were utilized for the three PICS. In each site, a reference spectrum is selected at a specific day in the vicinity of the region of interest (ROI) defined by Committee on Earth Observation Satellites (CEOS). A series of ROIs are predefined in the along-track direction with 196 spectral top-of-atmosphere reflectance values in each ROI. Based on the reference ROI spectrum, the spectral stability of these ROIs is evaluated by average deviations (ADs) and spectral angle mapper (SAM) methods in the specific ranges of time and geo-spatial locations. Time and ROI location-dependent SAM and AD results are very stable within +/- 2 deg and +/-1.7% of 1sigma standard deviations. Consequently, the Libya 4, Mauritania 2, and Libya 1 CEOS selected PICS are spectrally stable targets within the time and spatial swath ranges of the Hyperion collections.

average deviation↗
NASA NTRS2019

IDN Update

The objective of this presentation is to provide IDN (International Directory Network) updates on features and activities to the Committee on Earth Observation Satellites (CEOS) Working Group on Information Systems and Services (WGISS) and provider community. The following topics will be discussed during the presentation: IDN Activities (since WGISS-46); Registration of services with granules stored outside NASA CMR (Common Metadata Repository; Setting up CEOS 2-Step OpenSearch in the IDN (CMR); Update on efforts to provide consistent Quality Assurance (QA) Rule messaging.

WGISS↗
DOE OSTI2025

Enhancing Metal‐Support Interactions of Ru Catalysts via Relaxation of Oxygen Vacancies for Hydrogen Production

The stability of Ru-based catalysts under harsh electrochemical conditions is a critical challenge limiting their practical application in energy conversion systems. In this study, Ru catalysts supported on ZrO 2-x , CeO 2-x , and ZrCeO 2-x are synthesized via pyrolysis of metal-organic frameworks (MOFs) and systematically evaluated to elucidate the role of support interactions on catalytic performance and durability. Advanced characterization techniques, including HR-TEM, XRD, XPS, and EXAFS, revealed that Ru-ZrCeO 2-x exhibited superior structural stability compared to Ru-ZrO 2-x and Ru-CeO 2-x , particularly under high-potential sweep (HPS) conditions. The incorporation of Ce into ZrO 2-x is shown to stabilize oxygen vacancies and enhance the interaction between Ru catalyst and the support, thereby mitigating catalyst degradation. Density functional theory (DFT) calculations further confirmed that Ce doping decreases formation energy of the oxygen vacancy, providing a thermodynamically favorable environment for Ru stabilization. This work demonstrates the promise of ZrCeO 2-x as a robust support material for Ru-based catalysts, advancing their potential for durable and efficient energy applications.

hydrogen evolution reaction↗
DOE OSTI2016

CO 2 Hydrogenation over Oxide‐Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity

Abstract By simply changing the oxide support, the selectivity of a metal–oxide catalysts can be tuned. For the CO 2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO 2 , ZrO 2 , and TiO 2 ), replacing a TiO 2 support by CeO 2 or ZrO 2 selectively strengthens the binding of C,O‐bound and O‐bound species at the PtCo–oxide interface, leading to a different product selectivity. These results reveal mechanistic insights into how the catalytic performance of metal–oxide catalysts can be fine‐tuned.

Kattel, Shyam↗
DOE OSTI2015

In-situ and theoretical studies for the dissociation of water on an active Ni/CeO₂ catalyst: Importance of strong metal-support interactions for the cleavage of O-H bonds

Water dissociation is crucial in many catalytic reactions on oxide-supported transition-metal catalysts. Here, supported by experimental and density-functional theory results, we elucidate the effect of the support on O-H bond cleavage activity for nickel/ceria systems. Ambient-pressure O1s photoemission spectra at low Ni loadings on CeO₂(111) reveal a substantially larger amount of OH groups as compared to the bare support. Our computed activation energy barriers for water dissociation show an enhanced reactivity of Ni adatoms on CeO₂(111) compared with pyramidal Ni₄ particles with one Ni atom not in contact with the support, and extended Ni(111) surfaces. At the origin of this support effect is the ability of ceria to stabilize oxidized Ni²⁺ species by accommodating electrons in localized f-states. The fast dissociation of water on Ni/CeO₂ has a dramatic effect on the activity and stability of this system as a catalyst for the water-gas shift and ethanol steam reforming reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

CO 2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity

By simply changing the oxide support, the selectivity of a metal–oxide catalysts can be tuned. For the CO 2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO 2 , ZrO 2 , and TiO 2 ), replacing a TiO 2 support by CeO 2 or ZrO 2 selectively strengthens the binding of C,O-bound and O-bound species at the PtCo–oxide interface, leading to a different product selectivity. Lastly, these results reveal mechanistic insights into how the catalytic performance of metal–oxide catalysts can be fine-tuned.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L 3 ‐edge Puzzle

Abstract The Ce L 3 edge XAS spectra of CeO 2 and cerocene [Ce(C 8 H 8 ) 2 ] were calculated with relativistic ab‐initio multireference wavefunction approaches capable of reproducing the observed spectra accurately. The study aims to resolve the decades‐long puzzle regarding the relationship between the number and relative intensities of the XAS peaks and the 4f electron occupation in the ground state (GS) versus the core‐excited states (ESs). CeO 2 and cerocene exemplify the different roles of covalent bonding and wavefunction configurational composition in the observed intensity patterns. Good agreement is found between the calculated GS 4f‐shell occupations and the value derived from XAS measurements using peak areas ( n f ). The identity of the two‐peaked Ce L 3 edge is fully rationalized from the perspective of the relaxed wavefunctions for the GS and core ESs. The states underlying the different peaks differ from each other in a surprisingly simple way that can be associated with 4f 1 vs. 4f 0 sub‐configurations. Furthermore, part of one of the cerocene spectral peaks is associated with 4f 2 sub‐configurations. The pattern therefore reveals excited states that can be interpreted in terms of Ce IV and III oxidation numbers, as long assumed, with Ce II states additionally appearing in the cerocene spectrum. While this work demonstrates the rough accuracy of the conventional approach to determining n f from Ce L 3 ‐edge XAS, limitations are highlighted in terms of the ultimate accuracy of this approach and the potential of observing new types of excited states. The need to determine the sources of n f by calculations, is stressed.

Sergentu, Dumitru‐Claudiu↗
DOE OSTI2016

Infrared spectroscopy investigation of Fe-promoted Rh catalysts supported on Titania and Ceria for CO hydrogenation

The nature of the promotional effect of Fe addition to Rh/TiO 2 and Rh/CeO 2 catalysts for CO hydrogenation was investigated using FT-IR spectroscopy in an ultrahigh vacuum compatible transmission IR cell. CO adsorption experiments on Rh and FeRh showed vibrational signatures characteristic of linear and bridge bound CO on Rh0 as well as geminal-dicarbonyl species associated with Rh + . Compared to TiO 2 , the CeO 2 -supported catalysts show increased dispersion, reflected by decreased particle size, and a lower signal for linear versus geminal-dicarbonyl bonded CO. The absorption frequencies for CO on Rh/CeO 2 are also redshifted relative to Rh/TiO 2 , which results from a weaker Rh–CO interaction, likely due to the increased reducibility of the CeO 2 support. Upon addition of Fe, a new spectral feature is observed and attributed to CO bound to Rh in close contact with Fe, likely as a surface alloy. CO hydrogenation on (Fe)Rh catalysts on both supports was also studied. Compared to bare Rh, Fe containing catalysts promote formate and methoxy species on the surface at lower temperature (180 °C), which suggests an enhancement in methanol selectivity by Fe addition. Furthermore, at higher temperatures (220 °C), the spectral features appear similar, further confirming the role of Fe as a disrupter of large Rh o crystallites and regulator of CO dissociation and CH 4 formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Production of cerium dioxide microspheres by an internal gelation sol–gel method

An internal gelation sol-gel technique was used to prepare cerium dioxide microspheres with uniform diameters near 100 µm. In this process, chilled aqueous solutions containing cerium, hexamethylenetetramine (HMTA), and urea are transformed into a solid gel by heat addition and are subsequently washed, dried, and sintered to produce pure cerium dioxide. Cerous nitrate and ceric ammonium nitrate solutions were compared for their usefulness in microsphere production. Gelation experiments were performed with both cerous nitrate and ceric ammonium nitrate to determine desirable concentrations of cerium, HMTA, and urea in feed solutions as well as the necessary quantity of ammonium hydroxide added to cerium solutions. Analysis of the pH before and after sample gelation was found to provide a quantitative metric for optimal parameter selection along with subjective evaluations of gel qualities. The time necessary for chilled solutions to gel upon inserting into a hot water bath was determined for samples with a variety of parameters and also used to determine desirable formulations for microsphere production. A technique for choosing the optimal mixture of ceric ammonium nitrate, HMTA, and urea was determined using gelation experiments and used to produce microspheres by dispersion of the feed solution into heated silicone oil. Gelled spheres were washed to remove excess reactants and reaction products before being dried and sintered. X-ray diffraction of air-dried microspheres, sintered microspheres, and commercial CeO 2 powders indicated that air-dried and sintered spheres were pure CeO 2 .

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2017

Effect of Oxide Additives on Phase Evolution and Tribological Behavior of Zirconia-Toughened Alumina Composite

Four different zirconia-toughened alumina added with different pairs of oxides (CeO{sub 2}, TiO{sub 2}, CuO, ZnO and SnO{sub 2}) were prepared through the co-precipitation technique. Conventional sintering resulted in relative densities ≥96%. Phase analyses of these composites were performed by x-ray diffraction. Vicker’s hardness and tribological behavior of all ZTA composites were studied. Microstructure analysis of polished and worn surfaces was carried out to understand and correlate the mechanical/tribological behavior with the microstructure. A different wear mechanism is observed in ZTA containing CeO{sub 2} and TiO{sub 2} which resulted in considerable improvement in tribological behavior with a minimum specific wear rate of 9 × 10{sup −7} mm{sup 3}/Nm.

36 MATERIALS SCIENCE↗