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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Image Characterization of Reactions Generated by an Aeroengine Micromixing Injector for Lean Direct Injection of Hydrogen and Hydrogen/Natural Gas Blend

An aeroengine micromixing injector, originally designed for lean direct injection of jet fuel, was adapted to work with hydrogen, natural gas, and any blend in between. The ultimate goal of the design was to achieve low NOx emissions when operated on pure hydrogen; to better characterize its performance, flame imaging diagnostics was implemented. Three types of cameras mounted parallel to the injector base and pointing towards the quartz combustor cylinder with the same angle were operated simultaneously: Nikon D90, Dynacolor FB-N9-U, and Phantom v7.1, to capture the visible spectrum, OH* chemiluminescence, and dynamic behavior of the flames, respectively. The current work also includes the overlapping of visible spectrum and OH* chemiluminescence, as an effort to qualitatively define the heat release over the flame area, i.e., UV over visible domain. Additionally, a z-type schlieren configuration was employed to reinforce the presence of some small-scale details occurring near the injector outlet ports. Using the airbox pressure drop, preheat temperature, fuel composition and flame temperature as the factors of study, a Box Behnken model was designed yielding into a 16-points matrix for the operability region, at atmospheric pressure. The main responses were extracted from the OH* images, because of its correlation with the flame heat release, these being the flame area and its average brightness, the heat release area and its center of gravity and leading edge. To assess the importance of the main factors and their interactions, an analysis of variance (ANOVA) was performed for each response, considering as significant each contributor with a p-value below 0.05. For these five responses it was found that all four main factors need to be included into the model (most of them because its own significance, others to ensure the model hierarchy), as well as some common interactions as the preheat and flame temperatures or pressure drop and fuel composition, and quadratic terms from fuel composition or flame temperature. Three of the five models presented R2 and coefficient of variance (C.V.) indicators around 0.97 and 5%, respectively; the leading edge ANOVA yielded into R2=0.78 and C.V.=18.88%; and the heat release area showed R2=0.91 and C.V.=24.13%. Lastly, the confinement ratio effect of the combustor over the flame structure was quantified, for three different conditions: the original 80 mm inner diameter and 200 mm length cylinder was compared against a shorter 150 mm tube (same inner diameter) and a narrower 47 mm inner diameter one (same 200 mm length). The length had a smaller effect than the inner diameter, even though both factors were not strong enough to make a significant deviation on most of the flame parameters: the difference was within the repeatability margin of error for the brightness, flame area, and center of gravity and leading edge of the heat release area.

Imaging diagnostics, flame characterization, OH* c↗
DOE OSTI2024

Blending Behavioral Science and Physics-Based Models Inform Equitable Decarbonization Pathways in the US Housing Stock: Preprint

A just energy transition is an imperative of the Biden-Harris Administration, emphasizing the equitable distribution of benefits through energy-efficient and decarbonizing household technologies. Understanding the factors that increase a household's willingness to adopt these technologies helps policymakers implement more targeted and effective approaches. Our research addresses this by blending 550,000 housing stock types and energy simulation data with a nationally representative survey on residential technology adoption and decision-making (n=10,000). We identify energy equity gaps across tenure and income, highlighting disparities in energy burdens and insecurity. Findings show that households with prior modification experience are more willing to renovate, suggesting that small-scale retrofit programs could foster greater willingness. Energy secure but burdened homeowners are least willing to modify, highlighting the need to consider energy bill perceptions in policy design. Nearly half of US households that are energy burdened also face energy insecurity, with a significant gap in assistance for low-income households. We emphasize the need to understand household perceptions to improve policy. This research underscores the importance of understanding household behaviors to improve policy effectiveness, offering actionable insights for policymakers to promote equitable housing upgrades and advance a decarbonized future.

behavioral science↗
DOE OSTI2025

Combined TDLAS and chemiluminescence imaging in a flat flame burner operated with NH3/H2 blends

Ammonia is a promising hydrogen carrier due to its favorable storage and transport characteristics. However, its direct use in combustion systems is limited by low flammability and potential for high nitrogen oxide emissions. To better understand ammonia combustion, researchers conducted experiments using a flat flame burner and measured species profiles using tunable-diode-laser-absorption-spectroscopy and chemiluminescence imaging. They tested three flame conditions with different ammonia-hydrogen blends and oxygen levels. The results were compared to simulations using various kinetic mechanisms, including one that accounts for excited species chemistry. The goal is to provide direct information about species profiles in a simple system, isolating chemical kinetics from fluid dynamic effects, which can inform the development of more efficient and low-emission combustion systems using ammonia.

ammonia combustion↗
DOE OSTI2024

Crosslinked polyphosphazene blends for gas separation membranes

The disclosed invention relates to a composition comprising a crosslinked blend of polyphosphazene polymers. The composition comprises a first polyphosphazene and a second polyphosphazene, where the first polyphosphazene and the second polyphosphazene being bound by a thiol bearing crosslinking agent. Such compositions are useful as a membrane material for the separation of gasses in a gaseous mixture.

Hopkinson, David↗
DOE OSTI2022

Controlling pollutant emissions in a high-pressure combustor with fuel-diluent blending

This paper investigates the formation of nitric oxide (NO) and carbon monoxide (CO) emissions as a function of nitrogen (N 2 ) or carbon dioxide (CO 2 ) diluent content, added to a premixed reacting jet in crossflow. Here, reaction characteristics of a rich methane-air jet injected into a lean vitiated crossflow were analyzed at an elevated pressure of 5 atm. The jet was pre-heated and enriched with 0%, 15%, 30%, and 50% mass fraction to quantify the effect on pollutant emissions. Simulated results of the full chemistry Star-CCM+CFD model were verified with data taken in the experimental high-pressure combustion facility, which provides pressure, temperature and velocity profiles, as well as line-of-sight chemiluminescence and exit emission measurements. The analysis revealed the significant influence of the diluent to delay axial combustion; this mixing delay increased the axial flame lift-off and controlled any thermal ignition limitations. Increasing the diluent content increased the timescale for the flame to stabilize, which allowed for greater entrainment of crossflow oxidizer into the axial jet stream, and led to decreased pollutant emissions. Hence, crossflow entrainment is a critical driving force at high diluent content. Local nitric oxide (NO) emission formation in the axial stage was predicted numerically, showing the correlation between diluent addition, axial heat release, and the formation of nitric oxide pollution. The high diluent levels leaned out the jet mixture and delayed axial combustion, while reducing prompt and thermal NOx by mitigating flame hotspots and minimizing the timescale that the products remain at high temperatures.

03 NATURAL GAS↗
DOE OSTI2022

Binary Blend All‐Polymer Solar Cells with a Record Efficiency of 17.41% Enabled by Programmed Fluorination Both on Donor and Acceptor Blocks

Abstract Despite remarkable breakthrough made by virtue of “polymerized small‐molecule acceptor (PSMA)” strategy recently, the limited selection pool of high‐performance polymer acceptors and long‐standing challenge in morphology control impede their further developments. Herein, three PSMAs of PYDT‐2F, PYDT‐3F, and PYDT‐4F are developed by introducing different fluorine atoms on the end groups and/or bithiophene spacers to fine‐tune their optoelectronic properties for high‐performance PSMAs. The PSMAs exhibit narrow bandgap and energy levels that match well with PM6 donor. The fluorination promotes the crystallization of the polymer chain for enhanced electron mobility, which is further improved by following n ‐doping with benzyl viologen additive. Moreover, the miscibility is also improved by introducing more fluorine atoms, which promotes the intermixing with PM6 donor. Among them, PYDT‐3F exhibits well‐balanced high crystallinity and miscibility with PM6 donor; thus, the layer‐by‐layer processed PM6/PYDT‐3F film obtains an optimal nanofibril morphology with submicron length and ≈23 nm width of fibrils, facilitating the charge separation and transport. The resulting PM6/PYDT‐3F devices realizes a record high power conversion efficiency (PCE) of 17.41% and fill factor of 77.01%, higher than the PM6/PYDT‐2F (PCE = 16.25%) and PM6/PYDT‐4F (PCE = 16.77%) devices.

Zhou, Dehong↗
DOE OSTI2024

Probing the interface structure of block copolymer compatibilizers in semicrystalline polymer blends

Abstract The use of block copolymers to compatibilize immiscible plastics is an important strategy for upcycling municipal plastic wastes. Multiblock copolymers (MBCPs) have been proven to be more effective compatibilizers than di‐ and tri‐block copolymers. Herein, we probe the interface structure of an effective multiblock copolymer compatibilizer and compare that with an ineffective triblock copolymer (TBCP). The interface activity of the compatibilizers is understood through a combination of small‐angle neutron and x‐ray scatterings (SANS and SAXS), by using deuterated homopolymer matrix and protonated compatibilizers. SANS analysis suggests that the MBCP forms a thicker interface layer (7–9 nm) than the TBCP (0–4 nm). In addition, SANS data seems to point to a stronger tendency for the MBCP to locate at the interface. Both factors contribute to its effectiveness at compatibilizing immiscible homopolymers.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Direct Recycling of Blended Cathode Materials by Froth Flotation

We report that direct Li-ion battery recycling involves separating cathode active materials in the solid phase while preserving their electrochemical performance. To reuse the recycled ones in new batteries, it is necessary to separate individual cathode components, which would typically occur prior to the rejuvenation and any compositional reformulation processes. Herein, a froth flotation process is developed to separate pristine lithium nickel-manganese-cobalt oxide (LiNi 0.333 Mn 0.333 Co 0.333 O 2 , NMC111) and lithium manganese oxide (LMO) materials. The flotation results show that with multiple stages of the separation processes, a satisfactory separation is achieved with 95% grade or above of NMC111 in the froth product and 95% grade of LMO in the tailing product. The electrochemistry results show that the flotation chemicals have negligible impact on the electrochemical performance of recycled active materials, whereas the NMC111 exhibits a minor capacity fade after being in contact with deionized water at 2% solid concentration. An improvement in both the rate and cycling performance is achieved at 10% solid concentration or higher. It is found that there is little compositional and structural change to the aqueous recycled NMC111 powders. An effective and low-cost separation method for direct recycling mixed cathode compositions is demonstrated.

25 ENERGY STORAGE↗
DOE OSTI2026

In-Process Melt Separation of Depolymerized PET in PET/PE Blends for Upcycling via Twin-Screw Extrusion

Our previous work focused on depolymerizing polyethylene terephthalate (PET) in twin-screw extrusion, as part of a broader project to continuously separate PET from polyolefins in the melt. This study focused on linear low-density polyethylene (LLDPE) and PET films and the use of ethylene glycol (EG), diethylene glycol (DEG), triethylene glycol (TEG), and bis(2-hydroxyethyl) terephthalate (BHET) to depolymerize the PET in the extruder to levels above 90% Mw. In this work, the focus will shift to achieving separation of the two polymers in the twin-screw extruder, which is made possible due to a 90% reduction in the Mw of the PET, which caused a decrease of its viscosity by several orders of magnitude. Owing to the viscosity difference and pressure buildup in the die, the low-viscosity PET preferentially exited a degassing vent instead of going through the die. This is because the flow of the PET would travel through a non-pressure vent rather than through a high-pressure die. However, owing to the higher viscosity of the LLDPE, the pressure was too high to pass through such a small diameter vent hole. Supercritical CO 2 (SCCO 2 ) was used to assist in this extraction, but SCCO 2 negatively impacted the overall degree of separation. Through analysis of the separated materials, it was concluded that a high separation of the two materials was achieved. TGA and FTIR confirmed that the material separated from the vent was 100% PET. The material removed from the die was composed of 95% LLDPE and 5% PET.

36 MATERIALS SCIENCE↗
DOE OSTI2026

In‐Process Melt Separation of PE/PET Blends for Upcycling via Twin‐Screw Extrusion. Impact of Catalyst Reagents on PET Depolymerization

Part 1 of this work focused on depolymerizing polyethylene terephthalate (PET) in twin-screw extrusion, as part of a broader project to continuously separate PET from polyolefins in the melt. This study focused on linear low-density polyethylene (LLDPE) and PET films and the use of ethylene glycol (EG), diethylene glycol (DEG), triethylene glycol (TEG), and bis(2-hydroxyethyl) terephthalate (BHET) to depolymerize the PET in the extruder to levels above 90% Mw. In part 2, the focus will shift to achieving separation of the two polymers in the twin-screw extruder, which is made possible due to a 90% reduction in the Mw of the PET, which caused a decrease of its viscosity by several orders of magnitude. Owing to the viscosity difference and pressure buildup in the die, the low-viscosity PET preferentially exited a degassing vent instead of going through the die. This is because the flow of the PET would travel through a non-pressure vent rather than through a high-pressure die. However, owing to the higher viscosity of the LLDPE, the pressure was too high to pass through such a small diameter vent hole. Supercritical CO₂ (SCCO₂) was used to assist in this extraction, but SCCO₂ negatively impacted the overall degree of separation. Through analysis of the separated materials, it was concluded that a very high separation of the two materials was achieved. TGA and FTIR confirmed that the material separated from the vent was 100% PET. The material removed from the die was composed of 90% LLDPE and 10% PET.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Expanding the horizon of bio-naphtha beyond gasoline blend: property characterization and conversion opportunity assessment through technoeconomic and life-cycle analyses

Bio-naphtha, a common by-product of biorefineries, is expected to experience substantial growth in supply due to increasing demands for renewable diesel and synthetic aviation fuel (SAF). However, demand for bio-naphtha itself as a gasoline blendstock is limited because of the electrification of light-duty vehicles. This work investigated valorization opportunities for bio-naphtha from catalytic fast pyrolysis, hydrothermal liquefaction, Fischer–Tropsch synthesis, and hydrotreated esters and fatty acids pathways. These opportunities include producing polymer-grade olefin via steam cracking, SAF via steam cracking followed by olefin oligomerization, and renewable aromatics benzene, toluene, and xylene (BTX) and hydrogen via catalytic reforming. Process models were developed in Aspen Plus V14 and Aspen HYSYS V14 to calculate the mass and energy balances for each conversion step. Technoeconomic assessment and life-cycle analysis were conducted to evaluate the minimum fuel/product selling price, conversion cost, and life-cycle CO2 equivalent (CO2e) emission reduction. Technoeconomic assessment results suggest a minimum fuel/product selling price as low as $1.9/kg of olefins, $6.30/gal of gasoline-equivalent SAF, and $1.2/kg of BTX without any incentives. For all pathways, these prices are dominated by bio-naphtha feedstock costs, which account for at least 76% of the total cost. Compared with petroleum baselines, bio-naphtha-derived SAF, olefins, and BTX can achieve significant CO2e emission reductions from the use of renewable carbon resources. The results of life-cycle analysis and subsequent technoeconomic assessment, incorporating carbon credits, indicate the economic viability of using bio-naphtha for polymer-grade olefin and BTX production, with product costs comparable to market prices.

Xu, Shuang↗