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At least 469 records · Page 26

Iptycene synthesis: A new method for attaching a 2,3-anthracene moiety to the 9,10-positions of another anthracene moiety - Exceptional conditions for a Lewis acid catalyzed Diels-Alder reaction

An efficient three-step method for appending a 2,3-anthracene moiety to the 9,10-positions of an existing anthracene moiety is described. The first step uses excess 1,4-anthraquinone (3 equiv) and aluminum chloride (6 equiv) to obtain the anthracene-quinone cycloadduct (omission of the AlCl3 resulted in no adduct). The resulting diketone was reduced to the corresponding diol (excess LiAlH4), which was dehydrated to the arene with phosphorus oxychloride and pyridine. Specific examples include the preparation of heptipycene 8 from pentiptycene 6 (66 percent overall yield) and a similar conversion of 8 to the noniptycene 13 (75 percent overall yield). The methodology led to a markedly improved synthesis of tritriptycene 9 and the first synthesis of undecaiptycene 14.

Chen, Yong-Shing↗

Relative efficiency and accuracy of two Navier-Stokes codes for simulating attached transonic flow over wings

Two codes which solve the 3-D Thin Layer Navier-Stokes (TLNS) equations are used to compute the steady state flow for two test cases representing typical finite wings at transonic conditions. Several grids of C-O topology and varying point densities are used to determine the effects of grid refinement. After a description of each code and test case, standards for determining code efficiency and accuracy are defined and applied to determine the relative performance of the two codes in predicting turbulent transonic wing flows. Comparisons of computed surface pressure distributions with experimental data are made.

Bonhaus, Daryl L.↗

The ultra high resolution XUV spectroheliograph: An attached payload for the Space Station Freedom

The principle goal of the ultra high resolution XUV spectroheliograph (UHRXS) is to improve the ability to identify and understand the fundamental physical processes that shape the structure and dynamics of the solar chromosphere and corona. The ability of the UHRXS imaging telescope and spectrographs to resolve fine scale structures over a broad wavelength (and hence temperature) range is critical to this mission. The scientific objectives and instrumental capabilities of the UHRXS investigation are reviewed before proceeding to a discussion of the expected performance of the UHRXS observatory.

Walker, Arthur B. C., Jr.↗

Notched fatigue of single crystal PWA 1480 at turbine attachment temperatures

The focus is on the lower temperature, uncoated and notched features of gas turbine blades. Constitutive and fatigue life prediction models applicable to these regions are being developed. Fatigue results are presented which were obtained thus far. Fatigue tests are being conducted on PWA 1480 single crystal material using smooth strain controlled specimens and three different notched specimens. Isothermal fatigue tests were conducted at 1200, 1400, and 1600 F. The bulk of the tests were conducted at 1200 F. The strain controlled tests were conducted at 0.4 percent per second strain rate and the notched tests were cycled at 1.0 cycle per second. A clear orientation dependence is observed in the smooth strain controlled fatigue results. The fatigue lifes of the thin, mild notched specimens agree fairly well with this smooth data when elastic stress range is used as a correlating parameter. Finite element analyses were used to calculate notch stresses. Fatigue testing will continue to further explore the trends observed thus far. Constitutive and life prediction models are being developed.

Meyer, T. G.↗

The radiation pattern of a monopole antenna attached to a conducting box

A system investigation was undertaken to determine the radiation patterns of a monopole antenna mounted on a cubical conducting box over a ground plane. The effects of the location of the monopole and the electrical size of the box were compared with similar patterns measured over a flat ground plane and with numerically predicted values obtained from a method-of-moments patch code. It was concluded that the location at which a monopole antenna is mounted on a conducting box and the electrical size of the box clearly affect the overall radiation pattern of a monopole antenna. In general, mounting the antenna away from the center of the box will increase the depth of the nulls. In particular, planes will also increase the maximum E(phi) component of the field to the extent that it can become comparable to E(theta).

Chu, Andrew W. C.↗

Performance of popular turbulence models for attached and separated adverse pressure gradient flows

The performance of four popular eddy-viscosity turbulence models under adverse pressure gradient conditions is investigated. The Baldwin-Lomax, the Johnson-King, the Baldwin-Barth, and the Wilcox-omega models have been implemented into the INS code, which solves the incompressible Reynolds-averaged Navier-Stokes equations. Results are shown for the well known Samuel-Joubert flow and two new flowfields, recently reported by D. M. Driver (1991). The two new flowfields pose a stronger test of the models than the Samuel-Joubert flow, because of the more severe retardation of the boundary layer, including separation in one case. A detailed comparison of the numerical results and the experimental data is shown.

Menter, F. R.↗

Interaction of disturbances with an oblique detonation wave attached to a wedge

The linear response of an oblique overdriven detonation to impose free stream disturbances or to periodic movements of the wedge is examined. The free stream disturbances are assumed to be steady vorticity waves and the wedge motions are considered to be time periodic oscillations either about a fixed pivot point or along the plane of symmetry of the wedge aligned with the incoming stream. The detonation is considered to be a region of infinitesmal thickness in which a finite amount of heat is released. The response to the imposed disturbances is a function of the Mach number of the incoming flow, the wedge angle, and the exothermocity of the reaction within the detonation. It is shown that as the degree of overdrive increases, the amplitude of the response increases significantly; furthermore, a fundamental difference in the dependence of the response on the parameters of the problem is found between the response to a free stream disturbance and to a disturbance emanating from the wedge surface.

Lasseigne, D. G.↗

Support activities to maintain SUMS flight readiness, volume 2. Attachment A: Flight 61-C report

The Shuttle Upper Atmosphere Mass Spectrometer (SUMS), a component experiment of the NASA Orbital Experiments Program (OEX), was flown aboard the shuttle Columbia (OV102) mounted at the forward end of the nose landing gear well with an atmospheric gas inlet system fitted to the lower fuselage (chin panel) surface. The SUMS was designed to provide atmospheric data in flow regimes inaccessible prior to the development of the Space Transportation system (STS). The experiment mission operation begins about 1 hour to shuttle de-orbit entry maneuver and continues until reaching 1.6 torr (about 86 km altitude). The SUMS flew a total of three missions, 61C, STS-35, and STS-40. Between flights, the SUMS was maintained in flight ready status. The flight data has been analyzed by the NASA LaRC Aerothermodynamics Branch. Flight data spectrum plots and reports are presented in the Appendices to the Final Technical Report for NAS1-17399. This volume is the flight data report for flight 61-C.

Wright, Willie↗

Support activities to maintain SUMS flight readiness, volume 3. Attachment B: Flight STS-35 report, section A

The Shuttle Upper Atmosphere Mass Spectrometer (SUMS), a component experiment of the NASA Orbital Experiments Program (OEX), was flown aboard the shuttle Columbia (OV102) mounted at the forward end of the nose landing gear well with an atmospheric gas inlet system fitted to the lower fuselage (chin panel) surface. The SUMS was designed to provide atmospheric data in flow regimes inaccessible prior to the development of the Space Transportation System (STS). The experiment mission operation begins about 1 hour prior to shuttle de-orbit entry maneuver and continues until reaching 1.6 torr (about 86 km altitude). The SUMS flew a total of three missions, 61C, STS-35, and STS-40. Between flights, the SUMS was maintained in flight ready status. The flight data has been analyzed by the NASA LaRC Aerothermodynamics Branch. Flight data spectrum plots and reports are presented in the Appendices to the Final Technical Report for NAS1-17399. This volume presents flight data for flight STS-35 in graphical format.

Wright, Willie↗

Support activities to maintain SUMS flight readiness, volume 4. Attachment B: Flight STS-35 report, section B

The Shuttle Upper Atmosphere Mass Spectrometer (SUMS), a component experiment of the NASA Orbital Experiments Program (OEX), was flown aboard the shuttle Columbia (OV102) mounted at the forward end of the nose landing gear well with an atmospheric gas inlet system fitted to the lower fuselage (chin panel) surface. The SUMS was designed to provide atmospheric data in flow regimes inaccessible prior to the development of the Space Transportation System (STS). The experiment mission operation begins about 1 hour prior to shuttle de-orbit entry maneuver and continues until reaching 1.6 torr (about 86 km altitude). The SUMS flew a total of three missions, 61C, STS-35, STS-40. Between flights, the SUMS was maintained in flight ready status. The flight data has been analyzed by the NASA LaRC Aerothermodynamics Branch. Flight data spectrum plots and reports are presented in the Appendices to the Final Technical Report for NAS1-17399. This volume present spectra graphs of the reentry of flight STS-35.

Wright, Willie↗

Support activities to maintain SUMS flight readiness, volume 5. Attachment B: Flight STS-35 report, section C

The Shuttle Upper Atmosphere Mass Spectrometer (SUMS), a component experiment of the NASA Orbital Experiments Program (OEX), was flown aboard the shuttle Columbia (OV102) mounted at the forward end of the nose landing gear well with an atmospheric gas inlet system fitted to the lower fuselage (chin panel) surface. The SUMS was designed to provide atmospheric data in flow regimes inaccessible prior to the development of the Space Transportation System (STS). The experiment mission operation begins about 1 hour prior to shuttle de-orbit entry maneuver and continues until reaching 1.6 torr (about 86 km altitude). The SUMS flew a total of three missions, 61C, STS-35, and STS-40. Between flights, the SUMS was maintained in flight ready status. The flight data has been analyzed by the NASA LaRC Aerothermodynamics Branch. Flight data spectrum plots and reports are presented in the Appendices to the Final Technical Report for NAS1-17399. This volume presents spectral graphs of the reentry of flight STS-35.

Wright, Willie↗

Support activities to maintain SUMS flight readiness, volume 6. Attachment B: Flight STS-35 report, section D

The Shuttle Upper Atmosphere Mass Spectrometer (SUMS), a component experiment of the NASA Orbital Experiments Program (OEX), was flown aboard the shuttle Columbia (OV102) mounted at the forward end of the nose landing gear well with an atmospheric gas inlet system fitted to the lower fuselage (chin panel) surface. The SUMS was designed to provide atmospheric data in flow regimes inaccessible prior to the development of the Space Transportation System (STS). The experiment mission operation begins about 1 hour prior to shuttle de-orbit entry maneuver and continues until reaching 1.6 torr (about 86 km altitude). The SUMS flew a total of three missions, 61C, STS-35, STS-40. Between flights, the SUMS was maintained in flight ready status. The flight data has been analyzed by the NASA LaRC Aerothermodynamics Branch. Flight data spectrum plots and reports are presented in the Appendices to the Final Technical Report for NAS1-17399. This volume presents spectral graphs of the reentry of flight STS-35.

Wright, Willie↗

Support activities to maintain SUMS flight readiness, volume 7. Attachment B: Flight STS-35 report, section E

The Shuttle Upper Atmosphere Mass Spectrometer (SUMS), a component experiment of the NASA Orbital Experiments Program (OEX), was flown aboard the shuttle Columbia (OV102) mounted at the forward end of the nose landing gear well with an atmospheric gas inlet system fitted to the lower fuselage (chin panel) surface. The SUMS was designed to provide atmospheric data in flow regimes inaccessible prior to the development of the Space Transportation System (STS). The experiment mission operation begins about 1 hour prior to shuttle de-orbit entry maneuver and continues until reaching 1.6 torr (about 86 km altitude). The SUMS flew a total of three missions, 61C, STS-35, STS-40. Between flights, the SUMS was maintained in flight ready status. The flight data has been analyzed by the NASA LaRC Aerothermodynamics Branch. Flight data spectrum plots and reports are presented in the Appendices to the Final Technical Report for NAS1-17399. This volume presents data from the reentry of flight STS-35 in tabular and graphical format.

Wright, Willie↗

Support activities to maintain SUMS flight readiness, volume 8. Attachment B: Flight STS-35 report, section F

The Shuttle Upper Atmosphere Mass Spectrometer (SUMS), a component experiment of the NASA Orbital Experiments Program (OEX), was flown aboard the shuttle Columbia (OV102) mounted at the forward end of the nose landing gear well with an atmospheric gas inlet system fitted to the lower fuselage (chin panel) surface. The SUMS was designed to provide atmospheric data in flow regimes inaccessible prior to the development of the Space Transportation System (STS). The experiment mission operation begins about 1 hour prior to shuttle de-orbit entry maneuver and continues until reaching 1.6 torr (about 86 km altitude). The SUMS flew a total of three missions, 61C, STS-35, STS-40. Between flights, the SUMS was maintained in flight ready status. The flight data has been analyzed by the NASA LaRC Aerothermodynamics Branch. Flight data spectrum plots and reports are presented in the Appendices to the Final Technical Report for NAS1-17399. This volume presents tabular and graphical spectral data of the reentry of flight STS-35.

Wright, Willie↗

Rotating-unbalanced-mass devices and methods for scanning balloon-borne-experiments, free-flying spacecraft, and space shuttle/space station attached experiments

A method and apparatus for scanning balloon-borne experiments, free-flying spacecraft, or gimballed experiments mounted on a space shuttle or space station, makes use of one or more rotating unbalanced mass devices for selectively generating circular, line, or raster scan patterns for the experiment line of sight. An auxiliary control system may also be used in combination with the rotating unbalanced mass device, for target acquisition, keeping the scan centered on the target, or for producing complementary motion for raster scanning. The rotating unbalanced mass makes use of a mass associated with a drive shaft, such mass having a center of gravity which is displaced from the drive shaft rotation axis. The drive shaft is driven with a substantially constant angular velocity, thereby resulting in relatively low power requirements since no acceleration or deceleration of the mass is generally involved during steady state operations. The resulting centrifugal force of the rotating unbalanced mass is used to generate desired reaction forces on the experiment or spacecraft to create a desired scan pattern for the experiment line of sight.

Polites, Michael E.↗