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At least 451 records · Page 25

Manipulating polymer composition to create low-cost, high-fidelity sensors for indoor CO2 monitoring

Abstract Carbon dioxide (CO 2 ) has been linked to many deleterious health effects, and it has also been used as a proxy for building occupancy measurements. These applications have created a need for low-cost and low-power CO 2 sensors that can be seamlessly incorporated into existing buildings. We report a resonant mass sensor coated with a solution-processable polymer blend of poly(ethylene oxide) (PEO) and poly(ethyleneimine) (PEI) for the detection of CO 2 across multiple use conditions. Controlling the polymer blend composition and nanostructure enabled better transport of the analyte gas into the sensing layer, which allowed for significantly enhanced CO 2 sensing relative to the state of the art. Moreover, the hydrophilic nature of PEO resulted in water uptake, which provided for higher sensing sensitivity at elevated humidity conditions. Therefore, this key integration of materials and resonant sensor platform could be a potential solution in the future for CO 2 monitoring in smart infrastructure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hydrology controls thermokarst and alters carbon cycling and methane emissions in peatlands near the southern limit of permafrost

Permafrost peatlands store vast amounts of frozen carbon across northern landscapes. When ground ice melts, surface subsidence produces thermokarst landforms that expand wetlands at the edges of permafrost plateaus. Thermokarst represents an accelerating climate feedback, but uncertainties remain about how ground ice, hydrology, and vegetation interact to shape landscape change and carbon fluxes. We extended the process-based model ecosys to simulate thermokarst dynamics in laterally coupled 2D transects at a well-characterized boreal peatland site in Canada’s Northwest Territories. After benchmarking against site observations, we varied ground ice content and hydrologic boundary conditions across ranges typical near the southern permafrost limit. Simulations revealed distinct degradation regimes governed by the elevation difference between the frost table and the external water table. Rates of lateral retreat, the thaw-driven encroachment of wetlands into adjacent plateaus, ranged from 0 to >2 m yr −1 under identical weather forcing, consistent with observations and highlighting the strong role of WT and ground ice. Simulated vegetation dynamics indicate that black spruce mortality cannot be explained by anoxia alone, pointing to additional stressors such as root damage, pathogens, or physical destabilization. Despite large hydrologic shifts, net ecosystem CO 2 exchange remained a slight sink after collapse, while methane (CH 4 ) emissions rose by one to two orders of magnitude. As a result, lateral retreat substantially increases the greenhouse warming potential of permafrost peatlands (1.7 million km 2 in area), with simulated emissions of 0.1–10 Mt CO 2 -eq decade −1 depending on hydrology and retreat rates. These results underscore the need to account for both ground ice and hydrologic dynamics when assessing thermokarst-driven climate feedbacks.

carbon cycling↗

High-resolution mountain topography can inform global snow vulnerability estimates

Snow is changing globally. Computationally intensive snow reanalysis products and downscaled climate model projections allow for the estimation of historical and projected changes in snow over ∼4–10 km resolutions, but these resolutions are coarse relative to the scales needed for water supply and flood planning. Fine-scale digital elevation models (DEMs) are widely available but are underutilized to make first-order assessments of snow vulnerability. Here, we leverage DEMs at a 7.5 arc s (∼250 m) resolution, combining these with historical freezing level height estimates from ERA-5 to derive estimates of changes in the snow-receiving area (SRA) and its variability across global mountain ranges. Results show estimated SRA declines in 29% (1.9 million km2) of the global mountain area from 1982–2020; 66% of the mountainous areas had no change over the historical period. At +1.5 °C of warming relative to the pre-industrial control, global mountain SRA would decline by 9.5% (1.0 million km2) relative to recent conditions. This loss would be approximately doubled with +2 °C of warming. In a +4 °C warming scenario, an additional 34% (3.6 million km2) of SRA would be lost beyond the +2 °C case. Across individual mountain ranges, SRA losses can occur nonlinearly with warming, with some locations that have historically had relatively minor SRA losses at risk of substantially larger losses in warmer climates. Analysis using coarser-resolution DEMs can underestimate or overestimate SRA and its rate of loss, with the largest impacts in relatively warm, low-elevation mountain ranges. Results of this work provide estimates of projected loss in SRA at policy-relevant warming levels; inform the resolutions needed for process-based snow modeling; identify snow vulnerability hotspots; and provide a new integrated approach to snow vulnerability assessment that is achievable at global scales and highlights potential nonlinearities from recent trends to a variety of future warming scenarios.

climate, mountains↗

Applying Transfer Learning for Street-Scale Nuisance Flood Forecasting in Coastal-Urban Cities

An important challenge with Machine Learning (ML) is its transferability; that is, whether a ML model trained on one set of data can be applied to a second set of data without requiring a full re-training of the model. Transfer Learning (TL) addresses this challenge by transferring knowledge learned in the source domain (the data it was trained on) to the target domain (a second set of data that is statistically different but related, which the model was not trained on). This study investigates the use of TL for street-scale nuisance flood forecasting by exploring whether a ML model trained on data collected for one set of streets can effectively forecast flooding for another set of streets in the same city using TL. The envisioned use case is a city deploying a new flood depth monitoring sensor on a street and using TL to apply a ML model, trained on sensor data from an existing flood depth sensor network, to this new street. Eventually, the new flood depth sensor will have a sufficient dataset for training its own ML model, but TL can be used to fill the gap in time while this new dataset is being generated. This method is explored using a Long Short-Term Memory (LSTM) model trained on data for the flood-prone streets of Norfolk City, Virginia. The data used for training includes environmental time series (rainfall, tide), topographic features (Digital Elevation Model (DEM), Topographic Wetness Index (TWI), Depth To Water (DTW)), and street-scale flood depth time series obtained from a high-fidelity physics-based model, acting as a synthetic street-scale stream depth sensor dataset since actual stream depth sensor data is generally unavailable for most cities. A set of 180 flood-prone streets was used to train a base model, while another set of 180 flood-prone streets was used to re-train that model using different TL strategies. The results show that full-weight re-training proved most effective and minimal re-training of only the output layer was insufficient. The advantage of TL was most pronounced when target data was limited, meaning data collected at the new water depth sensor location included generally less than 18 flood events. As target data increased beyond 18 flood events, the benefit of TL diminished relative to training a ML model directly on the local flood events. These findings can assist cities as they implement street-scale flood sensing systems to create accurate forecasts for new sensing locations that do not yet have sufficient data records to train a local ML model.

Roy, Binata [Univ. of Virginia, Charlottesville, V↗

Evaluation of ERTS data for certain oceanographic uses

The author has identified the following significant results. (1) Sunglint effects over water can be expected in ERTS-1 images whenever solar elevations exceed 55 deg. (2) Upwellings were viewed coincidently by ERTS-1 and NOAA-2 in Lake Michigan on two occasions during August 1973. (3) A large oil slick was identified 100 km off the Maryland coast in the Atlantic Ocean. Volume of the oil was estimated to be least 200,000 liters (50,000 gallons). (4) ERTS-1 observations of turbidity patterns in Lake St. Clair provide circulation information that correlates well with physical model studies made 10 years ago. (5) Good correlation has been established between ERTS-1 water color densities and NOAA-2 thermal infrared surface temperature measurements. Initial comparisons have been made in Lake Erie during March 1973.

Strong, A. E.↗

Large Area Crop Inventory Experiment (LACIE). Effect of sun angle and haze on generation of LANDSAT imagery

The author has identified the following significant results. When heavy haze was present over a nonvegetated scene, the mean radiance values for all MSS channels were lowered, with the greatest decrease occurring in channels 1 and 2. Over a vegetated scene, any apparent decrease in mean radiance values due to haze may be marked by an increase in mean radiance values which occurred as vegetation increased in vigor during its growth cycle. Mean radiance values for nonvegetated targets (except water) were closely correlated to the changes in sun elevation angle throughout the year. A sun angle correction to a fixed reference data appeared to offer the possibility of compensating for haze covered areas by predicting the mean radiance values which would be closely correlated to the normal sun declination curve.

Chesnutwood, C. M.↗

Fluid inclusions in Martian samples: Clues to early crustal development and the hydrosphere

Major questions about Mars that could be illuminated by examining fluid inclusions in Martian samples include: (1) the nature, extent and timing of development (and decline) of the hydrosphere that existed on the planet; and (2) the evolution of the crust. Fluid inclusion analyses of appropriate samples could provide critical data to use in comparison with data derived from analogous terrestrial studies. For this study, sample handling and return restrictions are unlikely to be as restrictive as the needs of other investigators. The main constraint is that the samples not be subjected to excessively high temperatures. An aqueous fluid inclusion trapped at elevated pressure and temperature will commonly consist of liquid water and water vapor at room temperature. Heating (such as is done in the laboratory to fix P-V-T data for the inclusion) results in moderate pressure increases up to the liquid-vapor homogenization temperature followed by a sharp increase in pressure with continued heating because the inclusion is effectively a fixed volume system. This increased pressure can rupture the inclusion; precise limits are dependent on size, shape, and composition as well as the host material.

Brown, Philip E.↗

Projected Climate Impacts to South African Maize and Wheat Production in 2055: A Comparison of Empirical and Mechanistic Modeling Approaches

Crop model-specific biases are a key uncertainty affecting our understanding of climate change impacts to agriculture. There is increasing research focus on intermodel variation, but comparisons between mechanistic (MMs) and empirical models (EMs) are rare despite both being used widely in this field. We combined MMs and EMs to project future (2055) changes in the potential distribution (suitability) and productivity of maize and spring wheat in South Africa under 18 downscaled climate scenarios (9 models run under 2 emissions scenarios). EMs projected larger yield losses or smaller gains than MMs. The EMs' median-projected maize and wheat yield changes were 3.6% and 6.2%, respectively, compared to 6.5% and 15.2% for the MM. The EM projected a 10% reduction in the potential maize growing area, where the MM projected a 9% gain. Both models showed increases in the potential spring wheat production region (EM = 48%, MM = 20%), but these results were more equivocal because both models (particularly the EM) substantially overestimated the extent of current suitability. The substantial water-use efficiency gains simulated by the MMs under elevated CO2 accounted for much of the EMMM difference, but EMs may have more accurately represented crop temperature sensitivities. Our results align with earlier studies showing that EMs may show larger climate change losses than MMs. Crop forecasting efforts should expand to include EMMM comparisons to provide a fuller picture of crop-climate response uncertainties.

DSSAT↗

Antarctic Sea-Ice Freeboard and Estimated Thickness from NASA's ICESat and IceBridge Observations

ICESat completed 18 observational campaigns during its lifetime from 2003 to 2009. Data from all of the 18 campaign periods are used in this study. Most of the operational periods were between 34 and 38 days long. Because of laser failure and orbit transition from 8-day to 91-day orbit, there were four periods lasting 57, 16, 23, and 12 days. IceBridge data from 2009, 2010, and 2011 are used in this study. Since 2009, there are 19 Airborne Topographic Mapper (ATM) campaigns, and eight Land, Vegetation, and Ice Sensor (LVIS) campaigns over the Antarctic sea ice. Freeboard heights are derived from ICESat, ATM and LVIS elevation and waveform data. With nominal densities of snow, water, and sea ice, combined with snow depth data from AMSR-E/AMSR2 passive microwave observation over the southern ocean, sea-ice thickness is derived from the freeboard. Combined with AMSR-E/AMSR2 ice concentration, sea-ice area and volume are also calculated. During the 2003-2009 period, sea-ice freeboard and thickness distributions show clear seasonal variations that reflect the yearly cycle of the growth and decay of the Antarctic pack ice. We found no significant trend of thickness or area for the Antarctic sea ice during the ICESat period. IceBridge sea ice freeboard and thickness data from 2009 to 2011 over the Weddell Sea and Amundsen and Bellingshausen Seas are compared with the ICESat results.

Antarctic↗

Growing impact of wildfire on western US water supply

Streamflow often increases after fire, but the persistence of this effect and its importance to present and future regional water resources are unclear. This paper addresses these knowledge gaps for the western United States (WUS), where annual forest fire area increased by more than 1,100% during 1984 to 2020. Among 72 forested basins across the WUS that burned between 1984 and 2019, the multibasin mean streamflow was significantly elevated by 0.19 SDs (P < 0.01) for an average of 6 water years postfire, compared to the range of results expected from climate alone. Significance is assessed by comparing prefire and postfire streamflow responses to climate and also to streamflow among 107 control basins that experienced little to no wildfire during the study period. The streamflow response scales with fire extent: among the 29 basins where >20% of forest area burned in a year, streamflow over the first 6 water years postfire increased by a multibasin average of 0.38 SDs, or 30%. Postfire streamflow increases were significant in all four seasons. Historical fire–climate relationships combined with climate model projections suggest that 2021 to 2050 will see repeated years when climate is more fire-conducive than in 2020, the year currently holding the modern record for WUS forest area burned. These findings center on relatively small, minimally managed basins, but our results suggest that burned areas will grow enough over the next 3 decades to enhance streamflow at regional scales. Wildfire is an emerging driver of runoff change that will increasingly alter climate impacts on water supplies and runoff-related risks.

54 ENVIRONMENTAL SCIENCES↗

Growing Impact of Wildfire on Western US Water Supply

Streamflow often increases after fire, but the persistence of this effect and its importance to present and future regional water resources are unclear. This paper addresses these knowledge gaps for the western United States (WUS), where annual forest fire area increased by more than 1,100% during 1984 to 2020. Among 72 forested basins across the WUS that burned between 1984 and 2019, the multibasin mean streamflow was significantly elevated by 0.19 SDs ( P < 0.01) for an average of 6 water years postfire, compared to the range of results expected from climate alone. Significance is assessed by comparing prefire and postfire streamflow responses to climate and also to streamflow among 107 control basins that experienced little to no wildfire during the study period. The streamflow response scales with fire extent: among the 29 basins where >20% of forest area burned in a year, streamflow over the first 6 water years postfire increased by a multibasin average of 0.38 SDs, or 30%. Postfire streamflow increases were significant in all four seasons. Historical fire–climate relationships combined with climate model projections suggest that 2021 to 2050 will see repeated years when climate is more fire-conducive than in 2020, the year currently holding the modern record for WUS forest area burned. These findings center on relatively small, minimally managed basins, but our results suggest that burned areas will grow enough over the next 3 decades to enhance streamflow at regional scales. Wildfire is an emerging driver of runoff change that will increasingly alter climate impacts on water supplies and runoff-related risks.

wildfire↗

Oxygen Isotope Evidence for the Relationship between CM and CO Chondrites: Could they Both Coexist on a Single Asteroid

Water played a critical role in the early evolution of asteroids and planets, as well as being an essential ingredient for life on Earth. However, despite its importance, the source of water in the inner solar system remains controversial. Delivery of water to Earth via comets is inconsistent with their relatively elevated D/H ratios, whereas carbonaceous chondrites (CCs) have more terrestrial-like D/H ratios [1]. Of the eight groups into which the CCs are divided, only three (CI, CM, CR) show evidence of extensive aqueous alteration. Of these, the CMs form the single most important group, representing 34% of all CC falls and a similar percentage of finds (Met. Bull. Database). CM material also dominates the population of CC clasts in extraterrestrial samples [2, 3]. The Antarctic micrometeorites population is also dominated by CM and CI-like material and similar particles may have transported water and volatiles to the early Earth [4]. CCs, and CMs in particular, offer the best opportunity for investigating the evolution of water reservoirs in the early solar system. An important aspect of this problem involves identifying the anhydrous silicate component which co-accreted with ice in the CM parent body. A genetic relationship between the essentially anhydrous CO group and the CMs was proposed on the basis of oxygen isotope evidence [5]. However, previous CM whole-rock oxygen isotope data scattered about a line of approximately 0.5 that did not intersect the field of CO chondrites [5]. Here we discuss new oxygen isotope data which provides additional constraints on the relationship between CO and CM chondrites.

Greenwood, R. C.↗

New insights into creep characteristics of calcium silicate hydrates at molecular level

The fundamental mechanisms under concrete creep are far from being fully understood, especially at the molecular level. Hereby, a calcium-silicate-hydrate (C-S-H) molecular model is developed to explain, for the first time, the creep characteristics at various stress states, temperature levels and water contents, which are not accessible experimentally. Rather tensile and compressive loadings, C-S-H only creeps under shear loadings originating from the sliding of the calcium silicate layers over each other as the interlayer component (water and ions) acts as a lubricator. A heterogeneous creep characteristic is observed. Elevated temperature reduces the interlayer lubricator viscosity and weakens the interfacial adhesion between the layers and the interlayer lubricator, which accelerates C-S-H creep. The removal of interlayer water enhances the creep resistance, resulting from the reduced interlayer space and enhanced interfacial adhesion. The atomic-level mechanisms explain the inter-CSH-particle behaviours at the microscale, which bridges the gap between atomistic simulation and microcosmic phenomenon.

36 MATERIALS SCIENCE↗

ICESat Observations of Arctic Sea Ice: A First Look

Analysis of near-coincident ICESat and RADARSAT imagery shows that the retrieved elevations from the laser altimeter are sensitive to new openings (containing thin ice or open water) in the sea ice cover as well as to surface relief of old and first-year ice. The precision of the elevation estimates, measured over relatively flat sea ice, is approx. 2 cm Using the thickness of thin-ice in recent openings to estimate sea level references, we obtain the sea-ice free-board along the altimeter tracks. This step is necessitated by the large uncertainties in the time-varying sea surface topography compared to that required for accurate determination of free-board. Unknown snow depth introduces the largest uncertainty in the conversion of free-board to ice thickness. Surface roughness is also derived, for the first time, from the variability of successive elevation estimates along the altimeter track Overall, these ICESat measurements provide an unprecedented view of the Arctic Ocean ice cover at length scales at and above the spatial dimension of the altimeter footprint.

Kwok, Ron↗

ICESat Observations of Arctic Sea Ice: A First Look

Analysis of near-coincident ICESat and RADARSAT imagery shows that the retrieved elevations from the laser altimeter are sensitive to new openings (containing thin ice or open water) in the sea ice cover as well as to surface relief of old and first-year ice. The precision of the elevation estimates, measured over relatively flat sea ice, is approx. 2 cm. Using the thickness of thin-ice in recent openings to estimate sea level references, we obtain the sea-ice freeboard along the altimeter tracks. This step is necessitated by the large uncertainties in the sea surface topography compared to that required for accurate determination of freeboard. Unknown snow depth introduces the largest uncertainty in the conversion of freeboard to ice thickness. Surface roughness is also derived, for the first time, from the variability of successive elevation estimates along the altimeter track. Overall, these ICESat measurements provide an unprecedented view of the Arctic Ocean ice cover at length scales at and above the spatial dimension of the altimeter footprint of approx. 70 m.

Arctic Ocean↗

Atmospheric limitations to clock synchronization at microwave frequencies

Clock synchronization schemes utilizing microwave signals that pass through the Earth's atmosphere are ultimately limited by our ability to correct for the variable delay imposed by the atmosphere. The atmosphere is non-dispersive at microwave frequencies and imposes a delay of roughly 8 nanosec times the cosecant of the elevation angle. This delay is composed of two parts, the delay due to water vapor molecules (i.e., the wet delay), and the delay due to all other atmospheric constituents (i.e., the dry delay). Water vapor contributes approximately 5 to 10% of the total atmospheric delay but is highly variable, not well mixed, and difficult to estimate from surface air measurements. However, the techniques of passive remote sensing using microwave radiometry can be used to estimate the line of sight delay due to water vapor with potential accuracies of 10 to 20 picosec. The devices that are used are called water vapor radiometers and simply measure the power emitted by the water vapor molecule at the 22.2 GHz spectral line. An additional power measurement is usually included at 31.4 GHz in order to compensate for the effect of liquid water (e.g., clouds). The dry atmosphere is generally in something close to hydrostatic equilibrium and its delay contribution at zenith can be estimated quite well from a simple barometric measurement. At low elevation angles one must compensate for refractive bending and possible variations in the vertical refractivity profile. With care these effects can be estimated with accuracies on the order of 30 picosec down to elevation angles of 10 degree.

Resch, G. M.↗

A multidisciplinary study of earth resources imagery of Australia, Antarctica and Papua, New Guinea

The author has identified the following significant results. A thirteen category recognition map was prepared, showing forest, water, grassland, and exposed rock types. Preliminary assessment of classification accuracies showed that water, forest, meadow, and Niobrara shale were the most accurately mapped classes. Unsatisfactory results, were obtained in an attempt to discrimate sparse forest cover over different substrates. As base elevation varied from 7,000 to 13,000 ft, with an atmospheric visibility of 48 km, no changes in water and forest recognition were observed. Granodiorite recognition accuracy decreased monotonically as base elevation increased, even though the training set location was at 10,000 ft elevation. For snow varying in base elevation from 9400 to 8420 ft, recognition decreases from 99% at the 9400 ft training set elevation to 88% at 8420 ft. Calculations of expected radiance at the ERTS sensor from snow reflectance measured at the site and from Turner model calculations of irradiance, transmission and path radiance, reveal that snow signals should not be clipped, assuming that calculations and ERTS calibration constants were correct.

Fisher, N. H.↗

Renal Response to Chronic Centrifugation in Rats

Previously reported effects of chronic centrifugation on renal function in mammals are contradictory. The present study was conducted as an effort to provide a comprehensive analysis of renal response to chronic centrifugation (12 days at +2 Gz). Sixteen male Sprague-Dawley rats (210-230 g) were used: eight centrifuged (EC) and eight off centrifuge controls (OCC). During centrifugation EC had lower body weight and food consumption. EC showed a decrease (72%) in water intake for the first two days (T1 and T2) followed by significant increases from T4-T6. EC urine output increased two-fold over the first four days, returning to baseline by T9. EC urea excretion was elevated on T3 through T5. Creatinine, Na(+), K(+), and osmolar excretion were lower than OCC over the last four days of the study. Assuming constant plasma osmolarity and creatinine levels, EC free water clearance (C(sub H2O)) was elevated significantly on T4 when the peak urine output was exhibited. EC also had a greater C(sub H2O) over the last four days, associated with a significantly lower osmolar clearance and GFR. The initial diuresis exhibited during centrifugation can be attributed to a reduced water resorption and increased urea excretion. This diuresis was mediated independent of changes in GFR over the first eight days. However, differences in excretion seen after eight days of centrifugation are probably GFR mediated which would imply animals established a new homeostatic setpoint by that time. Centrifugation elicites an acute alteration in fluid homeostasis followed by adaptation within a week.

Ortiz, Rudy M.↗