Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “visible spectrum”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Highlights from Three Years of the Chandra X-Ray Observatory

August 12, 2002 marked the third anniversary of the first light observed with the Chandra X-Ray Observatory (CXO) which had been launched on July 23 of that same year. The CXO is the X-ray component of NASA's Great Observatory Program that also includes the Hubble Space Telescope for observations in the visible portion of the electromagnetic spectrum, the now defunct Compton Gamma-Ray Observatory and the soon-to-be-launched Space Infra-Red Telescope Facility. The scientific return from the Observatory has been spectacular. Images of objects as local as the moon's of Jupiter and comets, to those which show the details of the emission of the hot gas pervading clusters of galaxies have been obtained. The technical status of the instrumentation and the performance of the X-ray optics will be reviewed and an overview of some of the exciting results will be presented.

Weisskopf, Martin C.↗
NASA NTRS2006

Radiometric Characterization Results for the IKONOS, Quickbird, and OrbView-3 Sensor

Radiometric calibration of commercial imaging satellite products is required to ensure that science and application communities better understand commercial imaging satellite properties. Inaccurate radiometric calibrations can lead to erroneous decisions and invalid conclusions and can limit intercomparisons with other systems. To address this calibration need, the NASA Applied Sciences Directorate (ASD) at Stennis Space Center established a commercial satellite imaging radiometric calibration team consisting of three independent groups: NASA ASD, the University of Arizona Remote Sensing Group, and South Dakota State University. Each group independently determined the absolute radiometric calibration coefficients of available high-spatial-resolution commercial 4-band multispectral products, in the visible though near-infrared spectrum, from GeoEye(tradeMark) (formerly SpaceImaging(Registered TradeMark)) IKONOS, DigitalGlobe(Regitered TradeMark) QuickBird, and GeoEye (formerly ORBIMAGE(Registered TradeMark) OrbView. Each team member employed some variant of reflectance-based vicarious calibration approach, requiring ground-based measurements coincident with image acquisitions and radiative transfer calculations. Several study sites throughout the United States that covered a significant portion of the sensor's dynamic range were employed. Satellite at-sensor radiance values were compared to those estimated by each independent team member to evaluate the sensor's radiometric accuracy. The combined results of this evaluation provide the user community with an independent assessment of these sensors' absolute calibration values.

Holekamp, Kara↗
NASA NTRS2010

Highlights from 40 Years of Satellite UV Measurements

This year we are celebrating the 40th anniversary of the launch of the Backscatter Ultraviolet (BUV) instrument on NASA's Nimbus-4 satellite. The purpose of this instrument was to demonstrate the capability to measure total column ozone and its vertical distribution from space. The success of this instrument led to about a dozen instruments of this type on various NASA and NOAA satellites. These instruments used a single photomultiplier tube (PMT) that restricted the measurements to 6-12 discrete wavelengths in the 250-380 nm range. With the availability of solid-state detector arrays in the past decade it has been possible to make similar measurements but with hyperspectral (contiguous in wavelength) sampling and enhanced spectral resolution. This has allowed global mapping of several weakly-absorbing trace gases including S0 2, NO2, BrO, HCHO, and CIIOCHO. Since these measurements are affected by clouds and aerosols, a great deal of effort has gone into understanding their effect on ultraviolet radiation- both upwelling and downwelling. The downwelling UV radiation is chemically and biologically active and has both negative (genetic damage, air pollution) and positive (production of vitamin D and OH radical) environmental effects. I will discuss how the interaction of Rayleigh-scattered UV radiation with clouds and aerosols produce a variety of interesting effects that are leading to new methods of remote sensing of their properties. The UV measurements can greatly enhance the information that one derives from more traditional methods that use infrared and visible part of the solar spectrum.

Bhartia, Pawan K.↗
NASA NTRS2011

Initiating Molecular Growth in the Interstellar Medium via Dimeric Complexes of Observed Ions and Molecules

A feasible initiation step for particle growth in the interstellar medium (ISM) is simulated by means of ab quantum chemistry methods. The systems studied are dimer ions formed by pairing nitrogen containing small molecules known to exist in the ISM with ions of unsaturated hydrocarbons or vice versa. Complexation energies, structures of ensuing complexes and electronic excitation spectra of the encounter complexes are estimated using various quantum chemistry methods. Moller-Plesset perturbation theory (MP2, Z-averaged perturbation theory (ZAP2), coupled cluster singles and doubles with perturbative triples corrections (CCSD(T)), and density functional theory (DFT) methods (B3LYP) were employed along with the correlation consistent cc-pVTZ and aug-cc-pVTZ basis sets. Two types of complexes are predicted. One type of complex has electrostatic binding with moderate (7-20 kcal per mol) binding energies, that are nonetheless significantly stronger than typical van der Waals interactions between molecules of this size. The other type of complex develops strong covalent bonds between the fragments. Cyclic isomers of the nitrogen containing complexes are produced very easily by ion-molecule reactions. Some of these complexes show intense ultraviolet visible spectra for electronic transitions with large oscillator strengths at the B3LYP, omegaB97, and equations of motion coupled cluster (EOM-CCSD) levels. The open shell nitrogen containing carbonaceous complexes especially exhibit a large oscillator strength electronic transition in the visible region of the electromagnetic spectrum.

Bera, Partha P.↗
NASA NTRS2014

High-Speed Imaging Optical Pyrometry for Study of Boron Nitride Nanotube Generation

A high-speed imaging optical pyrometry system is designed for making in-situ measurements of boron temperature during the boron nitride nanotube synthesis process. Spectrometer measurements show molten boron emission to be essentially graybody in nature, lacking spectral emission fine structure over the visible range of the electromagnetic spectrum. Camera calibration experiments are performed and compared with theoretical calculations to quantitatively establish the relationship between observed signal intensity and temperature. The one-color pyrometry technique described herein involves measuring temperature based upon the absolute signal intensity observed through a narrowband spectral filter, while the two-color technique uses the ratio of the signals through two spectrally separated filters. The present study calibrated both the one- and two-color techniques at temperatures between 1,173 K and 1,591 K using a pco.dimax HD CMOS-based camera along with three such filters having transmission peaks near 550 nm, 632.8 nm, and 800 nm.

Inman, Jennifer A.↗
NASA NTRS2016

Radiative Characteristics of Clouds Embedded in Smoke Derived from Airborne Multiangular Measurements

Clouds in the presence of absorbing aerosols result in their apparent darkening, observed at the top of atmosphere (TOA), which is associated with the radiative effects of aerosol absorption. Owing to the large radiative effect and potential impacts on regional climate, above-cloud aerosols have recently been characterized in multiple satellite-based studies. While satellite data are particularly useful in showing the radiative impact of above-cloud aerosols at the TOA, recent literature indicates large uncertainties in satellite retrievals of above-cloud aerosol optical depth (AOD) and single scattering albedo (SSA), which are among the most important parameters in the assessment of associated radiative effects. In this study, we analyze radiative characteristics of clouds in the presence of wildfire smoke using airborne data primarily from NASA's Cloud Absorption Radiometer, collected during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites campaign in Canada during the 2008 summer season. We found a strong positive reflectance (R) gradient in the UV-visible (VIS)-near infrared (NIR) spectrum for clouds embedded in dense smoke, as opposed to an (expected) negative gradient for cloud-free smoke and a flat spectrum for smoke-free cloud cover. Several cases of clouds embedded in thick smoke were found, when the aircraft made circular/spiral measurements, which not only allowed the complete characterization of angular distribution of smoke scattering but also provided the vertical distribution of smoke and clouds (within 0.5-5 km). Specifically, the largest darkening by smoke was found in the UV/VIS, with R(sub 0.34 microns) reducing to 0.2 (or 20%), in contrast to 0.8 at NIR wavelengths (e.g., 1.27 microns). The observed darkening is associated with large AODs (0.5-3.0) and moderately low SSA (0.85-0.93 at 0.53 microns), resulting in a significantly large instantaneous aerosol forcing efficiency of 254 +/- 47 W/sq m/τ. Our observations of smoke-cloud radiative interactions were found to be physically consistent with theoretical plane-parallel 1-D and Monte Carlo 3-D radiative transfer calculations, capturing the observed gradient across UV-VIS-NIR. Results from this study offer insights into aerosol-cloud radiative interactions and may help in better constraining satellite retrieval algorithms.

absorbing aerosols↗
NASA NTRS2018

PACE Technical Report Series, Volume 7: Ocean Color Instrument (OCI) Concept Design Studies

Extending OCI hyperspectral radiance measurements in the ultraviolet to 320 nm on the blue spectrograph enables quantitation of atmospheric total column ozone (O3) for use in ocean color atmospheric correction algorithms. The strong absorption by atmospheric ozone below 340 nm enables the quantification of total column ozone. Other applications are possible but were not investigated due to their exploratory nature and lower priority.The first step in the atmospheric correction processing, which converts top-of-the-atmosphere radiances to water-leaving radiances, is removal of the absorbance by atmospheric trace gases such as water vapor, oxygen, ozone and nitrogen dioxide. Details of the atmospheric correction process currently used by the Ocean Biology Processing Group (OBPG) and will be employed for PACE with appropriate modifications, are described by Mobley et al. [2016]. Atmospheric ozone absorbs within the visible to near-infrared spectrum between ~450 nm and 800nm and most appreciably between 530 nm and 650 nm, a spectral region critical for maintaining NASA's chlorophyll-a climate data record and for PACE algorithms planned to characterize phytoplankton community composition and other ocean color products.While satellite-based observations will likely be available during PACE's mission lifetime, the difference in acquisition time with PACE, the coarseness in their spatial resolution, and differences in viewing geometries will introduce significant levels of uncertainties in PACE ocean color data products.

Cetinic, Ivona↗
NASA NTRS2019

Next-Generation Optical Sensing Technologies for Exploring Ocean Worlds - NASA FluidCam, MiDAR, and NeMO-Net

We highlight three emerging NASA optical technologies that enhance our ability to remotely sense, analyze, and explore ocean worlds–FluidCam and fluid lensing, MiDAR, and NeMO-Net. Fluid lensing is the first remote sensing technology capable of imaging through ocean waves without distortions in 3D at sub-cm resolutions. Fluid lensing and the purpose-built FluidCam CubeSat instruments have been used to provide refraction-corrected 3D multispectral imagery of shallow marine systems from unmanned aerial vehicles (UAVs). Results from repeat 2013 and 2016 airborne fluid lensing campaigns over coral reefs in American Samoa present a promising new tool for monitoring fine-scale ecological dynamics in shallow aquatic systems tens of square kilometers in area. MiDAR is a recently-patented active multispectral remote sensing and optical communications instrument which evolved from FluidCam. MiDAR is being tested on UAVs and autonomous underwater vehicles (AUVs) to remotely sense living and non-living structures in light-limited and analog planetary science environments. MiDAR illuminates targets with high-intensity narrowband structured optical radiation to measure an object’s spectral reflectance while simultaneously transmitting data. MiDAR is capable of remotely sensing reflectance at fine spatial and temporal scales, with a signal-to-noise ratio 10-10(exp 3) times higher than passive airborne and spaceborne remote sensing systems, enabling high-framerate multispectral sensing across the ultraviolet, visible, and near-infrared spectrum. Preliminary results from a 2018 mission to Guam show encouraging applications of MiDAR to imaging coral from airborne and underwater platforms whilst transmitting data across the air-water interface. Finally, we share NeMO-Net, the Neural Multi-Modal Observation & Training Network for Global Coral Reef Assessment. NeMO-Net is a machine learning technology under development that exploits high-resolution data from FluidCam and MiDAR for augmentation of low-resolution airborne and satellite remote sensing. NeMO-Net is intended to harmonize the growing diversity of 2D and 3D remote sensing with in situ data into a single open-source platform for assessing shallow marine ecosystems globally using active learning for citizen-science based training. Preliminary results from four-class Q17 coral classification have an accuracy of 94.4%. Together, these maturing technologies present promising scalable, practical, and cost-efficient innovations that address current observational and technological challenges in optical sensing of marine systems.

Ved Chirayath↗
NASA NTRSDate not supplied

Black-silicon as a Wideband Infrared Absorber for the Space Instruments: Fabrication, Modeling, and Characterization

The uniform black silicon (BSI) cryogenically etched has been demonstrated as a superior absorber in par with other ultra-absorbers such as carbon nano tubes in the visible and near-infrared spectrum. In this work, we discuss the fabrication, modeling, and characterization of the BSI aiming at the 2.5-5 microns range. We investigated a series of cryogenic parameters such as temperature, pressure, oxygen flowrate, power, and etching duration and fabricated a series of uniformly etched wafers. Additionally, we established at hree-dimensional mathematical model of a unit cell and manipulated the silicon needle geometry and shape. Our preliminary fabrication results show silicon needles of 8 micron height have five orders of magnitude specular reflectance in the infrared region. The modeling efforts how longer pillar heights could be better absorbers as the wavelength increases.

Wideband absorber↗
DOE OSTI2024

Multi-coat polymer photonic crystal films

Polymer composite photonic crystal materials are disclosed as coatings and topcoats which have high reflection (>30%) in a specific range of the electromagnetic spectrum, such as ultraviolet (<400 nm), visible (Vis, 400 nm-700 nm), or near-infrared radiation range (NIR, 700-2000 nm), and relatively low reflection (<20% reflection) in a second, different range of the electromagnetic spectrum. Surprisingly, it was found that through a formulation and additives approach, the optical properties of polymer composite photonic crystal films can be selectively modified from a variety of different coating methods, including spray deposition.

Pearson, Ryan Michael↗
NASA NTRS1981

Observations of strong ultraviolet absorptions in the spectrum of the DC white dwarf LDS 678 B

Evidence from spectroscopic observations that LDS 678 B has strong ultraviolet lines of neutral carbon in its spectrum is presented. The spectra are found to contain strong lines of C I in the ultraviolet and weak He I lines in the visible. The appearance of the star's spectrum and published photometry are consistent with its having an effective temperature near 10,600 K with a helium-dominated atmosphere and a carbon abundance lower than C:He = 0.001. The star's spectra are compared with those of the white dwarfs L879-14 and L145-141, which are cooler than LDS 678B, have C2 bands in the visible and also show strong evidence of strong ultraviolet C I lines. It is concluded that LDS 678 B has a temperature intermediate between the DB and C2 band white dwarfs and that the ultraviolet C I lines can be a useful means for finding carbon in the atmosphere of the cooler white dwarfs.

Wegner, G.↗
NASA NTRS1990

Evidence for an inner scale to the density turbulence in the interstellar medium

The form of the density power spectrum is studied. The relationship between the visibility and the properties of density turbulence is discussed. Observational determinations of the power-law index of the interstellar density power spectrum are presented. An inner scale is derived, and the effect of an inner scale in the interstellar plasma turbulence is examined. It is concluded that the host plasma for the density irregularities must be similar to the warm ionized medium in the Mckee-Ostriker model (1979) of the interstellar medium or the low-density envelopes of H II regions.

Spangler, Steven R.↗
DOE OSTI2020

Homogeneous broadening in the spectrum of a broadband erbium-doped fibre light source

Interference of wave trains separated out in an inhomogeneous emission spectrum of a superluminescent erbium-doped fibre source has been studied by scanning the wavelength of a spectrum analyser. The results demonstrate that, as the spectral resolution of the spectrum analyser decreases to a level corresponding to a sharp drop in interference fringe visibility relative to its original level, near 100 %, fringe visibility becomes dependent on the wavelength in the inhomogeneous spectrum of the source. The reason for this is that, at some characteristic resolution δλ (δλ > 0.5 nm in our case), the coherence time of wave trains is not limited by the spectral resolution of the spectrum analyser and is related to the inhomogeneous spectrum of the source, whose limiting width can be thought of as the homogeneous linewidth in the spectrum of the source. This feature can be used for evaluating homogeneous line broadening. (paper)

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

Visible-Light Photoinitiation of (Meth)acrylate Polymerization with Autonomous Post-Conversion

Conversion plateaus rapidly in radical photopolymerizations (RPPs) following discontinuation of irradiation due to rapid termination of reactive radicals, which restricts the wider use of RPPs in applications that involve nonuniform light access including those with attenuated light transmission or irregular surfaces. Based on our recent report of a radical dark-curing photoinitiator (DCPI) that continues polymerization beyond the cessation of irradiation by enabling latent redox initiation with photo-released amine in the presence of a suitable oxidant, we developed a new DCPI with an absorption spectrum that extends well into the visible range. Our design process involved a series of computational investigations of candidate molecules, including a systematic study of substituents and their position-dependent effects on absorption characteristics, electronic transitions, and the photochemical mechanism and its associated energetics. Our quantum chemical computations identified the target compound 5,7-dimethoxy-6-bromo-3-aroylcoumarin-DMPT/BPh4 and predicted that it would facilitate the dark-curing mechanism by concurrent photo-radical generation and photo-induced release of an efficient redox reductant under visible irradiation. This reductant-tethered chromophore was then synthesized and optically characterized with UV–vis spectroscopy that revealed its strong visible-light absorption with a molar absorptivity of 5710 M–1 cm–1 at 405 nm and 50 M–1 cm–1 at 455 nm. We then demonstrated extensive dark-curing of >35% additional conversion over 25 min following brief activation of the shelf-stable one-part system by irradiation with a 455 nm LED that was ceased at 20% conversion. In contrast, shuttering irradiation of the control formulation at that same point resulted in immediate cessation of conversion, which plateaued at 20%. We determined a remarkable initiator efficiency of 2.82 that results from the additional redox-generated radicals with a 77% photo-reductant generation quantum yield. The combination of superior photo- and dark-curing efficiencies of this new visible DCPI is expected to open new application opportunities in RPP, especially those involving resins that are highly light attenuating, surfaces that possess irregular features that produce uneven irradiance, and production lines where continued dark-curing downstream of the light activation step enhances line efficiencies.

absorption spectrum↗
NASA NTRS2003

Vesta's UV Lightcurve: Hemispheric Variation in Brightness and Spectral Reversal

Spectra of asteroid 4 Vesta obtained in October 1990 with the International Ultraviolet Explorer are reanalyzed and reinterpreted. A large portion of the eastern hemisphere (based on the prime meridian definition of Thomas et al., 1997a) is darker at UV Wavelengths than much of the western hemisphere. The UV lightcurve is in contrast with the visible lightcurve, which shows that the eastern hemisphere is brighter than the western. These IUE spectra of Vesta thus may be evidence for the "spectral reversal." first seen on the Moon by Apollo 17. where the visibly brighter lunar highlands are darker than the maria at far-UV wavelengths. This effect was linked to space weathering when it was noted (Wagner et al., 1987) that the spectral reversal appears in the laboratory spectra of lunar soils but not powdered lunar rocks. We investigate Vesta's UV lightcurve and spectral reversal, and its possible connection with space weathering. The addition to grain coatings of small amounts of submicroscopic iron (SMFe) through vapor deposition causes drastic spectral changes at UV-visible wavelengths (Hapke, 2001). while the longer wavelength spectrum remains largely unaffected. Other laboratory results (e.g., Hiroi and Pieters, 1998) indicate that the UV-visible wavelength range is affected by simulated weathering processes in a manner similar to what is seen on Vesta. It is likely that Vesta has experienced relatively minor amounts of space weathering, as indicated by the spectral reversal, along with the subtle visible-near infrared weathering effects (e.g., Binzel et al., 1997).

Hendrix, Amanda R.↗
NASA NTRS1991

Gamma Ray Observatory (GRO) Prelaunch Mission Operations Report (MOR)

The NASA Astrophysics Program is an endeavor to understand the origin and fate of the universe, to understand the birth and evolution of the large variety of objects in the universe, from the most benign to the most violent, and to probe the fundamental laws of physics by examining their behavior under extreme physical conditions. These goals are pursued by means of observations across the entire electromagnetic spectrum, and through theoretical interpretation of radiations and fields associated with astrophysical systems. Astrophysics orbital flight programs are structured under one of two operational objectives: (1) the establishment of long duration Great Observatories for viewing the universe in four major wavelength regions of the electromagnetic spectrum (radio/infrared/submillimeter, visible/ultraviolet, X-ray, and gamma ray), and (2) obtaining crucial bridging and supporting measurements via missions with directed objectives of intermediate or small scope conducted within the Explorer and Spacelab programs. Under (1) in this context, the Gamma Ray Observatory (GRO) is one of NASA's four Great Observatories. The other three are the Hubble Space Telescope (HST) for the visible and ultraviolet portion of the spectrum, the Advanced X-ray Astrophysics Facility (AXAF) for the X-ray band, and the Space Infrared Telescope Facility (SIRTF) for infrared wavelengths. GRO's specific mission is to study the sources and astrophysical processes that produce the highest energy electromagnetic radiation from the cosmos. The fundamental physical processes that are known to produce gamma radiation in the universe include nuclear reactions, electron bremsstrahlung, matter-antimatter annihilation, elementary particle production and decay, Compton scattering, synchrotron radiation. GRO will address a variety of questions relevant to understanding the universe, such as: the formation of the elements; the structure and dynamics of the Galaxy; the nature of pulsars; the existence of black holes; the possible existence of large amounts of antimatter, energetic and explosive phenomena occurring in galactic nuclei; the origin of the cosmic diffuse background; particle acceleration in the Sun, stars and stellar systems; processes in supernovae; and the origin and evolution of the universe itself.

Source record↗
NASA NTRS1982

Airborne multispectral linear array instruments at Goddard Space Flight Center

The fabrication of airborne instruments is contributing to the development of multispectral linear array technology at NASA's Goddard Space Flight Center. The linear array pushbroom radiometer (LAPR-I), was built to demonstrate capabilities for acquiring digital image data using linear arrays. The LAPR-I employed three arrays of 512 silicon photodiodes each to simultaneously acquire three channels of data for spectral bands within the visible and near-infrared portions of the spectrum. A second instrument, LAPR-II, uses four arrays each consisting of 512 silicon detectors. A filter wheel containing six spectral filters is used in conjunction with each array to allow filter changes in flight. This capability will facilitate studies into the utility of various bands within the visible and near infrared portions of the spectrum. The LAPR-II's aircraft mounting will allow off-nadir pointing (plus-or-minus 50 deg fore-and-aft and side-to-side) which will enable investigations of the radiometric and geometric effects of off-nadir viewing. A short wave infrared radiometer is also described.

Irons, J. R.↗