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At least 451 records · Page 25

Atmospheric windows for HF laser radiation between 2.7 and 3.2 microns.

A high resolution computer model study of the atmospheric transmittance in the 2.7 to 3.2 micron region of the spectrum is described, whose purpose was to identify atmospheric windows for the HF laser wavelengths available in this region. Three HF lines corresponding to the transitions P(12), 1 to 0, P(6), 3 to 2, and P(4), 5 to 4 are identified as having transmittances of 0.70 or greater over a 1-km sea level path.

Seals, R. K., Jr.↗

Research to Significantly Enhance Composite Survivability at 550 F in Oxidative Environments

Prairie View A&M University using the NASA FAR grant has embarked on several paths to accomplish the initial goals of: (1) synthesizing three ring aromatic diamines to be used as monomers in the synthesis of polyamide resins; and (2) study hydrothermal aging behaviors and glass transition changes of composites synthesized at NASA Glenn Research Center. In establishing the synthesis of the three ring aromatic diamine, it has become necessary to conduct preliminary synthesis to include the nitration of diphenylmethane. The concentration and temperature were altered to assess the effect of purity of isomeric product distribution in such electrophilic aromatic substitution reaction. Products were analyzed using H and C-NMR, Thin Layer Chromatography, High Pressure Liquid Chromatography and GC-Mass Spectrometry (in progress). Results indicate that by varying the concentration of the reaction, a mixture of products can be obtained. Other electrophilic aromatic substitution reactions are also in progress such as Friedel-Craft acylation reaction using diphenylmethane with 4-nitrobenzoyl chloride to afford other diamine products. Furthermore, PVAMU has nearly completed the hydrothermal studies to assess the oxidative stability of DSP443B and DSP442A panels formulated at NASA Glenn Research Center.

Byrd, Jim↗

5,120 Superconducting Bolometers for the PIPER Balloon-Borne CMB Polarization Experiment

We are constructing the Primordial Inflation Polarization Explorer (PIPER) to measure the polarization of the cosmic microwave background (CMB) and search for the imprint of gravity waves produced during an inflationary epoch in the early universe. The signal is faint and lies behind confusing foregrounds, both astrophysical and cosmological, and so many detectors are required to complete the measurement in a limited time. We will use four of our matured 1,280 pixel, high-filling-factor backshort-under-grid bolometer arrays for efficient operation at the PIPER CMB wavelengths. All four arrays observe at a common wavelength set by passband filters in the optical path. PIPER will fly four times to observe at wavelengths of 1500, 1100, 850, and 500 microns in order to separate CMB from foreground emission. The arrays employ leg-isolated superconducting transition edge sensor bolometers operated at 145 mK; tuned resonant backshorts for efficient optical coupling; and a second-generation superconducting quantum interference device multiplexer readout. We describe the design, development, and performance of PIPER bolometer array technology to achieve background-limited sensitivity for a cryogenic balloon-borne telescope.

Benford, Dominic J.↗

5,120 Superconducting Bolometers for the PIPER Balloon-Borne CMB Polarization Experiment

We are constructing the Primordial Inflation Polarization Explorer (PIPER) to measure the polarization o[ the cosmic microwave background (CMB) and search for the imprint of gravity waves produced during an inflationary epoch in the early universe. The signal is faint and lies behind confusing foregrounds, both astrophysical and cosmological, and so many detectors are required to complete the measurement in a limited time. We will use four of our matured 1,280 pixel, high-filling-factor backshort-under-grid bolometer arrays for efficient operation at the PIPER CMB wavelengths. All four arrays observe at a common wavelength set by passband filters in the optical path. PIPER will fly four times to observe at wavelengths of 1500, 1100, 850, and 500 microns in order to separate CMB from foreground emission. The arrays employ leg-isolated superconducting transition edge sensor bolometers operated at 128mK; tuned resonant backshorts for efficient optical coupling; and a second-generation superconducting quantum interference device (SQUID) multiplexer readout. We describe the design, development, and performance of PIPER bo|ometer array technology to achieve background-limited sensitivity for a cryogenic balloon-borne telescope.

Benford, Dominic J.↗

Highly Conductive Multifunctional Graphene Polycarbonate Nanocomposites

Graphene nanosheet bisphenol A polycarbonate nanocomposites (0.027 2.2 vol %) prepared by both emulsion mixing and solution blending methods, followed by compression molding at 287 C, exhibited dc electrical percolation threshold of approx.0.14 and approx.0.38 vol %, respectively. The conductivities of 2.2 vol % graphene nanocomposites were 0.512 and 0.226 S/cm for emulsion and solution mixing. The 1.1 and 2.2 vol % graphene nanocomposites exhibited frequency-independent behavior. Inherent conductivity, extremely high aspect ratio, and nanostructure directed assembly of the graphene using PC nanospheres are the main factors for excellent electrical properties of the nanocomposites. Dynamic tensile moduli of nanocomposites increased with increasing graphene in the nanocomposite. The glass transition temperatures were decreased with increasing graphene for the emulsion series. High-resolution electron microscopy (HR-TEM) and small-angle neutron scattering (SANS) showed isolated graphene with no connectivity path for insulating nanocomposites and connected nanoparticles for the conductive nanocomposites. A stacked disk model was used to obtain the average particle radius, average number of graphene layers per stack, and stack spacing by simulation of the experimental SANS data. Morphology studies indicated the presence of well-dispersed graphene and small graphene stacking with infusion of polycarbonate within the stacks.

Yoonessi, Mitra↗

Unmanned Aircraft System Traffic Management (UTM) Research Transition Team (RTT) Concept Working Group - Concept & Use Cases Package #2 Addendum: Technical Capability Level 3

This document is a product of the joint NASA and FAA Research Transition Team's (RTT) Concept Working Group (CWG) as part of the UAS Traffic Management (UTM) project. The scope of the document covers Technical Capability Level (TCL) 3 of the UTM research path and presents the 1) Terms and Definitions, 2) Foundational Principles, 3) Concept Narratives, 4) Use Cases, 5) Operational Views (OVs), and 6) Roles and Responsibilities of actors interacting within a TCL3 environment. The document includes additional use cases to accompany the RTT CWG Package #2 document.

UTM↗

Do Ionic Liquids Slow Down in Stages?

High impact recent articles have reported on the existence of a liquid–liquid (L–L) phase transition as a function of both pressure and temperature in ionic liquids (ILs) containing the popular trihexyltetradecylphosphonium cation (P 666,14 + ), sometimes referred to as the “universal liquifier”. The work presented here reports on the structural-dynamic pathway from liquid to glass of the most well-studied IL comprising the P 666,14 + cation. We present experimental and computational evidence that, on cooling, the path from the room-temperature liquid to the glass state is one of separate structural-dynamic changes. The first stage involves the slowdown of the charge network, while the apolar subcomponent is fully mobile. A second, separate stage entails the slowdown of the apolar domain. Whereas it is possible that these processes may be related to the liquid–liquid and glass transitions, more research is needed to establish this conclusively.

36 MATERIALS SCIENCE↗

Ring-Opening Dynamics of the Cyclopropyl Radical and Cation: the Transition State Nature of the Cyclopropyl Cation

Here, we provide compelling experimental and theoretical evidence for the transition state nature of the cyclopropyl cation. Synchrotron photoionization spectroscopy employing coincidence techniques together with a novel simulation based on high-accuracy ab initio calculations reveal that the cation is unstable via its allowed disrotatory ring-opening path. The ring strains of the cation and the radical are similar, but both ring opening paths for the radical are forbidden when the full electronic symmetries are considered. These findings are discussed in light of the early predictions by Longuet-Higgins alongside Woodward and Hoffman; we also propose a simple phase space explanation for the appearance of the cyclopropyl photoionization spectrum. The results of this work allow the refinement of the cyclopropane C–H bond dissociation energy, in addition to the cyclopropyl radical and cation cyclization energies, via the Active Thermochemical Tables approach.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Numerical Studies of Properties of Confined Helium

We carry out state of the art simulations of properties of confined liquid helium near the superfluid transition to a degree of accuracy which allows to make predictions for the outcome of fundamental physics experiments in microgravity. First we report our results for the finite-size scaling behavior of heat capacity of superfluids for cubic and parallel-plate geometry. This allows us to study the crossover from zero and two dimensions to three dimensions. Our calculated scaling functions are in good agreement with recently measured specific heat scaling functions for the above mentioned geometries. We also present our results of a quantum simulation of submonolayer of molecular hydrogen deposited on an ideal graphite substrate using path-integral quantum Monte Carlo simulation. We find that the monolayer phase diagram is rich and very similar to that of helium monolayer. We are able to uncover the main features of the complex monolayer phase diagram, such as the commensurate solid phases and the commensurate to incommensurate transition, in agreement with the experiments and to find some features which are missing from the experimental analysis.

Manousakis, Efstratios↗

Many-Body Majorana Braiding without an Exponential Hilbert Space

Qubits built out of Majorana zero modes constitute the primary path toward topologically protected quantum computing. Simulating the braiding process of multiple Majorana zero modes corresponds to the quantum dynamics of a superconducting many-body system. It is crucial to study the Majorana dynamics both in the presence of all other quasiparticles and for reasonably large system sizes. We present a method to calculate arbitrary many-body wave functions as well as their expectation values, correlators, and overlaps from time evolved single-particle states of a superconductor, allowing for significantly larger system sizes. We calculate the fidelity, transition probabilities, and joint parities of Majorana pairs to track the quality of the braiding process. Here, we show how the braiding success depends on the speed of the braid. Moreover, we demonstrate the topological CNOT two-qubit gate as an example of two-qubit entanglement. Our Letter opens the path to test and analyze the many theoretical implementations of Majorana qubits. Moreover, this method can be used to study the dynamics of any noninteracting superconductor.

Majorana bound states↗

Requirements Description of the REBUS Software for the Versatile Test Reactor

This report presents the modeling and simulation capabilities of Argonne National Laboratory’s fuel cycle analysis code, the REactor BUrnup System (REBUS), that will be relied on for the VTR project. These capabilities will then be used to establish the set of REBUS verification tasks necessary to verify REBUS for usage on the VTR project. A similar path was followed for the DIF3D software where its’ requirements and verification tasks were established. REBUS has been maintained by Argonne since the early 1960s to support its reactor design mission. That software transitioned from the original REBUS to REBUS-2 in the mid 1970s and to REBUS-3 in the mid 1980s. Since then REBUS has gone through many revisions to the current REBUS-11. Note that this version numbering is consistent with the progression of DIF3D, the base flux solver that REBUS is built upon. The name REBUS refers to a pictorial based puzzle as the original developers were inspired by having to track thousands of unique fuel assemblies as they are inserted into the reactor, depleted, shuffled, discharged, and reprocessed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Residual stress and microstructure in IN718-René41 graded superalloy fabricated by laser blown directed energy deposition

Additively printed Ni-based superalloy with a compositionally graded transition from IN718 to René41 was fabricated by laser blown-powder directed energy deposition (DED/LB-M), with the goals of meeting location-specific temperature capability and reducing component cost for hot gas path turbine components. Residual stress distribution in thin wall specimens with three sets of DED build parameters in the as-built and stress-relieved states was measured by neutron diffraction. For calculating residual stress, the calculated d0 method was found to be more appropriate as stress-free reference than using the lattice spacing measured from the stress-relief heat treated specimens. Longer dwell time (lower interpass temperature), higher energy input, smaller layer thickness resulted in a higher magnitude of tensile residual stresses at edges and compressive residual stresses at center of the specimens. The residual stress results did not show a strong dependence on graded compositions, indicating that the residual stress build-up was more geometry and process dependent. Non-destructive neutron imaging based on the attenuation coefficient qualitatively visualized the compositional variation in the bulk and showed good agreement with quantitative Electron Probe Micro-Analysis (EPMA) measurement. Grain structure, texture, and residual plastic strain along the build direction were characterized by Electron Backscatter Diffraction (EBSD). Long columnar grains with (001) preferred grain orientation were dominant along the build direction. Compositional change did not show an obvious effect on the epitaxial growth of dendrites and the continuation of the columnar grains. Residual plastic strain was relatively low in the as-built specimens.

36 MATERIALS SCIENCE↗

An evaluation of flight path formats head-up and head-down

Flight path primary flight display formats were incorporated on head-up and head-down electronic displays and integrated into an Advanced Concepts Flight Simulator. Objective and subjective data were collected while ten airline pilots evaluated the formats by flying an approach and landing task under various ceiling, visibility and wind conditions. Deviations from referenced/commanded airspeed, horizontal track, vertical track and touchdown point were smaller using the head-up display (HUD) format than the head-down display (HDD) format, but not significantly smaller. Subjectively, the pilots overwhelmingly preferred (1) flight path formats over attitude formats used in current aircraft, and (2) the head-up presentation over the head-down, primarily because it eliminated the head-down to head-up transition during low visibility landing approaches. This report describes the simulator, the flight displays, the format evaluation, and the results of the objective and subjective data.

Sexton, George A.↗

Communications system evolutionary scenarios for Martian SEI support

In the Space Exploration Initiative (SEI) mission scenarios, expanding human presence is the primary driver for high data rate Mars-Earth communications. To support an expanding human presence, the data rate requirement will be gradual, following the phased implementation over time of the evolving SEI mission. Similarly, the growth and evolution of the space communications infrastructure to serve this requirement will also be gradual to efficiently exploit the useful life of the installed communications infrastructure and to ensure backward compatibility with long-term users. In work conducted over the past year, a number of alternatives for supporting high data rate Mars-Earth communications have been analyzed with respect to their compatibility with gradual evolution of the space communications infrastructure. The alternatives include RF, millimeter wave (MMW), and optical implementations, and incorporate both surface and space-based relay terminals in the Mars and Earth regions. Each alternative is evaluated with respect to its ability to efficiently meet a projected growth in data rate over time, its technology readiness, and its capability to satisfy the key conditions and constraints imposed by evolutionary transition. As a result of this analysis, a set of attractive alternative communications architectures have been identified and described, and a road map is developed that illustrates the most rational and beneficial evolutionary paths for the communications infrastructure.

Kwong, Paulman W.↗

America's Next Great Ship: Space Launch System Core Stage Transitioning from Design to Manufacturing

The Space Launch System (SLS) Program is essential to achieving the Nation's and NASA's goal of human exploration and scientific investigation of the solar system. As a multi-element program with emphasis on safety, affordability, and sustainability, SLS is becoming America's next great ship of exploration. The SLS Core Stage includes avionics, main propulsion system, pressure vessels, thrust vector control, and structures. Boeing manufactures and assembles the SLS core stage at the Michoud Assembly Facility (MAF) in New Orleans, LA, a historical production center for Saturn V and Space Shuttle programs. As the transition from design to manufacturing progresses, the importance of a well-executed manufacturing, assembly, and operation (MA&O) plan is crucial to meeting performance objectives. Boeing employs classic techniques such as critical path analysis and facility requirements definition as well as innovative approaches such as Constraint Based Scheduling (CBS) and Cirtical Chain Project Management (CCPM) theory to provide a comprehensive suite of project management tools to manage the health of the baseline plan on both a macro (overall project) and micro level (factory areas). These tools coordinate data from multiple business systems and provide a robust network to support Material & Capacity Requirements Planning (MRP/CRP) and priorities. Coupled with these tools and a highly skilled workforce, Boeing is orchestrating the parallel buildup of five major sub assemblies throughout the factory. Boeing and NASA are transforming MAF to host state of the art processes, equipment and tooling, the most prominent of which is the Vertical Assembly Center (VAC), the largest weld tool in the world. In concert, a global supply chain is delivering a range of structural elements and component parts necessary to enable an on-time delivery of the integrated Core Stage. SLS is on plan to launch humanity into the next phase of space exploration.

Birkenstock, Benjamin↗

How do magnetized HED flows transition to collimated plasma jets? (Final Report)

We present results from a pulsed-power experiment designed to generate accretion-like flows in the laboratory that may be used to study the dynamics of astrophysical accretion-driven outflows. To emulate systems like Young Stellar Object (YSO) outflows, we create radially converging plasma flows in a short disk that transition into much longer bipolar outflows. Our experiment uses a ~1 MA pulsed-power driver to generate plasma from an array of thin aluminum wires mounted to a 3D-printed current path that controls the angular momentum and magnetic field topology. In this paper, we show that experimental data scale favorably to observed properties of YSO jets. This set of experiments tests the simplest version of our possible plasma dynamics, where outflows are generated without rotation or axial magnetic field present. The temperature, velocity and density of the disk and outflows are characterized using interferometry, gated optical and ultraviolet imaging, and Thomson scattering diagnostics. We discuss the Reynolds number, magnetic Reynolds number and Mach numbers calculated in three different stages of the experiment, and compare our results to 3D numerical simulations in the PERSEUS magnetohydrodynamics code. This report is a summary of the work done by the graduate students who were supported by the project.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Paving the Way for Net Zero Energy Codes through Performance Based Approaches

The prescriptive path is the most widely used approach for commercial code compliance in the United States. However, to achieve near-term net zero energy performance that many stakeholders in the buildings industry desire, it is clear that energy codes will need to transition from prescriptive to performance-based approaches. However, that transition is not without potential pitfalls. Among the concerns expressed by stakeholders are added complexity and cost, lack of confidence in energy modeling results, gamesmanship on the part of applicants, lack or qualified reviewers, challenges in promoting de-carbonization, and the inequity of trading long lived envelope efficiency for short lived measures such as building controls. This paper will discuss multiple approaches being evaluated and implemented by Pacific Northwest National Laboratory to improve the usability of the performance-based approach for both code compliance and beyond code programs to meet aggressive energy savings targets. A 'system performance' approach provides a simpler approach compared to whole building performance, while keeping tradeoffs limited to specific building systems. A simplified whole-building performance-based approach for small commercial buildings can cost effectively achieve deeper savings for buildings that typically follow the prescriptive compliance approach. Improved reporting and verification processes applied to the traditional performance path can provide greater confidence in simulation results and facilitate adoption of performance-based approaches. Prescriptive packages provide prescriptive solutions while targeting specific performance thresholds. This paper discusses the progress being made with each of these approaches and provides examples of their implementation in energy codes and beyond code programs.

Performance Based Codes, Appendix G, PRM, TSPR, Sy↗

Carrier properties of Bi(111) grown on mica and Si(111)

A comparison is presented between properties of Bi(111) films grown by Stranski-Krastanov epitaxy on Si(111) 7 × 7 and by van der Waals epitaxy on mica substrates. Thin film morphologies and electronic transport properties of Bi(111) films of variable thickness are investigated for each growth method. Atomic force micrographs for Bi(111) films on mica reveal clearly defined triangular regions consisting of layered steps with height 0.4 nm, corresponding to the Bi(111) bilayer height. Variable-temperature electronic transport measurements show the existence of a quantum confinement-induced energy gap in the film interiors, resulting in a semimetal-to-semiconductor transition. Magnetotransport analysis in a three-carrier model including metallic electrons in surface states and electrons and holes in the films' interiors provides a detailed study of densities, mobilities, and mean-free paths of the three carrier types. Further, improved electronic transport properties are found in Bi(111) films of higher thickness on mica compared to on Si(111), a likely result of the largely strain-free van der Waals epitaxial growth.

36 MATERIALS SCIENCE↗