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At least 451 records · Page 25

Characterization of Natural Consolidated Halloysite Nanotube Structures

Halloysite is a unique 1:1 clay mineral frequently appearing with nanotubular morphology, and having surfaces of different polarity with interesting and important technological applications. HNTs can be consolidated naturally in the earth by pressure and thermal flows. In this study of natural consolidated HNTs, the strength and hardness of these materials were found to be dependent on the presence of impurities (gibbsite, alunite, quartz, and other silica minerals), which accounted for the increased stability of such samples. In the absence of impurities, the strength of consolidated HNTs was significantly lower. The first 3D mapping of the pore structure of natural consolidated HNT is provided. The contributions of the porosity within the nanotubes and between the nanotubes were delineated using a combination of non-invasive ultra-small and small-angle X-ray scattering (USAXS/SAXS) analyses, BET/BJH pore size analyses, and computed tomography studies. A total porosity of 40%, as determined by X-ray attenuation and He porosimetry, was found for the natural consolidated HNTs, of which about one-third was due to the inter-HNT porosity. Nano-X-ray computed tomography (nano-XCT) analyses also indicated that 76% of the inter-HNT pores were smaller than 150 nm in diameter. The intra-HNT pore size determined by combined USAXS/SAXS and BET/BJH was about 10 nm. This pore network information is essential for the utilization of natural consolidated HNTs as a model geomaterial to investigate the effects of surface characteristics on confined fluid flow.

36 MATERIALS SCIENCE↗

Novel Synthesis and Characterization of Uranium-Zirconium Carbonitride by Direct Casting

UZrCN has exhibited thermophysical properties beneficial to high temperature reactor applications such as nuclear thermal rockets. The present work investigates a novel liquid phase synthesis method involving the admission of nitrogen gas during arc melting of uranium, zirconium, and carbon. Initial microstructural examinations using SEM indicated that the samples remain heterogenous with zirconium-rich cores in a uranium-rich matrix. Heterogeneity resulted from large differences in melting temperature of the major constituents and rapid solidification. Additional EDS, combustion analysis, and inert gas fusion analysis proved that the core regions have both uranium and zirconium and establish that carbon and nitrogen are retained during the fabrication process. XRD clarifies that the light elements did not form compounds with the uranium matrix but rather incorporated into the core region forming a sub-stoichiometric UZrCN. Heat treatment performed on equimolar U-Zr-C resulted in an increase in the homogenous phase present with an XRD pattern reflecting a ternary UZrCN despite small amounts of segregation in the final button.

36 - MATERIALS SCIENCE↗

Resident and transient coyotes exhibit differential patterns of movement behavior across heterogeneous landscapes in the southeastern United States

Coyotes (Canis latrans) are a highly adaptable canid species whose behavioral plasticity has allowed them to persist in a wide array of habitats throughout North America. As generalists, coyotes can alter movement patterns and change territorial strategies between residency (high site fidelity) and transiency (low site fidelity) to maximize fitness. Uncertainty remains about resident and transient coyote movement patterns and habitat use because research has reached conflicting conclusions regarding patterns of habitat use by both groups. We quantified effects of habitat on resident and transient coyote movement behavior using first passage time (FPT) analysis, which assesses recursive movement along an individual's movement path to delineate where they exhibit area-restricted search (ARS) behaviors relative to habitat attributes. We quantified monthly movement rates for 171 coyotes (76 residents and 53 transients) and then used estimated FPT values in generalized linear mixed models to quantify monthly habitat use for resident and transient coyotes. Transients had greater movement rates than residents across all months except January. Resident FPT values were positively correlated with agricultural land cover during fall and winter, but negatively correlated with agriculture during spring. Resident FPT values were also negatively correlated with developed habitats during May–August, deciduous land cover during June–August, and wetlands during September–January except November. FPT values of transient coyotes were positively correlated with developed areas throughout much of the year and near wetlands during July–September. Transient FPT values were negatively correlated with agriculture during all months except June and July. High FPT values (ARS behavior) of residents and transients were generally correlated with greater densities of edge habitat. Although we observed high individual variation in space use, our study found substantive differences in habitat use between residents and transients, providing further evidence that complexity and plasticity of coyote habitat use is influenced by territorial strategy.

54 ENVIRONMENTAL SCIENCES↗

Strategizing emission cuts in China to mitigate short-term warming from clean air policies

Aerosol-cloud interactions remain one of the largest sources of uncertainty in estimates of anthropogenic climate forcing. Reducing aerosols to achieve air quality improvement and climate goals can cause unintended warming due to the weakening of aerosol cooling. Here we investigate the climate impacts of spatially optimized sulfur dioxide (SO 2 ) emission reduction under a carbon-neutral pathway in China. We find that targeting reduction in highly polluted regions in China significantly suppresses the rise in effective radiative forcing due to aerosol-cloud interactions (ERF aci ) during 2020–2060. Owing to the nonlinear aerosol-cloud interaction, the optimized emission reduction strategy limits the regional average increase in ERF aci of more than 0.89 W m −2 to less than 0.13 W m −2 in the short-term future during 2020–2040 and weakens the ERF aci increase by two-thirds in 2060 over China. These findings demonstrate the critical role of targeted emission control in mitigating short-term climate risks while pursuing air quality goals.

Zhu, Yitong [Nanjing Univ. of Information Science ↗

Glassy Word Problems: Ultraslow Relaxation, Hilbert Space Jamming, and Computational Complexity

We introduce a family of local models of dynamics based on “word problems” from computer science and group theory, for which we can place rigorous lower bounds on relaxation timescales. These models can be regarded either as random circuit or local Hamiltonian dynamics and include many familiar examples of constrained dynamics as special cases. The configuration space of these models splits into dynamically disconnected sectors, and for initial states to relax, they must “work out” the other states in the sector to which they belong. When this problem has a high time complexity, relaxation is slow. In some of the cases we study, this problem also has high space complexity. When the space complexity is larger than the system size, an unconventional type of jamming transition can occur, whereby a system of a fixed size is not ergodic but can be made ergodic by appending a large reservoir of sites in a trivial product state. This finding manifests itself in a new type of Hilbert space fragmentation that we call fragile fragmentation. We present explicit examples where slow relaxation and jamming strongly modify the hydrodynamics of conserved densities. In one example, density modulations of wave vector q exhibit almost no relaxation until times O ( exp ( 1 / q ) ) , at which point they abruptly collapse. We also comment on extensions of our results to higher dimensions. Published by the American Physical Society 2024

Physics↗

Leaf 13 C data constrain the uncertainty of the carbon dynamics of temperate forest ecosystems

Stable carbon isotope discrimination occurred in plant biophysical and biogeochemical processes can help understand plant physiology and soil biogeochemistry with respect to carbon cycling. Here, we incorporated the photosynthetic carbon isotope discrimination into a process-based land surface model (iTEM) to test if stable carbon isotope composition (δ 13 C) can impose additional constraint on model parameters. Sequential data assimilation was implemented at six eddy covariance flux tower sites using carbon flux observations including gross primary productivity (GPP) and net ecosystem exchange (NEE) with and without considering foliar δ 13 C (δ 13 C f ) measurement constraints, respectively. Our model-data fusion showed that δ 13 C f can provide useful constraint on photosynthetic (V cmax25 , the maximum rate of carboxylation at 25°C) and stomatal (g1, the slope of stomatal function) parameters as well as the posterior carbon fluxes. When including δ 13 C f measurement, g1 spatially varies among the six sites and is significantly correlated with annual precipitation. We incorporated the statistical relationship between g1 and annual precipitation into iTEM, which is then used to quantify the regional carbon dynamic in temperate forest ecosystems of the Northern Hemisphere. Compared with the simulation only conditioned on carbon flux observations, regional carbon flux estimations performed slightly better against the FLUXCOM products and the uncertainties of modeled carbon fluxes were reduced by 27%. Our study demonstrated that δ 13 C f data constrains carbon flux uncertainties across space.

54 ENVIRONMENTAL SCIENCES↗

TROPOMI observations allow for robust exploration of the relationship between solar-induced chlorophyll fluorescence and terrestrial gross primary production

Solar-induced chlorophyll fluorescence (SIF) observed by satellites has advanced the monitoring of terrestrial photosynthesis regionally and globally. The relationship between SIF and gross primary production (GPP) at leaf, canopy, and ecosystem scales has received tremendous attention in recent years. It remains controversial whether the SIF-GPP relationship at the ecosystem scale is universal or dependent upon vegetation type. New SIF observations from the TROPOspheric Monitoring Instrument (TROPOMI) with unprecedented high spatial and temporal resolution provide a new opportunity to elucidate the SIF-GPP relationship. Here, we examine the SIF-GPP relationship for seven major vegetation types across the U.S. with TROPOMI SIF and in-situ GPP data for 83 eddy covariance flux sites. We find that TROPOMI SIF shows a strong and consistent relationship with tower-based GPP at both satellite footprint and grid-cell levels. The slope of the SIF-GPP relationship is similar among all the vegetation types except croplands, demonstrating a nearly universal (converging to ~13.5 g C m -2 d -1 /W m -2 μm -1 sr -1) rather than vegetation type-specific SIF-GPP relationship. This confirms that TROPOMI SIF can be used as a proxy for GPP across a wide variety of vegetation types and can also be used to quantify GPP by avoiding uncertainty associated with land cover maps. The C 4 crops have a much higher slope than the C 3 crops, and therefore croplands tend to have a higher slope than C 3 -dominated vegetation types (e.g., forests, shrublands, savannas). We also find that the TROPOMI SIF is well correlated with GPP under normal or wetter conditions, while their relationship becomes weaker under water stress. In conclusion, our TROPOMI-based study could improve our understanding of the SIF-GPP relationship at the ecosystem scale and advance the mapping of GPP globally with SIF observations from space.

54 ENVIRONMENTAL SCIENCES↗

Bioverse: A Simulation Framework to Assess the Statistical Power of Future Biosignature Surveys

Next-generation space observatories will conduct the first systematic surveys of terrestrial exoplanet atmospheres and search for evidence of life beyond Earth. While in-depth observations of the nearest habitable worlds may yield enticing results, there are fundamental questions about planetary habitability and evolution that can only be answered through population-level studies of dozens to hundreds of terrestrial planets. To determine the requirements for next-generation observatories to address these questions, we have developed Bioverse. Bioverse combines existing knowledge of exoplanet statistics with a survey simulation and hypothesis testing framework to determine whether proposed space-based direct imaging and transit-spectroscopy surveys will be capable of detecting various hypothetical statistical relationships between the properties of terrestrial exoplanets. Following a description of the code, we apply Bioverse to determine whether an ambitious direct imaging or transit survey would be able to determine the extent of the circumstellar habitable zone and study the evolution of Earth-like planets. Given recent evidence that Earth-sized habitable zone planets are likely much rarer than previously believed, we find that space missions with large search volumes will be necessary to study the population of terrestrial and habitable worlds. Moving forward, Bioverse provides a methodology for performing trade studies of future observatory concepts to maximize their ability to address population-level questions, including and beyond the specific examples explored here.

60 APPLIED LIFE SCIENCES↗

Hunga Tonga–Hunga Ha′apai Volcano Impact Model Observation Comparison (HTHH-MOC) project: experiment protocol and model descriptions

The 2022 Hunga volcanic eruption injected a significant amount of water vapor and a moderate amount of sulfur dioxide into the stratosphere, causing observable responses in the climate system. We have developed a model–observation comparison project to investigate the evolution of volcanic water and aerosols and their impacts on atmospheric dynamics, chemistry, and climate, using several state-of-the-art chemistry climate models. The project goals are (1) to evaluate the current chemistry–climate models to quantify their performance in comparison to observations and (2) to understand atmospheric responses in the Earth system after this exceptional event and investigate the potential impacts in the projected future. To achieve these goals, we designed specific experiments for direct comparisons to observations, for example from balloons and the Microwave Limb Sounder satellite instrument. Experiment 1 consists of two sets of free-running ensemble experiments from 2022 to 2031: one with fixed sea-surface temperatures and sea ice and one with coupled ocean. These experiments will help to understand the long-term evolution of water vapor and aerosols; quantify HTHH effects on stratospheric and mesospheric temperatures, dynamics, and transport; understand the impact of dynamic changes on ozone chemistry; quantify the net radiative forcings; and evaluate any surface climate impact. Experiment 2 is a nudged-run experiment from 2022 to 2023 using observed meteorology. To allow participation of more climate models with varying complexities of aerosol simulation, we include two sets of simulations in Experiment 2: Experiment 2a is designed for models with internally generated aerosol, while Experiment 2b is designed for models using prescribed aerosol surface area density. This experiment will help to analyze H 2 O and aerosol evolution, quantify the net radiative forcings, understand the impacts on mid-latitude and polar O 3 chemistry, and allow close comparisons with observations.

Zhu, Yunqian [Univ. of Colorado, Boulder, CO (Unit↗

Lederman Science Center at Fermilab

Fermilab is America's particle physics and accelerator laboratory. We bring the world together to solve the mysteries of matter, energy, space and time, for the benefit of all. LSC was opened in 1992, with the mission to serve as a bridge between Fermilab’s leading-edge science and our community. It was named after Leon M. Lederman – Nobel Prize winning physicist, Fermilab’s second director, and a passionate advocate for science education.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Very-Low-Frequency transmitters bifurcate energetic electron belt in near-earth space

Very-Low-Frequency (VLF) transmitters operate worldwide mostly at frequencies of 10–30 kilohertz for submarine communications. While it has been of intense scientific interest and practical importance to understand whether VLF transmitters can affect the natural environment of charged energetic particles, for decades there remained little direct observational evidence that revealed the effects of these VLF transmitters in geospace. Here we report a radially bifurcated electron belt formation at energies of tens of kiloelectron volts (keV) at altitudes of ~0.8–1.5 Earth radii on timescales over 10 days. Using Fokker-Planck diffusion simulations, we provide quantitative evidence that VLF transmitter emissions that leak from the Earth-ionosphere waveguide are primarily responsible for bifurcating the energetic electron belt, which typically exhibits a single-peak radial structure in near-Earth space. Since energetic electrons pose a potential danger to satellite operations, our findings demonstrate the feasibility of mitigation of natural particle radiation environment.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Aerosol effective radiative forcing increases Earth’s energy imbalance in recent decades

Earth’s energy imbalance (EEI), a key driver of climate change, has risen markedly over the last two decades. Greenhouse gas forcing, aerosol forcing, and cloud feedback all contribute to this increase. However, the role of aerosol forcing, particularly effective radiative forcing through aerosol-cloud interactions (ERF ACI ), remains highly uncertain and closely intertwined with cloud feedback. Here, we estimate shortwave ERF ACI using satellite observations and show its importance as a contributor to the EEI increase between 2003 and 2023. ERF ACI exhibits a significant increasing trend of 0.33 Wm −2 /decade averaged over oceans between 60°S and 60°N. The increasing trend of ERF ACI stems from a global decline in cloud droplet number concentration driven by decreasing anthropogenic aerosol emissions. It is of similar magnitude as the combined instantaneous forcing trend from greenhouse gases and aerosol-radiation interactions. Our results may reduce the gap between the simulated and observed shortwave contribution to EEI trends while implying a weak shortwave cloud feedback. They also suggest a stronger aerosol forcing than the multi-model mean.

Yuan, Tianle [NASA Goddard Space Flight Center (GS↗

Meta-analysis of North American Arctic and boreal aboveground biomass datasets: assessing accuracy, dynamics, and similarities

The North American arctic and boreal regions (ABRs) are rapidly warming and experiencing intensifying disturbances. Accurately quantifying aboveground biomass (AGB) is critical for understanding the impacts of these changes on the carbon cycle and for designing climate change mitigation strategies. Several AGB maps have been developed for the North American ABRs, including recent contributions from National Aeronautics and Space Administration’s Arctic-Boreal Vulnerability Experiment (ABoVE) campaign. However, these maps differ widely in training data, methodology, and resulting AGB density estimates. Presently, a comprehensive comparative evaluation is lacking, making it difficult for users to select datasets suited to their research or management needs. Here, in this study, we conducted a comparative analysis of nine AGB density datasets across North American ABRs, specifically for Alaska and Canada. We (1) summarized AGB by ecoregion and Canadian provinces, (2) evaluated their accuracy against field-based measurements, (3) analyzed spatial and temporal similarities among datasets, and (4) assessed their ability to capture disturbance (fire and harvest) impacts on AGB. We found substantial variation in regional and local AGB estimates across datasets, with overall accuracy ranging from R 2 = 0.25–0.62 and Bias% from −47.8% to 69.9% when validated against field plots. Despite these differences, most datasets have comparatively consistent spatial patterns in AGB (r > 0.8 for most cases). In contrast, agreement on the temporal patterns of AGB change is generally low. We found datasets with spatial resolutions ⩽300 m are capable of capturing disturbance impacts on AGB dynamics, though sensitivity varies across products. Our findings and dataset summary provide guidance for selecting appropriate AGB datasets for different applications within our study area. Our analysis also highlights the need to decrease map bias and increase capability to detect temporal change to decrease uncertainty of AGB datasets potentially by using training data which is representative of major plant functional types within the mapped area.

ABoVE↗

Weak lensing mass-richness relation of redMaPPer clusters in LSST DESC DC2 simulations

Cluster scaling relations are key ingredients in cluster abundance-based cosmological studies. In optical cluster cosmology, where clusters are detected through their richness, cluster-weak gravitational lensing has proven to be a powerful tool to constrain the cluster mass-richness relation. This work is conducted as part of the Dark Energy Science Collaboration (DESC), which aims to analyze the Legacy Survey of Space and Time (LSST) of the Vera C. Rubin Observatory, starting in 2026. Cluster properties inferred from weak lensing, such as mass, suffer from several sources of bias. In this paper, we aim to test the impact of modeling choices and observational systematics in cluster lensing on the inference of the mass-richness relation. We constrained the mass-richness relation of 3600 clusters detected by the redMaPPer algorithm in the cosmoDC2 extragalactic mock catalog of the LSST DESC DC2 simulation, covering 440 deg 2 , using number count measurements and either stacked weak lensing profiles or mean cluster masses in several intervals of richness (20 ≤ λ ≤ 200) and redshift (0.2 ≤ z ≤ 1). We provide the first constraints on the redMaPPer cluster mass-richness relation detected in cosmoDC2. We find that for an LSST-like source galaxy density, our constraints are robust to changes in the concentration-mass relation, as well as the dark matter density profile modeling choices, when source redshifts and shapes are perfectly known. We find that photometric redshift uncertainties can introduce bias at the 1σ level, which could be mitigated by an overall correction factor fitted jointly with the scaling parameters. We find that including positive shear-richness covariance in the fit shifts the results by up to 0.5σ. Our constraints also offer a fair comparison to a fiducial mass-richness relation, obtained from matching cosmoDC2 halo masses to redMaPPer-detected cluster richness results.

galaxy clusters↗