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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Detection and attribution of long-term and fine-scale changes in spring phenology over urban areas: A case study in New York State

Spring phenology plays an essential role in climate change, terrestrial ecosystem, and public health. Field-based monitoring and understanding of changes in spring phenology for long periods and in large regions are challenging due to the limited in-site observations. Space-based remotely sensed observations offer great potentials for monitoring decadal spring phenology changes from regional to global scales. However, the coarse-scale remotely sensed observations are insufficient to capture fine-scale spring phenology dynamics, especially in urban areas, and this makes it challenging for understanding the combined effects of climate change and urbanization on spring phenology. We derived the start of phenology season (SOS) in New York State using 30 m Landsat observations from 1990 to 2015 to understand the impact of the environment and urbanization on SOS. The results show that SOS for different years reveals heterogeneous spatial distribution. Most regions of New York State have been experiencing significant spring phenology changes in form of earlier onset of vegetation greening, ranging from 0.2 to 0.6 day/year during 1990 to 2015, and this trend varies slightly with latitudes and urbanization levels. Further, spatial correlation analysis shows that the increase in temperature and urbanization could both promote the advancement of SOS. However, the effect of urbanization (partial correlation coefficient (R) ranges from −0.289 to −0.542) on SOS is greater than the effect of temperature (R ranges from 0.006 to −0.192). The study generates a high spatio-temporal resolution spring phenology dataset for ecological, environmental and public health studies, especially in urban areas, and reveals the importance of better accounting for the urbanization effects when quantifying the SOS dynamics in phenology models.

Landsat↗
DOE OSTI2019

Assessing changes in US regional precipitation on multiple time scales

We estimate trends in US regional precipitation on multiple time spans and scales relevant to the detection of changes in climatic regimes. A large literature has shown that trend estimation in hydrological series may be affected by long-term persistence (LTP) and selection of sample length. We show that 2000-year proxy-based reconstructions of the Palmer Modified Drought Index for the US Southeast (SE) and Pacific Coast (PC) regions exhibit LTP and reveal post- 1900 changes to be within the range of longer-term natural fluctuations. We also use a new data base of daily precipitation records for 20 locations (10 PC and 10 SE) extending back in many cases to the 1870s. Over the 1901–2017 interval upward trends in some measures of average and extreme precipitation appear, but they are not consistently significant and in the full records back to 1872 they largely disappear. Furthermore, they also disappear or reverse in the post-1978 portion of the data set, which is inconsistent with them being responses to enhanced greenhouse gas forcing. We conclude that natural variability is likely the dominant driver of historical changes in precipitation and hence drought dynamics in the US SE and PC.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Multiscale characterization of phase change materials for building thermal energy storage applications

Phase change materials (PCMs) store and release large amounts of thermal energy because of their high latent energy storage capacity. However, long-term cyclic stability, supercooling and performance-scalability are some of the major challenges for their use in building thermal energy storage (TES) applications. Here, in this study, we present a comprehensive multiscale characterization of two commercially available organic PCMs, Puretemp 18 and Puretemp 23. At the microscale, differential scanning calorimetry (DSC) was used to characterize phase change temperature, specific heat, and latent heat. At the mesoscale, a heat flow meter apparatus (HFMA), following the ASTM C1784 standard, was employed to measure the phase change temperature, specific heat, and latent heat properties. A comparative analysis of latent heat as a function of temperature was conducted by integrating the DSC and HFMA results. At the macroscale, the thermal performance and cyclic stability of the TES system was evaluated using Puretemp 23. The TES system consisted of a finned tube heat exchanger with a storage volume of 0.0189 m 3 (5 gal), which represents a compact, real-world TES solution suitable for building energy storage. The results showed consistent thermal stability of the PCM over 200 cycles, and the supercooling temperature remained within 0.2 °C, which was not detected in smaller-scale characterization methods. Additionally, the macroscale testing methodology of the PCM revealed that the TES is able to charge and discharge stored latent energy within 2 h under a temperature differential of 16.67 °C measured between the inlet water temperature and the phase transition temperature of the PCM. The proposed multiscale PCM characterization method provides a systematic basis for comparing important thermal storage properties while also investigating the scalability, reliability and integration challenges in large scale TES applications.

Latent heat↗
DOE OSTI2016

Low-resolution gamma-ray spectrometry for an information barrier based on a multi-criteria template-matching approach

Gamma-ray spectrometry has been successfully employed to identify unique items containing special nuclear materials. Template information barriers have been developed in the past to confirm items as warheads by comparing their gamma signature to the signature of true warheads. Their development has, however, not been fully transparent, and they may not be sensitive to some relevant evasion scenarios. Here, we develop a fully open template information barrier concept, based on low-resolution measurements, which, by design, reduces the extent of revealed sensitive information. The concept is based on three signatures of an item to be compared to a recorded template. The similarity of the spectrum is assessed by a modification of the Kolmogorov–Smirnov test to confirm the isotopic composition. The total gamma count rate must agree with the template as a measure of the projected surface of the object. In order to detect the diversion of fissile material from the interior of an item, a polyethylene mask is placed in front of the detector. Neutrons from spontaneous and induced fission events in the item produce 2.223 MeV gamma rays from neutron capture by hydrogen-1 in the mask. This peak is detected and its intensity scales with the item's fissile mass. This analysis is based on MCNP Monte Carlo simulations of various plutonium configurations suggests that this concept can distinguish a valid item from a variety of invalid ones. The concept intentionally avoids any assumptions about specific spectral features, such as looking for specific gamma peaks of specific isotopes, thereby facilitating a fully unclassified discussion. Finally, by making all aspects public and allowing interested participants to contribute to the development and benchmarking, we enable a more open and inclusive discourse on this matter.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2026

Time of Flight Secondary Ion Mass Spectrometry for Characterization of Pt-Coated Porous Transport Layers in PEM Water Electrolyzers

Titanium-based porous transport layers (PTLs) and iridium-based catalyst layers (CLs) are two main components of proton exchange membrane water electrolyzers (PEMWEs). PTLs are typically coated with platinum to minimize interfacial losses and to support long-term operation. Optimizing coatings and the PTL-CL interface requires comprehensive characterization. This study establishes time-of-flight secondary ion mass spectrometry (ToF-SIMS) as a valuable technique for PTL characterization, addressing capabilities and limitations related to PTL morphology. A methodology was developed that uses a Cs + sputter beam for dynamic depth profiling, with data collected in both positive-ion (MCs + ) and negative-ion modes to generate depth profiles, 2D ion maps, and 3D ion reconstructions. ToF-SIMS detected relative differences in platinum-layer thickness between samples; these trends were validated by cross-sectional scanning transmission electron microscope (STEM) measurements and flat-titanium substrate controls. Interfacial oxide layers are identified in both ion modes, with enhanced oxide sensitivity in negative mode. The technique’s high sensitivity enables detection of nanometer-scale coatings and trace impurities within the bulk PTL structure. These results provide a methodological framework for analyzing Pt-coated PTLs, with the potential to extend to other components in PEMWEs and other electrolyzer systems.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Ionospheric Disturbances in GNSS TEC Data: SpaceX Falcon 9 Deorbit Maneuvers Over CONUS in April–May 2024

Traveling ionospheric disturbances (TIDs) driven by a large number of internal and external sources are detectable with dense networks of ground‐based Global Navigation Satellite System (GNSS) receivers' measurements of total electron content (TEC). We present the newly developed System for Rapid Analysis of Ionospheric Dynamics (S‐RAID), providing data and visual GNSS TEC products of TIDs of periods ~2–120 min and horizontal resolution up to tens of kilometers for years 2017–2024. The S‐RAID data reveal myriad natural and anthropogenic TIDs from meteorology and space weather, and from human spaceflight activities. In this report, we focus on new prominent disturbances found during SpaceX second stage deorbit maneuvers in April–May 2024. Signatures include waves emanating from the Falcon's trajectory above California and depletions following its deorbit and passage over Arizona. These findings suggest further opportunities to detect and quantify small‐scale events in the ionosphere as well as to understand the responses of the atmosphere‐ionosphere system to known inputs.

58 GEOSCIENCES↗
DOE OSTI2025

Leveraging unlabeled SEM datasets with self-supervised learning for enhanced particle segmentation

Scanning Electron Microscopes (SEMs) are widely used in experimental science laboratories, often requiring cumbersome and repetitive user analysis. Automating SEM image analysis processes is highly desirable to address this challenge. In particle sample analysis, Machine Learning (ML) has emerged as the most effective approach for particle segmentation. However, the time-intensive process of manually annotating thousands of SEM images limits the applicability of supervised learning approaches. Self-Supervised Learning (SSL) offers a promising alternative by enabling knowledge extraction from raw, unlabeled data. This study presents a framework for evaluating SSL techniques in SEM image analysis, focusing on novel methods leveraging the ConvNeXtV2 architecture for particle detection. A dataset comprising 25,000 SEM images is curated to benchmark these proposed SSL methods. The results demonstrate that ConvNeXtV2 models, with varying parameter counts, consistently outperform other techniques in particle detection across different length scales, achieving up to a 34% reduction in relative error compared to established SSL methods. Furthermore, an ablation study explores the relationship between dataset size and SSL performance, providing actionable insights for practitioners regarding model selection and resource efficiency. This research advances the integration of SSL into autonomous analysis pipelines and supports its application in accelerating materials science discovery.

Rettenberger, Luca↗
DOE OSTI2016

Discovery of a massive supercluster system at z ~ 0.47

Aims. Superclusters are the largest relatively isolated systems in the cosmic web. Using the SDSS BOSS survey, we search for the largest superclusters in the redshift range 0.43 < z < 0.71. Methods. We generate a luminosity-density field smoothed over 8 h -1 Mpc to detect the large-scale over-density regions. Each individual over-density region is defined as single supercluster in the survey. Here, we define the superclusters so that they are comparable to the superclusters found in the SDSS main survey. Results. We find a system that we call the BOSS Great Wall (BGW), which consists of two walls with diameters 186 and 173 h -1 Mpc and two other major superclusters with diameters of 64 and 91 h -1 Mpc. As a whole, this system consists of 830 galaxies with the mean redshift 0.47. We estimate the total mass to be approximately 2 × 10 17 h -1 M ⊙ .The morphology of the superclusters in the BGW system is similar to the morphology of the superclusters in the Sloan Great Wall region. Conclusions. The BGW is one of the most extended and massive systems of superclusters found so far in the Universe.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Atacama Cosmology Telescope measurements of a large sample of candidates from the Massive and Distant Clusters of WISE Survey

Galaxy clusters are an important tool for cosmology, and their detection and characterization are key goals for current and future surveys. Using data from the Wide-field Infrared Survey Explorer (WISE), the Massive and Distant Clusters of WISE Survey (MaDCoWS) located 2839 significant galaxy overdensities at redshifts 0.7 ≲ z ≲ 1.5, which included extensive follow-up imaging from the Spitzer Space Telescope to determine cluster richnesses. Concurrently, the Atacama Cosmology Telescope (ACT) has produced large area millimeter-wave maps in three frequency bands along with a large catalog of Sunyaev-Zeldovich (SZ)-selected clusters as part of its Data Release 5 (DR5). Aims. We aim to verify and characterize MaDCoWS clusters using measurements of, or limits on, their thermal SZ effect signatures. Here, we also use these detections to establish the scaling relation between SZ mass and the MaDCoWS-defined richness.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

A simple and rapid method for high-resolution visualization of single-ion tracks

Prompt determination of spatial points of single-ion tracks plays a key role in high-energy particle induced-cancer therapy and gene/plant mutations. In this study, a simple method for the high-resolution visualization of single-ion tracks without etching was developed through the use of polyacrylic acid (PAA)-N, N’-methylene bisacrylamide (MBAAm) blend films. One of the steps of the proposed method includes exposure of the irradiated films to water vapor for several minutes. Water vapor was found to promote the cross-linking reaction of PAA and MBAAm to form a bulky cross-linked structure; the ion-track scars were detectable at a nanometer scale by atomic force microscopy. This study demonstrated that each scar is easily distinguishable, and the amount of generated radicals of the ion tracks can be estimated by measuring the height of the scars, even in highly dense ion tracks. This method is suitable for the visualization of the penumbra region in a single-ion track with a high spatial resolution of 50 nm, which is sufficiently small to confirm that a single ion hits a cell nucleus with a size ranging between 5 and 20 μm.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Short range atomic migration in amorphous silicon

Experiments on self-diffusion in amorphous silicon between 400 and 500 °C are presented, which were carried out by neutron reflectometry in combination with {sup 29}Si/{sup nat}Si isotope multilayers. Short range diffusion is detected on a length scale of about 2 nm, while long range diffusion is absent. Diffusivities are in the order of 10{sup −19}–10{sup −20} m{sup 2}/s and decrease with increasing annealing time, reaching an undetectable low value for long annealing times. This behavior is strongly correlated to structural relaxation and can be explained as a result of point defect annihilation. Diffusivities for short annealing times of 60 s follow the Arrhenius law with an activation enthalpy of (0.74 ± 0.21) eV, which is interpreted as the activation enthalpy of Si migration.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Kinetic mix at gas-shell interface in inverted corona fusion targets

Gas-filled, laser-driven “inverted corona” fusion targets have attracted interest as a low-convergence neutron source and platform for studying kinetic physics. At the fill pressures under investigation, ejected particles from the shell can penetrate deeply into the gas before colliding, leading to significant mixing across the gas–shell interface. Here, we use kinetic-ion, fluid-electron hybrid particle-in-cell simulations to explore the nature of that mix. Simulations of the system demonstrate characteristics of a weakly collisional electrostatic shock, whereby a strong electric field accelerates shell ions into the rarefied gas and reflects upstream gas ions. This interpenetration is mediated by collisional processes: At higher initial gas pressure, fewer shell particles pass into the mix region and reach the hotspot. This effect is detectable through neutron yield scaling vs gas pressure. Predictions of neutron yield scaling show excellent agreement with experimental data recorded at the OMEGA laser facility, suggesting that 1D kinetic mechanisms are sufficient to capture the mix process.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

EXploring the dust content of galactic winds with Herschel. I. NGC 4631

We present a detailed analysis of deep far-infrared observations of the nearby edge-on star-forming galaxy NGC 4631 obtained with the Herschel Space Observatory. Our Photodetector Array Camera and Spectrometer (PACS) images at 70 and 160 μm show a rich complex of filaments and chimney-like features that extends up to a projected distance of 6 kpc above the plane of the galaxy. The PACS features often match extraplanar Hα, radio-continuum, and soft X-ray features observed in this galaxy, pointing to a tight disk–halo connection regulated by star formation. On the other hand, the morphology of the colder dust component detected on a larger scale in the Spectral and Photometric Imaging Receiver 250, 350, and 500 μm data matches the extraplanar H I streams previously reported in NGC 4631 and suggests a tidal origin. The PACS 70/160 μm ratios are elevated in the central ∼3.0 kpc region above the nucleus of this galaxy (the “superbubble”). A pixel-by-pixel analysis shows that dust in this region has a higher temperature and/or an emissivity with a steeper spectral index (β>2) than the dust in the disk, possibly the result of the harsher environment in the superbubble. Star formation in the disk seems energetically insufficient to lift the material out of the disk, unless it was more active in the past or the dust-to-gas ratio in the superbubble region is higher than the Galactic value. Some of the dust in the halo may also have been tidally stripped from nearby companions or lifted from the disk by galaxy interactions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Overview of results from the MST reversed field pinch experiment

An overview of recent results from the MST reversed field pinch programme is presented here. With neutral beam injection, bursty energetic particle (EP) modes are observed. The profiles of the magnetic and density fluctuations associated with these EP modes are measured using a far infrared interferometer–polarimeter. Equilibrium reconstructions of the quasi-single-helicity 3D helical state are provided by the V3FIT code that now incorporates several of MST's advanced diagnostics. The orientation of the helical structure is controlled using a new resonant magnetic perturbation technique. Gyrokinetic simulations based on experimental equilibria predict unstable trapped-electron modes (TEMs), and small-scale density fluctuations are detected in improved-confinement plasmas with TEM-like features. Upgraded pellet injection permits study of density and beta limits over MST's full range of operation, and an MST-record line-average density of 0.9 × 1020 m3 (n/nG = 1.4) has been obtained. Impurity ion temperature measurements reveal a charge-to-mass-ratio dependence in the rapid heating that occurs during a sawtooth crash. Runaway of NBI-born fast ions during the impulsive sawtooth event agrees with test-particle theory. Magnetic self-organization studies include measurements of the dynamo emf with an applied ac inductive electric field using oscillating field current drive.

beta limit↗
DOE OSTI2015

PROPERTIES OF QSO METAL-LINE ABSORPTION SYSTEMS AT HIGH REDSHIFTS: NATURE AND EVOLUTION OF THE ABSORBERS AND NEW EVIDENCE ON ESCAPE OF IONIZING RADIATION FROM GALAXIES

Using Voigt-profile-fitting procedures on Keck High Resolution Spectrograph spectra of nine QSOs, we identify 1099 C IV absorber components clumped in 201 systems outside the Lyman forest over 1.6 ≲ z ≲ 4.4. With associated Si IV, C II, Si II and N V where available, we investigate the bulk statistical and ionization properties of the components and systems and find no significant change in redshift for C IV and Si IV while C II, Si II and N V change substantially. The C IV components exhibit strong clustering, but no clustering is detected for systems on scales from 150 km s{sup –1} out to 50,000 km s{sup –1}. We conclude that the clustering is due entirely to the peculiar velocities of gas present in the circumgalactic media of galaxies. Using specific combinations of ionic ratios, we compare our observations with model ionization predictions for absorbers exposed to the metagalactic ionizing radiation background augmented by proximity radiation from their associated galaxies and find that the generally accepted means of radiative escape by transparent channels from the internal star-forming sites is spectrally not viable for our stronger absorbers. We develop an active scenario based on runaway stars with resulting changes in the efflux of radiation that naturally enable the needed spectral convergence, and in turn provide empirical indicators of morphological evolution in the associated galaxies. Together with a coexisting population of relatively compact galaxies indicated by the weaker absorbers in our sample, the collective escape of radiation is sufficient to maintain the intergalactic medium ionized over the full range 1.9 < z ≲ 4.4.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Clustering fossils in solid inflation

In solid inflation the single field non-Gaussianity consistency condition is violated. As a result, the long tenor perturbation induces observable clustering fossils in the form of quadrupole anisotropy in large scale structure power spectrum. In this work we revisit the bispectrum analysis for the scalar-scalar-scalar and tensor-scalar-scalar bispectrum for the general parameter space of solid. We consider the parameter space of the model in which the level of non-Gaussianity generated is consistent with the Planck constraints. Specializing to this allowed range of model parameter we calculate the quadrupole anisotropy induced from the long tensor perturbations on the power spectrum of the scalar perturbations. We argue that the imprints of clustering fossil from primordial gravitational waves on large scale structures can be detected from the future galaxy surveys.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Biasing and the search for primordial non-Gaussianity beyond the local type

Primordial non-Gaussianity encodes valuable information about the physics of inflation, including the spectrum of particles and interactions. Significant improvements in our understanding of non-Gaussanity beyond Planck require information from large-scale structure. The most promising approach to utilize this information comes from the scale-dependent bias of halos. For local non-Gaussanity, the improvements available are well studied but the potential for non-Gaussianity beyond the local type, including equilateral and quasi-single field inflation, is much less well understood. In this paper, we forecast the capabilities of large-scale structure surveys to detect general non-Gaussianity through galaxy/halo power spectra. We study how non-Gaussanity can be distinguished from a general biasing model and where the information is encoded. For quasi-single field inflation, significant improvements over Planck are possible in some regions of parameter space. We also show that the multi-tracer technique can significantly improve the sensitivity for all non-Gaussianity types, providing up to an order of magnitude improvement for equilateral non-Gaussianity over the single-tracer measurement.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Cosmic perturbations from a rotating field

Complex scalar fields charged under approximate U(1) symmetries appear in well-motivated extensions of the Standard Model. One example is the field that contains the QCD axion field associated with the Peccei-Quinn symmetry; others include flat directions in supersymmetric theories with baryon, lepton, or flavor charges. These fields may take on large values and rotate in field space in the early universe. The relevant approximate U(1) symmetry ensures that the angular direction of the complex field is light during inflation and that the rotation is thermodynamically stable and is long-lived. These properties allow rotating complex scalar fields to naturally serve as curvatons and explain the observed perturbations of the universe. The scenario imprints non-Gaussianity in the curvature perturbations, likely at a level detectable in future large scale structure observations. The rotation can also explain the baryon asymmetry of the universe without producing excessive isocurvature perturbations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗