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At least 451 records · Page 25

A generic scenario analysis of end-of-life plastic management: Chemical additives

Plastic growing demand and the increment in global plastics production have raised the number of spent plastics, out of which over 90% are either landfilled or incinerated. Both methods for handling spent plastics are susceptible to releasing toxic substances, damaging air, water, soil, organisms, and public health. Improvements to the existing infrastructure for plastics management are needed to limit chemical additive release and exposure resulting from the end-of-life (EoL) stage. This article analyzes the current plastic waste management infrastructure and identifies chemical additive releases through a material flow analysis. Additionally, we performed a facility-level generic scenario analysis of the current U.S. EoL stage of plastic additives to track and estimate their potential migration, releases, and occupational exposure. Potential scenarios were analyzed through sensitivity analysis to examine the merit of increasing recycling rates, using chemical recycling, and implementing additive extraction post-recycling. Our analyses identified that the current state of plastic EoL management possesses high mass flow intensity toward incineration and landfilling. Although maximizing the plastic recycling rate is a reasonably straightforward goal for enhancing material circularity, the conventional mechanical recycling method requires improvement because major chemical additive release and contamination routes act as obstacles to achieving high-quality plastics for future reuse and should be mitigated through chemical recycling and additive extraction. In conclusion, the potential hazards and risks identified in this research create an opportunity to design a safer closed-loop plastic recycling infrastructure to handle additives strategically and support sustainable materials management efforts to transform the US plastic economy from linear to circular.

54 ENVIRONMENTAL SCIENCES↗

Optimization for Bioenergy Systems

The Sustainable Aviation Fuel (SAF) Grand Challenge (Langholtz, 2024 ) seeks to generate 35 billion gallons of SAF each year by 2050, with corn stover, an agricultural byproduct, playing a key role as a feedstock. This study develops an optimization framework to enhance the quality and quantity of corn stover while ensuring economic and environmental viability. Using the Decision Support System for Agrotechnology Transfer (DSSAT) crop model, we simulate the effects of cover crops on rotation yield, soil moisture balance, and nitrogen cycling across diverse climates and soils. The model outputs, including yield data and soil quality changes, inform a Mixed-Integer Linear Programming (MILP) optimization model. This model aims to maximize economic and environmental returns by incorporating production costs, direct and indirect income, and environmental incentives. The optimization model evaluates 280 agriculture management plans composed of various crop management strategies, including corn stover removal rates, cover crop adoption, and fertilization practices. It seeks to identify the optimal combination of crop and tillage decisions for each subfield, maximizing profits while enhancing soil carbon sequestration and reducing greenhouse gas emissions. Outputs include detailed subfield locations, optimal management plans, and profits per hectare and per acre, allowing for comparison with literature values on farm profits. This study provides a robust optimization framework supporting the SAF Grand Challenge by proposing economically viable and environmentally sustainable strategies for corn stover utilization. The findings highlight corn stover's potential as a sustainable feedstock for SAF production, offering practical solutions to enhance its quality and quantity while maintaining soil health. Idaho is used as a case study to demonstrate the framework's applicability and effectiveness in real-world scenarios. Langholtz, M. H., Davis, M., Hellwinckel, C., De La Torre Ugarte, D., Efroymson, R., Jacobson, R., Milbrandt, A., Coleman, A., Davis, R., Kline, K. L., Badgett, A., Curran, S., Schmidt, E., Theiss, T., Fried, J., English, B., Lambert, L., Cook, H., Field, J., ... Walker, L. (2024). 2023 Billion-Ton Report: An Assessment of U.S. Renewable Carbon Resources. https://doi.org/10.2172/2441098 DSSAT Foundation. (2025). Decision Support System for Agrotechnology Transfer (DSSAT). Retrieved from https://dssat.net/

09 - BIOMASS FUELS↗

ARM Lead Mentor Selection Process

The Atmospheric Radiation Measurement (ARM) Program was created in 1989 with funding from the U.S. Department of Energy (DOE) to develop several highly instrumented ground stations to study cloud-formation processes and their influence on radiative transfer. This scientific infrastructure provides for fixed sites, mobile facilities, an aerial facility, and a data archive available for use by scientists worldwide through the ARM Climate Research Facility—a scientific user facility. The ARM Climate Research Facility currently operates more than 300 instrument systems that provide ground-based observations of the atmospheric column. To keep ARM at the forefront of climate observations, the ARM infrastructure depends heavily on instrument scientists and engineers, known as Mentors. Mentors must have an excellent understanding of instrumentation theory and operation for their instrument areas and have comprehensive knowledge of critical scale-dependent atmospheric processes. They must also possess the technical and analytical skills to develop new data retrievals that provide innovative approaches for creating research-quality data sets. The ARM Facility seeks the best overall qualified candidate, or team when appropriate, that can fulfill Mentor requirements in a timely manner. The roles and responsibilities of the ARM Instrument Operations Manager are provided in Appendix A. The key role and responsibilities and detailed responsibilities of ARM Lead Mentors are provided in Appendix B and Appendix C, respectively.

47 OTHER INSTRUMENTATION↗

Dynamic risk assessment for geologic CO 2 sequestration

At a geologic CO 2 sequestration (GCS) site, geologic uncertainty usually leads to large uncertainty in the predictions of properties that influence metrics for leakage risk assessment, such as CO 2 saturations and pressures in potentially leaky wellbores, CO 2 /brine leakage rates, and leakage consequences such as changes in drinking water quality in groundwater aquifers. The large uncertainty in these risk-related system properties and risk metrics can lead to over-conservative risk management decisions to ensure safe operations of GCS sites. The objective of this work is to develop a novel approach based on dynamic risk assessment to effectively reduce the uncertainty in the predicted risk-related system properties and risk metrics. We demonstrate our framework for dynamic risk assessment on two case studies: a 3D synthetic example and a synthetic field example based on the Rock Springs Uplift (RSU) storage site in Wyoming, USA. Results show that the U.S. National Risk Assessment Partnership’s Open Source Integrated Assessment Model (NRAP-Open-IAM) coupled with a conformance evaluation can be used to effectively quantify and reduce the uncertainty in the predictions of risk-related system properties and risk metrics in GCS.

58 GEOSCIENCES↗

Evaluation of FTWC Vent System

A monitored exhaust system has been designed for use in venting the Flanged Tritium Waste Containers (FTWCs) at LANL. This system will provide controlled exhaust and emissions monitoring for the FTWCs, and also provide general area exhaust around the venting operations to measure any emissions which may bypass the primary vent system. A full description of the process and need for the system is described in the Pre-Construction Application for this project. This document describes the commissioning testing performed on the FTWC vent system to prepare it for use. The system has been tested and shown to meet ANSI standard requirements and is fully suitable for use.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Notification of Operational Scope Change for the FTWC Venting Project at Los Alamos National Laboratory (LANL)

This letter is intended to provide you an update on the scope of work for the venting of the Flanged Tritium Waste Containers (FTWCs) at Los Alamos National Laboratory (LANL) Technical Area (TA-) 54. This project was described in the Application for Pre-Construction Approval 1 ("the Application") that was approved by EPA Region 6 on May 22, 2019. As operational planning for this project has been finalized, the scope of work described in the Application has slightly changed. The project has now determined that each FTWC may be vented multiple times, and these venting activities may take place at more than one location. The original application only discussed a single venting operation for each FTWC at a single location, TA-54. However, the radionuclide inventory and expected air releases remain bounded by the values described in the Application.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Supplemental Information Regarding the Application for Remediation of the Flanged Tritium Waste Containers at Los Alamos National Laboratory

This letter is in response to the October 18, 2021 letter from David Gray, Acting Regional Administrator, to Mr. Theodore Wyka, Manager of the National Nuclear Security Administration’s Los Alamos Field Office (NA-LA). That letter requested additional information regarding the Application for remediation of the Flanged Tritium Waste Containers (FTWCs) at Los Alamos National Laboratory (LANL) Technical Area 54, Area G. The Emissions Management Plan for the FTWC Venting Project is attached.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hydrological connectivity: a review and emerging strategies for integrating measurement, modeling, and management

This review synthesizes methods for measuring, modeling, and managing hydrologic connectivity, offering pathways to improve practices and address environmental challenges (e.g., climate change) and sustainability. As a key driver of water movement and nutrient cycling, hydrologic connectivity influences flood mitigation, water quality regulation, and biodiversity conservation. However, traditional field-based methods (e.g., dye tracing), indirect measurements (e.g., runoff analysis), and remote sensing techniques (e.g., InSAR) often struggle to capture the complexity of catchment-scale interactions. Similarly, modeling approaches—including process-based and percolation theory-based models, graph theory, and entropy-based metrics—face limitations in fully representing these interconnected processes. Both modeling and measurement techniques are constrained by inadequate spatial and temporal coverage, high data demands, computational complexity, and difficulties in representing subsurface connectivity. Subsequently, we critique current management practices that prioritize isolated variables (e.g., streamflow, sediment transport) over system-wide strategies and emphasize the need for adaptive, connectivity-based approaches in water resource planning and restoration. Moving forward, we highlight the importance of interdisciplinary collaboration, technological innovations (e.g., AI-driven modeling, real-time monitoring), and integrated frameworks to improve connectivity measurement, modeling, and adaptive management to restore fragmented hydrologic networks. This integrated approach sets the stage for transformative water resource management, fostering proactive policy development and stakeholder engagement.

Dwivedi, Dipankar↗

Grassland intensification effects cascade to alter multifunctionality of wetlands within metaecosystems

Sustainable agricultural intensification could improve ecosystem service multifunctionality, yet empirical evidence remains tenuous, especially regarding consequences for spatially coupled ecosystems connected by flows across ecosystem boundaries (i.e., metaecosystems). Here we aim to understand the effects of land-use intensification on multiple ecosystem services of spatially connected grasslands and wetlands, where management practices were applied to grasslands but not directly imposed to wetlands. We synthesize long-term datasets encompassing 53 physical, chemical, and biological indicators, comprising >11,000 field measurements. Our results reveal that intensification promotes high-quality forage and livestock production in both grasslands and wetlands, but at the expense of water quality regulation, methane mitigation, non-native species invasion resistance, and biodiversity. Land-use intensification weakens relationships among ecosystem services. The effects on grasslands cascade to alter multifunctionality of embedded natural wetlands within the metaecosystems to a similar extent. These results highlight the importance of considering spatial flows of resources and organisms when studying land-use intensification effects on metaecosystems as well as when designing grassland and wetland management practices to improve landscape multifunctionality.

54 ENVIRONMENTAL SCIENCES↗

Planning for Nuclear Power Plant Site Visits - 20481

The U.5. Department of Energy Office of Integrated Waste Management (DOE-IWM) is planning for future large-scale transport of commercial spent nuclear fuel (SNF) and high-level radioactive waste (HLW) to eventual disposal and/or storage facilities. As part of its planning efforts, DOE conducts evaluations of removing SNF from nuclear power plant sites. Site visits are a pivotal piece in the site evaluations that are conducted by DOE, and significant planning efforts are undertaken to design and implement site visits. Site visits typically include three days of surveys and meetings, including one day each for the nuclear power plant site visit, evaluating near-site transportation infrastructure, and meeting with community engagement panels or advisory boards. This paper outlines DOE-IWM's planning process for conducting nuclear power plant site visits and summarizes the key activities carried out to prepare for a site visit, including a discussion of the background research conducted prior to a site visit. Additionally, the paper describes the development of reference databases for site visits, the identification of unique site characteristics, and the use of geographic information system (GIS) applications to enhance the quality of the information collected during a site visit. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Y-12 Groundwater Protection Program Groundwater and Surface Water Sampling and Analysis Plan (CY 2021)

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2021 at the U.S. Department of Energy Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring is performed by the GWPP. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley and the Chestnut Ridge Regime is located south of Y-12. Additional surface water monitoring will be performed north of Pine Ridge along the boundary of the Oak Ridge Reservation. The following sections of this report provide details regarding the CY 2021 groundwater and surface water monitoring activities. Section 2 describes the monitoring locations in each regime and the processes used to select the sampling locations. A description of the field measurements and laboratory analytes is provided in Section 3. Sample collection methods and procedures are described in Section 4, and Section 5 lists the documents cited for more detailed operational and technical information. The narrative sections of the report reference several appendices. Figures (maps and diagrams) and tables (excluding a data summary table presented in Section 4) are in Appendix A and Appendix B, respectively. Groundwater Monitoring Schedules (when issued throughout CY 2021) will be inserted in Appendix C, and addenda to this plan (if issued) will be inserted in Appendix D. Laboratory requirements (bottle lists, holding times, etc.) are provided in Appendix E, and an approved Waste Management Plan is provided in Appendix F. Modifications to the CY 2021 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. Each modification to the monitoring program will be approved by the Y-12 GWPP manager and documented as an addendum to this sampling and analysis plan.

54 ENVIRONMENTAL SCIENCES↗

Y-12 Groundwater Protection Program Groundwater and Surface Water Sampling and Analysis Plan for Calendar Year 2022

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2022 at the U.S. Department of Energy Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley and the Chestnut Ridge Regime is located south of Y-12. Additional surface water monitoring will be performed north of Pine Ridge along the boundary of the Oak Ridge Reservation. The following sections of this report provide details regarding the CY 2022 groundwater and surface water monitoring activities. Section 2 describes the monitoring locations in each regime and the processes used to select the sampling locations. A description of the field measurements and laboratory analytes is provided in Section 3. Sample collection methods and procedures are described in Section 4, and Section 5 lists the documents cited for more detailed operational and technical information.

54 ENVIRONMENTAL SCIENCES↗

WIPP Safety Significant Confinement Ventilation System (SSCVS) Quality Assurance Program - 20237

Construction and major equipment fabrication are underway for a new ventilation exhaust system at the Waste Isolation Pilot Plant (WIPP). The new system will provide continuous HEPA filtration of the exhaust from the WIPP underground while meeting the ventilation demands for expanded waste emplacement and mining operations over the next 40 years. The SSCVS project has proceeded with the awarding of CD-3A for Long Lead Procurements followed by CD-2/3 approval for the construction of the facilities. The SSCVS project team made the decision to increase the quality oversight throughout the complete project per the Project Quality Assurance Plan (PQAP) such that it can ensure the final products meet applicable NQA-1 requirements and general quality requirements, and that the project will proceed to operations without significant delays due to post installation quality concerns. The PQAP was established prior to approval of the project at the CD-2/3 milestone. The SSCVS project has 2 major long lead procurements which commenced with the awarding of CD-3A. These procurements include the HEPA filter housing assemblies and the Exhaust Fans. There are 22 HEPA filter assemblies for the SSCVS, which are designated Safety Significant for pressure boundary confinement, per the approved PDSA. The exhaust fans also have Safety Significant components to maintain the pressure confinement boundary. NWP made the decision to install resident Quality Inspectors at the fabrication facilities to ensure the documentation for each fabricated unit meets all the QA requirements as defined in the respective contract documents. For the construction of the SSCVS Salt Reduction Building (SRB) and New Filter Building (NFB), dedicated, on-site quality inspectors have been utilized to ensure that all work being performed will comply with quality requirements and the Special Inspections as defined in IBC-2015. At each stage of inspection, hold points are placed into the work packages to ensure NWP QA personnel are present to inspect and verify the installations are in accordance with the design specifications, codes and standards. With this level of oversight, NWP anticipates that the level of quality related issues, as seen on multiple other DOE complex site projects, will be avoided and that the commissioning, start-up and hot operations will progress in a timely fashion, as all documentation will be in place and approved prior to initiation of these activities. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Historical Documentation of Buildings 0460 and 0463 at Technical Area 16 (Volume 1)

This report provides documentation as a standard mitigation measure to the adverse effects that occurred by the demolition of theses historic properties. To mitigate the adverse effects, LANL has followed Section 106 process contained in 36 CFR 800.6, resolution of adverse effects. In addition to these regulations and within this report, LANL has implemented the standards for documenting and reporting in accordance with the A Plan for the Management of the Cultural Heritage at Los Alamos National Laboratory, New Mexico (CRMP), LA-UR-19-21590, formerly LA-UR-15-27624. These standard reporting measures include archival-quality digital photographs of the building’s interior, exterior, outside landscape; updating LANL historic building survey forms including 11 in. x 17 in. copies (in a reduced scale) of key original and as-built drawings; identification and documentation of historically significant equipment and artifacts; a comprehensive list of LANL architectural drawings; construction-history maps of TA-16 including current Register Eligible and Ineligible Buildings; and a detailed use history of the building and technical division associated with its operation.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Conducting Industrial Hygiene Exposure Assessments at Scale Using Non-Parametric Upper Tolerance Limits at the Hanford Site - 20439

Chemical vapors are generated in the radioactive waste storage tanks at the Hanford Site due to ongoing chemical and radiological activity. Hanford's Tank Operations Contractor conducts exposure assessments for individual tank farms to identify, evaluate, and recommend controls or other worker protection measures for chemical, physical, and biological hazards present within each tank farm. These exposure assessments conform to the American Industrial Hygiene Association assessment strategy and recommended statistical procedures. The exposure assessment process involved manually processing tens of thousands of records that were collected over several years and entered into a central database. Working with Pacific Northwest National Laboratory, this process has been largely automated, providing a scalable analysis process that reduced processing time by over 90%, while providing defensible results and improved data quality. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Octopus processor for the CMS L1 muon trigger for High Luminosity LHC

The upgraded L1 muon trigger system of the CMS experiment in the High Luminosity Large Hadron Collider is based on custom processors featuring large Field Programmable Gate Arrays (FPGAs) connected by large numbers of optical links. These provide the I/O bandwidth and power necessary to process the complex algorithms used during the collection of physics data. The design and performance requirements of these processors creates significant challenges in signal integrity, power delivery, and thermal management. In this paper we describe the Octopus processor, featuring a large Xilinx Virtex Ultrascale+ FPGA and up to 128 links interfaced to optics through high quality twin-ax copper cables. Results on signal integrity at 25 Gb/s and the first demonstration of 50+ Gb/s links with pluggable optics in CMS are also shown, demonstrating bit error rates below 10 –15 at a 95% confidence level. The thermal performance is measured inside an Advanced-TCA crate with acceptable thermal margins up to 200 W of chip power. Future improvements are mentioned, potentially allowing operation at up to 300 W.

Instruments & Instrumentation↗

A novel construct for scaling groundwater–river interactions based on machine-guided hydromorphic classification

Hydrologic exchange between river channels and adjacent subsurface environments is a key process that influences water quality and ecosystem function in river corridors. Predictive numerical models are needed to understand responses of river corridors to environmental change and to support sustainable watershed management. We posit that systematic hydromorphic classification provides a scaling construct that facilitates extrapolation of outputs from local-scale mechanistic models to reduced-order models applicable at reach and watershed scales. This in turn offers the potential to improve large-scale predictions of river corridor hydrobiogeochemical processes. Here we present a new machine-guided hydromorphic classification methodology that addresses the key requirements of this objective, and we demonstrate its application to a segment of the Columbia River in the northwestern United States. The resulting hydromorphic classes form spatially coherent and physically interpretable hydromorphic units that exhibit distinct behaviors in terms of distributions of subsurface residence times (a primary control on critical biogeochemical reactions). This approach forms the basis of ongoing research that is evaluating the formulation of reduced-order models and transferability of results to other river reaches and larger scales.

54 ENVIRONMENTAL SCIENCES↗

National Energy Water Treatment & Speciation (NEWTS): A Water & Critical Minerals Database and Dashboard

The poster, presented at the American Geophysical Union (AGU) 2023 Conference, highlights NETL's National Energy Water Treatment & Speciation (NEWTS) Database & Dashboard. This poster reviews the work done to aggregate disparate water quality data for energy-related wastewater streams, to process and integrate the datasets, and enable easy integration with aqueous chemistry modeling software to support water management and beneficial reuse decision-making.

Wenzlick, Madison↗